CN101222847A - 杀真菌活性组合物 - Google Patents
杀真菌活性组合物 Download PDFInfo
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- CN101222847A CN101222847A CNA2006800261503A CN200680026150A CN101222847A CN 101222847 A CN101222847 A CN 101222847A CN A2006800261503 A CNA2006800261503 A CN A2006800261503A CN 200680026150 A CN200680026150 A CN 200680026150A CN 101222847 A CN101222847 A CN 101222847A
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- Prior art keywords
- fungicide
- formula
- composition
- compound
- methyl
- Prior art date
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- 239000013543 active substance Substances 0.000 title claims abstract description 31
- 239000000417 fungicide Substances 0.000 claims abstract description 89
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 78
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims description 82
- 150000001875 compounds Chemical class 0.000 claims description 70
- -1 fluorine ether azoles Chemical class 0.000 claims description 54
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 29
- 150000001412 amines Chemical class 0.000 claims description 18
- 241000894006 Bacteria Species 0.000 claims description 17
- UDSJPFPDKCMYBD-UHFFFAOYSA-N Metsulfovax Chemical compound S1C(C)=NC(C)=C1C(=O)NC1=CC=CC=C1 UDSJPFPDKCMYBD-UHFFFAOYSA-N 0.000 claims description 17
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 15
- 229940084434 fungoid Drugs 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- 239000004094 surface-active agent Substances 0.000 claims description 12
- 150000003851 azoles Chemical class 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 10
- 241000233866 Fungi Species 0.000 claims description 9
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 claims description 9
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 claims description 8
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- PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 claims description 7
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 7
- LMVPQMGRYSRMIW-KRWDZBQOSA-N fenamidone Chemical compound O=C([C@@](C)(N=C1SC)C=2C=CC=CC=2)N1NC1=CC=CC=C1 LMVPQMGRYSRMIW-KRWDZBQOSA-N 0.000 claims description 7
- UYJUZNLFJAWNEZ-UHFFFAOYSA-N fuberidazole Chemical compound C1=COC(C=2NC3=CC=CC=C3N=2)=C1 UYJUZNLFJAWNEZ-UHFFFAOYSA-N 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
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- SOUGWDPPRBKJEX-UHFFFAOYSA-N 3,5-dichloro-N-(1-chloro-3-methyl-2-oxopentan-3-yl)-4-methylbenzamide Chemical compound ClCC(=O)C(C)(CC)NC(=O)C1=CC(Cl)=C(C)C(Cl)=C1 SOUGWDPPRBKJEX-UHFFFAOYSA-N 0.000 claims description 6
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- 239000005863 Zoxamide Substances 0.000 claims description 6
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 claims description 6
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- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 6
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- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 claims description 6
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- NNPRCLUGHFXSOU-UHFFFAOYSA-N 4-chloro-n-[cyano(ethoxy)methyl]benzamide Chemical compound CCOC(C#N)NC(=O)C1=CC=C(Cl)C=C1 NNPRCLUGHFXSOU-UHFFFAOYSA-N 0.000 claims description 5
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- MXMXHPPIGKYTAR-UHFFFAOYSA-N silthiofam Chemical compound CC=1SC([Si](C)(C)C)=C(C(=O)NCC=C)C=1C MXMXHPPIGKYTAR-UHFFFAOYSA-N 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- ZEVCJZRMCOYJSP-UHFFFAOYSA-N sodium;2-(dithiocarboxyamino)ethylcarbamodithioic acid Chemical compound [Na+].SC(=S)NCCNC(S)=S ZEVCJZRMCOYJSP-UHFFFAOYSA-N 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- PUYXTUJWRLOUCW-UHFFFAOYSA-N spiroxamine Chemical compound O1C(CN(CC)CCC)COC11CCC(C(C)(C)C)CC1 PUYXTUJWRLOUCW-UHFFFAOYSA-N 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
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- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003447 sulfenic acid derivatives Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 235000012756 tartrazine Nutrition 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- CBDKQYKMCICBOF-UHFFFAOYSA-N thiazoline Chemical compound C1CN=CS1 CBDKQYKMCICBOF-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical compound COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- FJBGIXKIXPUXBY-UHFFFAOYSA-N {2-[3-(4-chlorophenyl)propyl]-2,4,4-trimethyl-1,3-oxazolidin-3-yl}(imidazol-1-yl)methanone Chemical compound C1=CN=CN1C(=O)N1C(C)(C)COC1(C)CCCC1=CC=C(Cl)C=C1 FJBGIXKIXPUXBY-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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Abstract
本发明涉及除了杀真菌剂N-[2-(1,3-二甲基丁基)-3-噻吩基]-1-甲基-3-(三氟甲基)-1H-吡唑-4-甲酰胺(吡噻菌胺)以外含有至少一种其他所定义的杀真菌剂的杀真菌活性组合物。本发明还涉及一种使用该组合物防治病原性真菌的方法以及所述组合物在防治病原性真菌中的用途。
Description
本发明涉及杀真菌活性组合物,该组合物除了杀真菌剂N-[2-(1,3-二甲基丁基)-3-噻吩基]-1-甲基-3-(三氟甲基)-1H-吡唑-4-甲酰胺(吡噻菌胺(penthiopyrad))外还包含至少一种特定的其他杀真菌剂,还涉及使用该组合物防治有害真菌的方法以及该组合物在防治有害真菌中的用途。
也以通用名吡噻菌胺已知的N-[2-(1,3-二甲基丁基)-3-噻吩基]-1-甲基-3-(三氟甲基)-1H-吡唑-4-甲酰胺例如在EP-A-0737682中被描述为高度有效的杀真菌剂。在本发明组合物中使用的其他活性化合物也是已知的杀真菌剂。
根据经验,当单独使用杀真菌剂时,它们的效果通常仅仅是暂时的,即在一定时间之后可以观察到有害真菌的重新生长。此外,某些有害真菌对单独的活性化合物产生抗药性。
在作物保护组合物的情况下,原则上希望增加活性化合物的特异性活性以及效果的可靠性。特别希望活性化合物,例如杀真菌剂能够有效防治损害因素,例如有害真菌,但同时与所关心的有用植物相容。就此而言,因此希望活性化合物可以尽可能低的施用率使用,尽可能高地实现与有用植物的相容性以及使作物保护剂残留物,例如杀真菌剂残留物在植物产品中的保留尽可能低。同时,作物保护组合物的有效性当然应尽可能高。
因此,本发明的目的是改善吡噻菌胺在防治有害真菌中的活性和/或增加常规杀真菌剂的活性。
惊人的是已经发现该目的通过组合使用吡噻菌胺与特定杀真菌剂而实现。
因此,本发明提供了一种杀真菌活性组合物,包含:
A)式A的N-[2-(1,3-二甲基丁基)-3-噻吩基]-1-甲基-3-(三氟甲基)-1H-吡唑-4-甲酰胺:
和
B)至少一种选自如下的其他杀真菌剂B:
B.1)选自如下的唑类杀真菌剂:丙硫菌唑(prothioconazole)、戊叉唑菌(triticonazole)、氟醚唑(tetraconazole)、粉唑醇(flutriafol)、烯菌灵(imazalil)、硅氟唑(simeconazole)、咪唑(oxpoconazole)、***酮(triadimefon)、氰霜唑(cyazofamid)、麦穗宁(fuberidazole)和噻唑菌胺(ethaboxam);
B.2)羧酰胺类杀真菌剂;
B.3)不同于B.1)组唑类杀真菌剂的杂环化合物;
B.4)选自如下的氨基甲酸盐类和二硫代氨基甲酸盐类杀真菌剂:代森联(metiram)、百维灵(propamocarb)、百维灵单盐酸盐、异丙菌胺(iprovalicarb)、苯噻菌胺(benthiavalicarb)、式B.4.1的氨基甲酸酯:
和式B.4.2的N-(1-(1-(4-氰基苯基)乙烷磺酰基)丁-2-基)氨基甲酸4-氟苯基酯:
和
B.5)选自如下的其他杀真菌剂:
B.5.1)含硫的杂环基化合物;
B.5.2)有机磷化合物;
B.5.3)有机氯化合物;
B.5.4)选自螺茂胺(spiroxamine)、环氟菌胺(cyflufenamid)和苯菌酮(metrafenone)的其他杀真菌剂。
本发明组合物可以为化合物A与至少一种杀真菌剂B的混合物。因此,本发明还提供了包含化合物A和至少一种杀真菌剂B的混合物。然而,该组合物还可以为化合物A与至少一种杀真菌剂B的任何组合,其中不要求A和B一起存在于相同配制剂中。
其中化合物A和至少一种杀真菌剂B不一起存在于相同配制剂中的本发明组合物的实例是双组分包装。因此,本发明还涉及双组分包装,其包含含有杀真菌剂A)、液体或固体载体和合适的话至少一种表面活性剂和/或至少一种常规助剂的第一组分以及含有至少一种杀真菌剂B)、液体或固体载体和合适的话至少一种表面活性剂和/或至少一种常规助剂的第二组分。合适的液体和固体载体、表面活性剂和常规助剂如下所述。
此外,本发明还涉及一种防治有害真菌的方法,包括使化合物A与至少一种B)组杀真菌剂的组合或包含化合物A和至少一种杀真菌剂B的本发明组合物作用于真菌、其栖息地或要防止真菌侵袭的材料、植物、种子、土壤、区域或空间。这里可以同时,即联合或分开,或依次使用活性化合物A和B。
此外,本发明还涉及化合物A与至少一种B)组杀真菌剂组合或包含化合物A和至少一种杀真菌剂B的本发明组合物在防治有害真菌中的用途。
下面对化合物A、杀真菌剂B和包含它们的组合物及其应用的合适和优选实施方案所给的说明单独和优选相互结合适用。
根据本发明合适的是式A的吡噻菌胺的外消旋体及其对映体以及这些对映体的非外消旋混合物。
唑类杀真菌剂B.1)为包含至少一个芳族氮杂环,例如至少一个吡咯、吡唑、咪唑、***、唑、噻唑、苯并咪唑、吡啶或嘧啶环的化合物。
羧酰胺类杀真菌剂B.2)优选选自苯酰菌胺(zoxamide)、氟吡菌胺(fluopicolide)、溴氟唑菌(thifluzamide)、萎锈灵(carboxin)、啶酰菌胺(boscalid)、环酰菌胺(fenhexamid)、噻酰菌胺(tiadinil)、氟吗啉(flumorph)、双炔酰菌胺(mandipropamid)、氰菌胺(fenoxanil)、硅噻菌胺(silthiofam)、式B.2.1的N-(2-(4-[3-(4-氯苯基)丙-2-炔氧基]-3-甲氧基苯基)乙基)-2-甲磺酰氨基-3-甲基丁酰胺(R=甲基)、式B.2.1的N-(2-(4-[3-(4-氯苯基)丙-2-炔氧基]-3-甲氧基苯基)乙基)-2-乙磺酰氨基-3-甲基丁酰胺(R=乙基):
(R=甲基、乙基)
和式B.2.2的N-(2-氰基苯基)-3,4-二氯异噻唑-5-甲酰胺:
杂环化合物B.3)为不属于唑类杀真菌剂B.1)的化合物。这些包括例如含有至少一个饱和或部分不饱和非芳族氮杂环的化合物,所述氮杂环例如为至少一个吡咯啉、吡咯烷、吡咯烷酮、吡唑啉、吡唑啉酮、吡唑烷、吡唑烷酮、吡唑烷二酮、咪唑啉、咪唑烷、咪唑烷酮、唑啉、唑烷、唑烷酮、噻唑啉、噻唑烷、哌啶或吗啉环等。还包括例如含有至少一个不含氮的芳族或非芳族单环或多环杂环,例如至少一个呋喃、二氢呋喃或四氢呋喃、噻吩、苯并吡喃或苯并吡喃酮环等的化合物。
杂环化合物B.3)优选选自唑酮菌(famoxadone)、咪唑菌酮(fenamidone)、丙氧喹啉(proquinazid)、噻二唑素(acibenzolar-S-methyl)、式B.3.1的2-丁氧基-6-碘-3-丙基苯并吡喃-4-酮:
式B.3.2的N,N-二甲基-3-(3-溴-6-氟-2-甲基吲哚-1-磺酰基)[1,2,4]***-1-磺酰胺:
和式B.3.3的3-[5-(4-氯苯基)-2,3-二甲基异唑烷-3-基]吡啶:
特别优选的(二硫代)氨基甲酸盐类杀真菌剂是代森联。
含硫杂环化合物B.5.1)优选为二噻农(dithianon)。
有机磷化合物B.5.2)优选为甲基立枯磷(tolclofos-methyl)。
有机氯化合物B.5.3)优选选自磺菌胺(flusulfamide)和对甲抑菌灵(tolylfluanid)。
若组分B)的杀真菌剂形成几何异构体,例如E/Z异构体,则可以在本发明组合物中使用纯异构体及其混合物。若这些化合物具有一个或多个手性中心且因此可以对映体或非对映体存在,则还可以在本发明组合物中使用纯对映体和非对映体及其混合物。
若组分A)和B)的杀真菌剂具有可离子化官能基团,则它们还可以其可农用盐形式使用。因此,当它们具有碱性官能基团时,例如它们可以其酸加成盐形式使用。通常而言,其阴离子对活性化合物的作用没有不利影响的那些酸的酸加成盐是合适的。
有用酸加成盐的阴离子主要是氯离子、溴离子、氟离子、碘离子、硫酸氢根、甲基硫酸根、硫酸根、磷酸二氢根、磷酸氢根、硝酸根、碳酸氢根、碳酸根、六氟硅酸根、六氟磷酸根、苯甲酸根,以及C1-C4链烷酸的阴离子,优选甲酸根、乙酸根、丙酸根和丁酸根。
例如下列活性化合物可以酸加成盐形式使用:式A的吡噻菌胺、咪唑菌酮、戊叉唑菌、氟醚唑、粉唑醇、烯菌灵、硅氟唑(semiconazole)、***酮、麦穗宁、噻唑菌胺、噻二唑素、螺茂胺、百维灵以及式B.3.3化合物。
制备式A的吡噻菌胺(组分A)的方法是已知的且例如描述于EP-A-737682或EP-A-1036793中,它们整体引入本文作为参考。
组分B的活性化合物同样是已知的杀真菌剂,其制备方法由现有技术已知。
因此,苯噻菌胺及其制备方法例如描述于Agrow 417(2003)中,该文献的公开内容整体引入本文作为参考。
硅氟唑及其制备方法例如描述于Agrow 324,26(1999)中,该文献的公开内容整体引入本文作为参考。
戊叉唑菌及其制备方法例如描述于Agrow 166,24(1992)中,该文献的公开内容整体引入本文作为参考。
环氟菌胺及其制备方法例如描述于Agrow 408,6(2002)中,该文献的公开内容整体引入本文作为参考。
苯菌酮和啶酰菌胺及其制备方法例如描述于Agrow 384,22(2001)中,该文献的公开内容整体引入本文作为参考。
氟吗啉及其制备方法例如描述于Agrow 452,22(2004)中,该文献的公开内容整体引入本文作为参考。
氟吡菌胺及其制备方法例如描述于WO 99/42447中,该文献的公开内容整体引入本文作为参考。
下列杀真菌剂及其制备方法描述于Crop Protection Handbook,第89卷,Meister Publishing,USA 2003中,该文献的公开内容整体引入本文作为参考:唑酮菌(第C 217页),咪唑菌酮(第C 219页),代森联(第C 321页),丙硫菌唑(第C 394页),氟醚唑(第C 449页),粉唑醇(第C 241页),烯菌灵(第C 269页),***酮(第C 464页),异丙菌胺(第C 277页),丙氧喹啉(第C 394页),麦穗宁(第C 247页),溴氟唑菌(第C 453页),萎锈灵(第C 104页),二噻农(第C 193页),环酰菌胺(第C 221页),苯酰菌胺(第C 490页),噻唑菌胺(第C 209页),噻二唑素(第C 35页),螺茂胺(第C 429页),对甲抑菌灵(第C 461页),硅噻菌胺(第C 421页),氰菌胺(第C 222页),百维灵和百维灵单盐酸盐(第C 387页)和甲基立枯磷(第C 460页)。
氰霜唑及其制备方法例如描述于Pest Manag.Sci.58,139(2001)中,该文献整体引入本文作为参考。
式B.4.1的羧酰胺及其制备方法例如描述于EP-A-1028125和WO02/006304中,它们整体引入本文作为参考。
其中R为甲基或乙基的式B.2.1化合物及其制备方法例如描述于WO2004/049804中,该文献整体引入本文作为参考。
式B.3.2化合物及其制备方法例如描述于US 6,620,812和WO03/053145中,它们整体引入本文作为参考。
式B.3.1化合物及其制备方法例如描述于WO 03/14103中,该文献整体引入本文作为参考。
式B.3.3化合物及其制备方法例如描述于EP-A-1035122中,该文献整体引入本文作为参考。
式B.2.2化合物及其制备方法例如描述于WO 2005/009130和WO2005/009131中,它们整体引入本文作为参考。
式B.4.2化合物及其制备方法例如描述于WO 2005/009130和WO2004/052102中,它们整体引入本文作为参考。
双炔酰菌胺及其制备方法例如描述于WO 01/87822和WO 03/041728中,它们整体引入本文作为参考。
在本发明组合物中,杀真菌活性组分A和B有利地以协同增效有效量使用,即以发生协同增效作用的重量比使用。“协同增效作用”是指对至少一种有害真菌的杀真菌作用以超加和方式增加;即杀真菌效力的增加比基于单个活性化合物的杀真菌效力预期的要明显更为显著。活性化合物组合的预期效力例如可以使用Colby公式确定(S.R.Colby,计算除草剂组合的协同增效和拮抗响应,Weeds,15,第20-22页)。
优选组分A与组分B的重量比为200∶1-1∶200,更优选100∶1-1∶100,例如2∶1-1∶100,特别优选75∶1-1∶75,例如2∶1-1∶75,尤其是10∶1-1∶10,例如2∶1-1∶10。
在本发明的特殊实施方案中,杀真菌剂B选自B.2)、B.3)、B.4)和B.5)组杀真菌剂及其混合物。
在本发明的另一特殊实施方案中,该混合物包含至少一种B.1)组(唑类)杀真菌剂和合适的话至少一种选自B.2)、B.3)、B.4)、B.5)组杀真菌剂及其混合物的其他杀真菌剂作为杀真菌剂B。
在本发明的优选实施方案中,该混合物包含至少一种B.4)组((二硫代)氨基甲酸盐)杀真菌剂和合适的话至少一种选自B.1)、B.2)、B.3)、B.5)组杀真菌剂及其混合物的其他杀真菌剂作为杀真菌剂B。
本发明组合物可以是二元和三元组合物或更高级组合物。在本发明范围内,二元组合物应理解为指作为杀真菌活性化合物除了式A化合物外还仅包含一种其他B组杀真菌剂的那些。相应地,三元组合物是作为杀真菌剂除了组分A外还包含两种不同的B组杀真菌剂的那些。因此,更高级组合物包含三种或更多种B组杀真菌剂。
优选的二元组合物实例列于表1中。
表1:包含式A化合物和B组杀真菌剂的二元组合物
组合物 | B组杀真菌剂 | 重量比化合物A∶化合物B |
1. | 丙硫菌唑 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
2. | 戊叉唑菌 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
3. | 氟醚唑 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
4. | 粉唑醇 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
5. | 烯菌灵 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
6. | 硅氟唑 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
7. | 咪唑 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
8. | ***酮 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
组合物 | B组杀真菌剂 | 重量比化合物A∶化合物B |
9. | 氰霜唑 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
10. | 麦穗宁 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
11. | 噻唑菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
12. | 苯酰菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
13. | 氟吡菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
14. | 溴氟唑菌 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
15. | 萎锈灵 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
16. | 啶酰菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
17. | 环酰菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
18. | 噻酰菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
19. | 氟吗啉 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
20. | 双炔酰菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
21. | 氰菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
22. | 硅噻菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
23. | 式B.2.1化合物(R=甲基) | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
24. | 式B.2.1化合物(R=乙基) | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
25. | 式B.2.2化合物 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
26. | 唑酮菌 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
27. | 咪唑菌酮 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
28. | 丙氧喹啉 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
29. | 噻二唑素 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
30. | 2-丁氧基-6-碘-3-丙基苯并吡喃-4-酮 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
31. | 式B.3.2化合物 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
32. | 式B.3.3化合物 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
33. | 代森联 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
34. | 百维灵单盐酸盐 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
35. | 异丙菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
36. | 苯噻菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
37. | 式B.4.1化合物 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
38. | 式B.4.2化合物 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
39. | 二噻农 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
40. | 甲基立枯磷 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
41. | 磺菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
组合物 | B组杀真菌剂 | 重量比化合物A∶化合物B |
42. | 对甲抑菌灵 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
43. | 螺茂胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
44. | 环氟菌胺 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
45. | 苯菌酮 | 100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10 |
在三元组合物中,化合物A和两种B组杀真菌剂也以使得发生上述定义内的协同增效作用的比例使用。优选在三元组合物中,化合物A的重量与两种B组杀真菌剂的总重量之比为100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10。这里两种B组杀真菌剂的重量比优选为100∶1-1∶100,特别优选50∶1-1∶50,尤其是10∶1-1∶10。
除了化合物A外,优选的三元组合物包含两种选自如下的其他杀真菌剂B:丙硫菌唑、戊叉唑菌、氟醚唑、粉唑醇、烯菌灵、硅氟唑、咪唑、***酮、氰霜唑、麦穗宁、噻唑菌胺、苯酰菌胺、氟吡菌胺、溴氟唑菌、萎锈灵、啶酰菌胺、环酰菌胺、噻酰菌胺、氟吗啉、双炔酰菌胺、氰菌胺、硅噻菌胺、式B.2.1化合物(R=甲基)、式B.2.1化合物(R=乙基)、式B.2.2化合物、唑酮菌、咪唑菌酮、丙氧喹啉、噻二唑素、2-丁氧基-6-碘-3-丙基苯并吡喃-4-酮、式B.3.2化合物、式B.3.3化合物、代森联、百维灵单盐酸盐、异丙菌胺、苯噻菌胺、式B.4.1化合物、式B.4.2化合物、二噻农、甲基立枯磷、磺菌胺、对甲抑菌灵、螺茂胺、环氟菌胺和苯菌酮。
特别优选的组合物除了包含化合物A外还包含代森联和合适的话其他杀真菌剂B。
在即用制剂中,例如在作物保护组合物形式的本发明组合物中,组分A和B可以悬浮、乳化或溶解形式联合或分开配制。施用形式完全取决于意欲的用途。
本发明组合物的杀真菌剂A和B可以直接、以其配制剂形式或由其制备的施用形式(如可直接喷雾溶液,粉末,包括高度浓缩的含水、油状或其他悬浮液或分散体在内的悬浮液或分散体,乳液,油分散体,糊,粉剂、撒播用组合物或颗粒)施用。施用通常通过喷雾、雾化、撒粉、撒播或浇灌来进行。施用形式和方法取决于意欲的用途;它们在每种情况下应确保活性化合物的最佳可能分布。
取决于本发明组合物的即用制剂存在的实施方案,它们包含一种或多种液体或固体载体,合适的话表面活性剂和合适的话其他常用于配制作物保护试剂的助剂。该类配制剂的配方对本领域熟练技术人员而言是熟知的。
含水施用形式例如可以通过加入水由乳液浓缩物、悬浮液、糊、可湿性粉末或水分散性颗粒制备。为制备乳液、糊或油分散体,可借助湿润剂、增粘剂、分散剂或乳化剂将活性化合物A和B直接或溶于油或溶剂中后在水中均化。然而,还可以制备由活性物质、湿润剂、增粘剂、分散剂或乳化剂以及合适的话溶剂或油组成的浓缩物且该浓缩物适于用水稀释。
杀真菌剂A和B在即用制剂中的浓度可在较宽范围内变化。它们通常为0.0001-10%,优选0.01-1%(活性化合物基于即用制剂的总重量的总含量,以重量%表示)。
杀真菌剂A和B还可成功用于超低容量法(ULV),其中可以使用包含超过95重量%活性化合物的配制剂,或甚至施用不含添加剂的活性化合物。
可以向活性化合物中加入各种类型的油、润湿剂、辅助剂、除草剂、不同于活性化合物A和B的杀真菌剂、杀虫剂、杀线虫剂、其他农药如杀菌剂、肥料和/或生长调节剂,合适的话甚至仅在紧临使用前加入(桶混合)。这些试剂通常与本发明使用的活性化合物A和B以1∶100-100∶1,优选1∶10-10∶1的重量比混合。
就此而言合适的辅助剂尤其是有机改性的聚硅氧烷,例如Break ThruS 240l;醇烷氧基化物,例如Atplus 245、Atplus MBA 1303、PlurafacLF 300和Lutensol ON 30;EP/PO嵌段聚合物,例如Pluronic RPE 2035和Genapol B;醇乙氧基化物,例如Lutensol XP 80;以及磺基琥珀酸二辛基酯钠,例如Leophen RA。
在许多情况下,根据本发明使用的杀真菌剂A和B与其他杀真菌剂的联合施用导致杀真菌活性谱的拓宽。
根据本发明使用的活性化合物A和B可以与其联合使用的下列杀真菌剂用来说明可能的组合,但不限制它们:
·酰基丙氨酸类,例如苯霜灵(benalaxyl)、甲霜灵(metalaxyl)、甲呋酰胺(ofurace)、霜灵(oxadixyl),
·胺衍生物,例如4-十二烷基-2,6-二甲基吗啉(aldimorph)、多果定(dodine)、吗菌灵(dodemorph)、丁苯吗啉(fenpropimorph)、苯锈啶(fenpropidin)、双胍盐(guazatine)、双胍辛醋酸盐(iminoctadine)、克啉菌(tridemorph),
·苯胺基嘧啶类,例如二甲嘧菌胺(pyrimethanil)、嘧菌胺(mepanipyrim)或环丙嘧啶(cyprodinil),
·抗菌素,例如放线菌酮(cycloheximide)、灰黄霉素(griseofulvin)、春雷素(kasugamycin)、多马霉素(natamycin)、多氧霉素(polyoxin)或链霉素(streptomycin),
·不同于B.1)组的唑类,例如双苯***醇(bitertanol)、糠菌唑(bromoconazole)、环唑醇(cyproconazole)、醚唑(difenoconazole)、烯唑醇(dinitroconazole)、氧唑菌(epoxiconazole)、腈苯唑(fenbuconazole)、喹唑菌酮(fluquinconazole)、氟硅唑(flusilazole)、粉唑醇、己唑醇(hexaconazole)、环戊唑菌(metconazole)、腈菌唑(myclobutanil)、戊菌唑(penconazole)、丙环唑(propiconazole)、丙氯灵(prochloraz)、戊唑醇(tebuconazole)、氟菌唑(triflumizole),
·二羧酰亚胺类,如异丙定(iprodione)、甲菌利(myclozolin)、杀菌利(procymidone)、烯菌酮(vinclozolin),
·二硫代氨基甲酸盐类,如福美铁(ferbam)、代森钠(nabam)、代森锰(maneb)、代森锰锌(mancozeb)、威百亩(metam)、甲基代森锌(propineb)、福代锌(polycarbamate)、福美双(thiram)、福美锌(ziram)、代森锌(zineb),
·杂环化合物,如敌菌灵(anilazine)、苯菌灵(benomyl)、多菌灵(carbendazim)、棉隆(dazomet)、异嘧菌醇(fenarimol)、氟酰胺(flutolanil)、呋吡唑灵(furametpyr)、稻瘟灵(isoprothiolane)、丙氧灭绣胺(mepronil)、氟苯嘧啶醇(nuarimol)、噻菌灵(probenazole)、啶斑肟(pyrifenox)、咯喹酮(pyroquilon)、喹氧灵(quinoxyfen)、甲基托布津(thiophanate-methyl)、三环唑(tricyclazole)、嗪氨灵(triforine),
·铜杀真菌剂,如波尔多液(Bordeaux混合物)、醋酸铜、王铜(copperoxychloride)、碱式硫酸铜,
·硝基苯基衍生物,如乐杀螨(binapacryl)、敌螨普(dinocap)、敌螨通(dinobuton)、异丙消(nitrophthal-isopropyl),
·苯基吡咯类,如拌种咯(fenpiclonil)或氟菌(fludioxonil),
·硫,
·其它杀真菌剂,如氯环丙酰胺(carpropamid)、百菌清(chlorothalonil)、清菌脲(cymoxanil)、哒菌清(diclomezine)、双氯氰菌胺(diclocymet)、乙霉威(diethofencarb)、克瘟散(edifenphos)、薯瘟锡(fentin-acetate)、嘧菌腙(ferimzone)、氟啶胺(fluazinam)、藻菌磷(fosetyl)、乙膦铝(fosetyl-aluminum)、六氯苯(hexachlorobenzene)、戊菌隆(pencycuron)、四氯苯酞(phthalide)、五氯硝基苯(quintozene),
·嗜球果伞素类(strobilurins),如腈嘧菌酯(azoxystrobin)、醚菌胺(dimoxystrobin)、烯肟菌酯(enestroburin)、氟嘧菌酯(fluoxastrobin)、亚胺菌(kresoxim-methyl)、叉氨苯酰胺(metominostrobin)、肟醚菌胺(orysastrobin)、啶氧菌酯(picoxystrobin)、唑菌胺酯(pyraclostrobin)或肟菌酯(trifloxystrobin),
·次磺酸衍生物,如敌菌丹(captafol)、克菌丹(captan)、抑菌灵(dichlofluanid)、灭菌丹(folpet),
·肉桂酰胺及类似化合物,如烯酰吗啉(dimethomorph)、氟联苯菌(flumetover)。
在本发明的特殊实施方案中,本发明组合物仅包含化合物A和至少一种杀真菌剂B作为杀真菌活性组分。
配制剂以已知方式制备,例如通过将活性化合物与溶剂和/或载体混合而制备,需要的话使用表面活性剂,即乳化剂和分散剂。对该目的合适的溶剂/载体主要为:
-水、芳族溶剂(如Solvesso产品、二甲苯)、石蜡(如矿物油馏分)、醇类(如甲醇、丁醇、戊醇、苄醇)、酮类(如环己酮、甲基羟基丁基酮、双丙酮醇、异亚丙基丙酮、异佛尔酮)、内酯(例如γ-丁内酯)、吡咯烷酮(吡咯烷酮、N-甲基吡咯烷酮、N-乙基吡咯烷酮、N-辛基吡咯烷酮)、乙酸酯(乙二醇二乙酸酯)、二元醇、脂肪酸二甲基酰胺、脂肪酸及脂肪酸酯。原则上还可以使用溶剂混合物。
-载体如磨碎的天然矿物(如高岭土、粘土、滑石、白垩)和磨碎的合成矿物(如细碎的硅石、硅酸盐);乳化剂如非离子和阴离子乳化剂(如聚氧乙烯脂肪醇醚、烷基磺酸盐和芳基磺酸盐)以及分散剂如木素亚硫酸盐废液和甲基纤维素。
合适的表面活性剂是木素磺酸、萘磺酸、苯酚磺酸、二丁基萘磺酸的碱金属盐、碱土金属盐和铵盐,烷基芳基磺酸盐,烷基硫酸盐,烷基磺酸盐,脂肪醇硫酸盐,脂肪酸和硫酸化脂肪醇乙二醇醚,还有磺化萘和萘衍生物与甲醛的缩合物,萘或萘磺酸与苯酚和甲醛的缩合物,聚氧乙烯辛基酚醚,乙氧基化异辛基酚、辛基酚、壬基酚,烷基苯基聚乙二醇醚,三丁基苯基聚乙二醇醚,三硬脂基苯基聚乙二醇醚,烷基芳基聚醚醇,醇和脂肪醇/氧化乙烯缩合物,乙氧基化蓖麻油,聚氧乙烯烷基醚,乙氧基化聚氧丙烯,月桂醇聚乙二醇醚缩醛,山梨醇酯,木素亚硫酸盐废液和甲基纤维素。
适于制备可直接喷雾溶液、乳液、糊或油分散体的物质是中沸点到高沸点的矿物油馏分,如煤油或柴油,此外还有煤焦油和植物或动物来源的油,脂族、环状和芳族烃,例如甲苯、二甲苯、石蜡、四氢化萘、烷基化萘或其衍生物、甲醇、乙醇、丙醇、丁醇、环己醇、环己酮、异亚丙基丙酮、异佛尔酮,强极性溶剂,例如二甲亚砜、2-吡咯烷酮、N-甲基吡咯烷酮、丁内酯或水。
粉末、撒播组合物和粉剂可以通过将活性物质与固体载体混合或一起研磨而制备。
颗粒如涂覆颗粒、浸渍颗粒和均质颗粒可以通过将活性化合物与固体载体粘附而制备。固体载体例如为矿土如硅胶、硅酸盐、滑石、高岭土、活性粘土(attaclay)、石灰石、石灰、白垩、红玄武土、黄土、粘土、白云石、硅藻土、硫酸钙、硫酸镁、氧化镁;磨碎的合成材料;肥料如硫酸铵、磷酸铵、硝酸铵、脲类;植物产品如谷粉、树皮粉、木粉和坚果壳粉,纤维素粉和其它固体载体。
用于处理种子的配制剂可以额外包含粘合剂和/或胶凝剂以及合适的话着色剂。
配制剂通常包含0.01-95重量%,优选0.1-90重量%,尤其是5-50重量%活性物质。活性物质以90-100%,优选95-100%(根据NMR光谱)的纯度使用。
对于种子处理,相关配制剂在稀释2-10倍后在即用制剂中得到0.01-60重量%,优选0.1-40重量%的活性物质浓度。
下列为配制剂实例:
1.用水稀释的产品
I)水溶性浓缩物(SL、LS)
将10重量份活性物质溶于90重量份水或水溶性溶剂中。或者,加入湿润剂或其它助剂。活性物质经水稀释溶解。得到活性物质含量为10重量%的配制剂。
II)分散性浓缩物(DC)
将20重量份活性物质溶于70重量份环己酮中并加入10重量份分散剂如聚乙烯基吡咯烷酮。活性物质含量为20重量%。用水稀释得到分散体。
III)可乳化的浓缩物(EC)
将15重量份活性物质溶于75重量份二甲苯中并加入十二烷基苯磺酸钙和蓖麻油乙氧基化物(在每种情况下为5重量份)。该配制剂的活性物质含量为15重量%。用水稀释得到乳液。
IV)乳液(EW、EO、ES)
将25重量份活性物质溶于35重量份二甲苯中并加入十二烷基苯磺酸钙和蓖麻油乙氧基化物(在每种情况下为5重量份)。借助乳化机(Ultraturrax)将该混合物引入30重量份水中并制成均相乳液。该配制剂的活性物质含量为25重量%。
V)悬浮液(SC、OD、FS)
在搅拌的球磨机中,将20重量份活性物质粉碎并加入10重量份分散剂和湿润剂以及70重量份水或有机溶剂,得到细碎活性物质悬浮液。该配制剂中的活性物质含量为20重量%。用水稀释得到稳定的活性物质悬浮液。
VI)水分散性颗粒和水溶性颗粒(WG、SG)
将50重量份活性物质细碎研磨并加入50重量份分散剂和湿润剂,借助工业装置(如挤出机、喷雾塔、流化床)将其制成水分散性或水溶性颗粒。该配制剂的活性物质含量为50重量%。用水稀释得到稳定的活性物质分散体或溶液。
VII)水分散性粉末和水溶性粉末(WP、SP、SS、WS)
将75重量份活性物质在转子-定子磨机中研磨并加入25重量份分散剂、湿润剂和硅胶。该配制剂的活性物质含量为75重量%。用水稀释得到稳定的活性物质分散体或溶液。
VIII)凝胶配制剂(GF)
在球磨机中将20重量份活性物质、10重量份分散剂、1重量份胶凝剂和70重量份水或有机溶剂混合,得到细碎悬浮液。
2.不经稀释而施用的产品
IX)粉剂(DP、DS)
将5重量份活性物质细碎研磨并与95重量份细碎高岭土充分混合。这得到活性物质含量为5重量%的可撒粉粉末。
X)颗粒(GR、FG、GG、MG)
将0.5重量份活性物质细碎研磨并结合95.5重量份载体。现行方法是挤出、喷雾干燥或流化床方法。这得到活性物质含量为0.5重量%的不经稀释而施用的颗粒。
XI)ULV溶液(UL)
将10重量份活性物质溶于90重量份有机溶剂如二甲苯中。这得到活性物质含量为10重量%的不经稀释而施用的产品。
对种子处理合适的配制剂例如为:
I 水溶性浓缩物(LS)
III 可乳化的浓缩物(EC)
IV 乳液(ES)
V 悬浮液(FS)
VI 水分散性颗粒和水溶性颗粒(SG)
VII 水分散性粉末和水溶性粉末(WS、SS)
VIII 凝胶配制剂(GF)
IX 粉剂和粉尘状粉末(DS)
对于种子处理,优选使用FS配制剂。该类配制剂通常包含1-800g/l活性物质,1-200g/l表面活性剂,0-200g/l防冻剂,0-400g/l粘合剂,0-200g/l着色剂和溶剂,优选水。
用于种子处理的活性化合物A和B的优选FS配制剂通常包含0.5-80%活性化合物,0.05-5%润湿剂,0.5-15%分散剂,0.1-5%增稠剂,5-20%防冻剂,0.1-2%消泡剂,1-20%颜料和/或染料,0-15%增粘剂或粘合剂,0-75%填料/赋形剂和0.01-1%防腐剂。
对种子处理用活性化合物A和B的配制剂合适的颜料或染料是颜料蓝15:4,颜料蓝15:3,颜料蓝15:2,颜料蓝15:1,颜料蓝80,颜料黄1,颜料黄13,颜料红112,颜料红48:2,颜料红48:1,颜料红57:1,颜料红53:1,颜料橙43,颜料橙34,颜料橙5,颜料绿36,颜料绿7,颜料白6,颜料棕25,碱性紫10,碱性紫49,酸性红51,酸性红52,酸性红14,酸性蓝9,酸性黄23,碱性红10,碱性红108。
合适的润湿剂和分散剂尤其为上述表面活性剂。优选的润湿剂是烷基萘磺酸盐,如二异丙基-或二异丁基萘磺酸盐。优选的分散剂是非离子或阴离子分散剂或非离子或阴离子分散剂的混合物。合适的非离子分散剂尤其是氧化乙烯/氧化丙烯嵌段共聚物,烷基酚聚乙二醇醚和三苯乙烯基苯酚聚乙二醇醚,例如聚氧乙烯辛基酚醚,乙氧基化异辛基酚、辛基酚、壬基酚,烷基酚聚乙二醇醚,三丁基苯基聚乙二醇醚,三硬脂基苯基聚乙二醇醚,烷基芳基聚醚醇,醇和脂肪醇/氧化乙烯缩合物,乙氧基化蓖麻油,聚氧乙烯烷基醚,乙氧基化聚氧丙烯,月桂醇聚乙二醇醚缩醛,山梨醇酯和甲基纤维素。合适的阴离子分散剂尤其为木素磺酸、萘磺酸、苯酚磺酸、二丁基萘磺酸的碱金属盐、碱土金属盐和铵盐,烷基芳基磺酸盐,烷基硫酸盐,烷基磺酸盐,脂肪醇硫酸盐,脂肪酸和硫酸化脂肪醇二醇醚,此外还有芳基磺酸酯/甲醛缩合物,例如磺化萘和萘衍生物与甲醛的缩合物,萘或萘磺酸与苯酚和甲醛的缩合物,木素磺酸盐,木素亚硫酸盐废液,甲基纤维素的磷酸化或硫化酸衍生物和聚丙烯酸盐。
适合用作防冻剂的原则上是所有降低水的熔点的物质。合适的防冻剂包括链烷醇,如甲醇、乙醇、异丙醇、丁醇、乙二醇、甘油、二甘醇等。
合适的增稠剂是所有可以在农化组合物中用于该目的的物质,例如纤维素衍生物、聚丙烯酸衍生物、苍耳烷、改性粘土和细碎二氧化硅。
适合用作消泡剂的是所有常用于配制农化活性化合物的消泡剂。特别合适的是聚硅氧烷消泡剂和硬脂酸镁。
适于用作防腐剂的是所有可以在农化组合物中用于该目的的防腐剂。作为举例可以提到二氯芬(dichlorophene),异噻唑类,如1,2-苯并异噻唑-3(2H)-酮、2-甲基-2H-异噻唑-3-酮盐酸盐、5-氯-2-(4-氯苄基)-3(2H)-异噻唑酮、5-氯-2-甲基-2H-异噻唑-3-酮、5-氯-2-甲基-2H-异噻唑-3-酮、5-氯-2-甲基-2H-异噻唑-3-酮盐酸盐、4,5-二氯-2-环己基-4-异噻唑啉-3-酮、4,5-二氯-2-辛基-2H-异噻唑-3-酮、2-甲基-2H-异噻唑-3-酮、2-甲基-2H-异噻唑-3-酮/氯化钙配合物、2-辛基-2H-异噻唑-3-酮以及苄醇半缩甲醛。
加入粘合剂/增粘剂以改善处理后有效组分在种子上的粘附。合适的粘合剂是基于EO/PO的嵌段共聚物表面活性剂,还有聚乙烯醇、聚乙烯基吡咯烷酮、聚丙烯酸酯、聚甲基丙烯酸酯、聚丁烯、聚异丁烯、聚苯乙烯、聚乙烯胺、聚乙烯酰胺、聚乙烯亚胺(Lupasol、Polymin)、聚醚以及衍生于这些聚合物的共聚物。
为了处理种子,原则上可以使用任何常用于处理种子或拌种的方法。具体而言,处理通过在适合该目的的设备,例如固体或固体/液体混合组分的混合设备中将种子与所需特定量的拌种配制剂直接或用水预先稀释后混合直到该组合物均匀分布在种子上而进行。合适的话随后进行干燥操作。
组分A和B可以联合或分开配制。
根据本发明使用的化合物A和至少一种B组杀真菌剂的组合在防治有害真菌中的使用通常通过用杀真菌有效量的这些活性化合物的组合处理真菌或需要防治真菌侵袭的种子、植物、植物部分、土壤、表面、空间或材料而进行。处理优选通过使真菌或需要防治真菌侵袭的种子、植物、植物部分、土壤、表面、空间或材料与两种活性化合物或包含这两种活性化合物的组合物接触而进行。为此,将组合物或各活性化合物施用于真菌或需要防治真菌侵袭的种子、植物、植物部分、土壤、表面、空间或材料。因此,组分A和B可以联合或分开施用。在分开施用的情况下,各活性物质可以同时施用,或者作为处理顺序的一部分依次一个接一个地施用,在依次施用的情况下,活性物质优选以几分钟至几天的间隔施用。
处理可以在材料、植物、种子、土壤、区域或空间被真菌侵染之前进行(预防性)和之后进行(治疗性)。
在作物保护中,杀真菌活性组分A和B可以在植物出苗之前、之中或之后施用。
本发明组合物对宽范围的有害真菌(植物病原性真菌),尤其是选自子囊菌纲(Ascomycetes)、半知菌纲(Deuteromycetes)、Peronosporomycetes(同义词:卵菌纲(Oomycetes))和担子菌纲(Basidiomycetes)的真菌具有优异的活性。它们中的一些内吸有效且可以作为叶面杀真菌剂、拌种用杀真菌剂和土壤杀真菌剂用于作物保护中。
它们对在各种作物植株如禾谷类(例如大麦、稻、黑麦、大豆、玉米、小麦、燕麦),梨果和核果(例如苹果、梨、木瓜(quince)、欧洲甜樱桃、酸樱桃、李子(plum)、李(quetsch)、桃、油桃、杏、杏仁),蔬菜(例如黄瓜、豆类、西红柿、土豆和葫芦科植物),豆类植物(例如菜豆、豌豆、小扁豆),棉花,禾草,香蕉,花生,咖啡,葡萄藤,观赏植物,甘蔗以及大量种子中防治大量真菌尤其重要。
它们特别适于防治下列植物病原性真菌:
●蔬菜、油籽油菜、糖用甜菜、水果和稻上的链格孢属(Alternaria),
●糖用甜菜和蔬菜上的丝囊霉属(Aphanomyces);
●玉米、禾谷类、稻和草坪中的平脐蠕孢属(Bipolaris)和内脐蠕孢属(Drechslera),
●禾谷类上的禾白粉菌(Blumeria graminis)(白粉病);
●草莓、蔬菜、花卉和葡萄藤上的灰葡萄孢(Botrytis cinerea)(灰霉病),
●莴苣上的莴苣盘梗霉(Bremia lactucae),
●玉米、大豆、稻和糖用甜菜上的尾孢属(Cercospora);
●玉米、禾谷类、稻上的旋孢腔菌属(Cochliobolus)(例如禾谷类上的禾旋孢腔菌(Cochliobolus sativus),稻上的宫部旋孢腔菌(Cochliobolusmiyabeanus)),
●大豆和棉花上的剌盘孢属(Colletotricum);
●禾谷类和玉米上的内脐蠕孢属(Drechslera),
●玉米上的突脐蠕孢属(Exserohilum),
●葫芦科植物上的二孢白粉菌(Erysiphe cichoracearum)和单丝壳白粉菌(Sphaerotheca fuliginea),
●各种植物上的镰孢霉属(Fusarium)和轮枝孢属(Verticillium),
●禾谷类上的禾顶囊壳(Gaeumanomyces graminis);
●禾谷类和稻上的赤霉属(Gibberella)(例如稻上的藤仓赤霉(Gibberellafujikuroi));
●稻上的Grainstaining complex;
●玉米和稻上的长蠕孢属(Helminthosporium);
●禾谷类上的Michrodochium nivale;
●禾谷类、香蕉和花生上的球腔菌属(Mycosphaerella),
●大豆上的豆薯层锈菌(Phakopsora pachyrhizi)和山马蟥层锈菌(Phakopsara meibomiae);
●大豆和向日葵上的拟茎点霉属(Phomopsis);
●土豆和西红柿上的致病疫霉(Phytophthora infestans);
●葡萄藤上的葡萄生单轴霉(Plasmopara viticola),
●苹果上的苹果白粉病菌(Podosphaera leucotricha),
●禾谷类上的小麦基腐病菌(Pseudocercosporella herpotrichoides),
●啤酒花和葫芦科植物上的假霜霉属(Pseudoperonospora),
●禾谷类和玉米上的柄锈菌属(Puccinia),
●禾谷类上的核腔菌属(Pyrenophora),
●稻上的稻瘟病菌(Pyricularia oryzae)、笹木伏革菌(Corticium sasakii)、帚梗柱孢属(Sarocladium oryzae)、稻叶鞘腐败病(S.attenuatum)、稻叶黑粉菌(Entyloma oryzae),
●草坪和禾谷类上的稻梨孢菌(Pyricularia grisea),
●草坪、稻、玉米、棉花、油籽油菜、向日葵、糖用甜菜、蔬菜和其他植物上的腐霉属(Pythium),
●棉花、稻、土豆、草坪、玉米、油籽油菜、糖用甜菜、蔬菜和其它植物上的丝核菌属(Rhizoctonia),
●油籽油菜和向日葵上的核盘菌属(Sclerotinia);
●小麦上的小麦壳针孢(Septoria tritici)和颖枯壳多孢(Stagonosporanodorum),
●葡萄藤上的葡萄钩丝壳(Erysiphe(同义词Uncinula)necator),
●玉米和草坪上的Setospaeria属,
●玉米上的丝轴黑粉菌(Sphacelotheca reilinia),
●大豆和棉花上的根串珠霉属(Thievaliopsis),
●禾谷类上的腥黑粉菌属(Tilletia),
●禾谷类、玉米和糖用甜菜上的黑粉菌属(Ustilago),和
●苹果和梨上的黑星菌属(Venturia)(黑星病)。
本发明混合物特别优选用于在葡萄藤和蔬菜作物以及观赏植物中防治灰霉属(Botrytis)以及在禾谷类中防治核腔菌属。具体而言,它们用于在大麦中防治核腔菌属,如大麦条纹德氏霉(Pyrenophora graminea)、偃麦草核腔菌(Pyrenophora tritici-repentis)和尤其是网斑病菌(Pyrenophorateres)(内脐蠕孢属)。
本发明的杀真菌活性组合物还可以用于防治有害真菌以保护材料(例如木材、纸张、漆分散体、纤维或织物)和保护储存产品,例如以防治拟青霉(Paecilomyces variotii)。
在作物保护中,纯活性化合物组合物,即没有配制助剂的A和B的所需施用率取决于植物丛的组成、植物的发育阶段、施用场所的气候条件和施用方法。A和B的总施用量通常为0.001-3kg/ha,优选0.005-2kg/ha,尤其是0.01-1kg/ha活性物质(a.s.)。
化合物A的所需施用率通常为0.1g/ha-1kg/ha,优选1-500g/ha或5-500g/ha a.s.。
组合物优选通过喷雾叶子而施用于植物上。这里例如可以通过常规喷雾技术使用载体水以约100-1000l/ha(例如300-400l/ha)的喷雾液量进行施用。通过低容量和超低容量法施用除草组合物是可能的,以微颗粒形式施用也是可能的。
在种子处理中,活性化合物的用量(杀真菌剂A)和B)的活性化合物总量)为1-1000g/100kg种子,优选1-750g/100kg,尤其是5-500g/100kg。
在材料和储存产品的保护中的施用中,活性化合物A)和B)的施用率取决于使用区域和所需效果。在材料保护中的常规总施用率例如为每立方米被处理材料0.001g-2kg,优选0.005g-1kg杀真菌剂A)和B)。
惊人的是,与基于单一化合物的杀真菌活性所预计的相比,包含式A化合物和至少一种选自组分B的杀真菌剂的本发明组合物对有害真菌具有更好的杀真菌活性,即以超加和方式使杀真菌活性增加。活性化合物组合的预计效力例如可以使用Colby公式(S.R.Colby,计算除草剂组合的协同增效和拮抗响应,Weeds,15,第20-22页)确定。这意味着通过将化合物A与至少一种杀真菌剂B联合使用以协同增效效果实现了对至少一种有害真菌的增强活性(协同增效现象)。为此,这些组合物可以更低的总施用率使用。
实施例
本发明组合物的协同增效活性可以由下列试验证实。
活性化合物以市售配制剂使用或以储备溶液使用。由25mg活性化合物制备储备溶液,使用溶剂/乳化剂体积比为99∶1的作为溶剂的丙酮和/或DMSO与乳化剂UniperolEL(具有乳化和分散作用的基于乙氧基化烷基酚的润湿剂)的混合物将其配成10ml。然后用水将体积配成100ml。
通过肉眼测定侵染叶面积%而进行评价。将这些百分数转化成以相对于未处理对照的%表示的效力。效力为0时已处理植物的侵染对应于未处理对照植物;效力为100时已处理植物未被侵染。
活性化合物组合的预期效力使用Colby公式(Colby,S.R.,“计算除草剂组合的协同增效和拮抗响应”,Weeds,15,第20-22页,1967)确定并与观察到的效力比较。
Colby公式:E=x+y-x·y/100
E使用浓度为a和b的活性化合物A和B的混合物时的预期效力,以相对于未处理对照的%表示,
x使用浓度为a的活性化合物A时的效力,以相对于未处理对照的%表示,
y使用浓度为b的活性化合物B时的效力,以相对于未处理对照的%表示。
对由网斑病菌引起的大麦网斑病的活性,2天保护性施用
将栽培品种为“Hanna”的盆栽大麦秧苗的叶子用活性化合物浓度如下所述的含水悬浮液喷雾至滴流点。喷雾涂层干燥后48小时,将试验植物用网斑病菌(同义词Drechslera teres)-网斑病病原体的含水孢子悬浮液接种。然后将试验植物放入温度为20-24℃且相对大气湿度为95-100%的温室中。6天后以整个叶面积的侵染%肉眼测定病害的发展程度。
表A:单独的活性化合物的活性
活性化合物 | 在喷雾液中的浓度[ppm] | 效力[%] |
对照(未处理) | - | -(90%侵染) |
化合物A | 40.5 | 220 |
代森联 | 250 | 0 |
表B:本发明组合物的活性
活性化合物组合 | 喷雾液浓度[ppm] | 混合比 | 计算的效力*[%] | 观察到的效力[%] |
化合物A+代森联 | 4250 | 1∶62.5 | 22 | 44 |
*根据Colby
由以上结果可以看出,本发明组合物协同增效起作用。
Claims (13)
1.一种杀真菌活性组合物,包含:
A)式A的N-[2-(1,3-二甲基丁基)-3-噻吩基]-1-甲基-3-(三氟甲基)-1H-吡唑-4-甲酰胺:
和
B)至少一种选自如下的其他杀真菌剂B:
B.1)选自如下的唑类杀真菌剂:丙硫菌唑、戊叉唑菌、氟醚唑、粉唑醇、烯菌灵、硅氟唑、咪唑、***酮、氰霜唑、麦穗宁和噻唑菌胺;
B.2)羧酰胺类杀真菌剂;
B.3)不同于B.1)组唑类杀真菌剂的杂环化合物;
B.4)选自如下的氨基甲酸盐类和二硫代氨基甲酸盐类杀真菌剂:代森联、百维灵、百维灵单盐酸盐、异丙菌胺、苯噻菌胺、式B.4.1的氨基甲酸酯:
和式B.4.2的N-(1-(1-(4-氰基苯基)乙烷磺酰基)丁-2-基)氨基甲酸4-氟苯基酯:
B.5)选自如下的其他杀真菌剂B:
B.5.1)含硫的杂环基化合物;
B.5.2)有机磷化合物;
B.5.3)有机氯化合物;
B.5.4)选自螺茂胺、环氟菌胺和苯菌酮的其他杀真菌剂。
4.根据前述权利要求中任一项的组合物,其中含硫的杂环化合物B.5.1)为二噻农。
5.根据前述权利要求中任一项的组合物,其中有机磷化合物B.5.2)为甲基立枯磷。
6.根据前述权利要求中任一项的组合物,其中有机氯化合物B.5.3)选自磺菌胺和对甲抑菌灵。
7.根据权利要求1的组合物,其中至少一种杀真菌剂B选自B.4)组氨基甲酸盐类和二硫代氨基甲酸盐类杀真菌剂。
8.根据前述权利要求中任一项的组合物,其中组分A)与组分B)的重量比为100∶1-1∶100。
9.根据前述权利要求中任一项的组合物,进一步包含至少一种惰性液体和/或固体载体和合适的话至少一种表面活性剂和/或至少一种常规助剂。
10.一种双组分包装,包含第一组分和第二组分,其中第一组分包含如权利要求1所定义的式A化合物、液体或固体载体和合适的话至少一种表面活性剂和/或至少一种常规助剂,第二组分包含至少一种如权利要求1-7中任一项所定义的杀真菌剂B、液体或固体载体和合适的话至少一种表面活性剂和/或至少一种常规助剂。
11.一种防治有害真菌的方法,包括使根据权利要求1-9中任一项所定义的组合物作用于真菌、其栖息地或需要防止真菌侵袭的材料、植物、种子或土壤。
12.根据权利要求11的方法,其中同时,即联合或分开,或依次施用所述组合物的杀真菌活性组分A)和B)。
13.根据权利要求1-9中任一项所定义的组合物在防治有害真菌中的用途。
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Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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2006
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- 2006-07-21 JP JP2008521982A patent/JP2009501768A/ja not_active Withdrawn
- 2006-07-21 EP EP06764245A patent/EP1909577A2/de not_active Withdrawn
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