CN101209912A - Environment-friendly type water cinder calcium silicate plate and preparation - Google Patents
Environment-friendly type water cinder calcium silicate plate and preparation Download PDFInfo
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- CN101209912A CN101209912A CNA2007100327916A CN200710032791A CN101209912A CN 101209912 A CN101209912 A CN 101209912A CN A2007100327916 A CNA2007100327916 A CN A2007100327916A CN 200710032791 A CN200710032791 A CN 200710032791A CN 101209912 A CN101209912 A CN 101209912A
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- calcium silicate
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00129—Extrudable mixtures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
- C04B2111/0062—Gypsum-paper board like materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses an environmental friendly calcium silicate board of water cinder, which is manufactured from raw materials of asbestos, paper fiber, hydrated lime, quartz powder and cement, and is characterized in that: the raw materials further comprise water cinder and dust and manufactured precipitation waste. The specific manufacturing ingredients is composed of the raw materials in proportion (part by weight): 90 to 100pbw of asbestos, 30 to 34pbw of paper fiber, 75 to 85pbw of hydrated lime, 50 to 100pbw of water cinder, 235 to 265pbw of quartz powder, 150 to 250pbw of cement, 20 to 35pbw of dust and 20 to 35pbw of manufactured precipitation waste. At the same time, the invention discloses a preparation method of the environment friendly calcium silicate board of water cinder which comprises steps that slurry is prepared firstly, then slabs are produced and steam cured and processed for board material, finally the board material is stored after detection. The invention has the advantages of environment protection, cost saving and stable quality, etc.
Description
Technical field
The present invention relates to water cinder calcium silicate plate that a kind of refuse that utilizes coal water slurry boiler discharging produces and preparation method thereof.
Background technology
Calcium silicate board is one of important materials for wall that is applied to modern architecture, because of it has that density is low, intensity is high, bulking factor is little, fire prevention, moistureproof, mothproof, mildew-resistant; Workability is good, surfacing, premium properties such as elegant in appearance, is widely used as indoor partition wall, suspended ceiling decoration material in modern architecture.At present, calcium silicate board commonly used mainly adopts other organic fibres such as a large amount of former mineral substance and silica powder, slaked lime powder, fibrous magnesium silicate, paper fiber to make, constantly soaring along with the raw mineral materials price, its production cost height, and expend raw mineral materials, incompatibility environmental requirement.And coal water slurry boiler produces a large amount of waste residue etc. in the industries such as present pottery, cement, can use on calcium silicate board, but not obtain utilizing, and how carrying out refuse reclamation is a problem that is worth discussion.
Summary of the invention
The objective of the invention is and provide a kind of refuse to be recycled environment-friendly type water cinder calcium silicate plate that compliance with environmental protection requirements, cost are low, up-to-standard and preparation method thereof in order to solve above-mentioned deficiency.
The technical solution that the present invention adopts in order to achieve the above object is as follows:
This environment-friendly type water cinder calcium silicate plate, mainly make by raw material asbestos, paper fiber, slaked lime, silica powder, cement, it is characterized in that, its raw material also comprises water cinder and dust and produces the precipitation waste material that its concrete production formula is made of following proportioning raw materials (weight part): asbestos 90-100 part, paper fiber 30-34 part, slaked lime 75-85 part, water cinder 50-100 part, silica powder 235-265 part, cement 150-250 part, dust 20-35 part, production precipitation waste material 20-35 part.
Wherein, dust and produce the precipitation waste material and can adopt the dust that the purifying air of enterprises such as Production of Ceramics collects and dust, the sulphur removal of coal water slurry boiler to take off dirt water.
Its preparation technology's method is to comprise the steps:
One, preparation slip; Above-mentioned slag and cyclone dust removal powder are measured according to dry weight, desulfurization and dedusting water is directly pumped in the storage slurry stirred pot stir, it is stand-by the slip (concentration 2.5%) that stirs to be pumped into the test tank metering again; The paper fiber loosened earlier make 3.5-5% concentration, measure standby; With the fibrous magnesium silicate metering, loosen into concentration 3.5-5%, the slip that degree of loosening reaches more than 90% is stand-by, and other raw material meterings are stand-by;
The various raw materials that measure are sent in the hollander pull an oar, be prepared into uniform slip, concentration is controlled at 18%-21%; Slip in the hollander is pumped in the bucket type pulp storage tank, add the slip of producing the backwater neutralization, being diluted to concentration 13-16%;
Two, slab preparation; Slip after neutralization, the dilution is tiled in slurry at the uniform velocity the felt equably by head box after paste roller mill is discongested again, through the draining step by step of natural dehydration, vacuum, the moulding extrusion dehydration regulation moisture to 31%-34%; Be slit into specified dimension through horizontal rip cutting again, through product thickness, surface quality testing, salable product patrix stacking; The scrap stock unification of unacceptable product and salable product is reclaimed and is pumped into pulp storage tank after the slurrying again and produce;
Three, it is steam-cured to carry out slab, behind the salable product patrix, through 8 hours quiet naturally stop maintenance after the slab of the demoulding, send into autoclave with the form of the every still of 11 dollies and carry out steam-cured; It is main crystalline flyash silicic acid calcium component that product after steam-cured forms with holder shellfish mullite;
Four, sheet material processing, detection warehouse-in; After product after reaching steam-cured requirement shifts out autoclave, send into drying machine drying by every mode; Through check product thickness, outward appearance, moisture up-to-standard product, change sanding, edging, chamfering process again over to and carry out product specification size and chamfer machining, qualified through mechanical properties test again, the buttress heap puts in storage and gets final product.
Above-mentioned steam-cured main technologic parameters control: boosted constant voltage 14 hours, step-down 2.3 hours, pressure 1.0-1.1 MPa, temperature 180-182 ℃ 3 hours.
Above-mentioned oven dry main technologic parameters control: the high-temperature area temperature is controlled at 135-155 ℃.
The main quality of above-mentioned sanding: control thickness e＜± 0.2mm; Edging, chamfer quality control: the length and width standard size≤± 2mm; Chamfering width 26-28mm, chamfering degree of depth 0.6-1.0mm.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
Product of the present invention adopts the raw materials for production that are different from traditional calcium silicate board, made full use of industrial waste, the three wastes (the slag of coal water slurry boiler, dust, dirt water is taken off in sulphur removal), gathering materials on the spot turns waste into wealth, reduced the consumption of former mineral substance, reduced second environmental pollution, be example with 1 6T coal water slurry boiler after testing, day produces the about 400kg of slag, dust 600kg, desulfurization and dedusting water reaches 600T, and be mixed with the dust about 10% in the desulfurization and dedusting water, desulfurization and dedusting water (about pH value 5-6) is handled needs lime, day medication costs such as caustic soda reach 650 yuan, raw-material chemical ingredients of bonded products forming process of the present invention and bonding water (production cycle water ph value 14-15) are directly as desulfurization and dedusting water, thereby stablizing its pH value is controlled at about 8-9, utilize slag, dust sulfur oxide content situation, reduce the consumption of silica powder, produce product and reduced cost, the product physics that it is produced, mechanical property has reached the industry quality standard requirement of calcium silicate board fully, only because three wastes material color is greyish black, the product of producing is darker than common color, behind the process surface decoration, with common calcium silicate board indistinction.
Embodiment
Embodiment one
This environment-friendly type water cinder calcium silicate plate, consider product colour and common approaching substantially, it is made of than (weight part) following set of dispense: asbestos 95kg, paper fiber 32kg, slaked lime 80kg, water cinder 50kg, silica powder 265kg, cement 200kg, dust 30kg, moist production precipitation waste material 30kg.The water cinder is made up of slag, dust, desulfurization and dedusting water that coal water slurry boiler produces.
Its preparation technology's method is to comprise following concrete steps:
One, preparation slip; Above-mentioned slag and dirt powder are measured according to dry weight, desulfurization and dedusting water is directly pumped in the storage slurry stirred pot stir, it is stand-by the slip (concentration 2.5%) that stirs to be pumped into the test tank metering again; The paper fiber loosened earlier make 3.5-5% concentration, measure standby; With the fibrous magnesium silicate metering, loosen into concentration 3.5-5%, the slip that degree of loosening reaches more than 90% is stand-by, and other raw material meterings are stand-by;
The various raw materials that measure are sent in the hollander pull an oar, be prepared into uniform slip, concentration is controlled at 18%-21%; Slip in the hollander is pumped in the bucket type pulp storage tank, add the slip of producing the backwater neutralization, being diluted to concentration 13-16%;
Two, slab preparation; Slip after neutralization, the dilution is tiled in slurry at the uniform velocity the felt equably by head box after paste roller mill is discongested again, through the draining step by step of natural dehydration, vacuum, the moulding extrusion dehydration regulation moisture to 31%-34%; Be slit into specified dimension through horizontal rip cutting again, through product thickness, surface quality testing salable product patrix stacking; The scrap stock unification of unacceptable product and salable product is reclaimed and is pumped into pulp storage tank after the slurrying again and produce, has promoted utilization of waste material better;
Three, it is steam-cured to carry out slab, behind the salable product patrix, through 8 hours quiet naturally stop maintenance after the slab of the demoulding, with the form of the every still of 11 dollies send into autoclave carry out steam-cured, about 154 2440 * 1220 * 6mm products of per car; Constant voltage 14 hours, step-down 2.3 hours, pressure 1.0-1.1 MPa, temperature 180-182 ℃ were boosted in steam-cured main technologic parameters control 3 hours; It is main crystalline flyash silicic acid calcium component that product after steam-cured forms with holder shellfish mullite;
Four, sheet material processing, detection warehouse-in; After product after reaching steam-cured requirement shifts out autoclave, send into drying machine drying by every mode, the control of oven dry main technologic parameters, the high-temperature area temperature is controlled at 135-155 ℃; Through check product thickness, outward appearance, moisture up-to-standard product, the sanding major quality controlling, thickness e＜± 0.2mm; Edging, chamfer quality control, the length and width standard size≤± 2mm; Chamfering width 26-28mm, chamfering degree of depth 0.6-1.0mm; Change sanding, edging, chamfering process again over to and carry out product specification size and chamfer machining, be up to the standards through physical and mechanical property, the buttress heap puts in storage and gets final product.It detects as following table through physical and mechanical property;
| The product situation | Folding strength (MPa) | Density g/cm 3 | Screw withdrawal force N/mm | Water ratio % | |||
| Numbering | Thickness | Vertically | Laterally | On average | |||
| 1 | 6 | 11.23 | 14.66 | 12.95 | 1.19 | 68.92 | 7.82 |
| 2 | 6 | 11.52 | 14.00 | 12.76 | 1.17 | 67.88 | 9.86 |
| 3 | 8 | 11.28 | 14.24 | 12.76 | 1.16 | 74.58 | 11.78 |
Through in conjunction with the every index of building material industry standard JC/T564-2000 " fiber reinforced calcium silicate board " standard regulation, water cinder calcium silicate plate of the present invention except 6mm product withdrawal force a little less than the standard, other indexs are all above the required standard prescribed value.
Embodiment two
This environment-friendly type water cinder calcium silicate plate, do not considering that this product colour is approaching substantially with common product, it is made of than (weight part) following set of dispense: asbestos 100kg, paper fiber 32kg, slaked lime 80kg, water cinder 100kg, silica powder 235kg, cement 200kg, dust 30kg, production precipitation waste material 30kg.
Because its preparation method with above-mentioned embodiment, is no longer repeated at this; But distinguishingly be, greyish black because of three wastes material color, it is dark than the usual production color to produce the product that obtains, pass through surface decoration again after, just with the usual production indistinction.
Above embodiment is only in order to illustrating that technical scheme of the present invention is not intended to limit, and the specific embodiment of the present invention is made amendment or the part technical characterictic is equal to replacement; And not breaking away from the spirit of technical solution of the present invention, it all should be encompassed in the middle of the technical scheme scope that the present invention asks for protection.
Claims (5)
1. environment-friendly type water cinder calcium silicate plate, mainly make by raw material asbestos, paper fiber, slaked lime, silica powder, cement, it is characterized in that, its raw material also comprises water cinder and dust and produces the precipitation waste material that its concrete production formula is made of following proportioning raw materials (weight part): asbestos 90-100 part, paper fiber 30-34 part, slaked lime 75-85 part, water cinder 50-100 part, silica powder 235-265 part, cement 150-250 part, dust 20-35 part, production precipitation waste material 20-35 part.
2. the preparation method of the described environment-friendly type water cinder calcium silicate plate of claim 1 is characterized in that, this preparation method comprises that step has,
One, preparation slip; Above-mentioned slag and dust are measured according to dry weight, desulfurization and dedusting water is directly pumped in the storage slurry stirred pot stir, it is stand-by that the 2.5% concentration slip that will stir again pumps into the test tank metering; The paper fiber loosened earlier make 3.5-5% concentration, measure standby; With the fibrous magnesium silicate metering, loosen into concentration 3.5-5%, the slip that degree of loosening reaches more than 90% is stand-by, and other raw material meterings are stand-by; The various raw materials that measure are sent in the hollander pull an oar, be prepared into uniform slip, concentration is controlled at 18%-21%; Slip in the hollander is pumped in the bucket type pulp storage tank, add the slip of producing the backwater neutralization, being diluted to concentration 13-16%;
Two, slab preparation; Slip after neutralization, the dilution is tiled in slurry at the uniform velocity the felt equably by head box after paste roller mill is discongested again, through the draining step by step of natural dehydration, vacuum, the moulding extrusion dehydration regulation moisture to 31%-34%; Be slit into specified dimension through horizontal rip cutting again, through product thickness, surface quality testing, salable product patrix stacking;
Three, slab is steam-cured; Behind the above-mentioned salable product patrix, through 8 hours quiet naturally stop maintenance after the slab of the demoulding, send into autoclave with the form of the every still of 11 dollies and carry out steam-curedly, it is main crystalline flyash silicic acid calcium component that the product after steam-cured forms with holder shellfish mullite;
Four, sheet material processing, detection warehouse-in; After product after reaching steam-cured requirement shifts out autoclave, send into drying machine drying by every mode; Through check product thickness, outward appearance, moisture up-to-standard product, change sanding, edging, chamfering process again over to and carry out product specification size and chamfer machining, qualified through mechanical properties test again, the buttress heap puts in storage and gets final product.
3. the preparation method of environment-friendly type water cinder calcium silicate plate according to claim 2 is characterized in that, in the step 2 after the examination and test of products, the scrap stock unification of unacceptable product and salable product is reclaimed and pumped into pulp storage tank after the slurrying again and produce.
4. the preparation method of environment-friendly type water cinder calcium silicate plate according to claim 2 is characterized in that, above-mentioned steam-cured main technologic parameters control in the step 3, boosted constant voltage 14 hours, step-down 2.3 hours 3 hours, pressure 1.0-1.1 MPa, temperature 180-182 ℃.
5. the preparation method of environment-friendly type water cinder calcium silicate plate according to claim 2 is characterized in that, above-mentioned oven dry main technologic parameters control in the step 4, and the high-temperature area temperature is controlled at 135-155 ℃; The main quality of above-mentioned sanding, control thickness e＜± 0.2mm; Edging, chamfer quality control, the length and width standard size≤± 2mm; Chamfering width 26-28mm, chamfering degree of depth 0.6-1.0mm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710032791A CN100577600C (en) | 2007-12-24 | 2007-12-24 | Environment-friendly type water cinder calcium silicate plate and preparation |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710032791A CN100577600C (en) | 2007-12-24 | 2007-12-24 | Environment-friendly type water cinder calcium silicate plate and preparation |
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| CN101209912A true CN101209912A (en) | 2008-07-02 |
| CN100577600C CN100577600C (en) | 2010-01-06 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101979355A (en) * | 2010-10-07 | 2011-02-23 | 宜春市金特建材实业有限公司 | Composite fiber calcium silicate board and preparation method thereof |
| CN102518223A (en) * | 2011-11-30 | 2012-06-27 | 赵德存 | External insulation board for external wall and manufacture method thereof |
| CN102875064A (en) * | 2011-07-14 | 2013-01-16 | 江苏康辉硅酸钙板有限公司 | Fiber-reinforced fly ash pressure plate and manufacturing method |
| CN103640276A (en) * | 2013-10-17 | 2014-03-19 | 苏州市梦里兰家具有限公司 | Flame-retardant fireproof veneered calcium silicate board |
| CN103936364A (en) * | 2014-03-25 | 2014-07-23 | 暨南大学 | High-performance concrete prepared by utilizing coal-water slurry slag |
| CN103964785A (en) * | 2014-05-07 | 2014-08-06 | 山东建筑大学 | Method for producing calcium silicate board from artificial stone plate wastes and quartz stone plate wastes |
| CN105252641A (en) * | 2015-09-10 | 2016-01-20 | 卓达新材料科技集团有限公司 | Automatic production line for plate |
| CN105819778A (en) * | 2016-03-16 | 2016-08-03 | 潍坊科技学院 | Preparation method of light, thermal insulation, and environment-friendly composite wall construction material |
| CN111496997A (en) * | 2020-04-22 | 2020-08-07 | 河北普州建材科技有限公司 | Preparation process of chrysotile reinforced calcium silicate board |
-
2007
- 2007-12-24 CN CN200710032791A patent/CN100577600C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101979355A (en) * | 2010-10-07 | 2011-02-23 | 宜春市金特建材实业有限公司 | Composite fiber calcium silicate board and preparation method thereof |
| CN101979355B (en) * | 2010-10-07 | 2012-07-25 | 宜春市金特建材实业有限公司 | Composite fiber calcium silicate board and preparation method thereof |
| CN102875064A (en) * | 2011-07-14 | 2013-01-16 | 江苏康辉硅酸钙板有限公司 | Fiber-reinforced fly ash pressure plate and manufacturing method |
| CN102518223A (en) * | 2011-11-30 | 2012-06-27 | 赵德存 | External insulation board for external wall and manufacture method thereof |
| CN102518223B (en) * | 2011-11-30 | 2013-12-11 | 赵德存 | External insulation board for external wall and manufacture method thereof |
| CN103640276A (en) * | 2013-10-17 | 2014-03-19 | 苏州市梦里兰家具有限公司 | Flame-retardant fireproof veneered calcium silicate board |
| CN103936364A (en) * | 2014-03-25 | 2014-07-23 | 暨南大学 | High-performance concrete prepared by utilizing coal-water slurry slag |
| CN103936364B (en) * | 2014-03-25 | 2016-02-10 | 暨南大学 | A kind of high performance concrete utilizing coal water slurry slag to prepare |
| CN103964785A (en) * | 2014-05-07 | 2014-08-06 | 山东建筑大学 | Method for producing calcium silicate board from artificial stone plate wastes and quartz stone plate wastes |
| CN103964785B (en) * | 2014-05-07 | 2015-10-21 | 山东建筑大学 | A kind of method of producing calcium silicon plate with artificial stone plate and quartz slate waste |
| CN105252641A (en) * | 2015-09-10 | 2016-01-20 | 卓达新材料科技集团有限公司 | Automatic production line for plate |
| CN105819778A (en) * | 2016-03-16 | 2016-08-03 | 潍坊科技学院 | Preparation method of light, thermal insulation, and environment-friendly composite wall construction material |
| CN111496997A (en) * | 2020-04-22 | 2020-08-07 | 河北普州建材科技有限公司 | Preparation process of chrysotile reinforced calcium silicate board |
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| CN100577600C (en) | 2010-01-06 |
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