CN101209904A - Plated film glass - Google Patents
Plated film glass Download PDFInfo
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- CN101209904A CN101209904A CNA2006101705965A CN200610170596A CN101209904A CN 101209904 A CN101209904 A CN 101209904A CN A2006101705965 A CNA2006101705965 A CN A2006101705965A CN 200610170596 A CN200610170596 A CN 200610170596A CN 101209904 A CN101209904 A CN 101209904A
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Abstract
The invention relates to coated glass, which comprises a glass substrate and a film layer, wherein, the film layer is a metal film which is directly adhered on at least one surface of the glass substrate. The color of the coated glass does not change with the different visual angles, can present various colors of metallic luster and can meet the requirement that the transmission rate is lower than 50 percent. The invention has very convenient production, and adhesion, pencil hardness and tenacity and solvent resistance can all the requirements.
Description
Technical field
The present invention relates to a kind of coated glass.
Background technology
The panel of various electronic products or form, for example the ambetti form of various electronic products such as mobile phone, MP3 generally selects for use inorganic silicate glass or acrylic glass as substrate, for supporting with whole prod, needs painted, plated film usually.Traditional colorize method is to plate blooming on glass substrate, and by adjusting wavelength, the kind of coating materials and the collocation of rete of blooming, blooming can present profuse color.Silk-screen black ink on rete again is to show the color of blooming.
Though such production method can obtain profuse color, but weak point is arranged also: the film system design of (1) optical film is complicated, and rete does not wait from several layers to tens of layers, and the time of plated film is longer, cost is higher, and needs high-accuracy equipment to finish.(2) optical film can produce the obvious color variation because the visual angle is different.
CN1749782A discloses a kind of coated glass eyeglass, it comprises a glass baseplate, be formed at glass baseplate first surface first rete and be formed at glass baseplate and second rete corresponding another surface of first surface; It is characterized in that: first rete is that multilayer optical film constitutes, and second rete is a multi-layer anti-reflective film, comes the balance optical thin film to stress that glass baseplate produced by anti-reflective film.This optical thin film is corresponding with the anti-reflective film number of plies, and this multilayer optical film is piled up by high-index material and low refractive material space and forms, and high-refraction material is tantalum pentoxide (Ta
2O
5), low refractive material is silicon-dioxide (SiO
2), the material of this anti-reflective film is the stacked evaporation layer of low-refraction compound and high refractive index metallic compound, the low-refraction compound is MgF
2, the high refractive index metallic compound is ZnO
2Or TiO
2This coated glass eyeglass not only can be eliminated the stress of plated film generation but also can improve optical property.But this coated glass eyeglass complicated process of preparation need be coated with rete number layer or tens of layer, and this coated glass eyeglass can produce obvious color and changes because the visual angle is different.
CN2188587Y discloses a kind of color metallized glass with three kinds of retes, form by glass substrate, underlying membrane, middle layer and outer membrane, it is characterized in that underlying membrane is the metal oxide film that adopts the preparation of ginseng oxygen reaction magnetocontrol sputtering, the middle layer is the metal or alloy film of non-reaction magnetocontrol sputtering preparation, and outer membrane is the transition metal oxide film of high rigidity and high corrosion resistance.Wherein, underlying membrane is stannic oxide or amino-oxide film, and metallic intermediate layer or alloy film are titanium, chromium or magnetism-free stainless steel, and outer membrane is titanium oxide or ammonia oxidation titanium.This color metallized glass can be enhanced productivity, and also can guarantee chemical stability, wear resistance and the work-ing life of coated glass.But obvious change can take place along with the difference at visual angle in the color of this color metallized glass.
Summary of the invention
The defective that obviously changes, the coated glass that provides a kind of color can not change along with the difference at visual angle can take place along with the difference at visual angle in the color that the objective of the invention is to overcome the color metallized glass that exists in the above-mentioned prior art.
The invention provides a kind of coated glass, this coated glass comprises glass substrate and rete, and wherein, described rete is a metallic membrane, and described metallic membrane is attached directly at least one surface of glass substrate.
Adopt coated glass provided by the invention, color can not change along with the difference at visual angle, can present various colors with metalluster, can reach transmitance and be lower than 50% requirement.The present invention uses metal painted, need not carry out complicated film system design, for the ambetti of particular color, particularly needs the making of ambetti form of metal-like very convenient.
Coated glass of the present invention; on metallic membrane, also be attached with protective layer; can protect metallic membrane not oxidized; be not subjected to scuffing, corrosive infringement; and can regulate and part is revised the transmitance of glass; the transmitance of the sheet glass of deposited metal film can be increased 2-5%, and the sticking power of reinforcing glass sheet, pencil hardness, intensity and solvent resistance.
Description of drawings
Fig. 1 is the structural representation of coated glass of the present invention.
Embodiment
Coated glass provided by the invention comprises glass substrate and rete, and wherein, described rete is a metallic membrane, and described metallic membrane is attached directly at least one surface of glass substrate.
According to coated glass provided by the invention, in the preferred case, described metallic membrane is one or more the film that is selected from silver, aluminium, tin, copper, chromium and the nickel, and the thickness of described metallic membrane is the 20-60 nanometer.
This metallic membrane is used for painted and regulates transmitance, can make glass present the gloss of metal, and color is dark more, and the transmitance of sheet glass is low more, otherwise then high more.By the different metallic substance of evaporation, can obtain the decoration film coating glass of different colours, for example evaporation metal chromium can obtain the coated glass of brown, evaporation nickel can obtain blue coated glass, with tin and aluminium mixing evaporation, can obtain the xanchromatic coated glass, evaporation silver can obtain the coated glass of silver color.
The inventor finds; adopt preferred embodiment provided by the invention; evaporation protective membrane on described metallic membrane; can protect metallic membrane not oxidized; be not subjected to scuffing, corrosive infringement; and can regulate and part is revised the transmitance of glass, the transmitance of the sheet glass of deposited metal film can be increased 2-5%, and the sticking power of reinforcing glass sheet, pencil hardness, intensity and solvent resistance.
According to preferred embodiment provided by the invention, described protective layer can be the various coatings that can play protection metal membrane interaction, and for example, described protective layer can be for being selected from one or more the protective layer in silicon oxide, aluminum oxide and the zirconium white.The thickness of protective layer is preferably the 55-600 nanometer, and in order to reach the transmitance of the glass that increases deposited metal film, the thickness of this protective layer is 1/4 visible wavelength of the integral multiple of 1-6 more preferably.
According to preferred embodiment provided by the invention, described metallic membrane is attached directly on the surface of described glass substrate, also is attached with the stress equilibrium layer on another surface of described glass substrate.This stress equilibrium layer plays the effect of the stress that the balanced protection layer causes, and can play the effect of the transmitance of part correction glass, with sticking power, pencil hardness, intensity and the solvent resistance of further raising sheet glass.
Described stress equilibrium layer can be the various effects that can play the stress that the balanced protection layer causes; and can play the stress equilibrium layer of the effect of part correction glass transmitance; for example, described stress equilibrium layer can be for being selected from one or more the stress equilibrium layer in silicon oxide, aluminum oxide and the zirconium white.The thickness of this stress equilibrium layer preferably thickness with described protective layer is identical.
According to coated glass provided by the invention, described glass substrate is silicate glass or acrylic glass.
The preparation method of coated glass provided by the present invention is included at least one surface of glass substrate and goes up deposited metal film.Under the preferable case, this method is included on the surface of glass substrate metallic membrane on the evaporation, then respectively at protective layer and stress equilibrium layer on the evaporation on the metallic membrane and on another surface of glass substrate.
The preparation method of coated glass provided by the present invention further is in advance water white glass substrate to be cleaned up and dries.
Specifically, this method may further comprise the steps:
1, clean glass substrate: the mode of cleaning can be chosen multiple known modes such as adopting machinery, chemistry, ultrasonic cleaning wantonly.Be the example explanation below with the chemical mode: pick an amount of lime carbonate fine powder after water white glass substrate is dipped in water with clean gauze, the wiping glass substrate surface of exerting oneself is equably rinsed well with tap water; The glass substrate of wiping put in the glass washing lotion (35 milliliters of potassium bichromate or chromic acid saturated solution, 1 milliliter of sulfuric acid) soaked 5-15 minute, wash down with tap water; With clean gauze the water on the glass substrate is dried, dripped alcohol ether mixed solution (1: 1) with dropper again and, allow liquid flow, remove residual moisture all over the firmly drying of back, whole surface in substrate surface; Drip several alcohol ether mixed solutions (1: 1) mixed solution again, under infrared(ray)lamp, rub hard glass substrate surface, till anhydrous mark and stains, wipe once with clean gauze again with clean gauze, baking, till glass substrate is hot, observe the surface, till no scratch free from dust.
2, plated film: use vacuum vapour deposition, be lower than 8.0 * 10
-3Under the vacuum of handkerchief, depositing metallic films on a surface of this glass substrate is by weight that changes metal in the furnace pot or transmitance and the color of controlling metallic membrane by film-thickness monitoring.
3, be lower than 8.0 * 10 then
-3Under the vacuum of handkerchief, evaporation layer protective layer on metallic membrane, the gauge control of this protective layer is at the integral multiple of the 1-6 of 1/4 visible wavelength.
4, be lower than 8.0 * 10 at last
-3Under the vacuum of handkerchief, the stress equilibrium layer that evaporation one deck is identical with protective layer thickness on the another side of glass substrate comes part to revise the transmitance of glass, with the performance of further raising sheet glass, can be used for the stress of balanced protection layer simultaneously.The thickness of this stress equilibrium layer is identical with the thickness of protective layer, is controlled at the integral multiple of the 1-6 of 1/4 visible wavelength equally.
Above-mentioned vacuum vapour deposition is a method known to those skilled in the art, is example with the preferred coated glass of the present invention, adopts TS series optical vacuum coating equipment, and the concrete steps of vacuum vapour deposition are:
1, material loading
Open door for vacuum chamber, on electrode, load onto furnace pot and put into the wire of the evaporation of wanting; In crucible, be respectively charged into the oxide particle that needs evaporation protective layer and stress equilibrium layer, get final product a little less than mouth of pot; Install and measure the transmitance of coated glass and the contrast sheet glass of wavelength; Add the glass substrate workpiece; Fasten door for vacuum chamber.
2, vacuumize
Open holding pump, diffusion pump; The diffusion pump oil temperature can be carried out work (being preset as 180 ℃) after reaching working temperature; Open mechanical pump, slightly take out valve, begin to bleed; Drive vacuumometer; Open glass substrate Workpiece Rotating switch, speed setting is 15-25; Drive the baking switch, temperature is set at 200-300 ℃; Be evacuated to turn off when being lower than 5 handkerchiefs and slightly take out valve, open foreline valve, essence is taken out valve; Be evacuated to and be lower than 8.0 * 10
-3Can begin plated film behind the handkerchief;
3, plated film
Elder generation's evaporation metal, the vaporization voltage of opening electrode lie prostrate to 80-120, open baffle plate, if during by film-thickness monitoring control transmitance, close baffle plate when then waiting to arrive the transmitance of setting; If during the control of the amount by metal transmitance, the surplus of then observing metal in the furnace pot by view port is guaranteed that metal evaporates fully can close baffle plate; Close electrode supply and switch to the electron beam gun pattern.
Treat that vacuum tightness rises to 8.0 * 10 again
-3Begin the evaporation protective layer during handkerchief; Open scanning power supply heater supply and high-voltage power supply successively; Open the electron beam gun conversion crucible on the switchboard plates material to the oxide compound that protective layer is housed position; Adjust the energy and the sweep amplitude fritting material to be plated of electron beam gun; By the time open baffle plate after the material fusion to be plated, the beginning plated film, the reading that the viewing optics film-thickness monitoring shows is closed baffle plate when reaching the wavelength that needs; Regulate beam energy to zero, close diaxon scanning; Turn off essence successively and take out valve, foreline valve, vacuumometer, mechanical pump; Close baking switch, turn switch; Opening inflation valve after at least 5 minutes inflates to vacuum chamber; Take out the workpiece that plates.
The upset workpiece is the another side of coatings extremely, beginning evaporation stress equilibrium layer; Repeat the 3rd the step vacuumize; The conversion crucible is to the position of the oxide compound plating material that the stress equilibrium layer is housed; Adjust the energy and the sweep amplitude fritting material to be plated of electron beam gun; By the time open baffle plate after the material fusion to be plated, the beginning plated film, the reading that the viewing optics film-thickness monitoring shows is closed baffle plate when reaching the wavelength that needs; Regulate beam energy to zero, close diaxon scanning; Turn off essence successively and take out valve, foreline valve, vacuumometer, mechanical pump; Close baking switch, turn switch; Opening inflation valve after at least 5 minutes inflates to vacuum chamber; Take out the workpiece that plates.
Obtain the preferred coated glass of the present invention through above-mentioned vacuum vapour deposition.
Below in conjunction with the mode of accompanying drawing the present invention is described in further detail, but should not think limiting the scope of the invention with embodiment.
Embodiment 1
The chromed transmitance of making steaming is 50% ± 5 brown coated glass:
1, (ultrasonic power is 600W water white inorganic silicate glass substrate 1 to be put into the single-channel type Ultrasonic Cleaners, frequency is 28KHz), guarantee that the glass substrate of putting into cleaning machine all immerses distilled water, cleaned 15 minutes, under 40 ℃ temperature, toasted 15 minutes afterwards.
2, use optical vacuum coating equipment (rise and win TS-600ZZS), the vacuum evaporation hafnium metal powfer, vacuum is evacuated to 8 * 10
-3Begin plated film during handkerchief, control the transmitance of metallic membrane, when transmitance reaches 50%, stop plated film by OFTM 2000 full-automatic optical thickness control instrument.On glass substrate evaporation thickness be about the chromium metal film 2 of 45 nanometers.
3, then on chromium metal film 2 evaporation one deck silicon oxide as the protective layer 3 of metallic membrane 2, by setting OFTM 2000 full-automatic optical thickness control instrument, with the gauge control of this silicon oxide layer 1/4 visible wavelength at 4 times.
By visual observation, the color of this coated glass can not change along with the difference of viewing angle, and presents metalluster.
The transmitance of making evaporation nickel is 50% ± 5 blue coated glass:
1, (ultrasonic power is 600W water white inorganic silicate glass substrate 1 to be put into the single-channel type Ultrasonic Cleaners, frequency is 28KHz), guarantee that the glass substrate of putting into cleaning machine all immerses distilled water, cleaned 25 minutes, under 40 ℃ temperature, toasted 15 minutes afterwards.
2, use optical vacuum coating equipment (rise and win TS-600ZZS), the vacuum evaporation metallic nickel, vacuum is evacuated to 8 * 10
-3Begin plated film during handkerchief, control the transmitance and the color of metallic membrane by the weight that changes nickel wire in the evaporation unit, the transmitance of substrate is 50% ± 5 when using 0.1 gram nickel wire.On glass substrate evaporation thickness be about the metallic nickel film 2 of 25 nanometers.
3, then on metallic nickel film 2 evaporation one deck zirconium white as the protective layer 3 of metallic membrane, by setting OFTM 2000 full-automatic optical thickness control instrument, with the gauge control of this zirconia layer 1/4 visible wavelength at 3 times.
4, last, by setting OFTM 2000 full-automatic optical thickness control instrument, evaporation one layer thickness is that the silicon oxide of 3 times 1/4 visible wavelength is used for the transmitance of part correction coated glass as stress equilibrium layer 4 on the another side of glass substrate 1, with the performance of further raising sheet glass, simultaneously can balance substrate internal stress.
By visual observation, the color of this coated glass can not change along with the difference of viewing angle, and presents metalluster.
The transmitance of making evaporation tin and aluminium is 20% ± 5 dark yellow coated glass:
1, (ultrasonic power is 600W water white acrylic glass substrate 1 to be put into the single-channel type Ultrasonic Cleaners, frequency is 28KHz), guarantee that the glass substrate of putting into cleaning machine all immerses distilled water, cleaned 30 minutes, under 40 ℃ temperature, toasted 15 minutes afterwards.
2, use optical vacuum coating equipment (rise and win TS-600ZZS), vacuum evaporation metallic tin and aluminium, vacuum is evacuated to 8 * 10
-3Begin plated film during handkerchief, earlier zinc-plated, aluminize again, control the transmitance and the color of metallic membrane by changing the weight of metallic tin and aluminium in the evaporation unit, the transmitance of substrate is 20% ± 5 when using 0.1 gram tin and 0.1 gram aluminium.On glass substrate evaporation thickness be about the metallic tin of 50 nanometers and the film 2 of aluminium.
3, then on metallic membrane 2 evaporation one deck aluminum oxide as the protective layer 3 of metallic membrane 2, by setting OFTM 2000 full-automatic optical thickness control instrument, with the gauge control of this alumina layer 1/4 visible wavelength at 5 times.
4, last, by setting OFTM 2000 full-automatic optical thickness control instrument, evaporation one layer thickness is that the silicon oxide of 5 times 1/4 visible wavelength is used for the transmitance of part correction glass as the stress equilibrium layer on the another side of glass substrate 1, with the performance of further raising sheet glass, simultaneously can balance substrate internal stress.
The coated glass of embodiment 1-3 is carried out the performance test of sticking power, pencil hardness, intensity and erosion resistance, and test-results is listed in table 1.
By visual observation, the color of this coated glass can not change along with the difference of viewing angle, and presents metalluster.
Table 1
Test event | The equipment and the method for inspection | Allowed band | The result |
The sticking power experiment | Hundred lattice cutter ASTM D3359 spacings: 1 millimeter pull-up angle: 90 ° of adhesive tape: 3M600 | 〉=3B | Embodiment 1:5B embodiment 2:5B embodiment 3:5B |
Pencil hardness test | Pencil hardness meter ASTM D3363 load: the 750g pencil: the trade mark is the UNI of Mitsubishi | 〉=H | Embodiment 1:4H embodiment 2:3H embodiment 3:5H |
Free drop test | Height of fall 1.5M | Product does not have embrittlement | Embodiment 1: intact embodiment 2: intact embodiment 3: intact |
Anti-solvent experiment | Solvent: 1, (boiling range is 60-95 ℃ to gasoline, octane content about 95%) 2, after Virahol (purity>98%) 3, artificial perspiration (PH 6.50 ± 0.10) soaked into above-mentioned three kinds of solvents with soft cloth respectively, |
Visual surface after 2 hours does not allow vestige | Embodiment 1: no sharp trace embodiment 2: no sharp trace embodiment 3: no sharp trace |
Artificial perspiration's compounding method is in the table: adding 1 successively and restrain analytically pure urea, the analytically pure sodium-chlor of 5 grams, the analytically pure lactic acid of 1.14 grams in 900 ml distilled waters, fully stir, is 1% ammoniacal liquor adjusting pH value to 6.50 ± 0.10 with concentration.
The presentation of results of table 1, the sticking power of coated glass of the present invention, hardness, intensity and solvent resistance portion have obviously surpassed the scope that above-mentioned standard allows.
Claims (10)
1. coated glass, this coated glass comprises glass substrate and rete, it is characterized in that, and described rete is a metallic membrane, and described metallic membrane is attached directly at least one surface of glass substrate.
2. coated glass according to claim 1, wherein, described metallic membrane is one or more the metallic membrane that is selected from silver, aluminium, tin, copper, chromium and the nickel.
3. coated glass according to claim 1 and 2, wherein, the thickness of described metallic membrane is the 20-60 nanometer.
4. coated glass according to claim 1 and 2, wherein, described coated glass also comprises protective layer, described protective layer is attached on the metallic membrane.
5. coated glass according to claim 4, wherein, described protective layer is one or more the protective layer that is selected from silicon oxide, aluminum oxide and the zirconium white.
6. coated glass according to claim 4, wherein, the thickness of described protective layer is the 55-600 nanometer.
7. coated glass according to claim 6, wherein, the thickness of described protective layer is the integral multiple of the 1-6 of 1/4 visible wavelength.
8. coated glass according to claim 4, wherein, described metallic membrane is attached directly on the surface of described glass substrate, also is attached with the stress equilibrium layer on another surface of described glass substrate.
9. coated glass according to claim 8, wherein, described stress equilibrium layer is one or more the stress equilibrium layer that is selected from silicon oxide, aluminum oxide and the zirconium white, the thickness of described stress equilibrium layer is identical with the thickness of described protective layer.
10. coated glass according to claim 1, wherein, described glass substrate is silicate glass or acrylic glass.
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CNA2006101705965A CN101209904A (en) | 2006-12-26 | 2006-12-26 | Plated film glass |
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CNA2006101705965A CN101209904A (en) | 2006-12-26 | 2006-12-26 | Plated film glass |
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CN112071930A (en) * | 2020-09-17 | 2020-12-11 | 山东金晶科技股份有限公司 | Blue cover plate glass for building integrated photovoltaic and preparation method thereof |
CN114280702A (en) * | 2021-11-12 | 2022-04-05 | 福建戴斯光电有限公司 | Ultraviolet metal film layer protection process and protective layer of ultraviolet metal film |
CN114280702B (en) * | 2021-11-12 | 2024-04-30 | 福建戴斯光电有限公司 | Ultraviolet metal film layer protection process and ultraviolet metal film protection layer |
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