CN101203273A - A product release system for atomizing cosmetic hair compositions containing cationic polymers - Google Patents

Abstract

A product release system for atomizing cosmetic hair compositions is described, which has (a) pressure-resistant packaging, (b) a capillary-containing spray head, and (c) a propellant-containing cosmetic composition, which contains at least one film-forming, hair-setting, or hair-conditioning cationic polymer. The atomization is done using the capillary. The capillary preferably has a diameter of 0.00394 (0.1) to 0.03937 in (1 mm) and a length of 0.1968 (5) to 3.937 in (100 mm). The spray rate is preferably 0.00035 (0.01) to 0.176 oz/s (5 g/s). The composition can particularly be a gel, wax, or emulsion.

Description

Be used for to comprise the product release system of the hair dressing composition atomizing of cationic polymer

Theme of the present invention is to be used to atomize the product release system of cosmetic composition, the cosmetic composition that described system has withstand voltage packing, comprises fog-spray nozzle capillaceous and comprise propellant, and wherein said compositions comprises at least a film forming, hair arrangement (hair-setting) or hair-conditioning cationic polymer.Therefore, theme of the present invention relates to the correlation method that is used for hair treatment.

Many hair caring products comprise cationic polymer as hair arrangement or hair-conditioning ingredients.The cationic polymer of form of foam can provide good cardability to hair later in being administered to wet sending out, and can obtain good an arrangement property and the good retentivity done.In shampoo, permanent wave solution, solid product and hair colourant, use cationic polymer to provide good rational and good the doing of wet Comb to send out retentivity.They can provide the stationarity of hairdo and increase does the hair volume of sending out.Yet, up to the present, cationic polymer is not used in the product of viscosity higher such as gel, wax, hair caring frost or inorganic agent widely, this is because the denseness of compositions and product and the difficulty of using that causes thus increase, and makes the advantage of cationic polymer to realize fully on hair.

From WO 03/051523 A1, recognize the method that is used for the atomization of liquid.According to the method, can form spraying by using capillary tube.But the application relevant with the atomized liquid compositions only described.The device that is used for the fluid product atomizing has been described, wherein by using capillary tube to form spraying among WO 03/051522 A2.Atomize but only described the use fluid composition, described fluid composition also can be highly viscous, yet wherein 5,000mPa.s is mentioned maximum sprayable viscosity.

Even need under administration form, still can to realize as pomade, typing gel, hair caring frost or creaminess inorganic agent the hair arrangement of cationic polymer and hair-conditioning advantageous feature and can with as described in the product that combines of advantageous feature and these administration forms.Specifically, theme of the present invention is distributivity, bulk effect, arrangement effect and/or hairdo stationarity, cardability, hair luster and/or the retentivity of conventional Hiar treatment compositions on hair that can not use as spraying before further improving, and/or with the hair of described compositions-treated.

Theme of the present invention is to be used to atomize the product release system of cosmetic composition.Described product release system has following feature:

(a) withstand voltage packing,

(b) comprise fog-spray nozzle capillaceous and

(c) comprise the cosmetic composition of propellant,

Wherein use capillary tube to atomize, and described compositions comprise at least a film forming, hair arrangement or hair-conditioning cationic polymer.

Term " atomizing " should be understood to mean with the loss particle form and come release products.The loss granule can have different shapes, denseness and size.The character of atomizing particle can comprise from the fine aerosol atomisation to liquid drops, snowflake shape drop, solid spraying thin slice and foamy all character of spraying.

Unless clearly indicate in addition, hereinafter the one-tenth component shown in (as percentage by weight %) is a benchmark with the base composition that does not contain propellant all.Advancing dosage is benchmark with the total composition that comprises propellant.

Described compositions nonfluid preferably under 25 ℃, and/or have greater than 5, the viscosity of 000mPa.s is (at 25 ℃ temperature and 12.9s ^-1Shear rate under, use HAAKE VT-550 flow graph, SV-DIN test body to measure).

According to the present invention, the character that stand-by compositions is relevant with denseness is benchmark (unless clearly indicating in addition) with the base composition that does not contain propellant.According to the present invention, the on-liquid compositions significantly is can not liquidity composition, and this can determine according to the fact that for example they can not flow down from the glass surface of 45 ° of inclinations under 25 ℃ temperature.Gel combination is characterised in that the oscillographic measurement that uses in the typical measuring range (0.01 to 40Hz), and the storage modulu G ' under 25 ℃ is greater than loss modulus G ".

At 25 ℃ temperature and 12.9s ^-1Shear rate under, use HAAKE VT-550 flow graph, SV-DIN test body to measure, the viscosity of stand-by compositions is preferably greater than 5,000 to maximum 100,000, and especially preferred 10,000 to 50,000mPa.s, or extremely preferred 25,000 to 35,000mPa.s.

The aerosol spray jar that is made of metal or plastics can be used as withstand voltage packing.Preferred metal is sheet tin and aluminum, and preferred plastics are polyethylene terephthalate.

Having the suitable spraying system that contains the capillary pipe spray head is described among WO 03/051523 A1 and WO 03/051522 A2.By fog-spray nozzle, use capillary tube to form spraying.Capillary tube preferably has 0.1 to 1mm, or especially 0.2 to 0.6mm diameter and preferred 5 to 100mm, or 5 to 50mm length especially.The spraying principle also was described in the 6th to 11 page of 2005 " AerosolEurope " the 13rd the 1st phase of volume.Spraying system is based on the capillary tube atomizing principles.Conventional swirl nozzle and absorption pipe (if necessary) are replaced by capillary tube.Compare with conventional spraying system, no longer need to consume energy and aerosol can content eddy flow that propellant is strengthened, and required solvent is to the high dilution of product.Valve in fog-spray nozzle (broad) capillary tube is during towards the outlet opening direction, even only use a spot of propellant, described product also can rise along taking in capillary wall, and is pushed into.So, the whiz from the liquid surface of the droplet in the propellant that flows, and continue to move swiftly as aerosol.Do not flow owing to both there has been the spin chamber to suppress product, can utilize, so the energy in the system can be used to produce required spraying more effectively yet without any atomizer.Can be by selecting the capillary geometry shape and by the intrinsic pressure spray rate of regulating that propellant or propellant mixture produced.Preferred spray rate is 0.01058 to 0.5g/s, especially is 0.1 to 0.3g/s.Can be by selecting capillary geometry shape and size intrinsic pressure or that composition viscosity is regulated the spray droplet that is produced by atomizing.By with trade name TRUSPRAY ^Derive from the product of Boehringer IngelheimmicroParts GmbH, the capillary tube atomization system that can obtain to suit.

Preferred droplets size distribution is that wherein dv (50) value is for example 50 to 100 μ m, maximum is those of 100 μ m, especially preference is as 70 to 90 μ m, maximum is those of 90 μ m, and/or wherein dv (90) value is for example 90 to 160 μ m, maximum is those of 160 μ m, and especially preference is as 115 to 150 μ m, and maximum is those of 150 μ m.Dv (50) or dv (90) value provide 50% or 90% the maximum gauge that all drops had.For example, by means of granule determinator,, can measure droplets size distribution as Malvern granulometry device based on laser beam diffraction.It also is preferred can forming the denseness thin slice similar to snow or the compositions of foam (spray foam) after ejection capillary pipe spray system.

Stand-by propellant can be selected from lower paraffin hydrocarbon, especially the hydrocarbon of C3 to C5, for example normal butane, iso-butane and propane or their mixture; And dimethyl ether or halothane hydrocarbon, as F 152a (1, the 1-Difluoroethane) or F 134 (tetrafluoroethane); And other gaseous propellant that exists when considering pressurization, as N ₂, N ₂O and CO ₂And the mixture of above-mentioned propellant.Described propellant is preferably selected from propane, normal butane, iso-butane, dimethyl ether, fluorinated hydrocarbons and their mixture.In addition, the content of propellant is preferably 15 to 85% weight, especially preferred 25 to 75% weight.

Described compositions comprises beauty treatment and goes up acceptable solvent, preferred water medium, pure medium or aqueous alcohol medium.Lower alcohol with 1 to 4 carbon atom as ethanol and isopropyl alcohol, can be used as alcohol and involved, and especially the typical case is used for those of cosmetic use.Described compositions can be in 2.0 to 9.5 pH scope.Especially preferred 4 to 8 pH scope, precondition are not have special administration form to need other pH value.Can comprise boiling point and be lower than 400 ℃ organic solvent or solvent mixture as additional cosolvent, its content is 0.1 to 15% weight, or preferred 1 to 10% weight.Hydrocarbon of non-branching or branching (as pentane, hexane, isopentane) and cycloalkane (as Pentamethylene. and cyclohexane extraction) are particularly suited for as additional cosolvent.These volatile hydrocarbon also can be used as propellant.Other especially preferred water-soluble solvent is glycerol, ethylene glycol and propylene glycol, and its content mostly is 30% weight most.

Product release system can be used to hair treatment as described in the present invention.Described compositions can be the reagent that is used for hair-care, repairs product or hair conditioner as hair, and it for example can be used as leave or rinse-off products is used; Be used for that hairdo is provisional to reshape and/or fixed reagent (setting agent), for example hair styling agents, hair lacquer, hair jelly, pomade, typing frost etc.; Permanent, impermanency or provisional hair coloring agents, for example oxidizing hair coloring agents or non-oxidizable hair coloring agents or bleaching hair agent; Hair structure persistency rebuild agent, for example gentleness is alkaline or tart agent for permanent hair waving or the hair straighten form that comprises Reducing agent, or comprises the hair-waving shape-fixing agent form of oxidant.

The content of described cationic polymer in stand-by compositions as described in the present invention is preferably 0.01 to 20% weight, or 0.05 to 10% weight, especially preferred 0.1 to 5% weight.Described polymer can be synthetic or natural polymer.Described polymer is preferably also can film forming hair arrangement and/or hair-conditioning polymer.Should be appreciated that natural polymer also can comprise the chemical modification of polymer of natural source.Be to be understood that, when being used for water, alcohol or aqueous alcohol solutions or dispersion with 0.01% to 5% amount, hair arrangement polymer is to show on hair that those that have that arrangement effect or demonstration have a stable hair style effect for example can increase those of the curling retentivity of water wave hair style, especially its " hair fixative " function be shown in 2004 in " International CosmeticIngredient Dictionary and Handbook " the 10th edition those.Be to be understood that, when being used for water, alcohol or aqueous alcohol solutions or dispersion with 0.01% to 5% amount, the hair-conditioning polymer is to show those with hair-conditioning or conditioning effect on hair, but for example improve cardability or increase those of glossiness, especially its " hair conditioner " function be shown in 2004 in " International Cosmetic Ingredient Dictionary and Handbook " the 10th edition those.Be to be understood that, when being used for water, alcohol or aqueous alcohol solutions or dispersion with 0.01% to 5% amount, film forming polymer be can those of deposited polymer thin film, especially its " film former " function are shown in 2004 in " International Cosmetic Ingredient Dictionaryand Handbook " the 10th edition on hair after the drying those.Described polymer also can have two or three characteristic that is called as " film forming ", " hair arrangement " and " hair-conditioning " simultaneously.

Cationic polymer is the polymer that has cation group or have amido (especially primary amine groups, secondary amine, tertiary amine groups or quaternary ammonium group).Cationic charge density preferred 1 is to 7meq/g.

Homopolymer or copolymer that suitable synthetic cationic polymers is made up of at least a following monomer: propenoic acid dialkyl aminoalkyl ester, methacrylate dialkyl aminoalkyl ester, acrylic acid alkyl monosubstituted amino Arrcostab and methacrylate alkyl monosubstituted amino Arrcostab, trialkyl isobutene. acyl-oxygen base alkylammonium, trialkyl acryloxyalkyl ammonium, dialkyl diallyl ammonium and vinyl quaternary ammonium monomer with cationic nitrogenous cyclic group.

Suitable cationic polymer preferably comprises quaternary ammonium group.Cationic polymer can be homopolymer or copolymer, and wherein said quaternary nitrogen group is included in the polymer chain or is preferred as the substituent group on one or more monomers.Comprise ammonium monomer can with the non-cationic monomer copolymerization.Suitable cationic monomer is the unsaturated compound with radical polymerization carried out of at least one cation group, especially the vinyl monomer that replaces of ammonium, for example have ring-type cation nitrogen groups such as pyridine, imidazoles or season ketopyrrolidine trialkyl methacryloxy alkylammonium, trialkyl acryloxyalkyl ammonium, dialkyl diallyl ammonium and vinyl quaternary ammonium monomer, as alkyl vinyl imidazoles, alkylvinylpyridines or alkyl vinyl ketopyrrolidine salt.Alkyl in these monomers is preferably low alkyl group, as C1 to C7 alkyl, and especially preferred C1 to C3 alkyl.

Comprise ammonium monomer can with the non-cationic monomer copolymerization.Suitable comonomer is for example acrylamide, MAAm, alkyl and dialkyl group acrylamide, alkyl and dialkyl group MAAm, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, caprolactam, vinyl pyrrolidone, vinyl esters such as vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, wherein the alkyl in these monomers is preferably C1 to C7 alkyl, and especially preferred C1 to C3 alkyl.

Suitable polymer with quaternary ammonium group is those of the called after polyquaternary ammonium salt (polyquaternium) described in " CTFA Cosmetic IngredientDictionary " for example, as methyl chloride vinyl imidazole/vinylpyrrolidone copolymer (polyquaternary ammonium salt-16) or quaternized vinyl pyrrolidone/dimethylaminomethyl ethyl acrylate copolymer (polyquaternary ammonium salt-11), and quaternary ammonium siloxanes polymer or siloxane oligomer, as the siloxane polymer (quaternary ammonium-80) that for example has the quaternary ammonium end group.

Preferred synthetic source cationic polymer:

Poly-(dimethyl diallyl ammonium chloride); The copolymer that forms by acrylamide and dimethyl diallyl ammonium chloride; By the formed quaternary ammonium polymer of the reaction of dithyl sulfate and a kind of copolymer, described copolymer is formed by vinyl pyrrolidone and dimethylaminoethyl methacrylate, and especially vinyl pyrrolidone/dimethylaminomethyl ethyl acrylate dimethyl sulfate copolymer is (as Gafquat ^755N, Gafquat ^734); The quaternary ammonium polymer that is formed by methyl chloride vinyl imidazole and vinyl pyrrolidone is (as LUVIQUAT ^HM 550); Polyquaternium-35; Polyquaternium-57; The polymer that forms by trimethyl ethyl methacrylate ammonium chloride; The terpolymer that is formed by dimethyl diallyl ammonium chloride, sodium acrylate and acrylamide is (as Merquat ^Plus 3300); The copolymer that forms by vinyl pyrrolidone, dimethylaminopropyl Methacrylamide and methacryl amido propyl group lauryl dimethyl ammonium chloride; The terpolymer that is formed by vinyl pyrrolidone, dimethylaminoethyl methacrylate and caprolactam is (as Gaffix ^VC 713); Vinyl pyrrolidone/methacryl amido oxypropyl trimethyl ammonium chloride copolymer is (as Gafquat ^HS 100); The copolymer that forms by vinyl pyrrolidone and dimethylaminoethyl methacrylate; The copolymer that forms by vinyl pyrrolidone, caprolactam and dimethylamino propyl acrylamide; By polyester or oligoester that the monomer of at least a first kind forms, the monomer of the described first kind is selected from the hydroxy acid that is replaced by at least one quaternary ammonium group; By the terminal dimethyl polysiloxane that replaces of quaternary ammonium group.

Derived from the suitable cationic polymer of natural polymer, especially be the cationic derivative of polysaccharide, the cationic derivative of cellulose, starch or melon ear for example.In addition, chitosan and chitosan derivative also suit.For example, cationic polysaccharide can be represented by following general formula

G-O-B-N ⁺R ^aR ^bR ^cX ^-

G is the anhydroglucose residue, for example starch or cellulose anhydroglucose;

B is a divalent linker, for example alkylidene, oxyalkylene, polyoxyalkylene or hydroxy alkylidene;

R ^a, R ^bAnd R ^cBe alkyl, aryl, alkylaryl, aralkyl, alkoxyalkyl or alkoxy aryl independently of one another, wherein any one can have maximum 18 carbon atoms, wherein R ^a, R ^bAnd R ^cIn the total number of carbon atoms maximum be preferably 20;

X is conventional counter anion, for example halogen ion, acetate, phosphate radical, nitrate anion or alkyl sulfate, preferably chloride ion.Cationic cellulose is those of INCI called after polyquaternary ammonium salt-4, polyquaternary ammonium salt-10 or polyquaternary ammonium salt-24 for example.Suitable cationic guar gum derivant has for example INCI name of Rhaball Gum CG-M 8M.

Especially preferred cationic active material is chitosan, chitosan salts and chitosan derivative.According to the present invention, spendable chitosan can be deacetylated wholly or in part chitin.As an example, molecular weight can be distributed in 20,000 to about 5,000,000g/mol, and for example 30,000 to 70, in the relative broad range of 000g/mol.Yet molecular weight is preferably greater than 100,000g/mo, and especially preferred 200,000 to 700,000g/mol.Degree of deacetylation is preferably 10% to 99%, and especially is preferably 60% to 99%.Preferred chitosan salts is for example Kytamer of Kytamer PC Chitosan PCA ^PC, it has molecular weight is about 200,000 to 300,000g/mol and degree of deacetylation are 70% to 85%.Can consider that chitosan derivative comprises quaternized, alkylation or hydroxyalkylation derivant for example ethoxy, hydroxypropyl or hydroxyl butyl chitosan.Chitosan or chitosan derivative are preferably to exist with form in them and in form or the part.With free basic group number is that benchmark calculates, and degree of neutralization is preferably at least 50%, especially preferably between 70% to 100%.For nertralizer, can use mineral acid compatible in any beauty treatment or organic acid basically, as formic acid, tartaric acid, malic acid, lactic acid, citric acid, 2-pyrrolidone-5-carboxylic acid, hydrochloric acid and other acid, wherein the 2-pyrrolidone-5-carboxylic acid is especially preferred.

The preferred cation polymer-derived is from natural source:

The cationic cellulose derivative that forms by hydroxyethyl-cellulose and diallyldimethylammonium chloride; The cationic cellulose derivative that the epoxide that is replaced by hydroxyethyl-cellulose and trimethyl ammonium forms; Chitosan and salt thereof; Hydroxyalkyl chitosan and their salt; Alkyl hydroxyalkyl chitosan and their salt; N-hydroxyalkyl chitosan alkyl ether.

In one embodiment, stand-by as described in the present invention compositions is a gel, and comprises at least a thickening agent or gel former, its content is preferably 0.01 to 20% weight, or 0.1 to 10% weight, 0.5 to 8% weight, or especially preferred 1 to 5% weight.The material that its " viscosifier " function is shown in 2004 in " International Cosmetic Ingredient Dictionary and Handbook " the 10th edition is especially suitable.Described thickening agent or gel former are preferably thickening polymer, and especially be preferably selected from the copolymer that the monomer by the monomer of at least a first kind and at least a second type forms, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, and the monomer of described second type is selected from acrylic acid and the formed ester of ethoxylized fatty alcohol; Cross linked polyacrylate; By the cross-linked copolymer that the monomer of the monomer of at least a first kind and at least a second type forms, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, and the monomer of described second type is selected from acrylic acid and the formed ester of C10 to C30 alcohol; By the copolymer that the monomer of the monomer of at least a first kind and at least a second type forms, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, and the monomer of described second type is selected from itaconic acid and the formed ester of ethoxylized fatty alcohol; The copolymer that forms by the monomer and the 3rd type monomer of the monomer of at least a first kind, at least a second type, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, the monomer of described second type is selected from itaconic acid and the formed ester of ethoxylation C10 to C30 alcohol, and described the 3rd type monomer is selected from C1 to C4 amino alkyl acrylates; By the copolymer that two or more monomers form, described monomer is selected from acrylic acid, methacrylic acid, acrylate and methacrylate; The copolymer that forms by vinyl pyrrolidone and acryloyl group dimethyl taurine ammonium; By acryloyl group dimethyl taurine ammonium be selected from the copolymer that the monomer of the ester of methacrylic acid and ethoxylized fatty alcohol forms; Hydroxyethyl-cellulose; Hydroxypropyl cellulose; The hydroxypropyl melon ear; The polyacrylic acid glycerol ester; The polymethyl acid glyceride; The copolymer that forms by at least a C2, C3 or C4 alkene and styrene; Polyurethane; The hydroxypropyl starch phosphate ester; Polyacrylamide; Form by maleic anhydride and methyl vinyl ether with the decadinene crosslinked copolymers; Algaroba glue; Guar gum; Xanthan gum; The dehydrogenation xanthan gum; Carrageenin; Karaya; Hydrolysed corn starch; The copolymer (as PEG-150/ stearyl alcohol/SMDI copolymer) that forms by poly(ethylene oxide), aliphatic alcohol and saturated methylenediphenyl diisocyanates.

In another embodiment, described compositions is a waxiness, and comprising at least a is down to be other water-insoluble material (if necessary) of liquid under solid wax and the room temperature at 25 ℃, the content of described wax is preferably 10 to 80% weight, especially be 20 to 60% weight, or 25 to 50% weight.The feature of waxiness denseness preferably is, and penetration number (measurement unit is 0,1mm, and test weight is 100g, and the testing time is 5 seconds, and probe temperature is 25 ℃; According to DIN 51 579) preferably in 2 to 70 scope, or especially in 3 to 40 scope, and/or described compositions can be melted, and has greater than 25 ℃, or preferably at 30 ℃ to 70 ℃, or especially preferred freezing point in 40 ℃ to 55 ℃ scopes.

Basically, the known any wax of prior art all can be used as wax or wax material.These waxes comprise that animal wax, vegetable wax, mineral wax and synthetic wax, microwax, coarse-grain wax, hard paraffin, mineral jelly, vaseline, ceresine, montanin wax, Fischer-Tropsch wax, polyolefin-wax such as polybutene, Cera Flava, lanocerin and derivant thereof such as wool wax alcohol, candelilla wax, Fructus Canarii albi wax, Carlow crust wax, Japan wax, Fructus Mali pumilae wax, hydrogenated fat, fatty acid ester, freezing point are 800 to 20 greater than 40 ℃ fatty glyceride, siloxane wax or hydrophilic wax such as molecular weight, 000, preferred 2,000 to 10, the high molecular weight polyethylene glycol wax of 000g/mol.Described wax or wax material have greater than 25 ℃, are preferably greater than the freezing point of 40 ℃ or 55 ℃.Penetration number (0,1mm, 100g, 5 seconds, 25 ℃; According to DIN 51 579) preferably 2 to 70, or especially in 3 to 40 scope.

In another embodiment, described compositions is an emulsion form, and wherein said denseness is preferably creaminess.Described emulsion can be water-in-oil emulsion, O/w emulsion, microemulsion or senior microemulsion.Except water, also preferably comprise and at least aly down be the hydrophobicity oil of liquid in room temperature (25 ℃), and at least a emulsifying agent.The content of oil is preferably 1 to 20% weight, or especially is 2 to 10% weight.Emulsifier content is preferably 0.01 to 30% weight, or especially is 0.1 to 20% weight, or 0.5 to 10% weight.

Appropriate liquid hydrophobicity oil has less than 25 ℃ fusing point and is preferably greater than 250 ℃, or especially greater than 300 ℃ boiling point.Also can use ethereal oil.Substantially, can use any oil of those skilled in the art known to usually.Suitable oil is vegetable oil or animal oil, mineral oil (liquid paraffin), silicone oil or their mixture.Hydrocarbon ils such as paraffin or isoparaffinic oil, squalane, by fatty acid and the formed oil of polyol (especially triglyceride), suit.Suitable vegetable oil is.For example, Oleum helianthi, Oleum Cocois, Oleum Ricini, lanolin oil, Jojoba oil, Semen Maydis oil, soybean oil.

Examples of suitable emulsifiers can comprise nonionic, anion, cation or zwitterionic surfactant.Suitable non-ionic surface active agent for example is:

-ethoxylized fatty alcohol, fatty acid, fatty glyceride or alkyl phenol, especially 2 to 30mol oxirane and/or 1 to 5mol expoxy propane and C8 to C22 aliphatic alcohol, with C12 to C22 fatty acid or with alkyl in contain the formed addition compound product of alkyl phenol of 8 to 15 carbon atoms

C12 to the C22 fatty-acid monoester and the diester of-1 to 30mol oxirane and glycerol addition compound product

The addition compound product of-5 to 60mol oxirane and Oleum Ricini or castor oil hydrogenated

-sucrose fatty acid ester, especially by sucrose and the formed ester of one or two C8 to C22 fatty acid, INCI: sucrose cocos nucifera oil acid esters, sucrose cocos nucifera oil acid esters, sucrose distearate, Surfhope SE Cosme C 1216, Sucrose myristate, sucrose oleate, sucrose palmitate, sucrose-ricinoleic acid ester, sucrose stearate

-by sorbitan and one, two or three C8 to C22 fatty acids are formed and ethoxylation degree is 4 to 20 ester

-fatty acid polyglycol glyceryl ester, especially by one, two or more C8 to C22 fatty acids with preferably have 2 to 20 the formed fatty acid polyglycol glyceryl of the unitary polyglycereol of glyceryl esters

-have alkyl androstanediol, oligomeric alkyl glucoside and the alkyl polyglucoside of C8 to C22 alkyl, as decyl glucoside or lauryl glucoside.

Suitable anion surfactant is for example carboxylate and carboxylate, alkyl ether sulfate and alkyl sulfate, fatty alcohol ether sulphate, sulfonic acid and their salt (as sulfosuccinate or fatty acid isethionate), phosphate ester and their salt, acylamino acid and their salt.Comprehensive description of these anion surfactants is found in announcement " FIEDLER-Lexikon derHilfsstoffe " [" FIEDLER-Dictionary of Adjuvants "] the 5th edition (2002) the 1st volume the 97th to 102, with this as detailed reference.Preferred surfactants is addition compound product and the formed ester of phosphoric acid, diester and/or three esters of 2 to 30mol oxirane and C8 to C22 aliphatic alcohol.

Suitable amphoteric surfactant is the derivant of aliphatic quaternary ammonium, Phosphonium and sulfonium compound for example, and it has following formula

R wherein ¹Representative has 8 to 18 carbon atoms and 0 to about 10 ethylene oxide units and 0 to 1 the unitary straight or branched alkyl of glycerol, alkenyl or hydroxyalkyl; Y is the group that comprises N-, P-or S-; R ²Be alkyl or monohydroxy alkyl with 1 to 3 carbon atom; If Y is a sulphur atom, then the x+y sum equals 2, and if Y be nitrogen-atoms or phosphorus atoms, then the x+y sum equals 3; R ³Be alkylidene or hydroxy alkylidene with 1 to 4 carbon atom, and Z ^(-)Represent carboxylate radical, sulfate radical, phosphonate radical or phosphate groups.Other amphoteric surfactantes also suit as betanin.The embodiment of betanin comprises C8 to C18 alkyl betaine, as cocoyl dimethyl carboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl-α-carboxyethyl betanin, cetyl dimethyl carboxymethyl betaine, oil base dimethyl-γ-carboxylic CAB and lauryl-two-(2-hydroxypropyl)-α-carboxyethyl betanin; C8 to C18 sulfobetaines is as cocoyl dimethyl methyl CAB, stearyl dimethyl methyl CAB, lauryl dimethyl sulfoethyl betanin, lauryl-two-(2-ethoxy) azochlorosulfonate propyl lycine; The carboxy derivatives of imidazoles, C8 to C18 alkyl dimethyl ammonium acetate, C8 to C18 alkyl dimethyl carbonyl ammonium carbamate and C8 to C18 fatty acid alkyl amido betaine are as fatty acid distribution of coconut oil amido propyl betaine and N-fatty acid distribution of coconut oil amide ethyl-N-[2-(carboxyl methoxyl group) ethyl] glycerol (CTFA title: cocoyl both sexes carboxyl glycinate).

Suitable cationic surfactant comprises amino or have the quaternized hydrophilic ammonium of positive charge in solution, and can be represented by following general formula

N ⁽⁺⁾R ¹R ²R ³R ⁴X ^(-)

R wherein ¹To R ⁴Representative has fat base, aryl, alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or the alkaryl of 1 to 22 carbon atom independently of one another, and wherein at least one group has at least 6, preferably at least 8 carbon atoms, and X ^-Represent anion, as halogen ion, acetate, phosphate radical, nitrate anion or alkyl sulfate, but preferred chloride ion.Except carbon atom and hydrogen atom, the fat base also can comprise cross-linking compounds or other group, as extra amino.The embodiment of suitable cationic surfactant is the chloride or the bromide salt of alkyl dimethyl benzyl ammonium, the chloride of alkyl trimethyl ammonium or bromide salt are (as cetyl trimethyl ammonium chloride or ammonium bromide, tetradecyl trimethyl ammonium chloride or ammonium bromide, alkyl dimethyl hydroxyethyl ammonium chloride or ammonium bromide, dialkyl dimethyl ammonium chloride or ammonium bromide), Fixanol (as chloride laurylpyridine or cetylpyridinium chloride), alkylamidoalkyl ethyl trimethyl ammonium ether sulfate, and chemical compound such as amine oxide (for example alkyl methyl amine oxide or alkyl aminoethyl dimethyl amine oxide) with cationic characteristic.Especially preferred C8-22 alkyl dimethyl benzyl ammonium chemical compound, C8-22 alkyl trimethyl ammonium compounds (especially cetyl trimethyl ammonium chloride), C8-22 alkyl dimethyl hydroxyethyl ammonium chemical compound, two-(C8-22 alkyl)-Dimethyl Ammonium chemical compound, C8-22 Fixanol, C8-22 alkylamidoalkyl ethyl trimethyl ammonium ether sulfate, C8-22 alkyl methyl amine oxide and C8-22 alkyl aminoethyl dimethyl amine oxide.

According to the present invention, stand-by cosmetic composition also can comprise at least a additional active cosmetic composition or the additive that is used for hair or skin/scalp.This active component or additive can be selected from for example hair-conditioning material, hair sorted material, silicone compounds, light protective material, antiseptic, pigment, direct osmosis type hair dyes, granular material, oxidant, Reducing agent and oxidizing hair coloring agents precursor product.According to type and specified purposes, described active component and content of additive are preferably 0.01 to 20% weight, or especially are 0.05 to 10% weight, or 0.1 to 5% weight.

In one embodiment, but reagent can comprise at least a polymer with anionic group or anionizable group as hair-conditioning or hair arrangement additive as described in the present invention, the content of described polymer is preferably 0.01 to 20% weight, or 0.05 to 10% weight, especially preferred 0.1 to 5% weight.But the group of anionization should be understood that it is acidic-group, as carboxylic acid, sulfonic acid or phosphate group, uses typical alkali, as organic amine or alkali metal or alkaline earth metal hydroxide, can make its deprotonation.Described anionic polymer can partially or completely be neutralized by antalkali.The reagent of preferred the above-mentioned type, wherein the acidic-group in the polymer has been neutralized 50% to 100%, or especially preferred 70% to 100%.Organic base or inorganic base can be used as nertralizer.Concrete alkali example also has amino alcohol inter alia as for example amino methyl propanol (AMP), triethanolamine or monoethanolamine, and ammonia, NaOH and KOH.

Described anionic polymer can be homopolymer or copolymer, has the monomeric unit that contains acidic-group derived from natural or synthetic source.If desired, described anionic polymer can with the comonomer polymerization that does not comprise acidic-group.Wherein the acidic-group that can be considered is sulfonic acid, phosphoric acid and hydroxy-acid group, wherein optimization acid's group.The suitable monomer that comprises acidic-group is for example acrylic acid, methacrylic acid .beta.-methylacrylic acid, maleic acid and maleic anhydride, maleic acid monoesters (the especially C1 to C7 of maleic acid alkyl monoester) and aldehydic acid or keto acid.The comonomer that is replaced by acidic-group is not an acrylamide for example, MAAm, alkyl and dialkyl group acrylamide, alkyl and dialkyl group MAAm, alkyl acrylate, alkyl methacrylate, the vinyl caprolactone, vinyl pyrrolidone, vinyl esters, vinyl alcohol, propylene glycol or ethylene glycol, the vinyl monomer that amine replaces is (as propenoic acid dialkyl aminoalkyl ester, the methacrylate dialkyl aminoalkyl ester, acrylic acid alkyl monosubstituted amino Arrcostab and methacrylate alkyl monosubstituted amino Arrcostab), wherein the alkyl in these monomers is preferably C1 to C7 alkyl, especially preferred C1 to C3 alkyl.

Suitable polymer with acidic-group can especially be the homopolymer of acrylic or methacrylic acid, (described monomer is selected from acrylate or methacrylate with monomeric copolymer in acrylic or methacrylic acid, acrylamide, MAAm and vinyl pyrrolidone), (described monomer is selected from and multifunctional dose of crosslinked or uncrosslinked vinyl esters for the homopolymer of .beta.-methylacrylic acid and .beta.-methylacrylic acid and monomeric copolymer, acrylate or methacrylate, acrylamide and MAAm).Suitable natural polymer is a lac for example.

Preferred polymers with acidic-group is:

The terpolymer that forms by acrylic acid, alkyl acrylate and N-alkyl acrylamide (the INCI name: acrylate/acrylamide copolymer), the terpolymer that forms by acrylic acid, ethyl acrylate and N tert butyl acrylamide especially; (the INCI name: VA/ crotonates copolymer) of crosslinked or uncrosslinked vinyl acetate/.beta.-methylacrylic acid copolymer; The copolymer that forms by one or more C1 to C5 alkyl acrylates, especially C2 to C4 alkyl acrylate and at least a monomer that is selected from acrylic or methacrylic acid (the INCI name: acrylate copolymer), as the terpolymer that forms by tert-butyl acrylate, ethyl acrylate and methacrylic acid; Kayexalate; Vinyl acetate/.beta.-methylacrylic acid/chain acid vinyl ester copolymer, for example copolymer that forms by vinyl acetate .beta.-methylacrylic acid and propionate; The copolymer that forms by vinyl acetate .beta.-methylacrylic acid and vinyl neodecanoate (INCI name: VA/ crotonates/vinyl propionate ester copolymer, VA/ crotonates/vinyl neodecanoate copolymer); Acrylic acid aminomethyl methacrylate-trimethoxysilyl propylmethacrylate copolymer; By vinyl pyrrolidone and at least another kind be selected from the copolymer that the monomer of acrylic acid and methacrylic acid and (if necessary) acrylate and methacrylate forms; The copolymer that forms by methyl vinyl ether and maleic acid mono alkyl ester (INCI name: the butyl ester of the ethyl ester of PVM/MA copolymer, PVM/MA copolymer); By allyl methacrylate and at least another kind be selected from the amino methyl propylate of the copolymer that the monomer of acrylic acid and methacrylic acid and (if necessary) acrylate and methacrylate forms; The cross-linked copolymer that forms by ethyl acrylate and methacrylic acid; The copolymer that forms by vinyl acetate, maleic acid one positive butyl ester and isobornyl acrylate; Be selected from the copolymer that the monomer of acrylic acid and methacrylic acid and (if necessary) acrylate and methacrylate forms by two or more; The copolymer that forms by octyl acrylamide and at least a monomer that is selected from acrylic acid and methacrylic acid and (if necessary) acrylate and methacrylate; By the polyester that diethylene glycol, cyclohexanedimethanol, M-phthalic acid and sulfoisophthalic acid form, the alkyl in the wherein above-mentioned polymer preferably has 1,2,3 or 4 carbon atom usually.

In one embodiment, reagent can comprise at least a amphion and/or amphiphilic polymers as hair-conditioning or hair arrangement additive as described in the present invention, the content of described polymer is preferably 0.01 to 20% weight, or 0.05 to 10% weight, or especially preferred 0.1 to 5% weight.Amphoteric ion polymer has at least one anionic charge and at least one cationic charge simultaneously.Amphiphilic polymers shows to have at least one acidic-group (as carboxylic acid or sulfonic acid group) and at least one basic group (as amino).Use typical alkali,, can make the acidic-group deprotonation as organic amine or alkali metal or alkaline earth metal hydroxide.

Preferred amphion or amphiphilic polymers are:

Copolymer, the especially copolymer that forms by octyl acrylamide, acrylic acid, metering system acid butyl amino ethyl ester, methyl methacrylate and hydroxypropyl methacrylate that forms by alkyl acrylamide, methacrylic acid alkylaminoalkyl and two or more monomers that is selected from acrylic acid and methacrylic acid and (if necessary) their esters (INCI name: octyl acrylamide/acrylate/fourth amino methyl ethyl acrylate copolymer); By the monomer of at least a first kind with quaternary ammonium group and the copolymer that at least a monomer with second type of acidic-group forms; The copolymer, the especially copolymer that forms by lauryl acrylate, stearyl acrylate base ester, ethylamine oxide methacrylate and at least a monomer that is selected from acrylic acid and methacrylic acid and (if necessary) their esters that form by acrylate fatty alcohol, alkyl amine oxide methacrylate and at least a monomer that is selected from acrylic acid and methacrylic acid and (if necessary) acrylate and methacrylate; The copolymer that forms by methacryloyl ethyl betanin and at least a monomer that is selected from methacrylic acid and methacrylate; The copolymer that forms by acrylic acid, methylmethacrylate and Methacrylamide oxypropyl trimethyl ammonium chloride (INCI name: polyquaternary ammonium salt-47); The copolymer that forms by acrylamide propyl trimethyl ammonium chloride and acrylate, or copolymer (the INCI name: polyquaternary ammonium salt-43) that forms by acrylamide, acrylamide propyl trimethyl ammonium chloride, 2-amido propyl acrylamide sulphonic acid ester and dimethylamino propylamine; Can by season the crotonyl betanin or season crotonyl the betaine ester oligomer or the polymer that make.

In one embodiment, reagent of the present invention comprises 0.01 to 15% weight, or at least a synthetic or natural nonionic film forming polymer of preferred 0.5 to 10% weight.

Suitable synthetic non-ionic polymers is homopolymer or the copolymer that is formed by at least a following monomer: vinyl lactam, as vinyl pyrrolidone or caprolactam; Vinyl esters is as vinyl acetate; Vinyl alcohol, vinyl formamide, acrylamide, MAAm, alkyl acrylamide, dialkyl group acrylamide, alkyl MAAm, dialkyl group MAAm, alkyl acrylate, alkyl methacrylate, alkyl maleimide such as ethyl maleimide or ethoxy maleimide and aklylene glycol such as propylene glycol or ethylene glycol, wherein alkyl in these monomers and/or alkylidene are preferably C1 to C7 alkyl, or especially preferred C1 to C3 alkyl.

Suitable homopolymer is those that are for example formed by caprolactam, vinyl pyrrolidone or N-vinyl formamide.Other suitable synthetic non-ionic polymers is for example polyacrylamide, polyethylene/polypropylene glycol copolymer, the copolymer that forms by vinyl pyrrolidone and vinyl acetate, by the terpolymer that vinyl pyrrolidone, vinyl acetate and propionate form, polyacrylamide; Polyvinyl alcohol, and polyethylene/polypropylene glycol copolymer.Suitable natural film forming polymer is for example based on saccharide those, and preferred glucosan is as cellulose and derivant thereof.Specifically, appropriate derivative be have alkyl and/or hydroxyalkyl substituent those, wherein alkyl can have for example 1 to 20, or preferred 1 to 4 carbon atom, as hydroxy alkyl cellulose.Preferred non-ionic polymers is: polyvinyl pyrrolidone, Vinylcaprolactam homopolymer, vinyl pyrrolidone/vinyl acetate copolymer, polyvinyl alcohol, isobutene ./ethyl maleimide/ethoxy maleimide copolymer; The copolymer that forms by vinyl pyrrolidone, vinyl acetate and propionate.

In one embodiment, reagent comprises at least a silicone compounds as the hair-conditioning additive as described in the present invention, and the content of described silicone compounds is preferably 0.01 to 15% weight, or especially preferred 0.1 to 5% weight.Described silicone compounds comprises volatility and nonvolatile siloxanes and solvable and be insoluble in siloxanes in the described reagent.An embodiment is high-molecular weight siloxanes, and described siloxanes has 0.001m under 25 ℃ ²/ s (1,000cSt) to 2m ²/ s (2,000,000cSt), or preferred 0.01m ²/ s (10,000cSt) to 1.8m ²/ s (1,800,000cSt), or 0.1m ²/ s (100,000cSt) to 1.5m ²/ s (1,500, viscosity 000cSt).Described silicone compounds comprises many alkyl and poly-aryl siloxanes, especially has methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl group.Polydimethylsiloxane, poly-di-ethyl siloxane and PSI are preferred.The arylation siloxanes of glossiness also preferably can be provided, and described siloxanes has and is at least 1.46, or is at least 1.52 refractive index.Specifically, described silicone compounds comprises INCI called after ring-type polymethyl siloxane, polydimethylsiloxane, dimethiconol, dimethicone copolyol, polyphenylene trimethicone, amino-terminated polydimethylsiloxane, the trimethyl silyl ammonia material for polydimethylsiloxane, siloxy silicic acid stearyl, poly methyl silsesquioxane and polydimethylsiloxane.Silicone resin and silicone elastomer also suit, and wherein these are highly cross-linked siloxanes.Preferred siloxanes is: the ring-type dimethyl siloxane, linear polydimethylsiloxane-, the block polymer that forms by polydimethylsiloxane and poly(ethylene oxide) and/or poly(propylene oxide), polydimethylsiloxane with end or side poly(ethylene oxide) or poly(propylene oxide) residue, polydimethylsiloxane with terminal hydroxyl, the polydimethylsiloxane that phenyl replaces, siloxane emulsion, silicone elastomer, siloxane wax, silicone gum (siliconegums), the amino siloxanes that replaces, and the siloxanes that is replaced by quaternary ammonium group.

In one embodiment, reagent comprises the light protective material as described in the present invention, and its content is preferably 0.01 to 10% weight, or 0.1 to 5% weight, or especially preferred 0.2 to 2% weight.Specifically, described smooth protective material comprises all mentioned among the EP 1 084 696 light protective materials.Preferred following these: the para-amino benzoic acid of 4-methoxy cinnamic acid-2-Octyl Nitrite, p-Methoxymethylcinnamate, 2-hydroxyl-4-methoxyl group benzophenone-5-sulfonic acid and many ethoxylations.

In one embodiment, reagent comprises 0.01 to 20% weight as described in the present invention, especially preferred 0.05 to 10% weight, or at least a hair-conditioning additive of extremely preferred 0.1 to 5% weight, and described additive is selected from betanin; Pantothenylol; The pantothenylol ether; Sorbitol; Protein hydrolysate; Plant extract; The A-B block copolymer that forms by alkyl acrylate and alkyl methacrylate; The A-B block copolymer that forms by alkyl methacrylate and acrylonitrile; The A-B-A block copolymer that forms by lactide and oxirane; The A-B-A block copolymer that forms by caprolactone and oxirane; The A-B-C block copolymer that forms by alkene or alkadiene chemical compound, styrene and alkyl methacrylate; The A-B-C block copolymer that forms by acrylic acid, styrene and alkyl methacrylate; Star block copolymer; Dissaving polymer; Dendritic; Intrinsic conductivity 3,4-polyethylene dioxythiophene and intrinsic conductivity polyaniline.

In one embodiment, reagent comprises 0.01 to 5% weight as described in the present invention, or at least a antiseptic of especially preferred 0.05 to 1% weight.Suitable antiseptic is that its " antiseptic " function is listed in those materials in " International Cosmetic Ingredient Dictionary and Handbook " the 10th edition, as phenyl phenol, benzyl p-hydroxybenzoate, butyl p-hydroxybenzoate, ethylparaben, p-Hydroxybenzoic acid isobutyl ester, p-Hydroxybenzoic acid isopropyl ester, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, butyl carbamic acid iodo propine fat, methyl dibromo glutaronitrile and DMDM Hydantoin.

A specific embodiments of the present invention relates to hair conditioner.Hair conditioner is for example take care of hair agent, inorganic agent, hair reparation product, purificant etc.Described hair conditioner comprises at least a hair-conditioning hair-conditioning ingredients, and described composition is selected from the surfactant of above-mentioned silicone compounds, cation or amine replacement and the polymer of cation or amine replacement.With the finished product is benchmark, and the consumption of described hair conditioner is between 0.01 to 10.0% weight, or especially between 0.01 to 5.0% weight.After on the hair that is administered to drying, humidity or moistening, hair conditioner can be retained on the hair as described in the present invention, or can be rinsed after suitable action time.The type that depends on hair action time.Generally speaking, can imagine action time between 0.5 to 30 minute, especially between 0.5 to 10 minute, and preferably between 1 to 5 minute.

Except above-mentioned cationic surfactant, cation that other is suitable or the amino surfactant that replaces are to have chemical formula R1-NH-(CH ₂) the n-NR2R3 structure

Or has a chemical formula R1-NH-(CH ₂) n-N ⁺R2R3R4X ^-Those of structure

Wherein R1 is acyl group or the alkyl residue with 8 to 24 carbon atoms; it can be side chain or straight chain, saturated or undersaturated; wherein acyl group and/or alkyl residue can comprise one or more OH groups; R2, R3 and R4 are independently of one another for having hydrogen, alkyl or the alkoxyalkyl residue of 1 to 6 carbon atom; they can be identical or different; saturated or unsaturated, and can be replaced X by one or more hydroxyls ^-Be anion, halogen ion or have general formula R SO especially ₃ ^-The chemical compound of structure, wherein R is the saturated or undersaturated alkyl residue with 1 to 4 carbon atom, and n is between 1 to 10, preferred 2 to 5 integer.

Described hair-conditioning reactive compound is preferably amidoamines and/or the quaternised amidoamines with above-mentioned chemical formula structure; wherein R1 is side chain or straight chain, the saturated or undersaturated acyl residue with 8 to 24 carbon atoms, and it can comprise at least one OH group.Preferred above-mentioned amine and/or quaternized amine, wherein having one among residue R2, R3 and the R4 at least is general molecular formula CH ₂CH ₂The residue of OR5 structure, wherein R5 is alkyl residue, hydroxyethyl or the H with 1 to 4 carbon atom.Can choose wantonly by quaternised suitable amine or amidoamines mainly is below the INCI called after these: the Oleum Ricini amido propyl betaine, Oleum Ricini amido propyl dimethylamine, Oleum Ricini amido propyl dimethyl lactate, Oleum Ricini amido propyl ethyl dimethyl ethyl ammonium sulfate, Oleum Ricini amido propyl trimethyl ammonium chloride, Oleum Ricini amido propyl trimethyl methyl ester ammonium sulfate, cocamido propyl betaine, cocamidopropyl propyl group dimethylamine, cocamidopropyl propyl group ethyl dimethyl ethyl ammonium sulfate, cocamidopropyl oxypropyl trimethyl ammonium chloride, mountain Yu amidopropyl dimethylamine, iso stearyl amidopropyl dimethylamine, stearyl amidopropyl dimethylamine, quaternary ammonium-33, endecatylene amidopropyl trimethyl methyl ester ammonium sulfate.

In a preferred embodiment, reagent comprises at least a pigment as described in the present invention.Described pigment can be the colored pigment that the dyeing effect is provided to product main body or hair, or they can be the gloss reinforcing pigments that the gloss effect is provided to product or hair.Painted or gloss effect in the hair is preferably provisional, and promptly they can be retained to when having one's hair wash next time, and can be by removing with typical shampoo washing hair.Described pigment is insoluble in the product main body, and its content is 0.01 to 25% weight, especially preferred 5 to 15% weight.Preferred granularity is 1 to 200 μ m, especially is 3 to 150 μ m, and especially is preferably 10 to 100 μ m.Described pigment is the coloring agent that is dissolved in hardly in the application media, and can be inorganic or organic.Inorganic-organic hybrid pigment also is possible.Preferred inorganic pigments.The advantage of inorganic pigment is that they have outstanding resistance to light, weather and temperature.Inorganic pigment can be made by natural source, is for example made by Chalk, ocher, umber, terre verte, burnt Terra di Siena or graphite.Described pigment can also be Chinese white, as titanium dioxide or zinc oxide; Black pigment is as iron oxide black; Colored pigment is as ultramarine or iron oxide red; Colour lustre pigments; Metal effect pigments; Pearlescent pigment; And fluorescence or phosphorescent pigment; If wherein at least a pigment is colored non-Chinese white, then be preferred.Metal-oxide, metal hydroxides and hydrated metal oxide, mixed dyes of Fe, sulfur-bearing silicate, metal sulfide, metal cyanide complex, metal sulfate, metal dichromate and metal molybdate and metal self (bronze pigments) are fit to.Titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI77492), rufous ferrum oxide (CI 77491), manganese violet (CI 77742), ultramarine (sulfo group lagoriolite, CI 77007, alizarol saphirol 29), hydrated chromium oxide (CI77289), barba hispanica (ferric ferrocyanide, CI77510) and carmine (fuchsin) be especially suitable.

Especially preferably the pigment that has pearly luster and color, it is based on by the Muscovitum and/or the Muscovitum of metal-oxide or metal oxychloride such as titanium dioxide or bismuth oxychloride coating, and other provides the material (if necessary) of color, as ferrum oxide, barba hispanica, ultramarine, carmine etc., and wherein can determine color by the thickness that changes coating.For example, this type of pigment can trade name Rona ^, Colorona ^, Dichrona ^And Timiron ^Sell by German Merck.

Organic pigment is for example natural pigment Ink sepiellae seu sepiae, Resina garciniae, bone black, Van Dyke palm fibre, indigo-blue, chlorophyll and other vegetable pigment.Synthetic organic pigment is for example AZOpigments, anthraquinone class, indigoid and diazine, quinacridone, phthalocyanine, isoindolinone, perylene, purple cyclic ketones, metal complex, alkali blue and diketo-pyrrolo pyrrole pigments.

In one embodiment, reagent comprises 0.01 to 10% weight as described in the present invention, or at least a granular material of especially preferred 0.05 to 5% weight.Suitable material is for example to be down solid and to be the material of particle form in room temperature (25 ℃).Silicon dioxide, silicate, aluminate, aluminium oxide, Muscovitum, salt (especially inorganic metal salt), metal oxides such as titanium dioxide, mineral and polymer beads are comparatively suitable.Granule is with insoluble, and the form of preferred stable dispersion is present in the reagent, and can be administered on the hair and after the solvent evaporates, be deposited on the hair with solid form.By provide enough big to compositions, can obtain stable dispersion can suppress the yield point that any solid particle sinks.By using suitable gel former, can obtain enough big yield point with suitable amount.Preferred granular material is silicon dioxide (silica gel, silicon dioxide) and slaine, especially inorganic metal salt, wherein especially preferred silicon dioxide.Slaine is for example alkali metal or alkaline-earth halide, as sodium chloride or potassium chloride; With alkali metal or alkali earth metal sulfate, as sodium sulfate or magnesium sulfate.

Another embodiment relates to and is used for the reagent that the hair structure persistency is rebuild, and it comprises at least a Reducing agent, keratin-reducing sulfhydryl compound especially, and its content is preferably 0.5 to 15% weight.Agent for permanent hair waving preferably exists with aqueous alkaline (pH=5 to 10) dosage form; it comprises the ammonium salt or the guanidinesalt of for example cysteine, cysteamine, N-acetyl group-L-cysteine, mercaptan carboxylic acid such as TGA or thiolactic acid or mercaptan carboxylic acid's salt such as TGA or thiolactic acid, with as the keratin-reducing sulfhydryl compound.By adding ammonia, organic amine, ammonium and basic carbonate or bicarbonate, obtain required basicity.Also can consider in water-bearing media, to have neutral or acid (pH=4.5 to 7) hair structure rebuild agent of effective dose sulphite or mercapto-carboxylic ester.Under first kind of situation, preferably, use sodium sulfite or potassium sulfite with the concentration of about 2 to 12% weight (pressing SO2 calculates), or the salt of sulphuric acid and organic amine, as monoethanolamine and guanidine.Under latter event, concentration that especially can about 5 to 50% weight (content that is equivalent to 2 to 16% weight TGAs) is used TGA monoethylene glycol ester or glyceride.The reagent that is used for the reconstruction of hair structure persistency as described in the present invention also can comprise the mixture of above-mentioned keratin-reducing chemical compound.For the oxidisability post processing, can use shape-fixing agent as described in the present invention, it comprises at least a oxidant.The oxidant embodiment that can be used in one of this type of shape-fixing agent is sodium bromate and Potassium bromate., Dexol, urea peroxide and hydrogen peroxide.The concentration of oxidant is about 0.5 to 10% weight.Be used for reagent that the hair structure persistency rebuilds and shape-fixing agent all can emulsion as described in the present invention form as described in the present invention and exist, or exist, especially can be used as cream, gel or paste to contain water base thickening form.

Stand-by as described in the present invention compositions also can comprise for example perfumery oil of additive component that any routine is used for hair treating agent; Opacifier is as glycol distearate, styrene/PVP copolymer or polystyrene; Wetting agent; Glossiness provides agent; The product dyestuff; Antioxidant; Every kind of components contents is preferably 0.01 to 10% weight, and wherein total content preferably is no more than 10% weight.

Theme of the present invention also relates to the method that is used for hair treatment, wherein

-product release system as described in the present invention is provided,

-via described product release system, can will be contained in wherein composition spray to hair, and

-described the compositions that is sprayed on the hair can rinse or be retained on the hair from hair after a period of time in effect.

With directly be sprayed on the hair on the contrary, also described product can be placed hands, or be placed on application device such as comb or the brush, be assigned to then in the hair, especially true when described product has the denseness of similar snow or its for thin slice or form of foam.

Product is subjected to their and adopts specific as described in the present invention stand-by aerosol spray system to carry out the constraint of specific application as described herein, it is characterized in that fabulous allocability, and the good hairdo stability with good retentivity and hair luster.Another advantage of product is as described herein, by simple change propellant, propellant compositions or propellant pressure, can regulate different spray characteristics exactly; These spray characteristics be before the following active ingredient compositions can not have.Described spray characteristics comprises from fine aerosol atomisation and snowflake shape drop to thin slice and foamy all character of spraying of spraying.

Following examples are applied to further specify theme of the present invention.

Embodiment

In following examples, independent active ingredient compositions is filled in the withstand voltage aerosol can with independent specified propellant, and is equipped with obtainable capillary pipe spray system of institute, as with trade name TRUSPRAY ^Derive from the capillary pipe spray system of Boehringer Ingelheim microParts GmbH.

Embodiment 1: the solid microemulsion

Active ingredient compositions:

Crude ash	Quantity
		Low viscosity paraffin	13.8g
Oil base polyoxyethylene ether-10	12.5g
		Oil base polyoxyethylene ether-5	12.5g
Polyquaternary ammonium salt-22	2.5g
		The PEG-40 castor oil hydrogenated	2.0g
Spice	0.2g
		Dekaben LMB	0.2g
Water	Surplus is to 100g

Denseness: translucent solid microemulsion

Fill with propellant:

	1-1	1-2	1-3	1-4	1-5
						Active ingredient compositions	50g	60g	70g	80g	40g
Propane/butane, 0.5MPa (4.8 crust)	50g		30g	10g	60g
						Propane/butane, 0.3MPa (2.7 crust)		40g
DME				10g

Spray characteristics:

1-1: dry gas colloidal sol mist

1-2: the aerosol mist that wets

1-3: snow shape drop form

1-4: spray foam

1-5: very fine dry gas colloidal sol

On the anthropometric dummy wig, carry out actual test.With one side of something in contrast, a left side of using aerosol 1-1 human body model wig is half of, and handles right half of with the highly viscous active ingredient compositions that does not contain propellant.Aerosol form is easy to distribute, and can use very exactly; And compare with pure active component, it is easier to be distributed in the hair.Compare with the hair of handling with pure active ingredient compositions, the hair of using the aerosol processing shows glossiness with remarkable improvement and the hairdo retentivity that significantly improves.

Embodiment 2: the Hairsetting gel

Active ingredient compositions:

Crude ash	Quantity
		Carbomer	1.5g
AMP	1.35g
		Polyquaternary ammonium salt-11	1.0g
PVP	2.0g
		Glycerol	1.5g
The PEG-40 castor oil hydrogenated	10g
		Spice	0.2g
Dekaben LMB	0.2g
		Water	Surplus is to 100g

Denseness: highly viscous clear gel

Fill with propellant:

	2-1	2-2	2-3	2-4	2-5
						Active ingredient compositions	50g	50g	50g	65g	40g
Propane/butane, 0.5MPa (4.8 crust)	50g
						Propane/butane, 0.3MPa (2.7 crust)		50g
DME			50g	35g	60g

Spray characteristics:

2-1: snow shape spraying

2-2: snow shape spraying

2-3: aerosol wet fog

2-4: spray foam

2-5: drop (snow shape)

Embodiment 3: the Hairsetting frost

Compositions:

Crude ash	Quantity
		Carbomer	1.00g
AMP	0.90g
		Polyquaternary ammonium salt-16	0.50g
Polyvinylpyrrolidone	3.00g
		Polydimethylsiloxane	15.00g
The PEG-40 castor oil hydrogenated	0.20g
		Spice	0.20g
Ethanol	25.00g
		Water	Surplus is to 100g

Denseness: highly viscous cream

Fill with propellant:

	3-1	3-2	3-3	3-4	3-5
						Active ingredient compositions	50g	50g	50g	60g	70g
Propane/butane, 0.5MPa (4.8 crust)	50g			40g	30g
						Propane/butane, 0.3MPa (2.7 crust)		50g
DME			50g

Spray characteristics:

2-1: aerosol mist

2-2: aerosol wet fog

2-3: spray foam

2-4: aerosol mist

2-5: aerosol mist

Embodiment 4: Hairsetting wax

Compositions:

Crude ash	Quantity
		Low viscosity paraffin	40.00g
Ceresin	20.00g
		Three ceteareth-4 phosphate ester	10.00g
The PEG-25 castor oil hydrogenated	2.50g
		Brazil wax	8.00g
Cera Flava	8.00g
		Propyl p-hydroxybenzoate	0.20g
Spice	0.30g
		Polyquaternary ammonium salt-4	2.50g
Ethanol	8.50g

Denseness: pasty state wax

Fill with propellant:

	4-1	4-2	4-3	4-4	4-5
						Active ingredient compositions	50g	50g	50g	70g	60g
Propane/butane, 0.5MPa (4.8 crust)	50g			30g	40g
						Propane/butane, 0.3MPa (2.7 crust)		50g
DME			50g

Real Execute example 5: the creaminess hair of similar emulsion is repaired product/handled thing

Active ingredient compositions:

Crude ash	Quantity
		16/octadecanol	10.00g
Low viscosity paraffin	4.00g
		Isopropyl myristate	4.00g
Polyquaternary ammonium salt-11	1.50g
		The cetyl trimethyl ammonium chloride	1.50g
Spice	0.40g
		Methyl parahydroxybenzoate	0.30g
Water	Surplus is to 100g

Denseness: thick cream

The propellant filler:

	5-1	5-2	5-3	5-4	5-5
						Active ingredient compositions	50g	50g	50g	60g	70g
Propane/butane, 0.5MPa (4.8 crust)	50g
						Propane/butane, 0.3MPa (2.7 crust)		50g
DME			50g	40g	30g

Spray characteristics:

5-1: snow shape spraying

5-2: snow shape spraying

5-3: aerosol wet fog

5-4: spray foam

5-5: spray foam

Embodiment 6: fragrant lotion

Compositions:

Crude ash	Quantity
		Stearyl alcohol	4.00g
Coconut oleoyl amine MEA	3.50g
		Polyquaternary ammonium salt-16	0.20g
The stearyl trimethyl ammonium chloride	1.50g
		Bisabolol	0.10g
Spice	0.20g
		The PHB methyl ester	0.20g
Water	Surplus is to 100g

Denseness: heavy-gravity suppurative mastitis

The propellant filler:

	6-1	6-2	6-3	6-4	6-5
						Active component	50g	50g	50g	60g	70g
Propane/butane, 0.5MPa (4.8 crust)	50g
						Propane/butane, 0.3MPa (2.7 crust)		50g
DME			50g	40g	30g

Spray characteristics:

6-1: snow shape spraying

6-2: snow shape spraying

6-3: aerosol wet fog

6-4: spray foam

6-5: spray foam

Claims (28)

1. the product release system of the hair dressing composition that is used to atomize, described system has following composition:

(a) withstand voltage packing,

(b) comprise fog-spray nozzle capillaceous and

(c) comprise the cosmetic composition of propellant,

Wherein use described capillary tube to atomize, and described compositions comprise at least a film forming, hair arrangement or hair-conditioning cationic polymer.

2. product release system as claimed in claim 1, wherein said capillary tube have the length of the diameter and the 0.1968-3.937 inch (5 to 100mm) of 0.00394-0.03937 inch (0.1 to 1mm).

3. the described product release system of each claim as described above, wherein said spray rate is 0.00035-0.176oz/s (0.01 to 5g/s).

4. the described product release system of each claim as described above, wherein said propellant is selected from propane, butane, dimethyl ether, fluorinated hydrocarbons and their mixture.

5. the described product release system of each claim as described above, wherein said cationic polymer is selected from homopolymer or the copolymer of being made up of at least a following monomer: propenoic acid dialkyl aminoalkyl ester, methacrylate dialkyl aminoalkyl ester, acrylic acid monoalkyl aminoalkyl ester and methacrylate alkyl monosubstituted amino Arrcostab, trialkyl isobutene. acyl-oxygen base alkylammonium, trialkyl acryloxyalkyl ammonium, dialkyl diallyl ammonium and the vinyl quaternary ammonium monomer with cationic nitrogenous cyclic group.

6. the described product release system of each claim as described above, wherein said cationic polymer is selected from the cationic cellulose derivative that is formed by hydroxyethyl-cellulose and diallyldimethylammonium chloride; The cationic cellulose derivative that the epoxide that is replaced by hydroxyethyl-cellulose and trimethyl ammonium forms; Poly-(dimethyl diallyl ammonium chloride); The copolymer that forms by acrylamide and dimethyl diallyl ammonium chloride; By the formed quaternary ammonium polymer of the reaction of dithyl sulfate and a kind of copolymer, described copolymer is formed by vinyl pyrrolidone and dimethylaminoethyl methacrylate; The quaternary ammonium polymer that forms by methyl chloride vinyl imidazole and vinyl pyrrolidone; Polyquaternium-35; The polymer that forms by trimethyl ethyl methacrylate ammonium chloride; Polyquaternium-57; By the terminal dimethyl polysiloxane that replaces of quaternary ammonium group; The copolymer that forms by vinyl pyrrolidone, dimethylaminopropyl Methacrylamide and methacryl amido propyl group lauryl dimethyl ammonium chloride; Chitosan and their salt; Hydroxyalkyl chitosan and their salt; Alkyl hydroxyalkyl chitosan and their salt; N-hydroxyalkyl chitosan alkyl ether; The copolymer that forms by caprolactam, vinyl pyrrolidone and dimethylaminoethyl methacrylate; The copolymer that forms by vinyl pyrrolidone and dimethylaminoethyl methacrylate; The copolymer that forms by vinyl pyrrolidone, caprolactam and dimethylamino propyl acrylamide; By polyester or oligoester that the monomer of at least a first kind forms, the monomer of the described first kind is selected from the hydroxy carboxylic acid that is replaced by at least one quaternary ammonium group.

7. the described product release system of each claim as described above, wherein said compositions is gel, wax or emulsion.

8. product release system as claimed in claim 8, wherein said gel type composition comprise the thickening agent or the gel former of at least a 0.01 to 20% weight.

9. product release system as claimed in claim 8, wherein said thickening agent or gel former are thickening polymer, described thickening polymer is selected from the copolymer that the monomer by the monomer of at least a first kind and at least a second type forms, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, and the monomer of described second type is selected from acrylic acid and the formed ester of ethoxylized fatty alcohol; Cross linked polyacrylate; By the cross-linked copolymer that the monomer of the monomer of at least a first kind and at least a second type forms, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, and the monomer of described second type is selected from acrylic acid and the formed ester of C10 to C30 alcohol; By the copolymer that the monomer of the monomer of at least a first kind and at least a second type forms, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, and the monomer of described second type is selected from itaconic acid and the formed ester of ethoxylized fatty alcohol; The copolymer that forms by the monomer and the 3rd type monomer of the monomer of at least a first kind, at least a second type, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, the monomer of described second type is selected from itaconic acid and the formed ester of ethoxylation C10 to C30 alcohol, and described the 3rd type monomer is selected from C1 to C4 amino alkyl acrylates; By the copolymer that two or more monomers form, described monomer is selected from acrylic acid, methacrylic acid, acrylate and methacrylate; The copolymer that forms by vinyl pyrrolidone and acryloyl group dimethyl taurine ammonium; By acryloyl group dimethyl taurine ammonium be selected from the copolymer that the monomer of the ester of methacrylic acid and ethoxylized fatty alcohol forms; Hydroxyethyl-cellulose; Hydroxypropyl cellulose; The hydroxypropyl melon ear; The polyacrylic acid glycerol ester; The polymethyl acid glyceride; The copolymer that forms by at least a C2, C3 or C4 alkene and styrene; Polyurethane; The hydroxypropyl starch phosphate ester; Polyacrylamide; Form by maleic anhydride and methyl vinyl ether with the decadinene crosslinked copolymers; Algaroba glue; Guar gum; Xanthan gum; The dehydrogenation xanthan gum; Carrageenin; Karaya; Hydrolysed corn starch; The copolymer that forms by poly(ethylene oxide), aliphatic alcohol and saturated methylenediphenyl diisocyanates.

10. what product release system as claimed in claim 7, wherein said waxiness compositions comprised at least a 10 to 80% weight is down solid wax at 77  (25 ℃).

11. product release system as claimed in claim 10, wherein said wax are selected from paraffin, polyolefin-wax, lanocerin, wool wax alcohol, candelilla wax, Fructus Canarii albi wax, Carlow crust wax, Japan wax, Fructus Mali pumilae wax, hydrogenated fat, fatty acid ester, fatty glyceride, fatty acid triglycercide, polyethylene glycol wax and siloxane wax.

12. product release system as claimed in claim 7, wherein said emulsion-type compositions is water-in-oil emulsion, O/w emulsion or microemulsion, and described compositions comprises oil and water that emulsifying agent that at least a content is 0.1 to 30% weight and at least a content are 1 to 20% weight.

13. product release system as claimed in claim 12, wherein said grease separation is from silicone oil, mineral oil, isoparaffinic oil, paraffin oil, squalane, sunflower seed oil, Oleum Cocois, Oleum Ricini, lanolin oil, Jojoba oil, Semen Maydis oil and soybean oil.

14. as claim 12 or 13 described product release systems, wherein said emulsifying agent is selected from the addition compound product of 2 to 30 moles of ethylene oxide and/or 1 to 5 mole of expoxy propane and C8 to C22 aliphatic alcohol; The addition compound product of 2 to 30 moles of ethylene oxide and/or 1 to 5 mole of expoxy propane and C12 to C22 fatty acid; The addition compound product that contains the alkyl phenol of 8 to 15 carbon atoms in 2 to 30 moles of ethylene oxide and/or 1 to 5 mole of expoxy propane and the alkyl; C12 to the C22 fatty-acid monoester and the diester of 1 to 30 moles of ethylene oxide and glycerol addition compound product; The addition compound product of 5 to 60 moles of ethylene oxide and Oleum Ricini or castor oil hydrogenated; The formed ester of the addition compound product of 2 to 30 moles of ethylene oxide and C8 to C22 aliphatic alcohol and phosphoric acid, diester and/or three esters; The ester of sucrose and one or two C8 to C22 fatty acid; By sorbitan and one, two or three C8 to C22 fatty acids are formed and ethoxylation degree is 4 to 20 ester; By one, two or more C8 to C22 fatty acids with have 2 to 20 formed polyglyceryl fatty acid esters of the unitary polyglycereol of glyceryl; Alkyl androstanediol; C8-22 alkyl dimethyl benzyl ammonium chemical compound; C8-22 alkyl trimethyl ammonium compounds; C8-22 alkyl dimethyl hydroxyethyl ammonium chemical compound; Two-(C8-22 alkyl)-Dimethyl Ammonium chemical compound; The C8-22 Fixanol; C8-22 alkylamidoalkyl ethyl trimethyl ammonium ether sulfate; C8-22 alkyl methyl amine oxide; C8-22 alkyl aminoethyl dimethyl amine oxide; Amido amine and quaternised amidoamines.

15. the described product release system of each claim as described above; wherein said compositions comprises at least a additional active component or additive, and described active component or additive are selected from hair-conditioning material, hair sorted material, silicone compounds, light protective material, antiseptic, pigment, direct osmosis type hair dyes, granular material, oxidant, Reducing agent and oxidative hair dyestuff former product.

16. product release system as claimed in claim 15, wherein said active component and content of additive are 0.01 to 20% weight.

17. as claim 15 or 16 described product release systems, wherein comprise non-ionic polymers as hair-conditioning or hair sorted material, described polymer is selected from polyvinylpyrrolidone, Vinylcaprolactam homopolymer, vinyl pyrrolidone/vinyl acetate copolymer, polyvinyl alcohol, isobutene ./ethyl maleimide/ethoxy maleimide copolymer; The copolymer that forms by vinyl pyrrolidone, vinyl acetate and propionate.

18. as claim 15 or 16 described product release systems, wherein comprise anionic polymer as hair-conditioning or hair sorted material, described polymer is selected from the terpolymer that is formed by acrylic acid, ethyl acrylate and N tert butyl acrylamide; Crosslinked or uncrosslinked vinyl acetate/.beta.-methylacrylic acid copolymer; The terpolymer that forms by tert-butyl acrylate, ethyl acrylate and methacrylic acid; Kayexalate; The copolymer that forms by vinyl acetate .beta.-methylacrylic acid and propionate; The copolymer that forms by vinyl acetate .beta.-methylacrylic acid and vinyl neodecanoate; Acrylic acid aminomethyl methacrylate-trimethoxysilyl propylmethacrylate copolymer; By the copolymer that vinyl pyrrolidone and another kind of at least monomer form, described monomer is selected from acrylic acid, methacrylic acid, acrylate and methacrylate; The copolymer that forms by methyl vinyl ether and maleic acid mono alkyl ester; The amino methyl propylate of the copolymer that forms by allyl methacrylate and another kind of at least monomer, described monomer is selected from acrylic acid, methacrylic acid, acrylate and methacrylate; The cross-linked copolymer that forms by ethyl acrylate and methacrylic acid; The copolymer that forms by vinyl acetate, maleic acid one positive butyl ester and isobornyl acrylate; By the copolymer that two or more monomers form, described monomer is selected from acrylic acid, methacrylic acid, acrylate and methacrylate; By the copolymer that octyl acrylamide and at least a monomer form, described monomer is selected from acrylic acid, methacrylic acid, acrylate and methacrylate; The polyester that forms by diethylene glycol, cyclohexanedimethanol, M-phthalic acid and sulfoisophthalic acid.

19. as claim 15 or 16 described product release systems, wherein comprise amphion or amphiphilic polymers as hair-conditioning or hair sorted material, described polymer is selected from the copolymer that is formed by octyl acrylamide, acrylic acid, metering system acid butyl amino ethyl ester, methyl methacrylate and hydroxypropyl methacrylate; By the copolymer that lauryl acrylate, stearyl acrylate base ester, ethylamine oxide methacrylate and at least a monomer form, described monomer is selected from acrylic acid, methacrylic acid, acrylate and methacrylate; By the copolymer that methacryloyl ethyl betanin and at least a monomer form, described monomer is selected from methacrylic acid and methacrylate; The copolymer that forms by acrylic acid, methylmethacrylate and Methacrylamide oxypropyl trimethyl ammonium chloride; By season the crotonyl betanin or season crotonyl the betaine ester oligomer or the polymer that make.

20. as each described product release system in the claim 15 to 19, wherein comprise at least a silicone compounds, described silicone compounds is selected from the ring-type dimethyl siloxane, linear polydimethylsiloxane-, the block polymer that forms by polydimethylsiloxane and poly(ethylene oxide) and/or poly(propylene oxide), polydimethylsiloxane with end or side poly(ethylene oxide) or poly(propylene oxide) residue, polydimethylsiloxane with terminal hydroxyl, the polydimethylsiloxane that phenyl replaces, siloxane emulsion, silicone elastomer, siloxane wax, silicone gum, the amino siloxanes that replaces, and the siloxanes that is replaced by one or more quaternary ammonium groups.

21. as each described product release system in the claim 15 to 20; wherein comprise at least a smooth protective material, described material is selected from the para-amino benzoic acid of 4-methoxy cinnamic acid-2-Octyl Nitrite, p-Methoxymethylcinnamate, 2-hydroxyl-4-methoxyl group benzophenone-5-sulfonic acid and many ethoxylations.

22. as each described product release system in the claim 15 to 21, wherein comprise active component and additive, described active component and additive are selected from betanin; Pantothenylol; The pantothenylol ether; Sorbitol; Protein hydrolysate; Plant extract; The A-B block copolymer that forms by alkyl acrylate and alkyl methacrylate; The A-B block copolymer that forms by alkyl methacrylate and acrylonitrile; The A-B-A block copolymer that forms by lactide and oxirane; The A-B-A block copolymer that forms by caprolactone and oxirane; The A-B-C block copolymer that forms by alkene or alkadiene chemical compound, styrene and alkyl methacrylate; The A-B-C block copolymer that forms by acrylic acid, styrene and alkyl methacrylate; Star block copolymer; Dissaving polymer; Dendritic; Intrinsic conductivity 3,4-polyethylene dioxythiophene and intrinsic conductivity polyaniline.

23. as each described product release system in the claim 15 to 22, wherein comprise at least a pigment, described pigment is selected from titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), rufous ferrum oxide (CI 77491), manganese violet (CI 77742), ultramarine (CI77007), hydrated chromium oxide (CI77289), barba hispanica (CI77510), bismuth oxychloride (CI77163), carmine (fuchsin), pigment with pearly luster and color, described pigment is based on by the Muscovitum of metal-oxide or metal oxychloride such as titanium dioxide or bismuth oxychloride coating, if necessary, also have other that material of color is provided, as ferrum oxide, barba hispanica, ultramarine or carmine, and wherein determine color by the thickness that changes described coating.

24. as each described product release system in the claim 15 to 23, wherein comprise at least a granular material, described granular material is selected from silicon dioxide, silicate, aluminate, aluminium oxide, Muscovitum, insoluble metallic salt, metal-oxide, mineral and insoluble polymer granule.

25. product release system as claimed in claim 1, wherein said compositions are gel and comprise

(a) at least a thickening polymer of 0.1 to 10% weight, described thickening polymer is selected from the copolymer that the monomer by the monomer of at least a first kind and at least a second type forms, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, and the monomer of described second type is selected from acrylic acid and the formed ester of ethoxylized fatty alcohol; Cross linked polyacrylate; By the cross-linked copolymer that the monomer of the monomer of at least a first kind and at least a second type forms, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, and the monomer of described second type is selected from acrylic acid and the formed ester of C10 to C30 alcohol; By the copolymer that the monomer of the monomer of at least a first kind and at least a second type forms, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, and the monomer of described second type is selected from itaconic acid and the formed ester of ethoxylized fatty alcohol; The copolymer that forms by the monomer and the 3rd type monomer of the monomer of at least a first kind, at least a second type, the monomer of the described first kind is selected from acrylic acid and methacrylic acid, the monomer of described second type is selected from itaconic acid and the formed ester of ethoxylation C10 to C30 alcohol, and described the 3rd type monomer is selected from C1 to C4 amino alkyl acrylates; By the copolymer that two or more monomers form, described monomer is selected from acrylic acid, methacrylic acid, acrylate and methacrylate; The copolymer that forms by vinyl pyrrolidone and acryloyl group dimethyl taurine ammonium; By acryloyl group dimethyl taurine ammonium be selected from the copolymer that the monomer of the ester of methacrylic acid and ethoxylized fatty alcohol forms; Hydroxyethyl-cellulose; Hydroxypropyl cellulose; The hydroxypropyl melon ear; The polyacrylic acid glycerol ester; The polymethyl acid glyceride; The copolymer that forms by at least a C2, C3 or C4 alkene and styrene; Polyurethane; The hydroxypropyl starch phosphate ester; Polyacrylamide; Form by maleic anhydride and methyl vinyl ether with the decadinene crosslinked copolymers; Algaroba glue; Guar gum; Xanthan gum; The dehydrogenation xanthan gum; Carrageenin; Karaya; Hydrolysed corn starch; The copolymer that forms by poly(ethylene oxide), aliphatic alcohol and saturated methylenediphenyl diisocyanates; With

(b) at least a film forming of 0.1 to 5% weight, hair arrangement or hair-conditioning cationic polymer, described polymer is selected from cationic polymer as claimed in claim 6.

26. product release system as claimed in claim 1, wherein said compositions are O/w emulsion, water-in-oil emulsion or microemulsion form and comprise

(a) at least a oil or the wax of 1 to 20% weight, described oil or wax are selected from silicone oil, mineral oil, isoparaffinic oil, paraffin oil, squalane, vegetable oil, paraffin, polyolefin-wax, lanocerin, wool wax alcohol, candelilla wax, Fructus Canarii albi wax, Carlow crust wax, Japan wax, Fructus Mali pumilae wax, hydrogenated fat, fatty acid ester, fatty glyceride, fatty acid triglycercide, polyethylene glycol wax and siloxane wax;

(b) at least a emulsifying agent of 0.01 to 30% weight; With

(c) at least a film forming of 0.01 to 20% weight, hair arrangement or hair-conditioning cationic polymer, described polymer is selected from cationic polymer as claimed in claim 6.

27. the purposes of the described product release system of each claim in carrying out hair treatment as described above.

28. a method that is used for hair treatment, wherein

-provide as each described product release system in the claim 1 to 26,

-via described product release system, will be included in wherein composition spray to hair, and

-described compositions rinsed or stays the described hair from described hair after effect a period of time.