CN101194626A - High-efficiency fungicide and method of preparing the same - Google Patents
High-efficiency fungicide and method of preparing the same Download PDFInfo
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- CN101194626A CN101194626A CNA2006101284608A CN200610128460A CN101194626A CN 101194626 A CN101194626 A CN 101194626A CN A2006101284608 A CNA2006101284608 A CN A2006101284608A CN 200610128460 A CN200610128460 A CN 200610128460A CN 101194626 A CN101194626 A CN 101194626A
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Abstract
The invention relates to a highly effective bactericidal agent, which is composed of preparation which is made from triazole-type medicament and auxiliary agent ethoxyl group modified poly trisiloxane which is filled in the agent, wherein the triazole-type medicament takes up 1%-70% of the weight of the preparation, and auxiliary agent ethoxyl group modified poly trisiloxane takes up 0.001-1% of the weight of the preparation. Because triazole-type bactericidal agent has excellent prevention and cure effect to pest diseases of various plants and crops, and further ethoxyl group modified poly trisiloxane is a novel organosilicon-type agricultural chemical auxiliary agent, which can improve the ductility of surfaces of plants which are difficult to be moistened and increase sprayed covering, and can evidently improve the penetration effect of the bactericidal agent.
Description
Technical field
The invention belongs to agricultural chemicals.
Background technology
Triazole bactericidal agent has fine control efficiency to root and the leaf diseases of various plants and crops, is used widely in agricultural production at present.But this agricultural chemicals osmotic effect is poor, if plant has the very difficult wetting then this medicine in surface (as the wax plant surface) just to be difficult to be ingested, must increase spray value for this crop.This has not only wasted medicine, does not also meet the requirement of pollution-less agriculture development.
Summary of the invention
It is good to the purpose of this invention is to provide a kind of osmotic effect, germicidal efficiency height, the agricultural chemicals of low toxicity, low-residual.
The present invention seeks to be achieved through the following technical solutions: this efficient germicide, the poly-trisiloxanes of auxiliary agent ethyoxyl modification that comprises the preparation of making by triazole type medicine and in preparation, added; Wherein triazole type medicine accounts for the 1%-70% of weight of formulation; The poly-trisiloxanes of auxiliary agent ethyoxyl modification is the 0.001%-1% of weight of formulation.
Described triazole type medicine is wherein a kind of during triazolone, alkene azoles alcohol or enemy's power are taken off.
Also contain wetting agent, dispersant and filler in the preparation, wherein wetting agent accounts for 5～30% of weight of formulation,, dispersant accounts for 5～35% of weight of formulation, filler accounts for 10～89% of weight of formulation.
Described wetting agent is at least a in natural wetting agent or the cationic wetting agent, and dispersant is at least a in industrial by-products and the anionic dispersing agent, and filler is at least a in mineral carrier or the synthetic vectors.
Described wetting agent is at least a in spaonin powder, silkworm excrement, neopelex, the washing powder, dispersant is at least a in lignosulfite, lignin, the alkyl naphthalene formaldehyde condensate sulfonates, and filler is at least a in kaolin, diatomite, the white carbon.
Making the method for described efficient germicide, is to take by weighing wherein a kind of in taking off of triazolone, the pure and mild enemy's power of alkene azoles by dosage, takes by weighing wetting agent, dispersant, filler and auxiliary agent by dosage again, then they is mixed.
Making the method for described efficient germicide, is to add the poly-trisiloxanes of auxiliary agent ethyoxyl modification by dosage in the wherein a kind of liquor in triazolone, alkene azoles alcohol or enemy's power are taken off, and they are mixed and make.
Because triazole bactericidal agent all has good control efficiency to the disease of various plants and crops, and the poly-trisiloxanes of ethyoxyl modification is a kind of novel silicone based insecticides adjuvant, it is to being difficult to the intake that wetting plant surface (as the wax plant surface) can improve ductility and increase agricultural chemicals, increasing spraying covers, can significantly improve the osmotic effect of bactericide, ductility, thus strengthen bactericidal activity, reduce the dispenser difficulty, reduced the agricultural chemicals usage amount.A kind of agricultural chemicals made from the poly-trisiloxanes of ethyoxyl modification that the inventor once took off triazolone, the pure and mild enemy's power of alkene azoles is wherein tested for many years, the result shows: the agricultural chemicals among 1 the present invention can significantly improve bactericidal activity, and wheat, paddy rice leaf diseases protection effect are improved 10-25% with former comparing with medicine;
2, can significantly reduce the usage amount of agricultural chemicals, reduce the agricultural chemicals drift, improve the agricultural chemicals availability.With former with medicine under the equal control efficiency, the usage amount of agricultural chemicals reduces 10-30% among the present invention.
3, no matter this medicine is the spraying of the amount of hanging down high concentration in use, or carries out high volume low-concentration spraying, and the insect pest of plant or crop is all had good control efficiency.
4, bactericide of the present invention can be widely used in the sterilization of various plants and crop.
Simple, easy to use advantage that this in addition agricultural chemicals also has manufacturing process.
Embodiment
Embodiment 1: the triazole type medicine in this efficient germicide is a triazolone, and it is the powder-type bactericide, and triazolone accounts for 1% of preparation in the bactericide, and wetting agent accounts for 5%, and dispersant accounts for 5%, and filler accounts for 89%; Auxiliary agent is 0.001% of a weight of formulation;
During manufacturing, take by weighing drug ingedient contained in the preparation earlier, that is: take by weighing the pure triazolone of 1 weight portion, the wetting agent of 5 weight portions, the dispersant of 5 weight portions, the filler of 89 weight portions, wherein wetting agent adopts spaonin powder, and dispersant is selected lignin for use, filler adopts kaolin, take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.001 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 2: the triazole type medicine in this efficient germicide is a triazolone, and it is the powder-type bactericide, and triazolone accounts for 70% of preparation in the bactericide, and wetting agent accounts for 10%, and dispersant accounts for 10%, and filler accounts for 10%; Auxiliary agent is 1% of a weight of formulation;
During manufacturing, take by weighing drug ingedient contained in the preparation earlier, that is: take by weighing the pure triazolone medicine of 70 weight portions, the dispersant of the wetting agent of 10 weight portions, 10 weight portions, the filler of 10 weight portions, wherein wetting agent adopts spaonin powder, dispersant is selected lignin for use, and filler adopts kaolin, takes by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 1 weight portion again as auxiliary agent, they are mixed, promptly become the finished product of powder-type bactericide.
Embodiment 3: the triazole type medicine in the efficient germicide of present embodiment is a triazolone, and it is the powder-type bactericide, and triazolone accounts for 5% of preparation in the bactericide, and wetting agent accounts for 7%, and dispersant accounts for 7%, and filler accounts for 81%; Auxiliary agent is 0.1% of a weight of formulation;
During manufacturing, take by weighing drug ingedient contained in the preparation earlier, that is: take by weighing the pure triazolone medicine of 5 weight portions, the dispersant of the wetting agent of 7 weight portions, 7 weight portions, the filler of 81 weight portions, wherein wetting agent adopts neopelex, dispersant is selected the alkyl naphthalene formaldehyde condensate sulfonates for use, and filler adopts white carbon, takes by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.1 weight portion again as auxiliary agent, they are mixed, promptly become the finished product of powder-type bactericide.
Embodiment 4: present embodiment is a kind of powder-type efficient germicide, and the triazole type medicine in it is a triazolone; Triazolone accounts for 10% of preparation in the bactericide, and wetting agent accounts for 15%, and dispersant accounts for 9%, and filler accounts for 66%; Auxiliary agent is 0.4% of a weight of formulation.
During manufacturing, take by weighing drug ingedient contained in the preparation earlier, that is: take by weighing the pure triazolone medicine of 10 weight portions, the dispersant of the wetting agent of 15 weight portions, 9 weight portions, the filler of 66 weight portions, wherein wetting agent adopts washing powder, dispersant is selected the alkyl naphthalene formaldehyde condensate sulfonates for use, and filler adopts diatomite, takes by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.4 weight portion again as auxiliary agent, they are mixed, promptly become the finished product of powder-type bactericide.
Embodiment 5: present embodiment is a kind of powder-type efficient germicide, and the triazole type medicine in it is a triazolone; Triazolone accounts for 58% of preparation in the bactericide, and wetting agent accounts for 10%, and dispersant accounts for 20%, and filler accounts for 12%; Auxiliary agent is 0.6% of a weight of formulation.
During manufacturing, take by weighing drug ingedient contained in the preparation earlier, that is: take by weighing the pure triazolone medicine of 58 weight portions, the dispersant of the wetting agent of 10 weight portions, 20 weight portions, the filler of 12 weight portions, wherein wetting agent adopts washing powder 5 weight portions, spaonin powder 5 weight portions, dispersant is selected alkyl naphthalene formaldehyde condensate sulfonates and lignin for use, both each 10 weight portions, filler adopts diatomite and each 6 weight portion of kaolin, take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.6 weight portion again as auxiliary agent, they are mixed, promptly become the finished product of powder-type bactericide.
Embodiment 6: the triazole type medicine in the efficient germicide of present embodiment is a triazolone, and wherein triazolone accounts for 18% of preparation in the bactericide, and wetting agent accounts for 30%, and dispersant accounts for 35%, and filler accounts for 17%; Auxiliary agent is 0.8% of a weight of formulation.
During manufacturing, take by weighing drug ingedient contained in the preparation earlier, that is: take by weighing the pure triazolone medicine of 18 weight portions, the dispersant of the wetting agent of 30 weight portions, 35 weight portions, the filler of 17 weight portions, wherein wetting agent adopts silkworm excrement, and dispersant is selected alkyl naphthalene formaldehyde condensate sulfonates 5 weight portions, lignosulfite 15 weight portions and lignin 15 weight portions for use, and filler adopts white carbon 12 weight portions and kaolin 5 weight portions; Take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.8 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 7: the triazole type medicine in the efficient germicide of present embodiment is a triazolone, and wherein triazolone accounts for 8% of preparation in the bactericide, and wetting agent accounts for 11%, and dispersant accounts for 13%, and filler accounts for 68%; Auxiliary agent is 0.005% of a weight of formulation.
During manufacturing, take by weighing the triazolone of 8 weight portions, the wetting agent of 11 weight portions, the dispersant of 13 weight portions earlier, the filler of 68 weight portions, in the wetting agent, silkworm excrement, neopelex respectively are 4 weight portions, and washing powder is 3 weight portions, in the dispersant, alkyl naphthalene formaldehyde condensate sulfonates 10 weight portions, lignosulfite 2 weight portions, lignin 1 weight portion is in the filler, diatomite 20 weight portions, white carbon 15 weight portions, kaolin 33 weight portions; Taking by weighing content again is poly-former medicine 0.5 weight portion of trisiloxanes of 98% ethyoxyl modification, and they are mixed, and promptly becomes finished product.
Embodiment 8: the triazole type medicine in the efficient germicide of present embodiment is a triazolone;
During manufacturing, take by weighing 23 weight portions triazolone, 25 weight portions wetting agent, the dispersant of 30 weight portions, the filler of 22 weight portions, in the wetting agent, silkworm excrement, each 8 weight portion of detergent alkylate sulphur washing powder, spaonin powder 1 weight portion, dispersant is a lignosulfite, is white carbon in the filler; Take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.008 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 9: present embodiment is a kind of powder-type efficient germicide, and the triazole type medicine in it is a triazolone;
During manufacturing, take by weighing 27 weight portions triazolone, 27 weight portions wetting agent, the dispersant of 27 weight portions, the filler of 19 weight portions, wetting agent adopts silkworm excrement, dispersant adopts the sourwood quality, filler adopts kaolin; Take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.02 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 10: the triazole type medicine in the efficient germicide of present embodiment is a triazolone;
During manufacturing, take by weighing 43 weight portions triazolone, 18 weight portions wetting agent, the dispersant of 24 weight portions, the filler of 15 weight portions, wetting agent adopts silkworm excrement and neopelex, they respectively are 9 weight portions, and dispersant adopts the alkyl naphthalene formaldehyde condensate sulfonates, and filler adopts kaolin, diatomite, white carbon, and they respectively are 5 weight portions; Take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.01 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 11: the triazole type medicine in the efficient germicide of present embodiment is a triazolone;
During manufacturing, take by weighing 54 weight portions triazolone, 30 weight portions wetting agent, the dispersant of 5 weight portions, the filler of 11 weight portions, wetting agent adopts spaonin powder, neopelex, washing powder, and they respectively are 10 weight portions, dispersant adopts lignosulfite and lignin, and they respectively are 2.5 weight portions, and filler adopts the kaolin of 6 weight portions and the diatomite of 5 weight portions.Take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.05 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 12: the triazole type medicine in the efficient germicide of present embodiment is a triazolone;
During manufacturing, take by weighing 63 weight portions triazolone, 8 weight portions wetting agent, the dispersant of 11 weight portions, the filler of 18 weight portions.Wetting agent adopts the spaonin powder of 5 weight portions, the washing powder of 3 weight portions, and dispersant adopts the alkyl naphthalene formaldehyde condensate sulfonates of 5 weight portions and the lignin of 6 weight portions, and filler adopts kaolin, diatomite, each 6 weight portion of white carbon.Taking by weighing content again is that 98% ethyoxyl modification gathers former medicine 1 weight portion of trisiloxanes as auxiliary agent, and they are mixed, and promptly becomes finished product.
Embodiment 13: the triazole type medicine in the efficient germicide of present embodiment is a triazolone; It is a kind of liquor.The content of triazolone is 15% in the preparation.Manufacture method is; Take by weighing that to contain the triazolone ratio be 15% missible oil 100 weight portions, content be poly-former medicine 0.06 weight portion of trisiloxanes of 98% ethyoxyl modification as auxiliary agent, they abundant mixings, promptly become finished product.
Embodiment 14: the triazole type medicine in the efficient germicide of present embodiment is a triazolone; It is a kind of liquor.The content of triazolone is 20% in the preparation.Manufacture method is; Take by weighing that to contain the triazolone ratio be 20% missible oil 100 weight portions, content be poly-former medicine 0.15 weight portion of trisiloxanes of 98% ethyoxyl modification as auxiliary agent, they abundant mixings, promptly become finished product.
Embodiment 15: the triazole type medicine in the efficient germicide of present embodiment is a triazolone; It is a kind of liquor.The content of triazolone is 25% in the preparation.Manufacture method is; Take by weighing that to contain the triazolone ratio be 25% missible oil 100 weight portions, poly-trisiloxanes 0.59 weight portion of pure ethyoxyl modification they abundant mixings, promptly becomes finished product as auxiliary agent.
Embodiment 16: present embodiment is a kind of powder-type efficient germicide, and the triazole type medicine in it is an alkene azoles alcohol, and wherein alkene azoles alcohol accounts for 1% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 1.
Embodiment 17: the triazole type medicine in this efficient germicide is an alkene azoles alcohol, and it is the powder-type bactericide, and alkene azoles alcohol accounts for 70% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 2.
Embodiment 18: the triazole type medicine in the efficient germicide of present embodiment is an alkene azoles alcohol, and it is the powder-type bactericide, and alkene azoles alcohol accounts for 5% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 3.
Embodiment 19: present embodiment is a kind of powder-type efficient germicide, and the triazole type medicine in it is an alkene azoles alcohol; Alkene azoles alcohol accounts for 10% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 4.
Embodiment 20: present embodiment is a kind of powder-type efficient germicide, and the triazole type medicine in it is an alkene azoles alcohol; Alkene azoles alcohol accounts for 58% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 5.
Embodiment 21: the triazole type medicine in the efficient germicide of present embodiment is an alkene azoles alcohol, and wherein alkene azoles alcohol accounts for 18% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 6.
Embodiment 22: the triazole type medicine in the efficient germicide of present embodiment is an alkene azoles alcohol, and wherein alkene azoles alcohol accounts for 8% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 7.
Embodiment 23: the triazole type medicine in the efficient germicide of present embodiment is an alkene azoles alcohol; Wherein alkene azoles alcohol accounts for 23% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 8.
Embodiment 24: the triazole type medicine in the efficient germicide of present embodiment is an alkene azoles alcohol; Wherein alkene azoles alcohol accounts for 27% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 9.
Embodiment 25: the triazole type medicine in the efficient germicide of present embodiment is an alkene azoles alcohol;
During manufacturing, take by weighing 50 weight portions alkene azoles alcohol, 8 weight portions wetting agent, the dispersant of 11 weight portions, the filler of 31 weight portions, wetting agent adopts silkworm excrement and neopelex, they respectively are 4 weight portions, and dispersant adopts the alkyl naphthalene formaldehyde condensate sulfonates, and filler adopts kaolin 21 weight portions, diatomite, white carbon, and they respectively are 5 weight portions; Take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.01 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 26: the triazole type medicine in the efficient germicide of present embodiment is an alkene azoles alcohol
During manufacturing, take by weighing 57 weight portions alkene azoles alcohol, 21 weight portions wetting agent, the dispersant of 6 weight portions, the filler of 16 weight portions, wetting agent adopts spaonin powder, dispersant adopts lignosulfite and lignin, and they respectively are 3 weight portions, and filler adopts the kaolin of 6 weight portions and the diatomite of 10 weight portions.Take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.05 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 27: the triazole type medicine in the efficient germicide of present embodiment is an enol ketone; It is a kind of liquor.The content of alkene azoles alcohol is 18% in the preparation.Manufacture method is; Take by weighing that to contain alkene azoles alcohol ratio be 18% missible oil 100 weight portions, content be poly-former medicine 0.09 weight portion of trisiloxanes of 98% ethyoxyl modification as auxiliary agent, they abundant mixings, promptly become finished product.
Embodiment 28: the triazole type medicine in the efficient germicide of present embodiment is an alkene azoles alcohol; It is a kind of liquor.The content of alkene azoles alcohol is 20% in the preparation.Manufacture method is; Take by weighing that to contain alkene azoles alcohol ratio be 20% missible oil 100 weight portions, poly-former medicine 0.35 weight portion of trisiloxanes of pure ethyoxyl modification they abundant mixings, promptly becomes finished product as auxiliary agent.
Embodiment 29: the triazole type medicine in the efficient germicide of present embodiment is an alkene azoles alcohol; It is a kind of liquor.The content of alkene azoles alcohol is 25% in the preparation.Manufacture method is; Take by weighing that to contain alkene azoles alcohol ratio be 25% missible oil 100 weight portions, poly-trisiloxanes 0.4 weight portion of pure ethyoxyl modification they abundant mixings, promptly becomes finished product as auxiliary agent.
Embodiment 30: present embodiment is a kind of powder-type efficient germicide, and the triazole type medicine in it is that enemy's power is taken off (having another name called propiconazole), and wherein enemy's power is taken off and accounted for 1% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 1.
Embodiment 31: the triazole type medicine in this efficient germicide is that enemy's power is taken off (having another name called propiconazole), and it is the powder-type bactericide, and enemy's power is taken off and accounted for 70% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 2.
Embodiment 32: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power is taken off (having another name called propiconazole), and it is the powder-type bactericide, and enemy's power is taken off and accounted for 5% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 3.
Embodiment 33: present embodiment is a kind of powder-type efficient germicide, and the triazole type medicine in it is that enemy's power is taken off (having another name called propiconazole); Enemy's power is taken off and is accounted for 10% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 4.
Embodiment 34: present embodiment is a kind of powder-type efficient germicide, and the triazole type medicine in it is that enemy's power is taken off; Enemy's power is taken off and is accounted for 58% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 5.
Embodiment 35: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power is taken off, and wherein enemy's power is taken off and accounted for 18% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 6.
Embodiment 36: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power is taken off, and wherein enemy's power is taken off and accounted for 8% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 7.
Embodiment 37: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power is taken off; Wherein enemy's power is taken off and is accounted for 23% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 8.
Embodiment 38: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power takes off wherein that alkene azoles alcohol accounts for 43% of preparation in the bactericide, and other content and manufacture method are identical with embodiment 10.
Embodiment 39: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power is taken off;
During manufacturing, take by weighing 60 weight portions alkene azoles alcohol, 5 weight portions wetting agent, the dispersant of 5 weight portions, the filler of 30 weight portions, wetting agent adopts silkworm excrement, and dispersant adopts the alkyl naphthalene formaldehyde condensate sulfonates, and filler adopts kaolin, diatomite, white carbon, and they respectively are 10 weight portions; Take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.059 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 40: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power is taken off,
During manufacturing, the enemy's power that takes by weighing 68 weight portions is taken off, 12 weight portions wetting agent, the dispersant of 10 weight portions, the filler of 10 weight portions, wetting agent adopts spaonin powder, dispersant adopts lignosulfite and lignin, and they respectively are 5 weight portions, and filler adopts the kaolin of 5 weight portions and the diatomite of 5 weight portions.Take by weighing the poly-trisiloxanes of the pure ethyoxyl modification of 0.7 weight portion again as auxiliary agent, they are mixed, promptly become finished product.
Embodiment 41: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power is taken off; It is a kind of liquor.The content that enemy's power is taken off in the preparation is 15%.Manufacture method is; Take by weighing that to contain enemy's power ratio of taking off be 15% missible oil 100 weight portions, content be poly-former medicine 1 weight portion of trisiloxanes of 98% ethyoxyl modification as auxiliary agent, they abundant mixings, promptly become finished product.
Embodiment 42: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power is taken off; It is a kind of liquor.The content that enemy's power is taken off in the preparation is 20%.Manufacture method is; Take by weighing that to contain enemy's power ratio of taking off be 20% missible oil 100 weight portions, poly-former medicine 1 weight portion of trisiloxanes of pure ethyoxyl modification they abundant mixings, promptly becomes finished product as auxiliary agent.
Embodiment 43: the triazole type medicine in the efficient germicide of present embodiment is that enemy's power is taken off; It is a kind of liquor.The content that enemy's power is taken off in the preparation is 25%.Manufacture method is; Take by weighing that to contain enemy's power ratio of taking off be 25% missible oil 100 weight portions, content be poly-former medicine 0.8 weight portion of trisiloxanes of 98% ethyoxyl modification as auxiliary agent, they abundant mixings, promptly become finished product.
Claims (7)
1. an efficient germicide is characterized in that: the poly-trisiloxanes of auxiliary agent ethyoxyl modification that it comprises the preparation of being made by triazole type medicine and is added in preparation; Wherein triazole type medicine accounts for the 1%-70% of weight of formulation; The poly-trisiloxanes of auxiliary agent ethyoxyl modification is the 0.001%-1% of weight of formulation.
2. efficient germicide according to claim 1 is characterized in that: described triazole type medicine is wherein a kind of during triazolone, alkene azoles alcohol or enemy's power are taken off.
3. efficient germicide according to claim 1 and 2, it is characterized in that: also contain wetting agent, dispersant and filler in the preparation, wherein wetting agent accounts for 5～30% of weight of formulation,, dispersant accounts for 5～35% of weight of formulation, filler accounts for 10～89% of weight of formulation.
4. efficient germicide according to claim 3, it is characterized in that: described wetting agent is at least a in natural wetting agent or the cationic wetting agent, dispersant is at least a in industrial by-products and the anionic dispersing agent, and filler is at least a in mineral carrier or the synthetic vectors.
5. bactericidal agent for preventing disease and increasing production according to claim 4, it is characterized in that: described wetting agent is at least a in spaonin powder, silkworm excrement, neopelex, the washing powder, dispersant is at least a in lignosulfite, lignin, the alkyl naphthalene formaldehyde condensate sulfonates, and filler is at least a in kaolin, diatomite, the white carbon.
6. make the method for efficient germicide as claimed in claim 5, it is characterized in that: take by weighing wherein a kind of in taking off of triazolone, the pure and mild enemy's power of alkene azoles by dosage, take by weighing wetting agent, dispersant, filler and auxiliary agent by dosage again, then they are mixed.
7. make the method for efficient germicide as claimed in claim 1 or 2, it is characterized in that: be to add the poly-trisiloxanes of auxiliary agent ethyoxyl modification by dosage in the wherein a kind of liquor in triazolone, alkene azoles alcohol or enemy's power are taken off, they are mixed and make.
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| CN101543219B (en) * | 2009-03-31 | 2012-07-18 | 华南农业大学 | Sterilizing composite compounded by diniconazole and tea saponin, preparation method and application thereof |
| CN101810190A (en) * | 2010-05-13 | 2010-08-25 | 江苏省绿盾植保农药实验有限公司 | Pyrazole kresoxim and thiophanate-methyl composite fungicide |
| CN101816306A (en) * | 2010-05-13 | 2010-09-01 | 江苏省绿盾植保农药实验有限公司 | Compound pesticide containing pymetrozine |
| CN102017995A (en) * | 2010-12-28 | 2011-04-20 | 马志强 | Chlorpyrifos-containing medicinal composition and application thereof |
| CN102017995B (en) * | 2010-12-28 | 2013-04-24 | 马志强 | Chlorpyrifos-containing medicinal composition and application thereof |
| CN106538611A (en) * | 2016-10-20 | 2017-03-29 | 中国农业科学院棉花研究所 | From bactericide its preparation method and the application of frutus cnidii |
| CN106561725A (en) * | 2016-10-20 | 2017-04-19 | 中国农业科学院棉花研究所 | Asarum-source botanical bactericide and preparation method and application thereof |
| CN106561727A (en) * | 2016-10-20 | 2017-04-19 | 中国农业科学院棉花研究所 | Botanical fungicide derived from tripterygium wilfordii, and preparation method and application thereof |
| CN106561727B (en) * | 2016-10-20 | 2019-05-28 | 中国农业科学院棉花研究所 | From the bactericide preparation method of tripterygium wilfordii and application |
| CN109169701A (en) * | 2018-09-14 | 2019-01-11 | 广东绿银生物科技有限公司 | Purposes of the mixture preparation of the modified poly- trisiloxanes organosilicon of ethyoxyl and avermectin composition in crop pest prevention and treatment |
| CN114007420A (en) * | 2019-05-08 | 2022-02-01 | 拜耳公司 | High diffusivity ULV formulations for fungicides |
| CN111296369A (en) * | 2020-02-26 | 2020-06-19 | 河南农业大学 | Automatic collect silkworm cocoon's silkworm breeding device |
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