CN101157846A - Centrifugal granulating method for producing sealing material and product and uses thereof - Google Patents
Centrifugal granulating method for producing sealing material and product and uses thereof Download PDFInfo
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- CN101157846A CN101157846A CNA2007101220507A CN200710122050A CN101157846A CN 101157846 A CN101157846 A CN 101157846A CN A2007101220507 A CNA2007101220507 A CN A2007101220507A CN 200710122050 A CN200710122050 A CN 200710122050A CN 101157846 A CN101157846 A CN 101157846A
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Abstract
The invention aims at providing a preparation method of making sealant materials. For example, the invention provides a sealant element for some parts needing to be sealed such as oxygen sensors of a core part in the electronic jet system of a vehicle, etc. The sealant element is made from inorganic nonmetal materials that are temperature-resistant, easy to fill, such as 1250 mesh talcum powder. Talcum powder particles needed by the sealant element is made by using centrifugal granulation technology. A technology test is made to confirm the parameter in the centrifugal granulation technology and gain the tiny diameter ball. The sphericity of the ball is distinct and good, which can stand certain intensity. The intensity and density of the little ball can be enhanced by increasing the time of making the ball. The final determined technology parameter can guarantee that the crushing power of the sealant element and the dispersion condition of balls can satisfy the demand for the parts needing to be sealed such as an assembly sensor, etc.
Description
Technical field
The present invention relates to a kind of preparation method and products thereof and purposes of sealing material, particularly a kind of preparation method based on talcous sealing material.
Background technology
Have a lot of devices to need sealing member in the modern industry, sealing member must possess the good characteristics of resistance to air loss.As in oxygen sensor (as shown in Figure 1), it is good, high temperature resistant and have the characteristics of good insulating concurrently to require sealing member must possess resistance to air loss.Have certain intensity by being prefabricated into, certain thickness annular solid small pieces are in the sealing station conquassation, but not the mode that directly adds powder at sealing station seals, when satisfying shape, size, crushing force etc., can sealing member be even, tiny particle when crushing have very important influence to sealing effectiveness.So need a kind of resistance to air loss of development that the sealing material of very high fillibility is well arranged again, because elastomeric material can not stand high temperature, the fillibility of metallic substance is poor again, so not only high temperature resistant but also have the ceramic use of good fillibility very extensive, wherein talcum powder is the main raw material as this sealing material.But talcous powder is tiny, at high temperature be difficult for to decompose again, the sealing material volume of being made by it is gently little, carry, easy to use, fill good sealing effect, can stand higher working temperature, embodied its reasonableness and advance; And talcous price is very cheap, so can reduce the whole cost of new type sealing element with talcum powder as the starting material of new type sealing element, has embodied the one side of its economy.
The first step of talcum powder being made the sealing member that satisfies performance requriements also is that a most important step is exactly powder handling.That the particle for preparing in the powder processing has is fibrous, needle-like, spindle shape, polyhedral, cobble shape and variform such as spherical, the wherein good fluidity of spherical granules, tap density height, even air hole distribution, thereby in moulding and sintering densification process, can effectively control, to obtain uniform microstructure, excellent property, conforming good product to the eliminating and the distribution of particulate growth and pore.Secondly, than the particle of other shapes, spherical granules is filled in the matrix material should not cause stress concentration, also can improve the ability of elastic-plastic deformation of matrix material, and material is easily processed, and in addition, spherical granules is difficult for reuniting owing to be a contact, is convenient to store.So seek out ideal microballoon type, prilling process is crucial.
The main branch that powder granulation technology is handled as powder body process, the main stirring-granulating method of prilling process, boiling granulation method, spray drying granulation method, pressure forming comminution granulation, spraying and dispersion vapodusting, the heat fusing method of forming and the centrifugal granulation etc. that in application process, occur at present.
Stirring-granulating method molding device is simple in structure, and single machine yield is big, and formed particle easily dissolves fast, drenched property is strong, and shortcoming is that uniform particles is bad, and formed granule strength is lower; Boiling granulation method is most effective in several method, but the particle of producing is comparatively loose, and proper sphere degree and surface smoothness are all very poor, is suitable for making less demanding particle or does early stage processing for other preparation; The space that the particle that the spray drying granulation method is produced stays when having moisture evaporation, more loose equally, though can continuous production, but output is lower, equipment is huge, a series of treatment facilities are supporting to need early stage extraction simultaneously, filter, concentrate etc., are suitable for making instant based food or Chinese medicine preparation; Compression molding can be made bigger agglomerate in the pressure forming comminution granulation, and made material also has suitable physical strength, and shortcoming is that the scope of application of equipment is less, and the material that has is difficult for the demoulding; Have on the extrusion process in the pressure forming comminution granulation that adaptive faculty is strong, output is big, epigranular, good, the granulating rate advantages of higher of granule strength; It is higher to extrude the simple and practical efficient of round as a ball comminution granulation in the pressure forming comminution granulation, and pellet density is big, and particle proper sphere degree and surface smoothness depend on the rotating speed of rotating disk and round as a ball time, and concave and convex phenomenon is arranged slightly; Spraying and disperse the vapodusting advantage to be that the granulation process of material and drying process carry out simultaneously, shortcoming is that granule strength is lower, granularity is less; The application of the heat fusing method of forming in China's powder industry is more general, and technology is also ripe.And the uniform particles densification that centrifugal granulation is made, surface smoothness and proper sphere degree are very high; can produce high qualification rate, high-quality spherical granules; be the Perfected process of producing high-density, small diameter particles in batches, centrifugal granulator is several times revised after the seventies comes out; existing multiple model appears on the market; at present, domestic this type technology maturation, effect is better; cost is not high, has been that pharmaceutical industry, micropill manufacturing research are extensively adopted.
Centrifugal granulator mainly is made up of stator (cylinder), rotating disk (end disk), top cover labyrinth, hot air chamber, transmission mechanism (stepless speed regulation) and product output mechanism etc.
The principle of centrifugal granulating is: the outer wall of whole round tube type cavity is as stator; end disk rotates as rotor high-speed; and energy stepless speed regulation; leave minimum circular clearance between stator and the rotor; the warm air that hot air chamber produces sprays into cavity thus; so just, set up the spouted rotating centrifugal field of force in tablets press inside; the feasible powder particle that adds automatically in this flow field; at centrifugal force; under the combined action of gravity and circumferential weld gas-jet; near the bottom of cylinder inboard wall, (be about cylindrical shell height 1/2) and form fluidization annular particle circle; the powder particle of this moment is not only done funicular circulating around the main frame rotating shaft; but also rotate hastily around the axis of particle self because of the stator inner wall rubbing effect, centrifugal granulating device schematic block diagram is as shown in Figure 2.The drop institute that powder particle is evenly sprayed on the one hand is wetting, and the fresh powder that then bonds equably in above-mentioned circulation particle circle on the other hand forms spheroid at last, finishes the granulation operation.The particle proper sphere degree, the density that make are all very high, can satisfy experimental requirements.
The annular solid small pieces are in the sealing station conquassation, and ideal crushing back dispersion state is determined by centrifugal granulating method to a great extent.
Summary of the invention
The purpose of this invention is to provide a kind of preparation method who prepares sealing material, as for need sealing elements such as core component oxygen sensor in the automobile electronic fuel oil jet system provide a kind of sealing member, the sealing part is made by ceramic talcum powder high temperature resistant, easy filling.Adopt centrifugal granulating method to prepare the required talcum powder powder particle of sealing member, and carry out technological test, to determine the parameter in the centrifugal granulating method, obtain the small particle size microballoon, its degree of sphericity is good, and certain intensity is arranged, and increases the granulation time to improve particulate intensity, density.The final processing parameter of determining can guarantee that the crushing force of sealing member and particles dispersed state need the requirement of sealing elements to satisfy assembly sensor etc.
The invention provides a kind of preparation method who prepares sealing material, it is characterized in that this method may further comprise the steps:
(1). prepare the ceramic meal, preferred 1250 purpose talcum powder;
(2). weighing polyethylene powder alcohol (PVA) and water, powdery PVA is poured in the cold water of corresponding proportioning, utilize water-bath to steam to powdery PVA again and be transparent glue-like, obtain mass percent 〉=2% and＜8% binding agent, preferred 4%, in order to improve the performance of powder, add an amount of Tetraglycol 99 (do dispersion agent with) and sodium polymethacrylate (making thickening material usefulness) in the binding agent, wherein binding agent and talcous mass ratio are 1: (2.5-3);
(3). with the ceramic meal, directly drop into the tablets press cylindrical shell as 1250 purpose talcum powder, after the main frame entry into service, that is joined (2) is pumped into by spray pump with the corresponding binding agent of input talcum powder amount, make certain size particles with centrifugal granulating method before the die mould, the centrifugal granulating parameter is: engine speed is (300-360) r/min, preferred 300r/min, the spray pump rotating speed is (5-10) r/min, preferred 10r/min, jet flow, parameters such as whiff pressure are conventional to be selected, behind the beginning granulation 35min, implement whitewashing (1-2) min after, the mode of whitewashing the intermittence that stops (4-5) min, the granulation time is (55 ± 10) minute, preferred 55 minutes;
(4). take out the powder seasoning, sieve out (75-250) purpose particle, be preferably (75-100) order, take by weighing the powder particle die mould of corresponding weight, preferred pressing mold or type are to improve stopping property, and die size is by deciding in requisition for the block construction of sealing;
(5). (4) gained material is put into porcelain boat, in its high temperature box type resistance furnace, regulate Heating temperature to (750 ± 10) and ℃ carry out sintering, preferred 750 ℃, sintering time is (20 ± 5) minute, preferred 20 minutes;
(6). measure the crushing force of gained material in (5) and the dispersion state after the fragmentation, make wear ring in the transmitter assembling process, can advance to loose evenly tiny particle, thereby fill the space of sealing groove rapidly, to reach good sealing effectiveness.
The present invention also provides a kind of and promptly is used for the parts of needs sealing arbitrarily according to prepared sealing material of above-mentioned arbitrary preparation method and uses thereof, in particular for the sealing material in the oxygen sensor in the engine electric spray system.
Current centrifugal granulating method is mainly used in pharmaceutical industry, and processing requirement is relatively low, and the production that centrifugal granulating method is used to not have seal remains a job that has novelty, challenge and have actual effect.
Process flow sheet is an example with the sealing member of core component oxygen sensor in the preparation automobile electronic fuel oil jet system as shown in Figure 3, the transverse section of different granulation time lower seal as shown in Figure 4, different granulation time lower seal crushing back dispersion state is as shown in Figure 5.The size of ready-formed sealing member is by the structures shape of transmitter, and wherein a kind of requirement of sealing member is: annular solid small pieces, thickness are 5.1mm, and external diameter is 14.5mm, and internal diameter is 8.9mm; The ability to bear decision of other ceramic components when crushing force is by assembling during assembling, it is 250～750N that the crushing force of above-mentioned sealing member requires.
The preparation technology of sealing material of the present invention can briefly be stated as: by centrifugal granulating method inorganic powder is processed into the particle that certain particle size distributes earlier, then be molded into the needed shapes of parts such as assembly sensor, last at suitable sintering temperature, make sealing member have certain intensity.The occasion that resistance to air loss is had requirement for oxygen sensor etc., the inorganic high-temp sealing member that uses this preparation process to produce can guarantee to satisfy corresponding requirements, quality stability and production efficiency in the production of inorganic high-temp sealing member can be guaranteed simultaneously, and lower starting material and production process cost can be guaranteed.Compression molding simultaneously and the inorganic high-temp sealing member with certain intensity be suitable for automatic assembling, improved the production efficiency and the yield rate of oxygen sensor etc.
Observe the section (Fig. 4) of the inorganic high-temp sealing material of this preparation technology's gained and can find that its interface is obvious, promptly particulate self intensity is high and have a certain toughness; State (Fig. 5) after the observation fragmentation is even, tiny particle in the time of can finding to crush, crushing back particulate state scatter, and filling properties is good; The crushing strength (table 1) of contrast inorganic high-temp sealing material can prove that it has suitable intensity.This has proved aforementioned this preparation technology's advantage on pattern and the performance effectively.
The later stage of development phase further is assemblied in this inorganic high-temp sealing member on the oxygen sensor, and every index also can both satisfy enterprise and request of national standard, can production application.
Description of drawings
The structure iron of accompanying drawing 1 oxygen sensor;
Accompanying drawing 2 centrifugal granulating device schematic block diagrams;
The integrated artistic schema of accompanying drawing 3 sealing members preparation;
The transverse section of accompanying drawing 4 different granulation time lower seal;
Dispersion state after the accompanying drawing 5 different granulation time lower seal crushing.
Embodiment
Following embodiment further illustrates content of the present invention in conjunction with the accompanying drawings, and unrestricted protection scope of the present invention:
Embodiment 1
(1). prepare 1.5Kg 1250 purpose talcum powder;
(2). weighing polyethylene powder alcohol (PVA) and water, powdery PVA is poured in the cold water of corresponding proportioning, utilize water-bath to steam to powdery PVA again and be transparent glue-like, obtain the binding agent of mass percent 2%, in order to improve the performance of powder, add an amount of Tetraglycol 99 (do dispersion agent with) and sodium polymethacrylate (making thickening material usefulness) in the binding agent, wherein binding agent and talcous mass ratio are 1: (2.5-3);
(3). directly drop into talcum powder described in (1) in the rotating disk of tablets press, after the main frame entry into service, pump into by spray pump joining binding agent in (2), make certain size particles with centrifugal granulating method before the die mould, the centrifugal granulating parameter is: engine speed is 330r/min, and the spray pump rotating speed is 5r/min, parameters such as jet flow, whiff pressure are got conventional the selection, behind the beginning granulation 35min, the mode of whitewashing the intermittence of implementing to stop behind the whitewashing 1min 4min, the granulation time is 45 minutes;
(4). take out the powder seasoning, sieve out (75-100) purpose particle, take by weighing the powder particle moulded section of (1.07 ± 0.01) g, die size is by deciding in requisition for the block construction of sealing;
(5). (4) gained material gained material is carried out sintering, regulate sintering temperature to 750 ℃, sintering time is 20 minutes;
(6). measure the crushing force of gained material in (5) and the dispersion state after the fragmentation, make wear ring in the transmitter assembling process, can advance to loose evenly tiny particle, thereby fill the space of sealing groove rapidly, to reach good sealing effectiveness.
Embodiment 2
(1). prepare 1.5Kg 1250 purpose talcum powder;
(2). weighing polyethylene powder alcohol (PVA) and water, powdery PVA is poured in the cold water of corresponding proportioning, utilize water-bath to steam to powdery PVA again and be transparent glue-like, obtain the binding agent of mass percent 4%, in order to improve the performance of powder, add an amount of Tetraglycol 99 (do dispersion agent with) and sodium polymethacrylate (making thickening material usefulness) in the binding agent, wherein binding agent and talcous mass ratio are 1: (2.5-3);
(3). directly drop into talcum powder described in (1) in the rotating disk of tablets press, after the main frame entry into service, pump into by spray pump joining binding agent in (2), make certain size particles with centrifugal granulating method before the die mould, the centrifugal granulating parameter is: engine speed is 300r/min, and the spray pump rotating speed is 10r/min, parameters such as jet flow, whiff pressure are got conventional the selection, behind the beginning granulation 35min, the mode of whitewashing the intermittence of implementing to stop behind the whitewashing 2min 5min, the granulation time is 55 minutes;
(4). take out the powder seasoning, sieve out (75-100) purpose particle, take by weighing the powder particle moulded section of (1.07 ± 0.01) g, die size is by deciding in requisition for the block construction of sealing;
(5). (4) gained material is put into porcelain boat, in its high temperature box type resistance furnace, regulate Heating temperature to 760 and ℃ carry out sintering, sintering time is 20 minutes;
(6). measure the crushing force of gained material in (5) and the dispersion state after the fragmentation, make wear ring in the transmitter assembling process, can advance to loose evenly tiny particle, thereby fill the space of sealing groove rapidly, to reach good sealing effectiveness.
Embodiment 3
(1). prepare 1.5Kg 1250 purpose talcum powder;
(2). weighing polyethylene powder alcohol (PVA) and water, powdery PVA is poured in the cold water of corresponding proportioning, utilize water-bath to steam to powdery PVA again and be transparent glue-like, obtain the binding agent of mass percent 5%, in order to improve the performance of powder, add an amount of Tetraglycol 99 (do dispersion agent with) and sodium polymethacrylate (making thickening material usefulness) in the binding agent, wherein binding agent and talcous mass ratio are 1: (2.5-3);
(3). directly drop into talcum powder described in (1) in the rotating disk of tablets press, after the main frame entry into service, pump into by spray pump joining binding agent in (2), make certain size particles with centrifugal granulating method before the die mould, the centrifugal granulating parameter is: engine speed is 360r/min, and the spray pump rotating speed is 10r/min, parameters such as jet flow, whiff pressure are got conventional the selection, behind the beginning granulation 35min, the mode of whitewashing the intermittence of implementing to stop behind the whitewashing 2min 5min, the granulation time is 65 minutes;
(4). take out the powder seasoning, sieve out (75-250) purpose particle, take by weighing the powder particle die mould of (1.07 ± 0.01) g, its size is by deciding in requisition for the block construction of sealing;
(5). (4) gained material is carried out sintering, regulate sintering temperature to 750 ℃, sintering time is 20 minutes;
(6). measure the crushing force of gained material in (5) and the dispersion state after the fragmentation, make wear ring in the transmitter assembling process, can advance to loose evenly tiny particle, thereby fill the space of sealing groove rapidly, to reach good sealing effectiveness.
The gained material can provide a kind of sealing member for core component oxygen sensor in the automobile electronic fuel oil jet system.By will be prefabricated into have certain intensity solid tablets in the sealing station conquassation, but not the mode that directly adds powder at sealing station seals, and is beneficial to the quality of the transmitter that guarantees assembling and enhances productivity.The size of ready-formed sealing member is by the structures shape of transmitter, and wherein a kind of requirement of sealing member is: annular solid small pieces, thickness are 5.1mm, and external diameter is 14.5mm, and internal diameter is 8.9mm; The ability to bear decision of other ceramic components when crushing force is by assembling during assembling, the crushing force of above-mentioned sealing member requires to be 250-750N.
Prepared batch to be tested before the sealing member assembling, and with wherein crushing of same stove, test data is as shown in table 1:
Table 1
| Specimen coding | Die mould power/MPa | Sintering temperature/℃ | After the burning | |
| Height/mm | Density crushing strength/MPa g/cm 3 | |||
| 4-1-1 | 122 | 760 | 5.04 | 1.916 |
| 4-1-2 | 122 | 5 | 1.923 | |
| 4-1-3 | 108 | 5.04 | 1.916 | ||
| 136 | 4.97 | 1.942 4.08 | |||
| 5-1-1 | 127 | 760 | 4.95 | 1.933 | |
| 5-1-2 | 129 | 4.95 | 1.942 | ||
| 5-1-3 | 141 | 4.9 | 1.965 | ||
| 144 | 4.96 | 1.942 3.32 | |||
| 5-1-4 | 118 | 760 | 5.02 | 1.916 | |
| 5-1-5 | 124 | 5.01 | 1.92 | ||
| 116 | 5.03 | 1.91 3.41 | |||
| 5-2-1 | 113 | 750 | 5.01 | 1.925 | |
| ＞188 | 5.00 | 1.924 2.93 | |||
| 6-2-1 | 126 | 760 | 4.99 | 1.919 | |
| 6-2-2 | 125 | 4.95 | 1.927 | ||
| 123 | 5.00 | 1.911 2.19 | |||
| 6-2-3 | 132 | 750 | 4.94 | 1.942 | |
| 6-2-4 | 113 | 5.03 | 1.906 | ||
| 6-2-5 | 136 | 4.92 | 1.959 | ||
| 132 | 4.91 | - | 2.58 | ||
Annotate: the agglomerating time all is 20min, and separating representative with thick horizontal line is to come from a stove, and-expression experimental data is lost numbering A-B-C
A:4,5,6 represents that respectively the time of granulation is respectively 45min, 55min, 65min
B:1,2 represents that respectively particulate order number is respectively (75-100) order, (75-250) order
C: expression test piece number (Test pc No.)
Sealing member assembles qualified parameter list, and is as shown in table 2.
Table 2
| Specimen coding | Electric capacity/PF | Resistance/K Ω | Electric current/A | Reaction times/S | Meet situation |
| Tolerance zone | 80-180 | 0.4-1.3 | ＜45 | ||
| 4-1-1 | 99.149 | 292.57 | 0.75 | 26.5 | √ |
| 5.1-4 | 102.868 | 296 | 0.65326 | 31.9 | √ |
| 6-2-3 | 104.408 | 290.99 | 0.63848 | 30.9 | √ |
According to being complete conformance with standard value range to the measuring result of the every item number certificate of sealing member shown in the table, promptly the sealing member sealing effectiveness meets up to standardly, and can normally use.
Claims (12)
1. the preparation method of a sealing material is characterized in that this method is a centrifugal granulating method, may further comprise the steps:
(1). prepare the ceramic meal;
(2). weighing polyethylene powder alcohol (PVA) and water, powdery PVA is poured in the cold water of corresponding proportioning, utilize water-bath to steam to powdery PVA again and be transparent glue-like, obtain mass percent 〉=2% and＜8% binding agent, in order to improve the performance of powder, add an amount of dispersion agent Tetraglycol 99 and thickening material sodium polymethacrylate in binding agent, wherein the mass ratio of binding agent and ceramic meal is 1: (2.5-3);
(3). the ceramic meal is directly dropped into the tablets press cylindrical shell, after the main frame entry into service, the corresponding binding agent of amount with dropping into the ceramic meal of being joined (2) is pumped into by spray pump, make certain size particles with centrifugal granulating method before the die mould, the centrifugal granulating parameter is: engine speed is (300-360) r/min, the spray pump rotating speed is (5-10) r/min, other parameters are conventional to be selected, behind the beginning granulation 35min, after implementing whitewashing (1-2) min, the mode of whitewashing the intermittence that stops (4-5) min, the granulation time is (55 ± 10) minute;
(4). take out the powder seasoning, sieve out (75-250) purpose particle, take by weighing the powder particle die mould of corresponding weight, its size is by deciding in requisition for the block construction of sealing;
(5). (4) gained material is carried out sintering, regulate sintering temperature to (650-850) ℃, sintering time is (20 ± 5) minute;
(6). measure the crushing force of gained material in (5) and the dispersion state after the fragmentation, make wear ring in the transmitter assembling process, advance to loose evenly tiny particle, thereby fill the space of sealing groove rapidly, to reach good sealing effectiveness.
2. preparation method as claimed in claim 1 is characterized in that the ceramic meal is 1250 purpose talcum powder.
3. preparation method as claimed in claim 2 is characterized in that powdery PVA mass percent is 4%.
4. preparation method as claimed in claim 3 is characterized in that engine speed is 300r/min, and the spray pump rotating speed is 10r/min.
5. preparation method as claimed in claim 4, the mode of whitewashing the intermittence that stops 5min behind the 2min that it is characterized in that implementing whitewashing.
6. preparation method as claimed in claim 5 is characterized in that the granulation time is 55 minutes.
7. preparation method as claimed in claim 6 is characterized in that sieving out (75-100) purpose particle.
8. preparation method as claimed in claim 7 is characterized in that die mould is moulded section, to improve the stopping property of material.
9. preparation method as claimed in claim 8 is characterized in that sintering temperature is (750 ± 10) ℃, and sintering time is 20 minutes.
10. sealing material as arbitrary preparation method's gained as described in the claim 1-9.
11. the purposes as sealing material as described in the claim 10 is characterized in that the sealing material is used for the parts that needs arbitrarily seal.
12. the purposes as sealing material as described in the claim 11 is characterized in that the sealing material is used for the oxygen sensor of engine electric spray system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007101220507A CN100465243C (en) | 2007-09-20 | 2007-09-20 | Centrifugal granulating method for producing sealing material and product and uses thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007101220507A CN100465243C (en) | 2007-09-20 | 2007-09-20 | Centrifugal granulating method for producing sealing material and product and uses thereof |
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| Publication Number | Publication Date |
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| CN101157846A true CN101157846A (en) | 2008-04-09 |
| CN100465243C CN100465243C (en) | 2009-03-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2007101220507A Expired - Fee Related CN100465243C (en) | 2007-09-20 | 2007-09-20 | Centrifugal granulating method for producing sealing material and product and uses thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106047291A (en) * | 2015-07-21 | 2016-10-26 | 凯晟动力技术（上海）股份有限公司 | Sealing material for oxygen sensor, and preparation and sealing methods thereof |
| CN108189269A (en) * | 2017-12-29 | 2018-06-22 | 溧阳市乔森塑料有限公司 | The prilling process of melamine formaldehyde molding compound and moulding compound particle obtained |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1524091A (en) * | 1977-03-11 | 1978-09-06 | Coal Industry Patents Ltd | Sealant material |
| CN1087975A (en) * | 1992-12-11 | 1994-06-15 | 中国南方航空动力机械公司 | A kind of fixation liquid sealing gasket |
| CN1632353A (en) * | 2003-12-23 | 2005-06-29 | 深圳市晶瑞达科技有限公司 | Composite sealed pressure feeding material for ultra-high pressure equipment |
| JP4636025B2 (en) * | 2004-10-08 | 2011-02-23 | ダイキン工業株式会社 | Fluoro rubber composition |
-
2007
- 2007-09-20 CN CNB2007101220507A patent/CN100465243C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106047291A (en) * | 2015-07-21 | 2016-10-26 | 凯晟动力技术（上海）股份有限公司 | Sealing material for oxygen sensor, and preparation and sealing methods thereof |
| CN106047291B (en) * | 2015-07-21 | 2019-03-22 | 凯晟动力技术（上海）股份有限公司 | It is a kind of for the sealing material of lambda sensor and its preparation and encapsulating method |
| CN108189269A (en) * | 2017-12-29 | 2018-06-22 | 溧阳市乔森塑料有限公司 | The prilling process of melamine formaldehyde molding compound and moulding compound particle obtained |
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| Publication number | Publication date |
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| CN100465243C (en) | 2009-03-04 |
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