CN101134864A - Cigarette label high-speed intaglio printing water-based ink - Google Patents
Cigarette label high-speed intaglio printing water-based ink Download PDFInfo
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- CN101134864A CN101134864A CN 200710139592 CN200710139592A CN101134864A CN 101134864 A CN101134864 A CN 101134864A CN 200710139592 CN200710139592 CN 200710139592 CN 200710139592 A CN200710139592 A CN 200710139592A CN 101134864 A CN101134864 A CN 101134864A
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- intaglio printing
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Abstract
The present invention discloses one kind of water-base ink for high speed intaglio printing of outer cigarette package, and belongs to the field of ink producing technology. The present invention solves the technological problem of providing water-base ink for high speed intaglio printing of outer cigarette package and with no static electricity accumulation, high safety and environment friendship. The water-base ink is prepared with water soluble acrylate emulsion 10-60 wt%, solid acrylate resin 0-10 wt%, base material wetting agent 0.2-2 wt%, defoaming agent 0.1-2 wt%, pH regulator 0.1-5 wt%, prefabricated pigment 8-33 wt%, ethanol 0-5 wt%, and water 13-41.6 wt%. It is used in high speed intaglio printing of outer cigarette package and may also be used for other printing purpose.
Description
Technical field
A kind of cigarette label high-speed intaglio printing water-based ink of the present invention is specifically related to employed a kind of water-based inks in the tobacco outer packaging high-speed intaglio printing process, belongs to printing ink and makes the field.
Background technology
Current, more and more serious because of mankind's activity, suitability for industrialized production to the negative impact that the earth and All Around The World cause, organize all obligated best endeavors protection environment of controlling oneself to the greatest extent as earth citizen everyone each, therefore need advocate Green Product globally.
Domestic tobacco is taken advantage of a situation and has been strengthened requirement to outer packaging, and the requirement of organic solvent residual is wherein continued to improve.Domestic cigarette-brand printing mainly adopts gravure, offset printing, wire mark, flexo mode to finish, especially the widest with high-speed intaglio printing, because the particular requirement of gravure mode, printing ink must adopt mobile well Newton type fluid, this just requires printing ink that high solid content can not be arranged, and solvent must reach 50%-80% or higher in the printing ink.
The printing ink that adopts in the domestic high-speed intaglio printing all is solvent type ink, it contains a large amount of volatile matters such as organic solvent, in printing process, these organic solvents must all vapor away ink film and could solidify at substrate surface, that is to say, organic volatile in the solvent type ink is wanted 100% emptying, environment is caused great pollution, operating environment organic solvent concentration height in the use, user's health is caused in various degree murder by poisoning, the organic solvent specific conductivity is very low, and the static that the equipment base material produces in running up very easily gathers, and has very large potential safety hazard.
Summary of the invention
Problem to be solved by this invention provides a kind of making does not have the cigarette label high-speed intaglio printing water-based ink that gathers static, safe and reliable, environment-protecting asepsis evil substantially in the production process.
The present invention is achieved in that a kind of cigarette label high-speed intaglio printing water-based ink, and it is formulated by following raw materials by weight:
Aqueous acrylic emulsion 10~60%
Acrylic solid resin 0~10%
Base material wetting agent 0.2~2%
Defoamer 0.1~2%
PH conditioning agent 0.1~5%
Pigment precast body 18~33%
Ethanol 0~5%
Water 13~41.6%
The substitute of above-mentioned aqueous acrylic emulsion is a water-based styrene/acrylic emulsion, or aqueous polyurethane dispersing liquid, or aqueous polyurethane/acrylic copolymeric resin, or modified acrylic acid emulsion, or water-borne acrylic resin solution, or water-based styrene/acrylic resin solution, or acrylic resin modified solution.
The substitute of above-mentioned PH conditioning agent is an ammoniacal liquor, or Monoethanolamine MEA BASF, or diethanolamine.
The substitute of above-mentioned pigment precast body is a pigment dyestuff, or mineral dye.
Above-mentioned alcoholic acid substitute is a Virahol, or n-propyl alcohol.
The preparation method of above-mentioned a kind of cigarette label high-speed intaglio printing water-based ink is: get acrylic solid resin, PH conditioning agent, defoamer, water earlier in stirring in the ratio adding still in the technical scheme; After heating up, 55~65 ℃ of insulations, each component is dissolved into clear liquid fully in still; Add pigment precast body and ethanol again and be stirred well to dissolving fully; At last, remaining ingredient is added and stir.
A kind of cigarette label high-speed intaglio printing water-based ink of the present invention compared with prior art has following beneficial effect:
1, the printing press that need not transform current use just can be realized substituting existing solvent type ink with water-based inks of the present invention, and the present invention is after using on the cigarette label high-speed intaglio printing product, can reach that smooth, high light is complete on the spot, the transition nature,, effective, print speed is suitable.
2, a spot of printing is residual little to human body and environmental hazard, does not almost have generation of static electricity in the printing process and the course of processing is safe, basic no-solvent type printing ink volatilization.
Effect of the present invention is illustrated by following contrast experiment, and experimental result is as follows:
Embodiment
Embodiment 1:
A kind of cigarette label high-speed intaglio printing water-based ink is made up of the component of following proportioning, and consumption is weight percent:
Aqueous acrylic emulsion (model is NeoCrylBT-44) 45%
Acrylic solid resin (model is CarbosetGA-1160) 3%
Base material wetting agent (model is Wet500) 0.5%
Defoamer (model is Foamex1488) 0.2%
PH conditioning agent 0.8%
Pigment precast body 25%
Ethanol 5%
Water 20.5%
Its preparation method is: get acrylic solid resin, defoamer, PH conditioning agent and water earlier in stirring in the ratio adding still in the technical scheme; After heating up, 60 ℃ of insulations, each component is dissolved into clear liquid fully in still; Add pigment precast body and ethanol again and be stirred well to dissolving fully, the pigment precast body is an inorganic solvent; At last, aqueous acrylic emulsion and base material wetting agent are added and stir.
Embodiment 2:
A kind of cigarette label high-speed intaglio printing water-based ink is made up of the component of following proportioning, and consumption is weight percent:
Water-based styrene/acrylic emulsion (model is JonCryl 8051) 10%
Acrylic solid resin (model is CarbosetGA-1160) 10%
Base material wetting agent (model is Wet500) 0.2%
Defoamer (model is Foamex1488) 0.8%
Diethanolamine 5%
Pigment dyestuff 33%
Virahol 3%
Water 38%
Its preparation method is: get acrylic solid resin, defoamer, diethanolamine and water earlier in stirring in the ratio adding still in the technical scheme; After heating up, 65 ℃ of insulations, each component is dissolved into clear liquid fully in still; Add pigment dyestuff and Virahol again and be stirred well to fully dissolving, last, water-based styrene/acrylic emulsion and base material wetting agent are added and stir.
Embodiment 3:
A kind of cigarette label high-speed intaglio printing water-based ink is made up of the component of following proportioning, and consumption is weight percent:
Aqueous polyurethane dispersing liquid (model is NeoRezR-984) 30%
Acrylic solid resin (model is Carboset GA-1160) 12%
Base material wetting agent (model is Wet500) 0.4%
Defoamer (model is Foamex1488) 1.2%
Ammoniacal liquor 1.8%
Pigment dyestuff 24%
Virahol 5%
Water 25.6%
Its preparation method is; Get acrylic solid resin, defoamer, ammoniacal liquor and water earlier in stirring in the ratio adding still in the technical scheme; After heating up, 55 ℃ of insulations, each component is dissolved into clear liquid fully in still; Add pigment dyestuff and Virahol again and be stirred well to fully dissolving, last, aqueous polyurethane dispersing liquid and base material wetting agent are added and stir.
Embodiment 4:
A kind of cigarette label high-speed intaglio printing water-based ink is made up of the component of following proportioning, and consumption is weight percent:
Aqueous polyurethane/acrylic copolymeric resin (model is NeoRezR-2040) 60%
Base material wetting agent (model is Wet500) 0.4%
Defoamer (model is Foamex1488) 1.2%
Monoethanolamine MEA BASF 1.8%
Mineral dye 20%
Water 35.6%
Its preparation method is: cancellation infusion, Monoethanolamine MEA BASF and water are in stirring in the ratio adding still in the technical scheme earlier; After heating up, 58 ℃ of insulations, each component is dissolved into clear liquid fully in still; Add mineral dye again and be stirred well to fully dissolving, last, aqueous polyurethane/acrylic copolymeric resin and base material wetting agent are added and stir.
Embodiment 5:
A kind of cigarette label high-speed intaglio printing water-based ink is made up of the component of following proportioning, and consumption is weight percent:
Modified acrylic acid emulsion (model is JonCryl74) 50%
Water soluble acrylic acid solid resin (model is CarbosetGA-1160) 7%
Base material wetting agent ((model is Wet500) 0.4%
Defoamer (model is Foamex1488) 1.2%
Diethanolamine 1.8%
Pigment precast body 16%
N-propyl alcohol 3%
Water 20.6%
Its preparation method is: the acrylic solid of water intaking property earlier resin, defoamer, diethanolamine and water are in stirring in the ratio adding still in the technical scheme; After heating up, 62 ℃ of insulations, each component is dissolved into clear liquid fully in still; Add pigment precast body and n-propyl alcohol again and be stirred well to fully dissolving, the pigment precast body is an organic solvent, and is last, modified acrylic acid emulsion and base material wetting agent are added and stirs.
Embodiment 6:
A kind of cigarette label high-speed intaglio printing water-based ink is made up of the component of following proportioning, and consumption is weight percent:
(model is NeoCrylA-1044 15% to water-based styrene/acrylic emulsion
Acrylic solid resin (model is CarbosetGA-1160) 10%
Base material wetting agent (model is Wet500) 0.2%
Defoamer (model is Foamex1488) 0.8%
PH conditioning agent 5%
Pigment dyestuff 31%
Virahol 3%
Water 35%
Its preparation method is: get acrylic solid resin, defoamer, PH conditioning agent and water earlier in stirring in the ratio adding still in the technical scheme; After heating up, 57 ℃ of insulations, each component is dissolved into clear liquid fully in still; Add pigment dyestuff and Virahol again and be stirred well to fully dissolving, last, water-based styrene/acrylic emulsion and base material wetting agent are added and stir.
Embodiment 7:
A kind of cigarette label high-speed intaglio printing water-based ink is made up of the component of following proportioning, and consumption is weight percent:
Water-based styrene/acrylic emulsion (model is JonCryl89) 20%
Acrylic solid resin (model is CarbosetGA-1160) 8%
Base material wetting agent (model is Wet500) 0.2%
Defoamer (model is Foamex1488) 0.8%
Diethanolamine 5%
Pigment dyestuff 30%
Ethanol 3%
Water 33%
Its preparation method is: get acrylic solid resin, defoamer, diethanolamine and water earlier in stirring in the ratio adding still in the technical scheme; After heating up, 61 ℃ of insulations, each component is dissolved into clear liquid fully in still; Add pigment dyestuff and ethanol again and be stirred well to fully dissolving, last, water-based styrene/acrylic emulsion and base material wetting agent are added and stir.
Embodiment 8:
A kind of cigarette label high-speed intaglio printing water-based ink is made up of the component of following proportioning, and consumption is weight percent:
Water-based styrene/acrylic emulsion (model is JonCryl352) 40%
Acrylic solid resin (model is CarbosetGA-1160) 9%
Base material wetting agent (model is Wet500) 0.2%
Defoamer (model is Foamex1488) 0.8%
Ammoniacal liquor 4%
Mineral dye 26%
Virahol 3%
Water 17%
Its preparation method is: get acrylic solid resin, defoamer, ammoniacal liquor and water earlier in stirring in the ratio adding still in the technical scheme; After heating up, 59 ℃ of insulations, each component is dissolved into clear liquid fully in still; Add mineral dye and Virahol again and be stirred well to fully dissolving, last, water-based styrene/acrylic emulsion and base material wetting agent are added and stir.
" NeoCryl ", " NeoRez " and " JonCryl " are the resin trade(brand)name of Avecia NeoResins among the above embodiment, " Carboset " is the solid resin trade(brand)name of Avecia NeoResins, and " Wet " is Degussa TegoCoating﹠amp; The base material wetting agent trade(brand)name of Ink Additivest, " Foamex " is Degussa Tego Coating﹠amp; The defoamer trade(brand)name of InkAdditivest.
Claims (5)
1. cigarette label high-speed intaglio printing water-based ink, it is characterized in that: it is formulated by following raw materials by weight:
Aqueous acrylic emulsion 10~60%
Acrylic solid resin 0~10%
Base material wetting agent 0.2~2%
Defoamer 0.1~2%
PH conditioning agent 0.1~5%
Pigment precast body 18~33%
Ethanol 0~5%
Water 13~41.6%.
2. according to claims 1 described a kind of cigarette label high-speed intaglio printing water-based ink, it is characterized in that: the substitute of aqueous acrylic emulsion is a water-based styrene/acrylic emulsion, or aqueous polyurethane dispersing liquid, or aqueous polyurethane/acrylic copolymeric resin, or modified acrylic acid emulsion, or water-borne acrylic resin solution, or water-based styrene/acrylic resin solution, or acrylic resin modified solution.
3. according to claims 1 described a kind of cigarette label high-speed intaglio printing water-based ink, it is characterized in that: the substitute of PH conditioning agent is an ammoniacal liquor, or Monoethanolamine MEA BASF, or diethanolamine.
4. a kind of cigarette label high-speed intaglio printing water-based ink according to claim 1 is characterized in that: the substitute of pigment precast body is a pigment dyestuff, or mineral dye.
5. according to claims 1 described a kind of cigarette label high-speed intaglio printing water-based ink, it is characterized in that: the alcoholic acid substitute is a Virahol, or n-propyl alcohol.
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CN 200710139592 CN101134864A (en) | 2007-10-15 | 2007-10-15 | Cigarette label high-speed intaglio printing water-based ink |
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CN 200710139592 CN101134864A (en) | 2007-10-15 | 2007-10-15 | Cigarette label high-speed intaglio printing water-based ink |
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Cited By (21)
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EP2233540A1 (en) * | 2009-03-24 | 2010-09-29 | Ideon LLC | Method of gravure printing with liquid radiation curable inks |
CN101979446A (en) * | 2010-11-18 | 2011-02-23 | 深圳市深赛尔实业有限公司 | Gravure ink capable of generating special surface effects and preparation method |
CN102382507A (en) * | 2011-09-06 | 2012-03-21 | 佛山市顺德区乐从镇盛昌油墨有限公司 | Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof |
CN102453410A (en) * | 2010-10-28 | 2012-05-16 | 上海印刷技术研究所 | Environmentally-friendly binding material and production and application thereof |
CN102602180A (en) * | 2012-03-19 | 2012-07-25 | 郭安民 | Traditional Chinese painting gravure printing process |
CN102838899A (en) * | 2012-09-11 | 2012-12-26 | 东莞市锐达涂料有限公司 | Water-soluble environmental-protection composite printing ink and preparation method thereof |
CN102964908A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | Water-based gravure special paper ink and method for preparing same |
CN103224738A (en) * | 2013-05-02 | 2013-07-31 | 东莞德芳油墨科技有限公司 | Aqueous environmental protection edge sealing strip prinking ink and preparation method thereof |
CN104073058A (en) * | 2014-07-15 | 2014-10-01 | 揭东县富德印刷材料有限公司 | Method for plastic soft package water-based intaglio printing ink |
CN104231735A (en) * | 2014-09-16 | 2014-12-24 | 洋紫荆油墨(中山)有限公司 | Water-based gravure ink for cigarette packs and preparation method of ink |
CN104449039A (en) * | 2014-12-26 | 2015-03-25 | 英科·卡乐油墨(苏州)有限公司 | Food packaging printing solvent-based ink and preparation method thereof |
CN104559463A (en) * | 2013-10-16 | 2015-04-29 | 深圳市顾康力化工有限公司 | Water-based silkscreen printing ink and preparation process thereof |
CN105238131A (en) * | 2014-06-18 | 2016-01-13 | 陈万成 | Non-absorbent silkscreen printing ink for gold and sliver cards |
CN105754407A (en) * | 2016-05-23 | 2016-07-13 | 南京金陵金箔股份有限公司 | Pure water-based ink and preparation method thereof |
CN106867307A (en) * | 2017-03-23 | 2017-06-20 | 厦门欧化实业有限公司 | A kind of aqueous composite ink and preparation method thereof |
CN108003703A (en) * | 2017-12-22 | 2018-05-08 | 许宏元 | A kind of binder for water-based ink and corresponding water-based ink |
CN108248234A (en) * | 2016-12-27 | 2018-07-06 | 江苏广博罗纳斯科技有限公司 | A kind of intaglio press printing technology |
CN109337440A (en) * | 2018-09-26 | 2019-02-15 | 浙江美浓世纪集团有限公司 | A kind of environment-friendly water-based gravure printing ink and preparation method thereof |
CN109651877A (en) * | 2019-01-08 | 2019-04-19 | 永发印务(东莞)有限公司 | A kind of composition and preparation method thereof of environment-friendly type aqueous intaglio printing silver inks |
CN110804341A (en) * | 2019-12-10 | 2020-02-18 | 中国印刷科学技术研究院有限公司 | Alcohol-water type ink, preparation method and application thereof |
CN114672187A (en) * | 2020-12-24 | 2022-06-28 | 湖南金固力油墨涂料有限公司 | Full-water-based intaglio printing ink |
-
2007
- 2007-10-15 CN CN 200710139592 patent/CN101134864A/en active Pending
Cited By (26)
Publication number | Priority date | Publication date | Assignee | Title |
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US8109211B2 (en) | 2009-03-24 | 2012-02-07 | Ideon Llc | Method of gravure printing with liquid radiation curable inks |
EP2233540A1 (en) * | 2009-03-24 | 2010-09-29 | Ideon LLC | Method of gravure printing with liquid radiation curable inks |
CN102453410A (en) * | 2010-10-28 | 2012-05-16 | 上海印刷技术研究所 | Environmentally-friendly binding material and production and application thereof |
CN101979446B (en) * | 2010-11-18 | 2012-08-22 | 深圳市深赛尔实业有限公司 | Gravure ink capable of generating special surface effects and preparation method |
CN101979446A (en) * | 2010-11-18 | 2011-02-23 | 深圳市深赛尔实业有限公司 | Gravure ink capable of generating special surface effects and preparation method |
CN102382507A (en) * | 2011-09-06 | 2012-03-21 | 佛山市顺德区乐从镇盛昌油墨有限公司 | Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof |
CN102602180A (en) * | 2012-03-19 | 2012-07-25 | 郭安民 | Traditional Chinese painting gravure printing process |
CN102838899A (en) * | 2012-09-11 | 2012-12-26 | 东莞市锐达涂料有限公司 | Water-soluble environmental-protection composite printing ink and preparation method thereof |
CN102964908A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | Water-based gravure special paper ink and method for preparing same |
CN102964908B (en) * | 2012-11-23 | 2014-05-07 | 东莞市佳烨化工科技有限公司 | Water-based gravure special paper ink and method for preparing same |
CN103224738A (en) * | 2013-05-02 | 2013-07-31 | 东莞德芳油墨科技有限公司 | Aqueous environmental protection edge sealing strip prinking ink and preparation method thereof |
CN103224738B (en) * | 2013-05-02 | 2015-12-23 | 东莞德芳油墨科技有限公司 | Aqueous, environmental protective edge band ink and preparation method thereof |
CN104559463A (en) * | 2013-10-16 | 2015-04-29 | 深圳市顾康力化工有限公司 | Water-based silkscreen printing ink and preparation process thereof |
CN105238131A (en) * | 2014-06-18 | 2016-01-13 | 陈万成 | Non-absorbent silkscreen printing ink for gold and sliver cards |
CN104073058A (en) * | 2014-07-15 | 2014-10-01 | 揭东县富德印刷材料有限公司 | Method for plastic soft package water-based intaglio printing ink |
CN104231735A (en) * | 2014-09-16 | 2014-12-24 | 洋紫荆油墨(中山)有限公司 | Water-based gravure ink for cigarette packs and preparation method of ink |
CN104449039A (en) * | 2014-12-26 | 2015-03-25 | 英科·卡乐油墨(苏州)有限公司 | Food packaging printing solvent-based ink and preparation method thereof |
CN105754407A (en) * | 2016-05-23 | 2016-07-13 | 南京金陵金箔股份有限公司 | Pure water-based ink and preparation method thereof |
CN105754407B (en) * | 2016-05-23 | 2018-04-24 | 南京金陵金箔集团股份有限公司 | A kind of water-based ink and preparation method thereof |
CN108248234A (en) * | 2016-12-27 | 2018-07-06 | 江苏广博罗纳斯科技有限公司 | A kind of intaglio press printing technology |
CN106867307A (en) * | 2017-03-23 | 2017-06-20 | 厦门欧化实业有限公司 | A kind of aqueous composite ink and preparation method thereof |
CN108003703A (en) * | 2017-12-22 | 2018-05-08 | 许宏元 | A kind of binder for water-based ink and corresponding water-based ink |
CN109337440A (en) * | 2018-09-26 | 2019-02-15 | 浙江美浓世纪集团有限公司 | A kind of environment-friendly water-based gravure printing ink and preparation method thereof |
CN109651877A (en) * | 2019-01-08 | 2019-04-19 | 永发印务(东莞)有限公司 | A kind of composition and preparation method thereof of environment-friendly type aqueous intaglio printing silver inks |
CN110804341A (en) * | 2019-12-10 | 2020-02-18 | 中国印刷科学技术研究院有限公司 | Alcohol-water type ink, preparation method and application thereof |
CN114672187A (en) * | 2020-12-24 | 2022-06-28 | 湖南金固力油墨涂料有限公司 | Full-water-based intaglio printing ink |
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Open date: 20080305 |