CN101113028A - Method for preparing demulsification clarifier - Google Patents
Method for preparing demulsification clarifier Download PDFInfo
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- CN101113028A CN101113028A CNA2007100417325A CN200710041732A CN101113028A CN 101113028 A CN101113028 A CN 101113028A CN A2007100417325 A CNA2007100417325 A CN A2007100417325A CN 200710041732 A CN200710041732 A CN 200710041732A CN 101113028 A CN101113028 A CN 101113028A
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- demulsification
- clarifier
- percent
- sewage
- hour
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- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention relates to a demulsification purifying agent and is characterized in that the purifying agent is composed by the components and proportions: 2-68 percent of sewage purifier, 2-37 percent of polymeric ferric sulfate, 5-45 percent of aluminum polychlorid, 6-57 percent of calcium chloride, and 19-47 percent of ferric chloride. The preparation steps are that: sewage purifier, polymeric ferric sulfate and aluminum polychlorid are dumped into a mixer and then calcium chloride and last water of 50 percent of the four raw materials are added; the mixture is stirred fully at a rate of 60 rpm for two to three hours to ensure the solid components are completely dissolved; the ferric chloride is added and the mixture is mixed continuously but at a rate of 50-80 rpm for half an hour to one hour; the mixture is filtered and packed into package buckles after the mixer is stopped for six to ten hours. The invention has excellent sewage treatment effect with low investment.
Description
Technical field
The present invention relates to a kind of preparation method of demulsification clarifier, the sewage disposal of automobile industry and mechanical industry belongs to environmental technology field.
Background technology
Automobile industry and mechanical industry, a large amount of emulsions and the clean-out system that need adopt in process of production, the main polluted factors that the chemical structure of itself can cause environment, the general high concentrated organic wastewater of handling, what adopt is calcium chloride and oxygenant, i.e. hydrochloric acid and sulfuric acid, and its shortcoming is:
1. process is complicated, and efficient is lower, the cost height;
2. investment is big, the operation easier height, and the safety seal is suffered from many.
Summary of the invention
The purpose of this invention is to provide a kind of good sewage processing effect, invest the preparation method of little demulsification clarifier.
For realizing above purpose, technical scheme of the present invention provides a kind of demulsification clarifier, it is characterized in that, is made up of following weight percent raw material:
Sewage clean 2%～68%
Bodied ferric sulfate 2%～37%
Polymerize aluminum chloride 5%～45%
Calcium Chloride Powder Anhydrous 6%～57%
Iron trichloride 19%～47%;
A kind of preparation method of demulsification clarifier the steps include:
The first step. sewage is clean, bodied ferric sulfate and polymerize aluminum chloride are to going in the stirrer, pour Calcium Chloride Powder Anhydrous again into and add 50% water of these four kinds of raw material summations, fully stir, stirring velocity per minute 60 changes, guarantee that solid constituent thoroughly dissolves hold-time 2-3 hour;
Second step. add iron trichloride again and continue to stir, stirring velocity per minute 50-80 changes, and the time is half-1 hour, shuts down 6-10 hour after-filtration packing of product bucket of packing into and gets final product.
Clean [the Al of sewage
2(OH)
nCl (6-n)] myF has strong clearance to the higher sewage of concentration; Bodied ferric sulfate [Fe
2(OH)
n(SO
4)
3-n/2]
mFull-cream class organic waste water there is better effects; Polymerize aluminum chloride [Al
2(OH)
nCl
6-n]
mDyeing waste water there is decolorizing effect; Calcium Chloride Powder Anhydrous CaCl
2Can be used as siccative, dewatering agent; Iron trichloride FeCl
3Be a kind of oxygenant, organism is had than strong oxidation, can be used as sterilizing agent, etching reagent use.
The present invention has ion-exchange, flocculation, breakdown of emulsion, multiple effects such as adsorption and oxidation reduction, can change wetting ability, the compression diffusion layer increases anti-ionization, finally reaches redox purpose, after adding the present invention in the waste water, the multinuclear base complex of surviving in hydrolytic process can adsorb tensio-active agent and multiple pollution factor in the waste water effectively, and polymerization becomes glue connection colony, when the raw waste water turbidity is spent greater than 500, its detergent power be related products 2-3 doubly, precipitation and separating rapidly is purified sewage at short notice.
Advantage of the present invention is a good sewage processing effect, invests little.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment
A kind of demulsification clarifier, form by following weight percent raw material:
Clean [the Al of sewage
2(OH)
nCl (6-n)] myF 55%
Bodied ferric sulfate [Fe
2(OH)
n(SO
4)
3-n/2]
m14%
Polymerize aluminum chloride [Al
2(OH)
nCl
6-n]
m10%
Calcium Chloride Powder Anhydrous CaCl
26%
Iron trichloride FeCl
315%;
A kind of preparation method of demulsification clarifier the steps include:
The first step. sewage is clean, bodied ferric sulfate and polymerize aluminum chloride are to going in the stirrer, pour Calcium Chloride Powder Anhydrous again into and add 50% water of these four kinds of raw material summations, fully stir, stirring velocity per minute 60 changes, guarantee that solid constituent thoroughly dissolves 2 hours hold-times;
Second step. add iron trichloride again and continue to stir, stirring velocity per minute 60 changes, and the time is half an hour, shuts down 8 hours after-filtration packing of product bucket of packing into and gets final product.
This invention is brown for liquid state, one-tenth, during use, and according to concentration of wastewater, elder generation's examination sample, determine this waste water dosage is entered the waste water reaction pond, add alkali, stir pH value 8.5 scopes of adjusting, add liquid polyacrylamide 5 ‰ again, stir and got final product in 1-2 minute, use very convenient.
The performance comparison table of the present invention and original product:
Annex: " demulsification clarifier " handles emulsifying waste water effect comparison table with relevant flocculation agent
| The emulsifying waste water pollution factor | COD 3030mg/L | Clearance % | BOD 182mg/L | Clearance % | Vegetable and animals oils 11.9 | Clearance % | Petroleum-type 8.2 | Clearance % | Zinc 14.7 | Clearance % | Remarks |
| " demulsification clarifier " | 454.5 | 85 | 36.4 | 80 | 0.6 | 95 | 0.82 | 90 | 1.18 | 92 | Water is Clear ﹠ Transparent, colourless, the alum particle is big, sludge settling is fast, drainability is good. |
| Bodied ferric sulfate | 1363.5 | 55 | 72.8 | 60 | 5.95 | 50 | 4.51 | 45 | 7.79 | 47 | Water is transparent inadequately, colourity is arranged, the alum particle is big, sludge settling is fast, drainability is good. |
| Polymerize aluminum chloride | 1515 | 50 | 100.1 | 45 | 6.3 | 47 | 3.69 | 55 | 5.15 | 65 | Water is transparent inadequately, colourless, the alum particle is little, sludge settling slow, drainability is poor. |
| Sewage is clean | 1060.5 | 65 | 78.26 | 57 | 5.83 | 51 | 4.35 | 47 | 5.59 | 62 | Water is more transparent, colourless, the alum particle is general, sludge settling is slow, drainability is general. |
| Iron trichloride | 9.09 | 70 | 72.8 | 60 | 5.95 | 50 | 4.27 | 48 | 8.53 | 42 | Water is transparent inadequately, have that colourity is brown, the alum particle is big, sludge settling is fast, drainability is good. |
| Calcium chloride | 1212 | 60 | 81.9 | 55 | 4.52 | 62 | 4.1 | 50 | 9.56 | 54 | Water is transparent inadequately, have that colourity is creamy white, the alum particle is little, sludge settling is fast, drainability is good. |
| Annotate: get 500mg/L with a kind of organic waste water, test conditions is identical.Result: the effect of the detergent power of " demulsification clarifier " and removal pollution factor improves 1-2 doubly than general flocculation agent effect. | |||||||||||
Claims (3)
1. a demulsification clarifier is characterized in that, is made up of following weight percent raw material:
Sewage clean 2%～68%
Bodied ferric sulfate 2%～37%
Polymerize aluminum chloride 5%～45%
Calcium Chloride Powder Anhydrous 6%～57%
Iron trichloride 19%～47%.
2. according to the described a kind of demulsification clarifier of claim 1, it is characterized in that described sewage is [Al only
2(OH)
nCl (6-n)] myF.
3. the preparation method of a demulsification clarifier the steps include:
The first step. sewage is clean, bodied ferric sulfate and polymerize aluminum chloride are to going in the stirrer, pour Calcium Chloride Powder Anhydrous again into and add 50% water of these four kinds of raw material summations, fully stir, stirring velocity per minute 60 changes, guarantee that solid constituent thoroughly dissolves hold-time 2-3 hour;
Second step. add iron trichloride again and continue to stir, stirring velocity per minute 50-80 changes, and the time is half-1 hour, shuts down 6-10 hour after-filtration packing of product bucket of packing into and gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100417325A CN101113028B (en) | 2007-06-07 | 2007-06-07 | Method for preparing demulsification clarifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100417325A CN101113028B (en) | 2007-06-07 | 2007-06-07 | Method for preparing demulsification clarifier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101113028A true CN101113028A (en) | 2008-01-30 |
| CN101113028B CN101113028B (en) | 2010-12-08 |
Family
ID=39021586
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100417325A Expired - Fee Related CN101113028B (en) | 2007-06-07 | 2007-06-07 | Method for preparing demulsification clarifier |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101113028B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276072A (en) * | 2010-06-11 | 2011-12-14 | 江苏贝斯特水处理科技有限公司 | Method for treating alkaline oily wastewater with demulsifier |
| CN102295335A (en) * | 2011-08-04 | 2011-12-28 | 安徽师范大学 | Flocculating-agent composition |
| CN102442721A (en) * | 2010-10-13 | 2012-05-09 | 中国石油化工股份有限公司 | Method for treating wastewater containing rubber latex |
| CN102976461A (en) * | 2012-12-11 | 2013-03-20 | 常州大学 | Agent for treating printing and dyeing wastewater |
| CN106629910A (en) * | 2016-12-16 | 2017-05-10 | 钦州市高新技术产业服务中心 | Demulsifying and purifying agent, and preparation method thereof |
-
2007
- 2007-06-07 CN CN2007100417325A patent/CN101113028B/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276072A (en) * | 2010-06-11 | 2011-12-14 | 江苏贝斯特水处理科技有限公司 | Method for treating alkaline oily wastewater with demulsifier |
| CN102442721A (en) * | 2010-10-13 | 2012-05-09 | 中国石油化工股份有限公司 | Method for treating wastewater containing rubber latex |
| CN102442721B (en) * | 2010-10-13 | 2013-05-01 | 中国石油化工股份有限公司 | Method for treating wastewater containing rubber latex |
| CN102295335A (en) * | 2011-08-04 | 2011-12-28 | 安徽师范大学 | Flocculating-agent composition |
| CN102295335B (en) * | 2011-08-04 | 2013-01-16 | 安徽师范大学 | Flocculating-agent composition |
| CN102976461A (en) * | 2012-12-11 | 2013-03-20 | 常州大学 | Agent for treating printing and dyeing wastewater |
| CN106629910A (en) * | 2016-12-16 | 2017-05-10 | 钦州市高新技术产业服务中心 | Demulsifying and purifying agent, and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101113028B (en) | 2010-12-08 |
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| PB01 | Publication | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20101208 Termination date: 20180607 |
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| CF01 | Termination of patent right due to non-payment of annual fee |