CN101103080B - 防滑涂料和涂布该涂料的基材 - Google Patents
防滑涂料和涂布该涂料的基材 Download PDFInfo
- Publication number
- CN101103080B CN101103080B CN2006800019247A CN200680001924A CN101103080B CN 101103080 B CN101103080 B CN 101103080B CN 2006800019247 A CN2006800019247 A CN 2006800019247A CN 200680001924 A CN200680001924 A CN 200680001924A CN 101103080 B CN101103080 B CN 101103080B
- Authority
- CN
- China
- Prior art keywords
- coating
- base material
- slip
- zinc
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000008199 coating composition Substances 0.000 title abstract description 5
- 239000000758 substrate Substances 0.000 title description 6
- 238000000576 coating method Methods 0.000 claims abstract description 77
- 239000011248 coating agent Substances 0.000 claims abstract description 74
- 239000000049 pigment Substances 0.000 claims abstract description 31
- 239000010445 mica Substances 0.000 claims abstract description 15
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 15
- 229920000768 polyamine Polymers 0.000 claims abstract description 15
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 15
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 48
- 239000003973 paint Substances 0.000 claims description 24
- 229910052725 zinc Inorganic materials 0.000 claims description 20
- 239000011701 zinc Substances 0.000 claims description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 19
- 239000002245 particle Substances 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002585 base Substances 0.000 description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 9
- 239000010959 steel Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000004927 clay Substances 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 150000002924 oxiranes Chemical group 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000013008 thixotropic agent Substances 0.000 description 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 239000013032 Hydrocarbon resin Substances 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000004705 aldimines Chemical class 0.000 description 2
- -1 aliphatic polyol Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- 229920006270 hydrocarbon resin Polymers 0.000 description 2
- 238000005488 sandblasting Methods 0.000 description 2
- 150000003335 secondary amines Chemical group 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- AECMQTCXISKOGO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethyl]phenol Chemical compound CN(C)CCC1=CC=CC=C1O AECMQTCXISKOGO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920003319 Araldite® Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CEKJAYFBQARQNG-UHFFFAOYSA-N cadmium zinc Chemical compound [Zn].[Cd] CEKJAYFBQARQNG-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229940083466 soybean lecithin Drugs 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000001039 zinc pigment Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/44—Amides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/251—Mica
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
- Y10T428/31522—Next to metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31529—Next to metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
防滑涂料组合物，其包含(i)粘结剂，包含聚环氧化物和多胺；(ii)含云母颜料，选自云母和云母铁矿以及它们的混合物；(iii)至少一种其它颜料；其中，以固体总体积为基准，含云母颜料含量至少为4％PVC，涂料的总PVC至少为35％。该防滑涂料固化后的滑动系数至少为0.50，该涂料组合物尤其能用于制造结构接合件。
Description
本申请要求于2005年1月7日提交的美国临时申请No.60/642,035的优先权，该临时申请的全文参考结合于本文。
本发明涉及涂覆的基材，尤其是用于结构接合处的涂覆的基材。许多金属基材，如用于化学工业、桥梁和高速公路建筑以及其它结构钢应用的金属基材在高腐蚀性环境中使用，这些基材必须用耐腐蚀的涂料保护。许多这样的应用，例如在建筑应用中连接I-梁所涉及的那些应用，也都要求在涂覆的梁相互接触时，例如所述梁在结构接合处用螺栓连接在一起时，涂料不会对梁的防滑性有明显的不利作用。
通常，两个结构部件之间的连接可以用螺栓或其它紧固器具固定。处于接触中的内面可以承受剪切力和张力，剪切力和张力导致接合处因接合处的一个部件相对于另一个部件的过度移动或滑动而最后破坏。因此，在许多应用中要求高防滑性。
已经确立了确定螺栓连接的结构接合处使用的涂层的滑动系数的规范。在2000年6月23日由结构连接科研委员会(Research Council on StructuralConnections)出版的Specification for Structural Joints Usins ASTM A-325or 490Bolts提出测试和确定面与面排列中如结构接合处涂层的滑动系数的标准方法，其内容(“规范”)参考结合于本文。参考的规范的复印件可从ResearchCouncil on Structural Connections，c/o American Institute of SteelConstruction，Inc.，1East Wacker Drive，Suite3100，Chicago，IL60601或在www.boltcouncil.org上获得。特别是，标题为“Testing Method to Determinethe Slip Coefficient for Coatings Used in Bolted Joints”的规范的附录列出了测试草案。该测试草案提供了钢板的制备方法，即在钢板上涂覆要求的涂料至规定的膜厚度，并使其干燥。三个测试板在特定的夹力(clamping force)下固定在夹具***中。中间的板以不同于外层的两个板的高度排列，然后，夹好的板上施加压缩负荷。增加该压缩负荷，测定板的移动。测定滑动负荷，滑动负荷定义为对应于测试板发生规定的变形量时的负荷，测定滑动系数Ks，按照下式该系数为滑动负荷与2倍夹力的比值：
Ks＝滑动负荷/2×夹力。
用五个读数的平均值来确定平均滑动系数。拉伸蠕变(tension creep)测试草案还在规范中提出，也可以测定蠕变变形，即板的相互移动。
对许多接合结构，要求平均滑动系数的“B类”评分至少为0.50。
可达到滑动系数B类评分至少为0.50的现有技术的富锌涂料是已知的。但是富锌涂料存在大量的缺陷。这种富锌涂料通常相对较贵，这些涂料上难以进行再涂覆，锌通常微粒很难维持在悬浮液中，对含锌材料的加工和处置为会造成环境问题。
此外，常见的优点是可以在远离实际建筑地点的位置涂覆钢基材，以便在基材货运和加工时将暴露于环境条件的情况减至最少。还能更方便和更快速涂覆处于工场环境中的基材，而不是在其已安装在建筑地点时进行涂覆。经常会要求基材上有多层涂料。例如，基材上可以涂覆底涂料和面涂料，并且在底涂料和面涂料之间可能有一层或多层中间涂层。
对于富锌底涂料的情况，任何滑动临界连接，如梁用螺栓接合在一起并与涂层发生面对面接触的区域，在施用对防滑性有不利影响的任何中间涂层或面涂料之前，需要用胶带揭除，或者掩蔽这些富锌底涂料的滑动临界连接处。这些附加的费力的步骤增加了在工场环境中制造涂覆的基材的成本和复杂性。
申请人已确定，一种设备，如结构连接件，包括第一涂覆基材和第二涂覆基材，所述的基材以面对面关系排列，以维持第一基材的涂覆表面与第二基材的涂覆表面间的接触，当涂料组合物各自包含以下组分时，这种设备具有优良的防滑性并且滑动系数至少为0.50：
(i)粘结剂，包含聚环氧化物和多胺；
(ii)含云母颜料，选自云母和云母铁矿以及它们的混合物；
(iii)至少一种其它颜料；
其中，含云母颜料含量至少为4％PVC，而各涂料的PVC总量至少为35％。在一个有用的实施方式中，本发明的涂料含有小于1重量％的锌微粒，优选基本上不含锌微粒。由于本发明的涂料组合物以面对面关系排列，具有优良的防滑性，包含在这种设备的基材需要时可以首先底涂以底涂料，如富锌底涂料，然后涂覆本发明的防滑涂料，不需要对滑动临界接合处进行掩蔽，之后，设置在该设备中。
用于本发明的涂料的粘结剂包含聚环氧化物和多胺的活性化合物。通常，这两种活性物质保持为独立的组分，直到在施用前进行混合。代表性的多胺和聚环氧化物为本领域已知。
可能用于实施本发明的聚环氧化物，每个分子上平均具有至少两个环氧基团，这种聚环氧化物包括脂族和芳族的聚环氧化物，如通过脂族多元醇或多酚与表卤代醇的反应制备的那些聚环氧化物。其它有用的环氧化物包括环氧化的油和环氧官能的共聚物，如源自丙烯酸缩水甘油酯或甲基丙烯酸缩水甘油酯之类的的烯键式不饱和环氧官能单体与其它可共聚单体组合的丙烯酸类聚合物。
能用于本发明的多胺包括每个分子平均具有至少两个活性胺基团的那些多胺。多胺为本领域众所周知，并且可以通过各种方法制备，例如通过丙烯酸或其它具有伯胺或仲胺官能团的不饱和单体的自由基聚合，或通过每个分子上具有平均至少两个氨基的胺与多羧酸反应，形成聚酰胺的胺，或通过伯胺与环氧物质的反应，产生仲胺和羟基官能团。多胺还可以是聚合物或较低分子量物质，如哌嗪、四亚乙基五胺、1，2-二氨基丙烷等。多胺还可以是在固化条件下转化为胺基团的胺前体，如酮亚胺或醛亚胺(aldimine)。
本发明的涂料还可以加有含云母颜料。本文中“含云母的”意图包括那些具有一般的层状结构或特性的颗粒物质，可包括云母状铁矿和云母。任选地，云母可以如本领域已知的用氧化铁进行处理，如在U.S.4,755,229提出的，该专利的内容参考结合于本文。对本发明的一些实施方式，以涂料的固体总体积为基准，含云母颜料的含量至少为4％PVC，对许多实施方式约为4-15％PVC，在有用的实施方式中，涂料的总PVC，包括所有颜料，为至少35％PVC。在某些实施方式中，涂料的PVC总量约为35-55％。
用于本发明的涂料除了含云母颜料外还包含至少一种其它颜料。在本发明的某些实施方式中，可使用二氧化硅颜料。其它颜料，如滑石、粘土、二氧化钛、炭黑和其它已知的有机或无机的颜料也可以加入。
配制的本发明的涂料还可以包含对涂料的防滑性没有不利影响的添加剂。可以使用适量的溶剂、触变剂、稀释剂、烃树脂、催化剂和其它材料。在一个有用的实施方式中，本发明的涂料为溶剂基的。
本发明的防滑涂料通常可以施用到任何基材，但特别是意图施用于金属基材，特别是铁制基材。在一个特定的实施方式中，尤其可用于将本发明的涂料施涂在已经喷砂处理或通过其它方式磨光的钢基材上。在一些实施方式中，基材上施用防滑涂料之前，任选涂覆底涂料。对某些实施方式，尤其对使用耐腐蚀底涂料，如富锌底涂料的情况是很有用的，在施用底涂料之前，可以将底涂料直接施涂在基材上，并使其干燥。富锌底涂料的配方为本领域众所周知。
对某些实施方式，在本发明固化或干燥后的防滑涂料的至少一部分表面上施用面涂料的涂料组合物，对提供多涂料的最后精整也是有用的。面涂料可以是本领域已知在使用这些产品的适当条件下能够固化或干燥的任何面涂料。面涂料可包含例如两组分的聚氨酯或聚酰胺涂料，聚环氧化物、醇酸树脂等。为使本发明的涂料，例如在结构接合组装件获得极好的防滑性质，意图与类似的防滑涂料部件处于面对面排列的、本发明的固化后涂料部分，在剩余的涂覆后的表面的一部分或全部上施用面涂料之前可以被掩蔽或遮蔽，以确保本发明固化后的涂料与类似的防滑面直接接触。或者，在组装结构接合件的时候，使用涂覆有本发明的防滑涂料，然后在仍露出的表面的一部分或全部上使用面涂料。
如果底涂料，如富锌底涂料与本发明的涂料组合使用，通常施用该底涂料，使干膜厚度(dft)约为0.5-10密尔。本发明的涂料直接施涂到基材，或者施涂在已经涂布在基材上的底涂料上时，施涂本发明的涂料提供的干膜厚度约为1-20密尔dft。当本发明的固化涂料的至少一部分上需要附加面涂料的时候，可以将面涂料施用在本发明的涂料上，提供的面涂料的干膜厚度约为1-20密尔。涂覆有本发明防滑涂料的基材可以按与固化的防滑涂料面对面接触的方式设置在设备中，仍保持所需的防滑性。
选择下面的实施例来说明特定的实施方式，并有利于更完整地理解本发明。除非另外指出，“份”指重量份，“百分数”是重量％。颜料体积是涂料中的颜料的体积与总的非挥发性物质(即颜料和粘结剂)的体积比。
实施例1
如下制备两组分的多胺/环氧化物涂料：
多胺组分
多胺组分按照下面所述，通过在高速混合机中混合所列物质制备：
物质 份数
聚酰胺树脂1 151.8
烃树脂2 59.2
2，4，6-三(二甲基氨基乙基)苯酚 13.7
增粘树脂3 340.5
二甲苯 28.6
大豆卵磷脂 6.9
消泡剂/湿润添加剂4 1.4
表面活性剂5 3.2
粘土颜料6 19.0
触变剂7 22.0
二甲苯 117.5
碱式钼酸镉锌颜料 80.0
红色氧化物颜料 65.0
炉黑颜料 1.0
Mica221云母颜料 215.0
二氧化硅颜料8 128.0
二氧化硅颜料9 215.0
1来自Cognis的Versamid115-70％NVM聚酰胺的胺树脂
2Nevoxy EPX-LH烷基苯酚烃
3来自Neville Chemicals的Cumar R-27-10香豆素茚树脂
4来自Byk Chemie的Byk052聚乙烯基醚
5来自AKZO Chemicals的Arquad2C-75
6来自Englehard的Attagel40绿坡缕土粘土
7来自Elementis的MPA1078X触变蜡
8来自Illinois Mineral Company的INSIL1240
9来自Malvern Minerals的1250Novacite
这种多胺组分本身的颜料体积浓度(PVC)为52.99％，固体重量(NVM)为76.87重量％(NVM)，固体体积(NW)为59.41体积。
聚环氧化物组分
物质 份数
甲基正戊基酮 97.1
二甲苯 53.0
环氧树脂10 251.4
增粘树脂11 115.9
消泡剂12 2.8
触变剂13 20.6
二氧化硅颜料14 451.2
二氧化硅颜料15 190.1
二甲苯 30.3
粘土颜料16 24.3
二甲苯 4.83
湿润剂/消泡剂17 3.0
10来自Ciba Geigy的Araldite GZ540X-90环氧树脂，255当量重量
11来自Neville Chemicals的Cumar R-27-10香豆素茚树脂
12来自Byk Chemie的Byk052聚乙烯基醚
13来自Elementis的MPA1078X触变蜡
14来自Illinois Mineral Company的INSIL1240
15来自Malvern Minerals的1250Novacite
16来自Englehard的Attagel40绿坡缕土粘土
17来自AKZO Chemicals的Arquad2C-75
这种聚环氧化物组分本身的PVC为45.21％，，NVM为81.86％，NW为67.44％。
将所述聚环氧化物组分和多胺组分按照1:1的体积比进行混合，提供最终的可固化涂料，将其施用在经过喷砂的钢基材上，以及底涂了可商购的富锌底涂料Zinc Clad
II Plus底涂料(购自Sherwin-Williams Company)的钢基材上。按本文所述对涂覆的钢板的滑动系数和抗蠕变性进行测试。喷砂处理过的钢板涂覆了本发明的涂料后，显示滑动系数为0.53，并符合如由Research Councilon Structural Connections订立的对使用ASTM A325或A490螺钉的结构接合件的规范提出的“B”类要求。这种底涂了Zinc
II Plus的钢板显示滑动系数为0.56，也符合“B”类要求。
采用组合两种组分制得的防滑涂料，以涂料的固体总量为基准，其PVC为49.1％，云母颜料的PVC仅为7.6％。
虽然已由多个具体实施方式描述了本发明，但在不偏离权利要求书要求的精神和范围内，可以进行其它的变动和修改。本文中所列的专利申请、专利和出版物的全部内容参考结合于本文。
Claims (7)
1.一种基材，其涂覆有多层涂料组合物，所述多层涂料组合物包含以下组分：
(1)施用在所述基材上的含锌底涂料；
(2)施用在所述含锌底涂料层上的第二涂料，所述第二涂料包含：
(i)粘结剂，其包含聚环氧化物和多胺；
(ii)含云母颜料，其选自云母和云母铁矿以及它们的混合物；和
(iii)至少一种其它颜料；
其中，以第二涂料的固体总体积为基准，含云母颜料的含量为至少4％PVC，第二涂料的总PVC为至少35％。
2.如权利要求1所述的基材，其特征在于，在所述第二涂料表面的部分或全部表面上施涂第三涂料。
3.如权利要求2所述的基材，其特征在于，所述第三涂料是双组分聚氨酯。
4.如权利要求2所述的基材，其特征在于，所述第三涂料并未施涂在第二涂料的全部表面上。
5.如权利要求1所述的基材，其特征在于，所述第二涂料的特性是固化后的滑动系数至少为0.50。
6.如权利要求1所述的基材，其特征在于，所述第二涂料的锌微粒含量小于1重量％。
7.如权利要求1所述的基材，其特征在于，所述第二涂料基本上不含锌微粒。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64203505P | 2005-01-07 | 2005-01-07 | |
| US60/642,035 | 2005-01-07 | ||
| PCT/US2006/000500 WO2006074395A1 (en) | 2005-01-07 | 2006-01-06 | Slip-resistant coating composition and substrate coated therewith |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101103080A CN101103080A (zh) | 2008-01-09 |
| CN101103080B true CN101103080B (zh) | 2012-04-18 |
Family
ID=36263763
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800019247A Expired - Fee Related CN101103080B (zh) | 2005-01-07 | 2006-01-06 | 防滑涂料和涂布该涂料的基材 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7348061B2 (zh) |
| CN (1) | CN101103080B (zh) |
| CA (1) | CA2593205C (zh) |
| MX (1) | MX2007008181A (zh) |
| WO (1) | WO2006074395A1 (zh) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7283519B2 (en) * | 2001-04-13 | 2007-10-16 | Esn, Llc | Distributed edge switching system for voice-over-packet multiservice network |
| EP2029680A4 (en) * | 2006-05-02 | 2010-10-20 | Whiteley Corp Pty Ltd | SAFETY COVERS |
| US20090169880A1 (en) * | 2007-12-31 | 2009-07-02 | Huber Engineered Woods Llc | Overlaid panel with an improved coefficient of friction |
| US8061257B2 (en) * | 2008-03-03 | 2011-11-22 | United States Gypsum Company | Cement based armor panel system |
| CL2009000372A1 (es) * | 2008-03-03 | 2009-11-13 | United States Gypsum Co | Panel cementicio blindado reforzado con fibra, que comprende un nucleo cementicio de una fase curada constituida de cemento inorganico, mineral inorganico, relleno puzolanico, policarboxilato y agua, y una capa de recubrimiento unida a una superficie de la fase curada. |
| CL2009000373A1 (es) * | 2008-03-03 | 2009-10-30 | United States Gypsum Co | Metodo para hacer un panel resistente a explosivos, con las etapas de preparar una mezcla cementicia acuosa de cemento, rellenos inorganicos y puzolanico, agente autonivelante de policarboxilato, y formar la mezcla en un panel con refuerzo de fibra, luego curar, pulir, cortar y curar el panel. |
| CL2009000371A1 (es) * | 2008-03-03 | 2009-10-30 | United States Gypsum Co | Composicion cementicia, que contiene una fase continua que resulta del curado de una mezcla cementicia, en ausencia de harina de silice, y que comprende cemento inorganico, mineral inorganico, relleno puzolanico, policarboxilato y agua; y uso de la composicion en una panel y barrera cementicia. |
| CN109577155B (zh) * | 2019-01-10 | 2021-02-09 | 江苏工程职业技术学院 | 一种建筑机械用铣刨机 |
| CN111849241A (zh) * | 2020-07-24 | 2020-10-30 | 安徽江锐新材料有限公司 | 用于低温环境的环氧云铁中间漆固化剂及其制备方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1167900A (en) * | 1966-10-19 | 1969-10-22 | British Paints Ltd | Coating Composition. |
| CA1090953A (en) | 1976-05-26 | 1980-12-09 | Louis Armanini | Iron oxide coated mica nacreous pigments |
| JPS5813670A (ja) * | 1981-07-17 | 1983-01-26 | Dainippon Toryo Co Ltd | 亜鉛メッキ被膜表面の処理方法 |
| JPS5815570A (ja) * | 1981-07-22 | 1983-01-28 | Dainippon Toryo Co Ltd | 送電鉄塔用塗料組成物 |
| US4522879A (en) | 1981-10-26 | 1985-06-11 | E. I. Du Pont De Nemours And Company | Two-package urethane maintenance primer |
| US4482661A (en) * | 1983-07-14 | 1984-11-13 | The Valspar Corporation | Aluminized epoxy-urethane coating |
| US4514445A (en) | 1983-11-08 | 1985-04-30 | Dai Nippon Toryo Co., Ltd. | Process for forming a corrosion resistant coating |
| US4758281A (en) * | 1986-09-12 | 1988-07-19 | International Minerals & Chemical Corp. | Anti-corrosive protective coatings |
| US4755229A (en) | 1987-02-09 | 1988-07-05 | The Mearl Corporation | Colored micaceous pigments |
| US5013770A (en) | 1989-07-27 | 1991-05-07 | Basf Corporation | Cross-linkable surface-modified micaceous particulates and coating compositions containing the same |
| CA2031128A1 (en) * | 1989-12-01 | 1991-06-02 | Yoshio Ishida | Two-component epoxy resin compositions |
| US5320871A (en) * | 1992-06-05 | 1994-06-14 | Springborn Laboratories, Inc. | Underwater coating for submerged substrates |
| US5618860A (en) | 1993-05-19 | 1997-04-08 | Ameron International Corporation | Epoxy polysiloxane coating and flooring compositions |
| US5585427A (en) | 1994-11-07 | 1996-12-17 | Ppg Industries, Inc. | Pigment dispersing additive for coating compositions |
| NL1003987C2 (nl) * | 1996-09-10 | 1998-03-11 | Vms Holding Ag | Werkwijze voor het bedekken van een oppervlak en samengestelde afdeklaag. |
| US6211262B1 (en) | 1998-04-20 | 2001-04-03 | Spectra Group Limited, Inc. | Corrosion resistant, radiation curable coating |
| US6107387A (en) | 1999-02-22 | 2000-08-22 | Ppg Industries Ohio, Inc. | Acidified aqueous dispersions of high aspect ratio clays |
| US6468336B1 (en) | 1999-05-26 | 2002-10-22 | J.C. Hempel's Skibsfarve-Fabrik A/S | Water-borne zinc silicate shop primers |
| US6309757B1 (en) | 2000-02-16 | 2001-10-30 | Ppg Industries Ohio, Inc. | Gas barrier coating of polyamine, polyepoxide and hydroxyaromatic compound |
| WO2002077112A1 (en) * | 2001-02-01 | 2002-10-03 | Theodorus Wilhelmus Streng | Underwater coating based on epoxy |
| US6639025B2 (en) | 2002-02-01 | 2003-10-28 | Ameron International Corporation | Elastomer-modified epoxy siloxane compositions |
-
2006
- 2006-01-06 WO PCT/US2006/000500 patent/WO2006074395A1/en active Application Filing
- 2006-01-06 US US11/326,937 patent/US7348061B2/en active Active
- 2006-01-06 MX MX2007008181A patent/MX2007008181A/es active IP Right Grant
- 2006-01-06 CN CN2006800019247A patent/CN101103080B/zh not_active Expired - Fee Related
- 2006-01-06 CA CA2593205A patent/CA2593205C/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US7348061B2 (en) | 2008-03-25 |
| US20060178455A1 (en) | 2006-08-10 |
| WO2006074395A1 (en) | 2006-07-13 |
| CA2593205A1 (en) | 2006-07-13 |
| CN101103080A (zh) | 2008-01-09 |
| MX2007008181A (es) | 2007-08-07 |
| CA2593205C (en) | 2010-11-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101103080B (zh) | 防滑涂料和涂布该涂料的基材 | |
| KR101011114B1 (ko) | 방청안료 함유 다관능성 에폭시 수지계 도료 조성물, 그의도막, 그의 도막으로 피복된 기재 및 방식방법 | |
| US7037958B1 (en) | Epoxy coating | |
| WO2001060883B1 (de) | Verwendung von wässrigen polyurethan-dispersionen in formulierungen für rissüberbrückende beschichtungssysteme | |
| CN107541014A (zh) | 环氧树脂组合物 | |
| US6316529B1 (en) | Two-component coating agent based on an epoxy resin for cement-bound backgrounds | |
| EP2283056B1 (en) | Novel fast curing ultra high solids low voc coating system for aggressive corrosive environments | |
| KR100897417B1 (ko) | 세라믹계 2액형 방식도료 조성물 | |
| JP2007247290A (ja) | コンクリート剥落防止表面被覆工法 | |
| KR20140024467A (ko) | 도로 표지 조성물 시스템 | |
| JP2016534181A (ja) | コーティング系 | |
| AU636841B2 (en) | Solvent resistant refinish paint composition and method of applying same | |
| JP2007099832A (ja) | 有機ジンクリッチ塗料組成物 | |
| Makhmetova et al. | An Overview of Epoxy Resins as coating to protect metals from corrosion | |
| RU2351624C1 (ru) | Полимерная композиция для защитного антикоррозионного покрытия барьерного типа | |
| JP6916350B1 (ja) | 塗料組成物及び塗膜 | |
| KR101012000B1 (ko) | 방수바닥재 조성물 | |
| JP5210494B2 (ja) | 施工方法 | |
| Figovsky | Nonisocyanate hybrid polyurethane floorings based on cyclic carbonates: optimal compositions and service properties | |
| JP2676019B2 (ja) | 塗料用組成物 | |
| WO2009031914A1 (fr) | Composition polymère destinée à une couche anticorrosive de protection de type barrière | |
| JPS62109868A (ja) | 鉄筋コンクリ−ト防食用コ−ト材 | |
| CN100516153C (zh) | 聚氯乙烯萤丹涂料 | |
| JP2002356981A (ja) | 劣化度の判定可能な防食被覆層を有する床およびそれを形成する工法 | |
| JPS6143669A (ja) | 防食塗料組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190202 Address after: Ohio, USA Patentee after: Xuanwei Investment Management Co.,Ltd. Address before: Ohio, USA Patentee before: Xuanwei Headquarters Co. Effective date of registration: 20190202 Address after: Ohio, USA Patentee after: Xuanwei Headquarters Co. Address before: Ohio, USA Patentee before: THE SHERWIN-WILLIAMS CO. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120418 |