CN101074805A - Triple-effective adsorptive-absorbing composite refrigerator - Google Patents

Triple-effective adsorptive-absorbing composite refrigerator Download PDF

Info

Publication number
CN101074805A
CN101074805A CN 200710057666 CN200710057666A CN101074805A CN 101074805 A CN101074805 A CN 101074805A CN 200710057666 CN200710057666 CN 200710057666 CN 200710057666 A CN200710057666 A CN 200710057666A CN 101074805 A CN101074805 A CN 101074805A
Authority
CN
China
Prior art keywords
absorber
pipeline
links
evaporimeter
pressure generator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 200710057666
Other languages
Chinese (zh)
Inventor
马洪亭
张于峰
邓娜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin University
Original Assignee
Tianjin University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin University filed Critical Tianjin University
Priority to CN 200710057666 priority Critical patent/CN101074805A/en
Publication of CN101074805A publication Critical patent/CN101074805A/en
Pending legal-status Critical Current

Links

Images

Landscapes

  • Sorption Type Refrigeration Machines (AREA)

Abstract

This invention discloses a tri-function adsorption complex freezing device, it includes a adsorber A and B which are set coordinately, a freezer A, a evaporator A, a high temperature source, a high voltage former, a low voltage former, a freezer B, a collector, a outside freezer B, a evaporator B, a fan tray pipe. Because the COP of this invention can attach 1.6, it produces the same freezing when consuming the same energy as the traditional electrical compressor. Comparing to the single function and double function LiBr freezer, this complex high freezing efficiency device can work at large temperature scale, and especially it can be used to freeze the residue heat of high temperature smoke. The COP of this invention can be 30-50% higher than the LiBr freezer; it gets rid of the corrosion and crystale of the LiBr freezer.

Description

Triple-effective adsorptive-absorbing composite refrigerator
Technical field
The present invention relates to refrigerating field, relate in particular to a kind of novel triple-effective adsorptive-absorbing composite refrigerator, the compound-refrigerating technology that adsorption refrigeration unit and absorption refrigeration circulation is connected can high efficiente callback glass, the waste heat of industrial production dischargings such as cement, pottery, oil, chemical industry freezes.
Background technology
Directly the Refrigeration Technique that drives with heat energy has absorption type refrigerating and absorption refrigeration.Wherein the absorption type refrigerating unit has shortcomings such as moving discontinuous and instability, and the adsorbance of adsorbent is less, and the refrigerating capacity ability is lower, and the operational efficiency of system is lower, and coefficient of performance COP has only 0.3-0.5, so never be used widely; Sorption type refrigerating technology is divided into the circulation of traditional single-action kind of refrigeration cycle and dual-effect refrigeration, and traditional single-effective absorption kind of refrigeration cycle is by a generator, and condenser, evaporimeter, absorber and pipeline valve are formed.Because the heat of input only by the generator utilization once, so refrigeration performance is relatively poor, COP has only 0.5-0.7.The double effect absorption kind of refrigeration cycle then is made up of high pressure and 2 generators of low pressure, a condenser, an evaporimeter and an absorber, after being cooled by low pressure generator, the water vapour elder generation that high pressure generator comes out enters condenser again, be utilized twice from the heat of outside input, therefore refrigeration performance is better, and COP can bring up to about 1.2.But want to continue to improve COP, with regard to the temperature that needs to develop triple effect and multiple-effect Absorption Refrigerator and improve thermal source, and the too high decomposition failure that can cause the corrosion inhibiter lithium chromate of temperature, aggravation lithium bromide water solution be to Corrosion of Metallic Materials, and the crystallization etc. that brings lithium bromide also insurmountable problem at present.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art, provide a kind of COP can reach about 1.6, and intermediate equipment and moving component are few, stable, reliable, solved corrosion of present refrigeration machine and crystallisation problems, can be directly with the triple-effective adsorptive-absorbing composite refrigerator of thermal source driving.
Triple-effective adsorptive-absorbing composite refrigerator of the present invention, this device comprises:
(a) an absorber A and an absorber B of being set up in parallel;
(b) condenser A, the import of this condenser A links to each other with the port of export of described absorber A, B by first, second pipeline that a valve is housed respectively;
(c) evaporimeter A, the water inlet end of this evaporimeter A links to each other with the water out end of described condenser A by the 3rd pipeline, and its steam (vapor) outlet end links to each other with the port of export of described absorber A, B by the 4th, the 5th pipeline that valve is housed respectively;
(d) high temperature heat source, this high temperature heat source links to each other with described absorber B by the high temperature heat source transfer pipeline that valve is housed;
(e) high pressure generator, this high pressure generator links to each other with described absorber A by the heat transfer conduit that valve is housed, described high temperature heat source transfer pipeline and described heat transfer conduit are in series by three groups of pipelines that are arranged in parallel being made up of two pipelines by every group respectively, on the pipeline of described every group of parallel pipeline a valve is housed, on the pipeline on described first group of pipeline pump is housed, this group pipeline is used for the backheat between absorber A and the absorber B and returns matter, and described second group of pipeline and the 3rd group of pipeline are used for high temperature heat source is sent into described absorber A and absorber B;
(f) low pressure generator;
(g) condenser B, the steam entrance point of this condenser B link to each other with the steam outlet end of described high pressure, low pressure generator by the 6th pipeline, the 7th pipeline that passes low pressure generator respectively;
(h) absorber, the liquid outlet end of this absorber is by being equipped with the high pressure of solution pump, low pressure generator feed flow pipeline and described high pressure, the inlet of low pressure generator links to each other, the inlet end of this absorber passes through high pressure, low pressure generator liquid back pipe road and described high pressure, the liquid outlet end of low pressure generator links to each other, described high pressure feed flow pipeline and liquid back pipe road are provided with a double pipe heat exchanger, described low pressure feed flow pipeline and liquid back pipe road are provided with another double pipe heat exchanger, and this absorber will send back to this absorber overhead spray absorption from the solution that this absorber lower curtate is extracted out again by a circulation pipe that solution pump is housed;
(i) external cooler B, the cooling tube of this external cooler B be separately positioned on condenser B and link to each other with heat exchange coil in the absorber;
(J) evaporimeter B, the liquid-inlet end of this evaporimeter B links to each other with the liquid outlet end of described condenser B by the 8th pipeline, its steam outlet end links to each other with the vapour inlet end of described absorber, and the solution that described evaporimeter B will extract out from this evaporimeter B bottom by a circulation pipe that solution pump is housed send back to this evaporimeter B again and carry out spraying and sprinkling evaporation;
(k) fan coil, the entrance end of this fan coil links to each other with the two ends of heat circulation pipe respectively, described heat circulation pipe be separately positioned on described evaporimeter A and link to each other with heat exchange coil among the B.
Because apparatus of the present invention have higher combination property coefficient, COP can reach about 1.6, and the primary energy amount that therefore identical refrigerating capacity consumed is suitable with traditional voltage compression type refrigerating machine, and intermediate equipment and moving component are few, stable, reliable, strengthened the market competitiveness; And this compound efficient refrigerating plant is compared with the double-effect lithium bromide refrigeration machine with single-action, can in wider temperature range, work, especially can be used in the utilizing waste heat for refrigeration of high-temperature flue gas, combination property coefficient COP exceeds 30%~50% than the COP (generally about 1.2) of double-effect lithium bromide refrigeration machine, has overcome problems such as corrosion that the lithium bromide refrigerator of present commercialization exists and crystallization.
Description of drawings
Accompanying drawing is a triple-effective adsorptive-absorbing composite refrigerator schematic diagram of the present invention.
The specific embodiment
Below in conjunction with the drawings and specific embodiments the present invention is done to describe in detail.
As shown in the figure, triple-effective adsorptive-absorbing composite refrigerator of the present invention, this device comprises: an absorber A4 and an absorber B5 of being set up in parallel; A condenser A1, the import of this condenser A links to each other with the port of export of described absorber A4, B5 by first, second pipeline that a valve is housed respectively; An evaporimeter A2, the water inlet end of this evaporimeter A links to each other with the water out end of described condenser A1 by the 3rd pipeline, and its steam (vapor) outlet end links to each other with the port of export of described absorber A, B by the 4th, the 5th pipeline that valve is housed respectively; A high temperature heat source 7, this high temperature heat source links to each other with described absorber B5 by the high temperature heat source transfer pipeline 16 that valve is housed; A high pressure generator 8, this high pressure generator 8 links to each other with described absorber A4 by the heat transfer conduit 17 that valve is housed, described high temperature heat source transfer pipeline and described heat transfer conduit are in series by three groups of pipelines that are arranged in parallel being made up of two pipelines by every group respectively, on the pipeline of described every group of parallel pipeline a valve is housed, on the pipeline on described first group of pipeline 18 pump is housed, this group pipeline is used for the backheat between absorber A4 and the absorber B5 and returns matter, and described second group of pipeline 19 and the 3rd group of pipeline are used for high temperature heat source is sent into described absorber A and absorber B; A low pressure generator 9; A condenser B10, the water vapour entrance point of this condenser B10 link to each other with the steam outlet end of described high pressure, low pressure generator by the 6th pipeline, the 7th pipeline that passes low pressure generator respectively; An absorber 13, the water outlet end of this absorber is by being equipped with the high pressure of solution pump 12, low pressure generator feed flow pipeline and described high pressure, the inlet of low pressure generator links to each other, the inlet end of this absorber passes through high pressure, low pressure generator liquid back pipe road and described high pressure, the liquid outlet end of low pressure generator links to each other, described high pressure feed flow pipeline and liquid back pipe road are provided with a double pipe heat exchanger 11, described low pressure feed flow pipeline and liquid back pipe road are provided with another double pipe heat exchanger 11, and this absorber 13 sprays absorption by the top that a circulation pipe that solution pump is housed will send back to this absorber again from the solution that this absorber bottom is extracted out; An external cooler B14, the cooling tube of this external cooler B14 links to each other with heat exchange coil in being separately positioned on condenser B10, absorber 13; An evaporimeter B15, the liquid-inlet end of this evaporimeter B15 links to each other with the liquid outlet end of described condenser B10 by the 8th pipeline, its steam outlet end links to each other with the vapour inlet end of described absorber, and described evaporimeter B will send back to the top spraying and sprinkling evaporation of this evaporimeter B from the solution of this evaporimeter B bottom extraction again by a circulation pipe that solution pump is housed; A fan coil 6, the entrance end of this fan coil links to each other with the two ends of heat circulation pipe respectively, described heat circulation pipe be separately positioned on described evaporimeter A and link to each other with heat exchange coil among the B.
The operation principle of apparatus of the present invention is as follows:
High temperature heat source 7 at first enters high temperature level absorption type refrigerating unit, adsorbent zeolite among heating absorber A4 or the B5, desorb evaporation from zeolite after cold-producing medium water is heated, enter condenser A1 by pipeline and valve, the liberated heat device A3 that is cooled takes away and is condensed into aqueous water, enter evaporimeter A2 then, evaporate behind the heat of the cold coal water of absorption external system.The water vapour that produces enters absorber A4 or B5 is adsorbed the absorption of agent zeolite, thereby finishes high temperature level kind of refrigeration cycle.Owing to 2 absorbers (A4 and B5) are arranged at this refrigeration unit, can realize adsorbing and the hocketing of desorption process by the time switch of by-pass valve control, guarantee the continuity and the backheat to each other of kind of refrigeration cycle and return matter, thus raising coefficient of performance COP.Experiment and studies show that zeolite-water conservancy project is verified still can reach the higher coefficient of performance under higher adsorption temp.
Flow into low temperature level double-effect lithium bromide absorption type refrigeration unit through the high temperature heat source after the cooling of absorption type refrigerating unit, lithium bromide water solution in the heating high-pressure generator 8, the cold-producing medium aqueous vapor that its mid-boiling point is lower changes into high-pressure water vapor, separate with the absorbent lithium bromide, the concentration of remaining lithium bromide water solution then can raise gradually.The high-pressure water vapor that high pressure generator 8 produces is passing through low pressure generator 9 and is emitting the laggard condenser B10 of the going into discharge liquid heat-transmission of part heat and condense into water.The water vapour that is produced by low pressure generator 9 then directly enters condenser B10 discharge liquid heat-transmission and condenses into water.Liberated heat was taken away by external cooler B14 when water vapour liquefied in condenser B10.HTHP condensate water among the condenser B10 becomes the low-pressure water with evaporating pressure through the choke valve decompression, inflow evaporator B15 then, the heat (realizing refrigeration) that absorbs external system also flashes to low pressure water vapor, enters absorber 13 then and is absorbed by the dense lithium bromide water solution from high pressure and low pressure generator and emit heat.Heat is taken away by external cooler B14.Lithium bromide water solution after the dilution sends into high pressure generator 8 after by solution pump 12 pressurization and low pressure generator 9 is heated once more, thereby finishes low temperature level double-effect lithium bromide absorption type kind of refrigeration cycle.
For improving utilization efficiency of heat energy, the absorber A4 and the B5 of the high temperature level of this compound-refrigerating device, and the high pressure generator 8 of low temperature level and low pressure generator 9 all adopt high-performance heat transfer components-heat pipe directly to reclaim the waste heat of flue gas, and retrieve lithium bromide water solution after the heat heating dilution of the pyrosol of high pressure and low pressure generator with 2 double pipe heat exchangers 11, realized the classification utilization of residual heat resources, therefore can improve the heat energy utilization rate and the coefficient of performance of whole system, the comprehensive COP of hybrid system is reached more than 1.6.

Claims (1)

1. triple-effective adsorptive-absorbing composite refrigerator is characterized in that this device comprises:
(a) an absorber A and an absorber B of being set up in parallel;
(b) condenser A, the import of this condenser A links to each other with the port of export of described absorber A, B by first, second pipeline that a valve is housed respectively;
(c) evaporimeter A, the water inlet end of this evaporimeter A links to each other with the water out end of described condenser A by the 3rd pipeline, and its steam (vapor) outlet end links to each other with the port of export of described absorber A, B by the 4th, the 5th pipeline that valve is housed respectively;
(d) high temperature heat source, this high temperature heat source links to each other with described absorber B by the high temperature heat source transfer pipeline that valve is housed;
(e) high pressure generator, this high pressure generator links to each other with described absorber A by the heat transfer conduit that valve is housed, described high temperature heat source transfer pipeline and described heat transfer conduit are in series by three groups of pipelines that are arranged in parallel being made up of two pipelines by every group respectively, on the pipeline of described every group of parallel pipeline a valve is housed, on the pipeline on described first group of pipeline pump is housed, this group pipeline is used for the backheat between absorber A and the absorber B and returns matter, and described second group of pipeline and the 3rd group of pipeline are used for high temperature heat source is sent into described absorber A and absorber B;
(f) low pressure generator;
(g) condenser B, the steam entrance point of this condenser B link to each other with the steam outlet end of described high pressure, low pressure generator by the 6th pipeline, the 7th pipeline that passes low pressure generator respectively;
(h) absorber, the liquid outlet end of this absorber is by being equipped with the high pressure of solution pump, low pressure generator feed flow pipeline and described high pressure, the inlet of low pressure generator links to each other, the inlet end of this absorber passes through high pressure, low pressure generator liquid back pipe road and described high pressure, the liquid outlet end of low pressure generator links to each other, described high pressure feed flow pipeline and liquid back pipe road are provided with a double pipe heat exchanger, described low pressure feed flow pipeline and liquid back pipe road are provided with another double pipe heat exchanger, and this absorber will send back to this absorber overhead spray absorption from the solution that this absorber lower curtate is extracted out again by a circulation pipe that solution pump is housed;
(i) external cooler B, the cooling tube of this external cooler B be separately positioned on condenser B and link to each other with heat exchange coil in the absorber;
(J) evaporimeter B, the liquid-inlet end of this evaporimeter B links to each other with the liquid outlet end of described condenser B by the 8th pipeline, its steam outlet end links to each other with the vapour inlet end of described absorber, and the solution that described evaporimeter B will extract out from this evaporimeter B bottom by a circulation pipe that solution pump is housed send back to this evaporimeter B again and carry out spraying and sprinkling evaporation;
(k) fan coil, the entrance end of this fan coil links to each other with the two ends of heat circulation pipe respectively, described heat circulation pipe be separately positioned on described evaporimeter A and link to each other with heat exchange coil among the B.
CN 200710057666 2007-06-19 2007-06-19 Triple-effective adsorptive-absorbing composite refrigerator Pending CN101074805A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200710057666 CN101074805A (en) 2007-06-19 2007-06-19 Triple-effective adsorptive-absorbing composite refrigerator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200710057666 CN101074805A (en) 2007-06-19 2007-06-19 Triple-effective adsorptive-absorbing composite refrigerator

Publications (1)

Publication Number Publication Date
CN101074805A true CN101074805A (en) 2007-11-21

Family

ID=38976003

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200710057666 Pending CN101074805A (en) 2007-06-19 2007-06-19 Triple-effective adsorptive-absorbing composite refrigerator

Country Status (1)

Country Link
CN (1) CN101074805A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101957102A (en) * 2010-05-14 2011-01-26 王开明 Generator of lithium bromide air conditioner improving concentrated solution outputting way

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101957102A (en) * 2010-05-14 2011-01-26 王开明 Generator of lithium bromide air conditioner improving concentrated solution outputting way
CN101957102B (en) * 2010-05-14 2012-10-03 王开明 Generator of lithium bromide air conditioner improving concentrated solution outputting way

Similar Documents

Publication Publication Date Title
CN108211648B (en) Heat recovery type condensation and temperature and pressure swing adsorption combined process oil gas recovery device
CN101737995B (en) Micro-positive pressure running adsorption refrigeration system
CN1766462A (en) Ammonia absorption type refrigerating apparatus utilizing waste heat of exhaust
CN103394267A (en) Oil gas recovery device combining condensation and adsorption
CN101059290A (en) Ammonia absorption type refrigeration and hot pump dual-purpose system and cool and heat supply method
Mohammed et al. Productivity improvements of adsorption desalination systems
US11940187B2 (en) Water treatment system of coupling heat pump with multi-effect evaporation and operating method thereof
CN201949793U (en) Absorption-type freeze drying machine driven by waste heat of air compressor
CN110498462B (en) Industrial waste liquid treatment system and method based on carrier gas extraction low-temperature mass transfer
CN101776347B (en) Absorption type refrigerating unit with pressure recovery part
CN1299087C (en) Back heating type generator of heat pipe with composite adsorbent being adopted
CN2856872Y (en) Lithium bromide double-effective absorbing, directly heating air conditioner for engine
CN1075883C (en) Direct-burning type lithium bromide absorption type heat pump set system
CN201973952U (en) Lithium bromide absorption evaporative condensation water chiller
CN1587865A (en) Double effect lithium bromide bsorptive refrigerator using smoke waste heat
CN110762947A (en) Air cooling device in low-pressure air separation system
CN101074805A (en) Triple-effective adsorptive-absorbing composite refrigerator
CN109631405A (en) A kind of boosting type heat chemistry adsorption heat pump circulatory system with cooling cycle
CN201828081U (en) Glass shell absorption and adsorption type refrigerating system
CN212253259U (en) Compression condensing unit for automatically controlling defrosting system by utilizing hot fluorine gas
CN110332727B (en) Industrial waste heat driven adsorption type water purification and refrigeration system and application thereof
CN1158494C (en) Multistage absorption type refrigerating apparatus
CN110500688B (en) Dilution type refrigeration heat pump system for air conditioning by utilizing dilution heat
CN210602326U (en) Multi-cycle refrigeration system utilizing zeolite adsorption
CN101776345A (en) High-efficient 1.x-effect absorption-type refrigeration device

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication