CN101069588A - Air-battery smart nano health-care shoe pad - Google Patents
Air-battery smart nano health-care shoe pad Download PDFInfo
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- CN101069588A CN101069588A CN 200710041298 CN200710041298A CN101069588A CN 101069588 A CN101069588 A CN 101069588A CN 200710041298 CN200710041298 CN 200710041298 CN 200710041298 A CN200710041298 A CN 200710041298A CN 101069588 A CN101069588 A CN 101069588A
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Abstract
The present invention relates to a kind of air cell intelligent nano health-care shoe pad. Said health-care shoe pad successively includes surface layer, functional layer, isolation layer, secondary functional layer and undersurface layer. It is characterized by that said functional layer is formed from two layers of cloth material, between said two layers of cloth material a composite material layer is added, said composite material layer is formed from nano iron covered with high nitrogen doped carbon nano tube. Said high-nitrogen doped carbon nano tube can be used for adsorbing foot sweat and oxygen gas in the air, and said carbon nano tube and nano iron in the composite material can be formed into the air cell power supply to produce constant voltage and slowly-releasing current. Said air cell intelligent nano health-care shoe pad has several health-care functions of resisting bacteria, eliminating stink and magnetic health-care, etc.
Description
Technical field
The present invention relates to a kind of high nitrogen doped corrugated carbon nanotube composite with parcel nanometer iron is the air cell nano health-care shoe pad of major function material.
Background technology
Current society increases beriberi patient's quantity because leather shoes replace cloth shoes, staple fibre to replace the cross infection of cotton and public place gradually.Beriberi and pin are smelly has brought considerable bothering for many people, not only can damage health, and be difficult to cure, and more because it has infectiousness, often makes the people self-doubt, influences human communication.With the product that pin directly contacts is shoe-pad, and the shoe-pad that exploitation effectively improves foot's environment obviously suppresses beriberi, generation and infection that pin is smelly, and is closely bound up with health with the mankind's daily life.
The antibacterial deodorizing shoes of at present relevant patent report is lined with medicine type, as long-acting pure Chinese medicine health-care Antibromic shoe pads, patent No. ZL96240916.2; The bamboo charcoal type, as Bamboo charcoal shoe-pad, patent No. ZL02253060.6; Active carbon type, as: a kind of active carbon Antibromic shoe pads, patent No. ZL 03280046.0.Not only deodorizing effect of medicinal health-care deoderizing shoe-pad is short, and what have also can produce new pollution; Simple active carbon or bamboo charcoal absorbent-type Antibromic shoe pads are also because of deodorizing timeliness and the not satisfactory actual requirement that is difficult to reach people of power of regeneration.Therefore, invent the high-efficiency multi-function shoe-pad of a kind of antibiotic, deodorizing, health care, its market potential is very big.
Summary of the invention
Is the shoe-pad that material is made for overcoming prior art with medicine, bamboo charcoal, active carbon, the deodorizing timeliness is short, the efficacy of a drug can not be regenerated, can not use lastingly, even also can cause new drawbacks such as pollution, the invention provides a kind of high nitrogen doped corrugated carbon nanotube (Fe@CNx) composite with parcel nanometer iron is the air cell nano health-care shoe pad of major function material, not only the absorbing sweat performance is good, collect antibiotic, deodorizing, magnetic health-care acts on all over the body, and strong absorption, deodorizing timeliness are long, function is renewable, and smelly patient brings glad tidings for the beriberi pin.
CNT is a kind of novel carbon nanomaterial, and specific activity charcoal and bamboo charcoal have stronger adsorption capacity.CNT can and experimentally significantly improve its structure, chemistry, conduction and thermodynamic property from theory after nitrogen mixes, and the CNT after the nitrogen doping is to no toxic biological.Synthesize nitrogen doped carbon nanotube at present, all iron catalyst is removed before use with acid.In order to obtain more novel material behavior, as improving surface electronic cloud density or improving surface polarity, improve in the nitrating bamboo-like carbon nano tubes itrogen content of getter with nitrogen doped or simultaneously therein the coated metal particle be a kind of efficient ways.Do not increase environmental problem again for reaching this purpose, the high nitrogen doped corrugated carbon nanotube composite material that uses catalysis process to obtain wrapping up nanometer iron will have following advantage: (1) water absorbing properties is good; (2) original position parcel performance is good; (3) outer surface is big; (4) good stability.These are its electrode material as air cell condition are provided.
Air-battery smart nano health-care shoe pad, it is made in proper order according to top layer, functional layer, separation layer, functional layer, top layer and forms, it is characterized in that: functional layer is to add a kind of high nitrogen doped corrugated carbon nanotube (Fe@CNx) composite that wraps up nanometer iron between two layers of cloth, and with the internal layer that is applied to functional layer after binding agent evenly mixes; High nitrogen doped corrugated carbon nanotube in the composite is by the pin sweat and the airborne oxygen of absorption foot, and the nanometer iron formation air cell power supply with in the composite makes air cell produce constant voltage and slowly-releasing electric current.
Every pair of its iron of shoe-pad and high nitrogen doped corrugated carbon nanotube weight are formed can be 0.1～9, and nitrogen and carbon ratio are greater than 0.1.
Every pair of its iron of shoe-pad and high nitrogen doped corrugated carbon nanotube weight are formed can be 0.5～5, and nitrogen and carbon ratio are greater than 0.12.
Every pair of its iron of shoe-pad and high nitrogen doped corrugated carbon nanotube weight are formed can be 1～2, and nitrogen and carbon ratio are greater than 0.13.
Functional material of the present invention is meant parcel nanometer iron and high nitrogen doped corrugated carbon nanotube; When the function of use material, functional material contacts abundant more with air with pin sweat, its sterilization, deodorizing and electromagnetic health-care effect are brought into play well more, air-battery smart nano health-care shoe pad according to the inventive method making, not only the absorbing sweat performance is good, collect antibiotic, deodorizing, magnetic health-care acts on all over the body, and strong absorption, deodorizing timeliness are long, function is renewable.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples.
Fig. 1 is an operation principle schematic diagram of the present invention;
Fig. 2 is an air-battery smart nano health-care shoe pad structural representation of the present invention.
1. top layer, 2. functional layer, 3. separation layer.
The specific embodiment
High nitrogen doped corrugated carbon nanotube (Fe@CNx) composite of the parcel nanometer iron that the used catalysis method of the present invention obtains, the weight composition uses aFe: bC: cN to represent, and c/b ratio is represented with x; The value of a is 0.2～10, and the value of b is 0.60～0.95, and the value of c is 0.05～0.40.
Air-battery smart nano health-care shoe pad, as shown in Figure 2, it is made according to the order on top layer 1, functional layer 2, separation layer 3, functional layer 2, top layer 1 and forms, be characterized in: functional layer 2 is to add a kind of high nitrogen doped corrugated carbon nanotube (Fe@CNx) composite that wraps up nanometer iron between two layers of cloth, and above-mentioned material and binding agent are mixed the internal layer that is applied to each functional layer; High nitrogen doped corrugated carbon nanotube in the composite is by the pin sweat and the airborne oxygen of absorption foot, and the nanometer iron formation air cell power supply with in the composite makes air cell produce constant voltage and slowly-releasing electric current.
Operation principle of the present invention as shown in Figure 1, CN
xBe high nitrogen doped corrugated carbon nanotube, the equation of air cell operation principle is: anodal 1/2O
2+ H
2O+2e=2OH
-Negative pole Fe-2e=Fe
2+High nitrogen doped corrugated carbon nanotube in the composite is by the pin sweat and the airborne oxygen of absorption foot, form the air cell power supply with the nanometer iron in the composite, the 0.5V constant voltage and the little electric current that produce, can suppress fungi growth, and generate alkaline hydroxyl at positive pole, increased the effect of improving beriberi; Simultaneously, owing to little electric current is arranged, can reach effect to foot's electromagnetic health-care by around the nanometer iron; Pin sweat is serious more, and the raw material that is equivalent to air cell is many more, thereby deodorizing effect is good more, and this is the embodiment of its intelligent regulating action.
Every pair of its iron of shoe-pad and high nitrogen doped corrugated carbon nanotube weight are formed can be 0.1～9, and nitrogen and carbon ratio are greater than 0.1; Better the weight composition can be 0.5～5, and nitrogen and carbon ratio are greater than 0.12; Preferably the weight composition can be 1～2, and nitrogen and carbon ratio are greater than 0.13.
Embodiment 1: take by weighing the high nitrogen doped corrugated carbon nanotube material of 2.0g parcel nanometer iron, nitrogen and carbon ratio are 0.11, mix with the 2.0g common bond, evenly are applied to the intraformational bed of each functional layer of a pair of shoe-pad.The shoe-pad that obtains is through on probation, can significantly remove pin smelly, improve foot's environment.
Embodiment 2: take by weighing the high nitrogen doped corrugated carbon nanotube material of 4.0g parcel nanometer iron, nitrogen and carbon ratio are 0.13, mix with the 2.0g common bond, evenly are applied to the intraformational bed of each functional layer of a pair of shoe-pad.The shoe-pad that obtains is through on probation, can brute force remove pin smelly, improve foot's environment.
Embodiment 3: take by weighing the high nitrogen doped corrugated carbon nanotube material of 1.0g parcel nanometer iron, nitrogen and carbon ratio are 0.14, mix with the 2.0g common bond, evenly are applied to the intraformational bed of each functional layer of a pair of shoe-pad.The shoe-pad that obtains is through on probation, can partly remove pin smelly, improve foot's environment.
Claims (4)
1. air-battery smart nano health-care shoe pad, it is made in proper order according to top layer, functional layer, separation layer, functional layer, top layer and forms, it is characterized in that: functional layer is to add a kind of high nitrogen doped corrugated carbon nanotube (Fe@CNx) composite that wraps up nanometer iron between two layers of cloth, and with the internal layer that is applied to functional layer after binding agent evenly mixes; High nitrogen doped corrugated carbon nanotube in the composite is by the pin sweat and the airborne oxygen of absorption foot, and the nanometer iron formation air cell power supply with in the composite makes air cell produce constant voltage and slowly-releasing electric current.
2. air-battery smart nano health-care shoe pad according to claim 1 is characterized in that: every pair of its iron of shoe-pad and high nitrogen doped corrugated carbon nanotube weight are formed can be 0.1～9, and nitrogen and carbon ratio are greater than 0.1.
3. air-battery smart nano health-care shoe pad according to claim 1 is characterized in that: every pair of its iron of shoe-pad and high nitrogen doped corrugated carbon nanotube weight are formed can be 0.5～5, and nitrogen and carbon ratio are greater than 0.12.
4. air-battery smart nano health-care shoe pad according to claim 1 is characterized in that: every pair of its iron of shoe-pad and high nitrogen doped corrugated carbon nanotube weight are formed can be 1～2, and nitrogen and carbon ratio are greater than 0.13.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710041298A CN101069588B (en) | 2007-05-25 | 2007-05-25 | Air-battery smart nano health-care shoe pad |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710041298A CN101069588B (en) | 2007-05-25 | 2007-05-25 | Air-battery smart nano health-care shoe pad |
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| Publication Number | Publication Date |
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| CN101069588A true CN101069588A (en) | 2007-11-14 |
| CN101069588B CN101069588B (en) | 2010-05-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200710041298A Expired - Fee Related CN101069588B (en) | 2007-05-25 | 2007-05-25 | Air-battery smart nano health-care shoe pad |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10454094B2 (en) | 2013-07-29 | 2019-10-22 | Huawei Technologies Co., Ltd. | Cathode active material for lithium-ion secondary battery and preparation method thereof, cathode pole piece for lithium-ion secondary battery, and lithium-ion secondary battery |
| CN111485326A (en) * | 2020-03-13 | 2020-08-04 | 苏州椰为媒纤维制品科技有限公司 | Production method of mothproof palm fiber mat |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2268412Y (en) * | 1996-09-16 | 1997-11-26 | 庄琪章 | Long service life health-care odor eliminating shoepad with Chinese medicines |
| CN2511161Y (en) * | 2001-07-24 | 2002-09-18 | 何秀英 | Bactericidal and deodoring nano-environment protecting shoe pad |
| CN1395895A (en) * | 2002-08-26 | 2003-02-12 | 王晓喜 | Nano shoe pad |
| CN2563972Y (en) * | 2002-09-09 | 2003-08-06 | 王正郁 | Bamboo charcoal shoe-pad |
| CN1480393A (en) * | 2003-07-07 | 2004-03-10 | 复旦大学 | Bamboo Knotlike nano carbon tube material containing nitrogen and synthetic method |
| CN2648867Y (en) * | 2003-09-29 | 2004-10-20 | 贺艳琴 | Active carbon deodorizing shoe pad |
-
2007
- 2007-05-25 CN CN200710041298A patent/CN101069588B/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10454094B2 (en) | 2013-07-29 | 2019-10-22 | Huawei Technologies Co., Ltd. | Cathode active material for lithium-ion secondary battery and preparation method thereof, cathode pole piece for lithium-ion secondary battery, and lithium-ion secondary battery |
| CN111485326A (en) * | 2020-03-13 | 2020-08-04 | 苏州椰为媒纤维制品科技有限公司 | Production method of mothproof palm fiber mat |
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| CN101069588B (en) | 2010-05-19 |
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