CN101049279A - Antibacterial shampoo of Nano silver, and preparation method - Google Patents
Antibacterial shampoo of Nano silver, and preparation method Download PDFInfo
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- CN101049279A CN101049279A CN 200710027921 CN200710027921A CN101049279A CN 101049279 A CN101049279 A CN 101049279A CN 200710027921 CN200710027921 CN 200710027921 CN 200710027921 A CN200710027921 A CN 200710027921A CN 101049279 A CN101049279 A CN 101049279A
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- solution
- silver
- nano silver
- aqueous solution
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 27
- 239000002453 shampoo Substances 0.000 title claims abstract description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims description 35
- 238000002360 preparation method Methods 0.000 title claims description 13
- 238000000034 method Methods 0.000 claims abstract description 5
- 230000008569 process Effects 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 28
- 239000004332 silver Substances 0.000 claims description 23
- 229910052709 silver Inorganic materials 0.000 claims description 23
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000084 colloidal system Substances 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000001648 tannin Substances 0.000 claims description 9
- 235000018553 tannin Nutrition 0.000 claims description 9
- 229920001864 tannin Polymers 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- OWEGWHBOCFMBLP-UHFFFAOYSA-N 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethylbutan-2-one Chemical compound C1=CN=CN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 OWEGWHBOCFMBLP-UHFFFAOYSA-N 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229960003344 climbazole Drugs 0.000 claims description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical group [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 abstract description 4
- 206010059866 Drug resistance Diseases 0.000 description 5
- 241000588724 Escherichia coli Species 0.000 description 5
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 4
- 241000191967 Staphylococcus aureus Species 0.000 description 4
- 241000222122 Candida albicans Species 0.000 description 3
- 229940095731 candida albicans Drugs 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 229940088710 antibiotic agent Drugs 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 241000606153 Chlamydia trachomatis Species 0.000 description 1
- 241000194033 Enterococcus Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000588653 Neisseria Species 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 208000019802 Sexually transmitted disease Diseases 0.000 description 1
- 241000295644 Staphylococcaceae Species 0.000 description 1
- 241000193996 Streptococcus pyogenes Species 0.000 description 1
- 206010053615 Thermal burn Diseases 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229940038705 chlamydia trachomatis Drugs 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 231100000286 mucous membrane, eye irritation or corrosion testing Toxicity 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000008557 oxygen metabolism Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Abstract
An antibacterial nano-Ag shampoo features that its active bactericiding component is silver nanoparticles. Its preparing process is also disclosed.
Description
Technical field:
The present invention relates to shampoo and preparation method thereof technical field, particularly a kind of antibacterial shampoo of Nano silver and preparation method thereof.
Background technology:
Nanometer silver solution has the characteristics of the following aspects:
1, safety is good
Acute oral toxicity test: the true border of nano-silver antiseptic solution nontoxic level material; One time intact skin stimulates: nonirritant; Repeatedly intact skin stimulates: nonirritant; Acute eye irritation test/corrosion test: be nonirritant.
2, wide spectrum, potent sterilization
The silver granule can directly enter thalline and oxygen metabolism enzyme and (SH) combine, thalline is choked to death, can kill microorganisms such as most of antibacterials of being in contact with it, fungus, mycete, spore.Discover through domestic eight big authoritative institutions: silver is to pathogenic bacteria of drug-resistant such as drug resistance escherichia coli, drug resistance golden staphylococci, drug-resistant pseudomonas aeruginosa, streptococcus pyogenes, drug resistance enterococcus, and anaerobe etc. have comprehensive antibacterial activity; To burn and scald injure the common antibacterial of wound surface such as staphylococcus aureus, escherichia coli, bacillus pyocyaneus, Candida albicans and other G+, the G-pathogenic bacterium all have bactericidal action; To chlamydia trachomatis, cause that the gonococcus of sexually transmitted disease also has powerful bactericidal action.
3, have no drug resistance
Nanometer silver can be directly killing bacteria apace, make its forfeiture fertility, antibacterial can not produce drug resistance.
4, antiinflammatory, healing of wound effect
5, minimum inhibitory concentration MIC is low
Bibliographical information is arranged, the zeolite antibacterial agent of silver ion (argentiferous 2.5%) to escherichia coli, staphylococcus aureus, bacillus pyocyaneus, Candida albicans MIC be respectively 62.5,125,62.5,250mg/kg; Industry standard is 8 one kinds of antibacterial shampoo of Nano silver and preparation method thereof mg/kg to escherichia coli, staphylococcus aureus; Nanometer silver solution is 10mg/kg to the MIC of above several antibacterials.
6, good processability
The carrying silver ion antibacterial is generally pressed powder, in use generally will handle it, makes its good dispersion in base material; Nano titanium oxide has the trend of spontaneous reunion, will pass through dispersion treatment before using.The nanometer silver solution that disappears is liquid, and nanoparticulate dispersed is good, need not anticipate good processability before the use.
7, good endurance
In the nanometer silver solution, the surface adsorption of silver has protecting colloid, has solved silver-colored oxidation and discoloration problem well, and simultaneously, silver slowly discharges silver ion, thereby has durable antibiotic.
8, good stability
Based on the characteristics of above nanometer silver solution, be widely used in the article of everyday use aspect, can make anti-bacterial hand lotion, antibacterial bath cream, antibiotic shampoo, Antibacterial soaps etc.
Summary of the invention:
Purpose of the present invention provide a kind of prescription rationally, the higher antibacterial shampoo of Nano silver of cost performance and preparation method thereof.
For achieving the above object, the present invention adopts following technical scheme: it comprises following composition, by mass percentage,
AES 15～25
K12 6～12
16 mixed alcohols 1.5～2.5
638 thickening agents 0.5～1.0
6501 2.5～5
M550 2.5～3.5
BS-12 2.5～3.5
Pearling agent 1.0～2.0
Lanoline 1.0～2.0
The active climbazole 0.5～0.9 of CLM
Glycerol 1.5～2.5
Cellulose gum CMC 0.3～0.6
1000ppm nanometer silver solution 3.0～10
Essence 0.2～0.5
Water surplus.
Wherein, described 1000ppm nanometer silver solution self-control; its preparation method is: agitation and dropping dilute ammonia solution in 1.6% the silver nitrate solution; behind the resolution of precipitate to be generated; with the dilution of 10 times water, add tannin aqueous solution and protecting colloid aqueous solution, heated and stirred to 75 ℃; constant temperature 15～30 minutes can make the stable bronzing nanometer silver solution of dispersibility.
Described tannin aqueous solution is 100ml, and wherein containing the tannin amount is 0.8g; The protecting colloid aqueous solution is 50ml, wherein contains protecting colloid 1g.
A kind of preparation method of antibacterial shampoo of Nano silver, its step is as follows, heat water to 80 ℃, in whipping process, cool to 50 ℃ after AES, the K12 of adding dissolving formula ratio, 638 thickening agents, lanoline, the pearling agent successively, mix with cellulose gum CMC solution stirring, after adding, add all the other each material by formula ratio with the active climbazole solution stirring of the solvent CLM of warm water, transferring pH value with citric acid is about 7, transfers viscosity with sodium chloride after reducing to room temperature.
Beneficial effect of the present invention is, has well solved defectives such as existing chemical antibacterial is poisonous, chafe, poor durability, and the antibacterial shampoo of Nano silver through reasonable process and formulation has high cost performance; This shampoo can not only be removed the dirt on hair and the scalp, health is had no adverse effects, and can the physiological function of hair, scalp be played a driving role, and makes hair light, attractive in appearance and compliance.
The specific embodiment:
The present invention includes following composition, by mass percentage,
AES 16
K12 8
16 mixed alcohols 1.6
638 thickening agents 0.6
6501 3
M550 3
BS-12 3
Pearling agent 1.5
Lanoline 1
The active climbazole 0.75 of CLM
Glycerol 2
Cellulose gum CMC 0.3
1000ppm nanometer silver solution 5
Essence 0.2
Water surplus
Described 1000ppm nanometer silver solution self-control; its preparation method is: agitation and dropping dilute ammonia solution in 1.6% the silver nitrate solution; behind the resolution of precipitate to be generated, the water dilution with 10 times adds tannin aqueous solution and protecting colloid aqueous solution; heated and stirred to 75 ℃; constant temperature 15～30 minutes can make the stable bronzing nanometer silver solution of dispersibility, wherein; nano-Ag particles is atomic little, and mean diameter is 5nm.
Described tannin aqueous solution is 100ml, and wherein containing the tannin amount is 0.8g; The protecting colloid aqueous solution is 50ml, wherein contains protecting colloid 1g.
Preparation method of the present invention, its step is as follows: heat water to 80 ℃, in whipping process, cool to 50 ℃ after AES, the K12,638 of adding dissolving formula ratio, lanoline, the pearling agent successively, mix with cellulose gum CMC solution stirring, after adding with the active climbazole solution stirring of the solvent CLM of warm water, by good all the other each material that add of prescription, transferring pH value with citric acid is about 7, transfers viscosity to required standard with sodium chloride after reducing to room temperature.
Because the synthetic nano-Ag particles of the present invention is atomic little, mean diameter is 5nm, and surface area is bigger, so have superpower activity and stronger tissue permeability, its bactericidal action is hundreds of times of common silver.
Through entrusting the detection of microorganism detection center, Guangdong Province, nanometer silver solution is tested microorganism killing tested; Test strain has escherichia coli (ATCC25922), staphylococcus aureus (ATCC 6538), candida albicans (ATCC 10231), Pseudomonas aeruginosa (ATCC 9027), bacillus subtilis black mutation (ATCC 9372), and the present invention has very strong bactericidal effect to above-mentioned strain.
The nanometer silver solution of preparation, placed 1 year after, its color does not change, and does not have precipitation, still is transparency liquid.The disinfectant solution of good seal under 54 ℃ of calorstats, was deposited silver content rate of descent≤4.5 14 days.According to disinfection technology standard version in 2002 as can be known: through 54 ℃ of disinfectant solution of depositing 14 days, bactericidal active ingredient rate of descent≤10%, then storage life, can be decided to be 1 year.
The shampoo that the present invention is prepared, its color and luster and fragrance meet company standard; Physical and chemical index meets following standard: pH value 4.0～8.0 in the time of 25 ℃, and working substance content is not less than 10%, and foam, heat-resisting, cold-resistant, viscosity etc. all meet present rower.
Claims (4)
1, a kind of antibacterial shampoo of Nano silver is characterized in that: it comprises following composition,
By mass percentage,
AES 15～25
K12 6～12
16 mixed alcohols 1.5～2.5
638 thickening agents 0.5～1.0
6501 2.5～5
M550 2.5～3.5
BS-1?2 2.5～3.5
Pearling agent 1.0～2.0
Lanoline 1.0～2.0
The active climbazole 0.5～0.9 of CLM
Glycerol 1.5～2.5
Cellulose gum CMC 0.3～0.6
1000ppm nanometer silver solution 3.0～10
Essence 0.2～0.5
Water surplus.
2, a kind of antibacterial shampoo of Nano silver according to claim 1; it is characterized in that: the self-control of 1000ppm nanometer silver solution; its preparation method is: agitation and dropping dilute ammonia solution in 1.6% the silver nitrate solution; behind the resolution of precipitate to be generated; with the dilution of 10 times water, add tannin aqueous solution and protecting colloid aqueous solution, heated and stirred to 75 ℃; constant temperature 15～30 minutes can make the stable bronzing nanometer silver solution of dispersibility.
3, a kind of antibacterial shampoo of Nano silver according to claim 2 is characterized in that: the tannin aqueous solution is 100ml, and wherein containing the tannin amount is 0.8g; The protecting colloid aqueous solution is 50ml, wherein contains protecting colloid 1g.
4, a kind of preparation method of antibacterial shampoo of Nano silver, it is characterized in that: its step is as follows, heat water to 80 ℃, in whipping process, cool to 50 ℃ after AES, the K12 of adding dissolving formula ratio, 638 thickening agents, lanoline, the pearling agent successively, mix with cellulose gum CMC solution stirring, after adding, add all the other each material by formula ratio with the active climbazole solution stirring of the solvent CLM of warm water, transferring pH value with citric acid is about 7, transfers viscosity with sodium chloride after reducing to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100279217A CN101049279B (en) | 2007-04-30 | 2007-04-30 | Antibacterial shampoo of Nano silver, and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100279217A CN101049279B (en) | 2007-04-30 | 2007-04-30 | Antibacterial shampoo of Nano silver, and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101049279A true CN101049279A (en) | 2007-10-10 |
| CN101049279B CN101049279B (en) | 2010-06-23 |
Family
ID=38781020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100279217A Expired - Fee Related CN101049279B (en) | 2007-04-30 | 2007-04-30 | Antibacterial shampoo of Nano silver, and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101049279B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102090993A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Anhydrous hand washing agent for sterilization and disinfection during paroxysmal calamities like earthquake and debris flow |
| CN102860923A (en) * | 2012-09-21 | 2013-01-09 | 华绣科技有限公司 | Nano-silver antibacterial liquid soap and preparation method thereof |
| CN102871864A (en) * | 2012-10-26 | 2013-01-16 | 广东同德药业有限公司 | Antimicrobial and dandruff-removing nano-silver hair foaming emulsion |
| CN103999873A (en) * | 2014-06-18 | 2014-08-27 | 杜一挺 | Nano-silver antibacterial agent and preparation method thereof |
| CN106377486A (en) * | 2016-09-06 | 2017-02-08 | 广西大学 | Method for preparing scurf-removing itching-relieving hair shampoo |
| CN109512713A (en) * | 2019-01-04 | 2019-03-26 | 广州亿美化妆品生物科技有限公司 | A kind of nano silver toner and preparation method thereof |
| CN112370366A (en) * | 2020-12-16 | 2021-02-19 | 乐比(广州)健康产业有限公司 | Shampoo and preparation method thereof |
| CN112891279A (en) * | 2021-03-31 | 2021-06-04 | 李绍旭 | Traditional Chinese medicine scalp care composition, preparation method and application thereof |
| CN116602890A (en) * | 2023-05-31 | 2023-08-18 | 广州家化化学有限公司 | Anti-dandruff shampoo containing nano-gold and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1179646C (en) * | 2001-04-20 | 2004-12-15 | 朱红军 | Aggregation-preventing nanometer wide-spectrum antibacterial silve powder and its inductrial production process |
| WO2003055456A1 (en) * | 2001-12-21 | 2003-07-10 | Rhodia Inc. | Stable surfactant compositions for suspending components |
-
2007
- 2007-04-30 CN CN2007100279217A patent/CN101049279B/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102090993A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Anhydrous hand washing agent for sterilization and disinfection during paroxysmal calamities like earthquake and debris flow |
| CN102090993B (en) * | 2010-09-08 | 2013-03-06 | 成进学 | Anhydrous hand washing agent for sterilization and disinfection during paroxysmal calamities like earthquake and debris flow |
| CN102860923A (en) * | 2012-09-21 | 2013-01-09 | 华绣科技有限公司 | Nano-silver antibacterial liquid soap and preparation method thereof |
| CN102860923B (en) * | 2012-09-21 | 2013-11-27 | 华绣科技有限公司 | Nano-silver antibacterial liquid soap and preparation method thereof |
| CN102871864A (en) * | 2012-10-26 | 2013-01-16 | 广东同德药业有限公司 | Antimicrobial and dandruff-removing nano-silver hair foaming emulsion |
| CN102871864B (en) * | 2012-10-26 | 2014-04-09 | 广东同德药业有限公司 | Antimicrobial and dandruff-removing nano-silver hair foaming emulsion |
| CN103999873A (en) * | 2014-06-18 | 2014-08-27 | 杜一挺 | Nano-silver antibacterial agent and preparation method thereof |
| CN106377486A (en) * | 2016-09-06 | 2017-02-08 | 广西大学 | Method for preparing scurf-removing itching-relieving hair shampoo |
| CN109512713A (en) * | 2019-01-04 | 2019-03-26 | 广州亿美化妆品生物科技有限公司 | A kind of nano silver toner and preparation method thereof |
| CN112370366A (en) * | 2020-12-16 | 2021-02-19 | 乐比(广州)健康产业有限公司 | Shampoo and preparation method thereof |
| CN112370366B (en) * | 2020-12-16 | 2023-04-25 | 乐比(广州)健康产业有限公司 | Shampoo and preparation method thereof |
| CN112891279A (en) * | 2021-03-31 | 2021-06-04 | 李绍旭 | Traditional Chinese medicine scalp care composition, preparation method and application thereof |
| CN116602890A (en) * | 2023-05-31 | 2023-08-18 | 广州家化化学有限公司 | Anti-dandruff shampoo containing nano-gold and preparation method thereof |
| CN116602890B (en) * | 2023-05-31 | 2024-02-09 | 广州家化化学有限公司 | Anti-dandruff shampoo containing nano-gold and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN101049279B (en) | 2010-06-23 |
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