CN101048127A - Hair cosmetic - Google Patents

Hair cosmetic Download PDF

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Publication number
CN101048127A
CN101048127A CNA2005800368879A CN200580036887A CN101048127A CN 101048127 A CN101048127 A CN 101048127A CN A2005800368879 A CNA2005800368879 A CN A2005800368879A CN 200580036887 A CN200580036887 A CN 200580036887A CN 101048127 A CN101048127 A CN 101048127A
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Prior art keywords
hair
cosmetic composition
hair cosmetic
alcohol
quality
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Application number
CNA2005800368879A
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Chinese (zh)
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CN101048127B (en
Inventor
长野种雅
圷隆宏
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Shiseido Co Ltd
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Shiseido Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

Disclosed is a hair cosmetic composition containing a cationic surfactant, and a polyhydric alcohol selected from erythritol, diglycerin, 1,3-butyleneglycol and propylene glycol and/or a sugar alcohol. The total amount of the polyhydric alcohol and/or the sugar alcohol contained in the hair cosmetic composition is 10-50% by mass. This hair cosmetic composition repairs damaged hair and imparts it smoothness without making the hair greasy or stiff.

Description

Hair cosmetic composition
Technical field
The present invention relates to hair cosmetic composition, in more detail, the present invention relates to nurse the hair of damaged, the hair cosmetic composition of the hair conditioner of the sensation that is not clamminess again or hardens, hair maintenance agent etc.
Background technology
In the past,, be beneficial to combing, and give hair suitable moisture feeling, in hair cosmetic composition, suitably cooperated various oil contents or water soluble polymer etc. usually in order to nurse the hair of damaged.
But, using when being called as the oil preparation of hydrocarbon ils, ester oil, combing aftersensation hair is heavy, also has the tendency that is clamminess.On the other hand, under the situation of the wetting agent of hydrous water soluble macromolecular etc.,, grow with time the trend that can occur hardening though have the effect of moisture feeling when just having used.And such hair also can not obtain satisfied usability because of the difference of its kind with wetting agent.So people wish to develop the hair that can nurse damaged, can feel the hair cosmetic composition that hair is not clamminess, does not harden and feels again.
As for solving the technology that this defective is developed, the known specific amino acids class amphoteric surfactant that is combined with, and be combined with the hair cosmetic composition (opening the 2000-86453 communique) of the wetting agent, carbamide class wetting agent or the saccharide wetting agent that derive from plant with reference to the spy as wetting agent.
In addition, in cosmetic hair with typing effectiveness, by cooperating specific high polymerization Polyethylene Glycol, oil preparation, non-ionic surface active agent and water-soluble alcohol, can prepare and not be clamminess, and give the cosmetic hair (opening the 2003-26545 communique) of hair compliance with reference to the spy.
Summary of the invention
But above-mentioned spy opens the hair cosmetic composition of putting down in writing in the 2000-86453 communique, has the too moistening problem that is clamminess of hair that makes.In addition, the spy opens the cosmetic hair of putting down in writing in the 2003-26545 communique, exists hair to be hardened or dry and astringent problem.
Therefore, the object of the present invention is to provide the hair that can nurse damaged, can allow hair not be clamminess again and the sensation of hardening, and the good hair cosmetic composition of the cardability of hair.
The present invention is a kind of hair cosmetic composition, it contains cationic surfactant, and contain and be selected from erithritol, diglycerol, 1, at least a polyhydric alcohol in 3-butanediol, the propylene glycol and/or sugar alcohol and form, the total use level of polyhydric alcohol and/or sugar alcohol is 10~50 quality % of hair cosmetic composition gross mass.
Wherein, among polyhydric alcohol or sugar alcohol, preferred sugar alcohol.As sugar alcohol, can enumerate xylitol, fructose, Sorbitol, mannitol, inositol, glucose, lactose, maltose or sucrose.
Preferably in hair cosmetic composition of the present invention, further cooperate following general formula (I), (II) more than a kind or 2 kinds and the modified siloxane of (III) representing,
In the above-mentioned formula, m=30~500, n=1~15, a=0~30, b=5~30;
Figure A20058003688700061
In the above-mentioned formula, p=20~200, q=1~5, r=5~15;
Figure A20058003688700062
In the above-mentioned formula, m+n=3000~10000, n/ (m+n)=0.001~0.005.
Hair cosmetic composition of the present invention, not only effect excellence aspect the hair of nursing damaged, and the sensation that is not clamminess or hardens, and the cardability of hair is good.
The specific embodiment
Below preferred forms of the present invention is described.
The singulative that uses in this description and the appending claims is seen from context clearly to show and be not odd number, can be understood as to comprise a plurality of objects.
Cationic surfactant
As the cationic surfactant that uses among the present invention, for example can use alkyl quaternary ammonium salts, alkyl pyridine  salt or the amine salt of stearyl trimethyl ammonium chloride, mountain Yu base trimethyl ammonium chloride, VARISOFT TA100 etc., monoalkyl hydroxy alkyl ether chlorination ammonium salt, polyoxypropylene diethylmethyl ammonium salt, dialkyl amide base propyl group methyl amine salt, hydroxypropyl-dialkyl ammonium salt, hydroxypropyl-dialkyl amide base ammonium salt, dialkyl amide base ethyl diethyldithiocarbamate ammonium hydroxide salt, alkyl dimethyl benzyl ammonium salt etc.Wherein, preferred alkyl quaternary ammonium salt.
In the hair cosmetic composition total amount, preferred 0.01~10 quality % of the use level of cationic surfactant, more preferably 0.1~4.0 quality %.During less than 0.01 quality %, might not reach effect, and when surpassing 10 quality %, hair is clamminess as the object of the invention.
Polyhydric alcohol and sugar alcohol
The polyhydric alcohol that uses among the present invention is selected from erithritol, diglycerol, 1,3 butylene glycol and propylene glycol.As for other polyhydric alcohol, for example, dipropylene glycol, glycerol, isoprenediol then can not obtain good hair cardability.
As the sugar alcohol that uses among the present invention, for example can enumerate xylitol, fructose, Sorbitol, mannitol, inositol, glucose, lactose, maltose alcohol or sucrose etc.Among polyhydric alcohol or sugar alcohol, preferred sugar alcohol, the more preferably Sorbitol among the sugar alcohol, sucrose.
In the hair cosmetic composition total amount, above-mentioned specific polyhydric alcohol and/or preferred 10~50 quality % of total use level of sugar alcohol, more preferably 15~40 quality %.Its use level might not reach purpose effect of the present invention during less than 10 quality %, and uses when surpassing 50 quality %, and hair is clamminess.
Modified siloxane
Except that above-mentioned necessary composition, in the present invention, preferred above-mentioned general formula (I), (II) more than a kind or a kind or the modified siloxane of (III) representing of further cooperating.
The preferred use level of above-mentioned modified siloxane is 0.1~10 quality %.0.1 can improve the cardability of hair when quality % is above.And use when surpassing 10 quality %, hair is clamminess.
Other
In the scope of not damaging purpose of the present invention, except that above-mentioned necessary composition, as required, can also in hair cosmetic composition of the present invention, cooperate various adding ingredients commonly used in the present hair cosmetic composition.As this adding ingredient, for example can enumerate, anion surfactant, non-ionic surface active agent, amphoteric surfactant, high polymer siloxane chemical compound, organic acid such as citric acid or succinic acid or malic acid or its salt, the aminoacid of glycine or alanine or lysine etc., the anionic polymer of vinyl, cationic polymer, the amphiphilic polymers of acrylic compounds, non-ionic polymers, antibacterial, higher alcohol, hydrocarbon, natural oil, ester oil, coloring agent, spice, solvent (for example: ethanol, carbitol derivatives etc.), polyhydric alcohol beyond the composition of the present invention of ethylene glycol or glycerol etc., fatty acid etc.These adding ingredients can use a kind, also can be used in combination more than 2 kinds, in addition, can also cooperate in the suitable operation of preparation hair cosmetic composition.
Hair cosmetic composition of the present invention for example can be widely used as, hair maintenance agent, shampoo, hair conditioner, hair conditioner, typing foam etc.
Embodiment
Below enumerate embodiment the present invention is described more specifically, but the present invention is not limited in these embodiment.Unless Special Statement, use level is represented with quality %.
Embodiment 1~22 and comparative example 1~7
According to conventional method, prepare hair cosmetic composition according to each formula components shown in following table 1~table 4.For the hair cosmetic composition of being produced, according to following benchmark, the cardability of hair when estimating flushing, the cardability of dry back hair.
1. the cardability of hair when washing, the cardability of dry back hair
As the combing testing machine, use combing evaluation test machine コ one ミ Application グ テ ス one (manufacturing of テ Network ノ Ha シ モ ト (technohashimoto) company), and measure according to following method.
The load of measuring the hair of bleaching and the mutual tractive of comb and the hair bundle being subjected to.
Based on by the data that said method was obtained, judge according to following metewand.The determination data and the result of determination that obtain are shown in table 1~table 3 in the lump.
(metewand)
◎: as 1.0 o'clock, value was below 0.8 with the numerical value of comparative example 1.
Zero: as 1.0 o'clock, value was greater than 0.8 with the numerical value of comparative example 1, but was below 0.95.
△: as 1.0 o'clock, the value of embodiment was greater than 0.95 with the numerical value of comparative example 1, but was below 1.0.
*: as 1.0 o'clock, value was greater than 1.0 with the numerical value of comparative example 1.
Table 1
(quality %)
Composition Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
Stearyl alcohol 5 5 5 5 5 5 5 5
Shan Yu base trimethyl ammonium chloride 2 2 2 2 2 2 2 2
Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01
Erithritol 15 30 - - - - - -
Diglycerol - - 15 30 - - - -
Xylitol - - - - 15 - - -
Fructose - - - - - 15 - -
Sorbitol - - - - - - 15 30
Mannitol - - - - - - - -
Inositol - - - - - - - -
Glucose - - - - - - - -
Lactose - - - - - - - -
Maltose alcohol - - - - - - - -
Sucrose - - - - - - - -
1,3 butylene glycol - - - - - - - -
Propylene glycol - - - - - - - -
Purified Water In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
(assessment item)
The cardability of hair during flushing 0.88 0.94 0.88 0.88 0.69 0.73 0.60 0.55
The cardability of dry back hair 0.70 0.79 0.84 0.71 0.79 0.80 0.78 0.67
(assessment item)
The cardability of hair during flushing
The cardability of dry back hair
Table 2
(quality %)
Composition Embodiment 9 Embodiment 10 Embodiment 11 Embodiment 12 Embodiment 13 Embodiment 14 Embodiment 15 Embodiment 16
Stearyl alcohol 5 5 5 5 5 5 5 5
Shan Yu base trimethyl ammonium chloride 2 2 2 2 2 2 2 2
Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01
Erithritol - - - - - - - -
Diglycerol - - - - - - - -
Xylitol - - - - - - - -
Fructose - - - - - - - -
Sorbitol - - - - - - - -
Mannitol 15 - - - - - - -
Inositol - 15 - - - - - -
Glucose - - 15 - - - - -
Lactose - - - 15 - - - -
Maltose alcohol - - - - 15 - - -
Sucrose - - - - - 15 - -
1,3 butylene glycol - - - - - - 30 -
Propylene glycol - - - - - - - 30
Modified siloxane (in the above-mentioned formula (I), m=50, n=5, a=0, the chemical compound of b=5) - - - - - - - -
Modified siloxane (in the above-mentioned formula (III), m=5000, the chemical compound of n=25) - - - - - - - -
Modified siloxane (in the above-mentioned general formula (II), p=100, q=5, the chemical compound of r=10) - - - - - - - -
Purified Water In right amount In right amount In right amount In right amount In right amount In right amount In right amount In right amount
(assessment item)
The cardability of hair during flushing 0.63 0.62 0.70 0.70 0.60 0.53 0.87 0.89
The cardability of dry back hair 0.76 0.74 0.61 0.65 0.73 0.61 0.73 0.73
(assessment item)
The cardability of hair during flushing
The cardability of dry back hair
Table 3
(quality %)
Composition Embodiment 17 Embodiment 18 Embodiment 19 Embodiment 20 Embodiment 21 Embodiment 22
Stearyl alcohol 5 5 5 5 5 5
Shan Yu base trimethyl ammonium chloride 2 2 2 2 2 2
Citric acid 0.01 0.01 0.01 0.01 0.01 0.01
Erithritol - - - - - -
Diglycerol - - - - - -
Xylitol - - - - - -
Fructose - - - - - -
Sorbitol 15 30 30 - - -
Mannitol - - - - - -
Inositol - - - - - -
Glucose - - - - - -
Lactose - - - - - -
Maltose alcohol - - - - - -
Sucrose - - - 15 15 30
1,3 butylene glycol - - - - - -
Propylene glycol - - - - - -
Modified siloxane (in the above-mentioned formula (I), m=50, n=5, a=0, the chemical compound of b=5) 1 - - 3 - 5
Modified siloxane (in the above-mentioned formula (III), m=5000, the chemical compound of n=25) - 3 - - 5 1
Modified siloxane (in the above-mentioned formula (II), p=100, q=5, the chemical compound of r=10) - - 10 - - 2
Purified Water In right amount In right amount In right amount In right amount In right amount In right amount
(assessment item)
The cardability of hair during flushing 0.56 0.58 0.48 0.53 0.40 0.41
The cardability of dry back hair 0.53 0.45 0.43 0.51 0.45 0.35
(assessment item)
The cardability of hair during flushing
The cardability of dry back hair
Table 4
(quality %)
Composition Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4 Comparative example 5 Comparative example 6 Comparative example 7
Stearyl alcohol 5 5 5 5 5 5 5
Shan Yu base trimethyl ammonium chloride 2 2 2 2 2 2 2
Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 0.01
Sucrose 3 60 - - - - 15
Dipropylene glycol - - 30 - - - -
Glycerol - - - 15 30 - -
Propylene glycol - - - - - 15 30
Purified Water In right amount In right amount In right amount In right amount In right amount In right amount In right amount
(assessment item)
The cardability of hair during flushing 0.97 0.95 1.01 0.99 0.95 0.99 1.06
The cardability of dry back hair 0.99 1.05 1.04 0.98 1.01 1.04 1.07
(assessment item)
The cardability of hair during flushing ×
The cardability of dry back hair × × × × ×
Below show the cooperation example of hair cosmetic composition of the present invention.
Embodiment 23: hair conditioner
Shan Yu base trimethyl ammonium chloride 2.0 quality %
Stearyl alcohol 5.0
Sucrose 15.0
Modified siloxane 1.0
(in the above-mentioned general formula (I), m=50, n=5, a=0, the chemical compound of b=5)
Antiseptic is an amount of
Spice is an amount of
The Purified Water surplus
Embodiment 24: hair conditioner
Shan Yu base trimethyl ammonium chloride 3.2 quality %
Stearyl alcohol 7.0
Sorbitol 30.0
Modified siloxane 3.0
(in the above-mentioned general formula (III), m=5000, the chemical compound of n=25)
Antiseptic is an amount of
Spice is an amount of
The Purified Water surplus
Embodiment 25: hair conditioner
Shan Yu base trimethyl ammonium chloride 2.0 quality %
Stearyl alcohol 5.0
Fructose 15.0
Modified siloxane 2.0
(in the above-mentioned general formula (II), p=100, q=5, the chemical compound of r=10)
Antiseptic is an amount of
Spice is an amount of
The Purified Water surplus
Embodiment 26: hair conditioner
Shan Yu base trimethyl ammonium chloride 2.0 quality %
Stearyl alcohol 5.0
Sucrose 15.0
Modified siloxane 2.0
(in the above-mentioned formula (I), m=400, n=10, a=24, the chemical compound of b=24)
Modified siloxane 1.0
(in the above-mentioned formula (III), m=10000, the chemical compound of n=10)
Antiseptic is an amount of
Spice is an amount of
The Purified Water surplus
Embodiment 27: hair spray (hair mist)
Dimethyl polysiloxane 1.0 quality %
Ethanol 5.0
Stearyl alcohol 0.1
Behenyl alcohol 0.2
Sucrose 12.0
Dipropylene glycol 1.0
1,3 butylene glycol 1.0
Alkyl trimethyl ammonium chloride (77%) 0.5
Vinyl pyrrolidone/N N-dimethyl aminoethyl methacrylic acid copolymerization 2.5 things
P-Hydroxybenzoate is an amount of
The Purified Water surplus
Spice is an amount of
Embodiment 28: suppurative mastitis
Volatility isoparaffin 10.0 quality %
Dimethyl polysiloxane 2.0
Sorbitol 20.0
Polyethylene glycol 6000 1.0
Two isostearic acid polyglycerin ester 0.5
Sodium hydroxide 0.06
Phenyl phenol is an amount of
Sodium versenate is an amount of
Carrageenan 0.5
Dimethyl distearyl ammonium salt hectorite 0.5
Alkyl trimethyl ammonium chloride 0.3
Stearyl alcohol 1.0
Carboxy vinyl polymer 0.5
High polymerization dimethyl polysiloxane 2.0
The Purified Water surplus
Spice is an amount of
Embodiment 29: eruption amine
Ethanol 10.0 quality %
Sucrose 15.0
Behenyl alcohol 1.0
Alkyl trimethyl ammonium chloride (77%) 0.1
ユ カ Off イ one マ one SM 10.0
Polyoxyethylene/methyl polysiloxane copolymer 1 .0
Volatility isoparaffin 5.0
High polymerization dimethyl polysiloxane 1.0
The Purified Water surplus
Spice is an amount of
Embodiment 30: hair spray
Sucrose 20.0 quality %
Ethanol 5.0
ユ カ Off オ one マ one SM 12.0
2-alkyl-N-carboxymethyl-N-hydroxyethyl imidazoles  betanin 1.0
Polyoxyethylene hardened castor oil (60E.O.) 0.5
Alkyl trimethyl ammonium chloride 0.2
Stearyl alcohol 0.5
The p-Methoxybenzoic acid ester is an amount of
The Purified Water surplus
Spice is an amount of
Stock solution/propellant=92/8 (L.P.G.0.43MPa: DME=80: 20)

Claims (4)

1. hair cosmetic composition, contain cationic surfactant, and contain and be selected from erithritol, diglycerol, 1, at least a polyhydric alcohol in 3-butanediol, the propylene glycol and/or sugar alcohol and form, the total use level of polyhydric alcohol and/or sugar alcohol is 10~50 quality % of hair cosmetic composition gross mass.
2. hair cosmetic composition contains cationic surfactant and sugar alcohol and forms, and the use level of sugar alcohol is 10~50 quality % of hair cosmetic composition gross mass.
3. hair cosmetic composition as claimed in claim 1 or 2, above-mentioned sugar alcohol are to be selected from least a in xylitol, fructose, Sorbitol, mannitol, inositol, glucose, lactose, maltose alcohol and the sucrose.
4. hair cosmetic composition as claimed in claim 1 also contains following general formula (I), (II) and (III) at least a in the modified siloxane of expression,
Figure A2005800368870002C1
In the above-mentioned formula (I), m=30~500, n=1~15, a=0~30, b=5~30;
Figure A2005800368870003C1
In the above-mentioned formula (II), p=20~200, q=1~5, r=5~15;
Figure A2005800368870003C2
In the above-mentioned formula (III), m+n=3000~10000, n/ (m+n)=0.001~0.005.
CN2005800368879A 2004-11-05 2005-11-02 Hair cosmetic Active CN101048127B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2004321808A JP5086522B2 (en) 2004-11-05 2004-11-05 Hair cosmetics
JP321808/2004 2004-11-05
PCT/JP2005/020491 WO2006049311A1 (en) 2004-11-05 2005-11-02 Hair cosmetic composition

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Publication Number Publication Date
CN101048127A true CN101048127A (en) 2007-10-03
CN101048127B CN101048127B (en) 2011-01-05

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WO (1) WO2006049311A1 (en)

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Publication number Priority date Publication date Assignee Title
CN102458348A (en) * 2009-06-25 2012-05-16 株式会社资生堂 Hair cosmetic
WO2020133212A1 (en) * 2018-12-28 2020-07-02 Henkel Ag & Co. Kgaa Solid hair conditioning composition

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JP4837544B2 (en) * 2005-12-21 2011-12-14 ホーユー株式会社 Method for suppressing decrease in dyeability or decolorization in dyeing process or decoloring process after decoloring, and fiber treatment composition
JP4837543B2 (en) * 2005-12-21 2011-12-14 ホーユー株式会社 Method for stabilizing the color tone of dyed fibers
JP4825141B2 (en) * 2007-01-15 2011-11-30 ホーユー株式会社 Hair treatment composition and hair treatment method
EP3311790B1 (en) * 2015-06-22 2019-11-06 Kao Corporation Hair treatment agent
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Publication number Priority date Publication date Assignee Title
CN102458348A (en) * 2009-06-25 2012-05-16 株式会社资生堂 Hair cosmetic
CN102458348B (en) * 2009-06-25 2014-07-09 株式会社资生堂 Hair cosmetic
WO2020133212A1 (en) * 2018-12-28 2020-07-02 Henkel Ag & Co. Kgaa Solid hair conditioning composition

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CN101048127B (en) 2011-01-05
JP5086522B2 (en) 2012-11-28
WO2006049311A1 (en) 2006-05-11

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