CN100593049C - Coated paper product and the method for producing the same - Google Patents

Coated paper product and the method for producing the same Download PDF

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Publication number
CN100593049C
CN100593049C CN200510093947.2A CN200510093947A CN100593049C CN 100593049 C CN100593049 C CN 100593049C CN 200510093947 A CN200510093947 A CN 200510093947A CN 100593049 C CN100593049 C CN 100593049C
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China
Prior art keywords
paper product
coated paper
parts
coating
weight
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Expired - Fee Related
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CN200510093947.2A
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Chinese (zh)
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CN1740441A (en
Inventor
J·T·布朗
R·穆克阿迈拉
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Rohm and Haas Co
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Rohm and Haas Co
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Publication of CN1740441A publication Critical patent/CN1740441A/en
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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/42Coatings with pigments characterised by the pigments at least partly organic
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/10Mixtures of chemical and mechanical pulp
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/50Proteins
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/54Starch
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52Additives of definite length or shape
    • D21H21/54Additives of definite length or shape being spherical, e.g. microcapsules, beads
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/27Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y10T428/273Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating

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  • Paper (AREA)

Abstract

The present invention relates to a coated paper product and the method for producing the same. High levels of an organic pigment, an inorganic pigment, relatively high levels of a binder, as well as,water are combined to form a coating composition which is applied to a low weight paper web. Then, the coated paper web is dried and calendered at relatively low calender intensity. A high bulk low weight or ultra-low weight coated paper product results which exhibits optical and printing properties comparable to its heavier counterparts.

Description

Coated paper product and production method thereof
Technical field
The present invention relates to a kind of coated paper product, this product makes lightweight, inexpensive coated paper product have the more superior performance of heavier coated paper product, and has kept optics, sense of touch and the printing characteristic of heavier coated paper product simultaneously.In addition, the also relevant method of producing this coated paper product of the present invention.
Background technology
As U.S. Pat 6531183 described a kind of preparation methods that when keeping high bulk density, can also improve the coated paper product characteristic, the coating composition that one deck contains the plastic pigment particle is used on the surface that is included in body paper at least, and make the press polish instrument of body paper, roller temperature that this instrument maintains is relatively low and nip pressure by the multiple pressure district.In addition, U.S. Pat 6387213 has disclosed the outward appearance that has non-coated paper and near the printing paper of the printability of coated paper, its preparation method is: the coating of every each face that makes paper being used the 5-25 pound.
Summary of the invention
The present invention at problem be when obtaining good bulk density, optical characteristics and printing characteristic, to reduce the weight of coating, and regulate the last optical condition that contains the ground wood pulp stationery relatively at a low price.
One aspect of the present invention is a kind of coated paper product, and it is composed as follows:
Every order uses the 16-36 pound to contain the not coating paper web (paper web) of ground wood pulp paper pulp;
Wherein, coating is all carried out with a kind of water-based paint compositions in the two sides of paper web, and this coating composition comprises:
By per 100 parts of dried total pigment, 0 to 45 part of inorganic pigment,
By per 100 parts of dried total pigment, 55 to 100 parts of tool hole polymeric pigment particles, its particle diameter is 0.2 to 5 μ m, pore volume 20-80%,
By per 100 parts of dried total pigment, 10 to 50 parts of starch or polymerization of protein adhesive, wherein,
Every each face of the coated paper product behind the dry glazing that makes has 1 to 3 pound dry paint composition, and every to make the weight of paper product be 18 to 40 pounds, and it is about 90 that opacity equals for a short time, and glossiness is 40 to 85, and its brightness is 70 to 83.Employed 1 order of this paper is equivalent to 3300 square feet.
Another aspect of the present invention is the method for producing a kind of coated paper product, may further comprise the steps:
Make 16 to 36 pounds the one side at least that contains the ground wood pulp paper web carry out coating with a kind of coating composition every, this coating composition comprises:
By per 100 parts of dried total pigment, 0 to 45 part of inorganic pigment,
By per 100 parts of dried total pigment, 55 to 100 parts of tool hole polymeric pigment particles, its particle diameter is 0.2 to 5 μ m, pore volume 20-80%,
By per 100 parts of dried total pigment, 10 to 50 parts of starch base or protein-based polymeric binder, and moisture is higher than 60% Aquo-composition total moisture content,
Coating composition on the dry paper product makes and leaves 1 to 3 pound dry coating paper compound on every each face that makes the dry coating paper product; Every to make the weight of dry coating paper product be 18 to 40 pounds, and it is about 90 that opacity equals for a short time, and glossiness is 40 to 85, and its brightness is 70 to 83;
And make dry coated paper product by the press polish instrument, wherein, the press polish instrument contains 2 cylinders and 1 road nip at least.
Be on dry matter basis, every part of total granules of pigments and 55 to 100 parts contain hole aggregated particles combination, and the combination of the total granules of pigments of every volume and 10 to 50 parts of starch and/or casco can reduce employed coating weight together with aforesaid rolling condition; And, can generate the paper of lightweight and ultralight matter like this, the fiber of its use is higher than the employed ratio of typical coated paper to being coated with stratum proportion.Preferably, every weight of coated paper product that makes is between the 24-34 pound.
In addition, be on dry matter basis, every part of total granules of pigments and 55 to 100 parts of combinations that contain the hole aggregated particles, and the combination of the volume of every part of total granules of pigments and 10 to 50 parts of starch and/or casco together with aforementioned rolling condition can the output equivalent weight under the higher papery of intensity, thereby improve the paper feed or the productive rate of paper machine, other paper performance in print steps subsequently that the while but lays particular stress on than equality strength is better.Use this combination also to bring some other characteristics, comprising: the more traditional coated paper of laying particular stress on of lighter coated paper has littler compression, body paper persistence and hardness.And the optical property of coated paper product, sense of touch and printing characteristic still can be kept the quite level of initially quantitatively higher coated paper product.
With the regulation amount be coated with this coating composition after, calculated glossiness (measuring) according to 75 ° of testing sequences of TAPPI, opacity (measuring), and brightness (measuring) according to TAPPI testing sequence T452-0M-92 according to TAPPI testing sequence T425-0M-91.This coated paper have with the non-porous polymeric pigment coated suitable characteristic of paper, and be at least 2 times of this coated paper with pigment coated its weight of paper of non-porous polymeric.The preferable range of opacity and glossiness is respectively 85-90 and 50-55.
Comprise tool hole polymeric pigment particle in the coating of the present invention, hereinafter described particle, its particle size range is at 0.2 to 5.0 micron, and preferred 0.3 to 2.0 micron, and pore volume is between about 20 to 80%, between the preferred 40-70%.The density range of these particles is between 0.4-1.0g/cc, and preferred range is 0.4-0.6g/cc.In addition, each in these particles all contains single or multiple hollow (hole); These holes can be spherical or irregular, and pore region can be isolate or communicate.These particles can have the appearance of similar sponge, and the surface of these particles can be from smooth harmless to coarse perforation.Such particle is published in, in following these patents: U.S. Pat 4427836, U.S. Pat 5036109, U.S. Pat 5157084, U.S. Pat 5216044, U.S. Pat 5409776, U.S. Pat 5494971, U.S. Pat 5521253, U.S. Pat 5527613, U.S. Pat 5989630, U.S. Pat 6020435, U.S. Pat 6139961 and U.S. Pat 6673451.In addition, these particles can be crosslinked and charged; The example of crosslinked charged particle is published in the U.S. Pat 6624272.
Other polymeric pigment particle include but not limited to, the solid polystyrene bead, such as DOW711 and DOW722, both by the Dow chemical company make (Midland, Mich.); Solid polymethacrylates bead; The configuration of surface that defines in U.S. Pat 5510422 and european patent application publication numbering 0842992A2 (comprises at least one polymer nuclear phase (nuclear phase contains a hole at least), at least one polymer shell mutually (shell is mutually at least partly around core), and at least one is with core hole and the outside passage that links to each other of hole) and the polymer beads of composition; And any glass transition temperature is higher than 40 ℃ polymer beads and may be used to the present invention.
In addition, the present invention can also comprise coloring earth.Suitable coloring earth comprises, but be not limited only to the kaolinton of the kaolin of the calcium carbonate of milling and precipitating, kaolin, calcination, delamination and structure, titanium dioxide, alumina silicate, magnesium silicate, magnesium carbonate, amorphous silicon di-oxide, zinc oxide, zinc hydroxide, aluminium oxide, aluminium hydroxide, talcum, satin white, barium sulfate and calcium silicates.
Starch and polymerization of protein adhesive suitable among the present invention comprise, but be not limited only to the carboxymethyl cellulose after casein, starch and wheat flour, gelatin and alginates, cellulose, hydroxyethylcellulose, methylcellulose and natural products are modified, dextrin, ethyl starch (comprising the ethyl cornstarch), lignin or the like.With the starch of natural, CATION, anion and/or zwitterionic starch and synthetic cationic polymer reaction gained as the dry tenacity agent.The native starch that uses is as, the mixture of cornstarch, farina, wheaten starch, rice starch, tapioca, sago starch, sorghum starch, tapioca, pea starch, rye starch or above-mentioned native starch.Other suitable starch has rye meal and other meal.The protein starch that contains from rye, wheat and legume crop is suitable for too.The amylopectin weight percentage is at least 95% native starch and also is applicable to the cation modified of polymer.Preferred amylopectin weight percentage is at least 99% starch.This kind of starch can obtain with following method: traditional native starch is taked the classification of starch to separate or use some to plant method for planting to make the crop pure amylopectin of output basically.The amylopectin weight percentage is at least 95% starch, and preferred percentage by weight is at least 99% starch, and market is on sale.These starch sell forms as, waxy maize starch, cured shape farina or cured shape wheaten starch.Natural starch can be modified separately or with the cationic polymer mixing.
The synthesized polymer adhesive that comprises among the present invention is about, and is on dry matter basis, and per 100 parts of total pigment add about 0 to 25 part of composite adhesives; Preferably, by per 100 parts of dried total pigment, 5 to 25 composite adhesiveses.Be applicable to that synthesized polymer adhesive of the present invention comprises, but be not limited only to, homopolymer, copolymer or trimer, polymer such as acrylic acid and/or methacrylate, polyvinyl acetate, polyvinyl alcohol, phenylpropyl alcohol copolymer; butylbenzene copolymer; vinylacetate-acrylic copolymer; ethylene-vinyl acetate copolymer; vinylacetate-T-shaped vinyl acetate (vinyl versatate) copolymer; vinylacetate-maleic acid vinyl ester copolymers; vinylacetate-vinyl chloride-acrylic acid trimer; ethylidine-vinyl chloride-acrylic acid trimer; polyurethane; polyethylene butyral resin; the acrylate copolymer of structure; the cyanoacrylate polymer of anoxybiotic; polyvinyl chloride; polyvinylidene chloride; polyethylene; ethylene-vinyl acetate copolymer; polypropylene; ethylene/acrylic acid copolymer; ethylene/methacrylic acid; be subjected to irradiated polyethylene; polyamide; polyester; epoxy; contain phenol; contain amino; contain furans; contain polyimides; natural rubber etc., styrene (alkane) copolymer and trimer; do not have and fill and styrene (alkane) block coefficient; neoprene; acrylonitrile-butadiene rubber; butene rubber; polybutene rubbers; ethylene-propylene-diene rubber; silicon rubber and animal glue etc.Polymer or prepolymer can optionally contain weight content up to about 10% a certain function monomer, for example, but are not limited only to monomer of carboxylic acid, phosphate, sulfate, sulfonate and acid amides and composition thereof, non-functional monomer and composition thereof.Preferred polymeric binder is the water-soluble emulsion polymer.
In a preferred embodiment, composite adhesives comprises, cinnamic acrylic ester, styrene-butadiene, styrene-butadiene-acrylonitrile, ethyl acetate and ethylene-acrylate.
Coating moisture of the present invention is higher than 60% of coating composition gross weight.Moisture is lower than 60% product can obtain comparable result.
Coating of the present invention can also contain trace, just be lower than coating composition gross weight 20%, the conventional adhesive additive is as crosslinking agent, slipping agent, thickener, alkali, optical polish agent, defoamer, dispersion resin, mould inhibitor, anti-microbial agents, milkiness pigment, expansion pigment and developer.The component that these selectivity are added can add in the coating prepared product respectively or be added in the premix.
Method of the present invention comprises with coating machine carries out coating with aforesaid coating to body paper, and then with the coated paper drying, make every every face of coated paper product that makes leave 1 to 3 pound dry paint composition, preferably, every dry paint composition that makes the every face of coated paper product leave the 1.0-2.5 pound.
Suitable coating machine include but not limited to, short stop (pressurize) time, roller coating machine, jet, metering applying glue pressure apparatus, spray equipment, curtain and peg.In one embodiment, coating machine is a short time to drag the cutter spreader, and its edge of a knife is 0.457mm/45 °.In another embodiment, coating machine is a kind of injection coating machine.
Suitable drying means include but not limited to, the combination of dry or these methods of infrared, air-flow and air bells cap.In one embodiment, with infrared ray and hot air dryer coated paper is carried out drying, the target humidity that reaches is 5%.
Then, coated paper reaches required glossiness of final paper product and smoothness through press polish again.Under the condition of steady temperature and pressure, reduce the roller number and can reduce press polish intensity, thereby obtain the more paper of bulky.Keeping under the constant situation of roller and number of nips, the reduction temperature and pressure has the effect that generates than the bulky paper equally.Can be with two soft-nip calendering machines that are arranged in order on line, or press polish is carried out on the two sides of coating paper web simultaneously with the multiple pressure district supercalendering unit of off-line, to obtain the target glossiness of 50-55.Other suitable calender include but not limited to, Jamis, Optiload (prolongation nip) and Shoe calender, but on line or off-line are used.Press polish instrument of the present invention is made up of a series of nip and roller.The number of nip is in 1 to 11 scope, and the number of roller is in 2 to 12 scope.Rolling condition of the present invention is softer than the rolling condition that is used for typical lightweight coated paper.
In one embodiment, press polish is carried out on the two sides of lightweight coated paper simultaneously, thereby obtained the target glossiness of 50-55 with two on line soft-nip calendering machines that are arranged in order.Soft-nip calendering machine roller is heated to 70-200 ℃, and each nip is used the pressure load of 100-350kN/m and obtains the target glossiness.
In another embodiment, with at least 3 but the separation supercalender that is no more than 5 nips carries out press polish to the lightweight coated paper, speed is 500m/min, and temperature is 50 to 150 ℃.Except the gravity load of roller, no longer apply any pressure.
The specific embodiment
In following embodiment, paper and coating is made in leading (pilot) coating instrument and is used.The body paper that is used for embodiment is that basis weight is 24 pounds/3300 square feet the wood paper that contains, with the interval velocity that is coated with of 4000ft/min coating (once one side) is carried out on the two sides of this body paper with short time pressurize (blade: 0.457mm/45 °) coating machine, and carry out drying to reach 5% target humidity with IR and hot air dryer.
Embodiment 1
Experimental detail:
Embodiment 1 is the control coatings paper product, and its coating does not contain tool hole polymeric pigment particle in each total pigment volume concentration.Coatings applications uses short time pressurize (blade coating machine) to carry out coating with the speed of 4000 feet per minute clocks in body paper (body paper that contains 24 pounds of ground woods), each one side, and recording coating weight with series connection β gauge like this is 5.5 pounds/order/face.When second face is carried out coating operation, with half soft-nip calendering roller by 2 series connection of paper web, every group temperature all maintains 170 ℃, and the pressure of nip maintains 350kN/m, like this, the sheet gloss of products obtained therefrom is about 52-53 (the glossiness meter by series connection records).Last at coating operation, with remaining coating but half coil paper of press polish is not by separating 5 nips of supercalendering unit, temperature maintenance is at 80 ℃, and the nip of application load is 150PSI, and the sheet gloss of products obtained therefrom is about 51-52 (the glossiness meter by series connection records).The press polish of soft nip the results are shown in the table.
Embodiment 2-7
Experimental detail:
What the coating of paper product contained 55 to 100 powder among the embodiment 2-7 in each total pigment volume concentration contains the hole aggregated particles.As previously mentioned, with short time pressurize (blade coating machine) with the speed of 4000 feet per minute clocks with coatings applications on body paper, each one side, however the weight of the embodiment 2-7 floating coat that records with the β gauge of connecting is 2.0 pounds/order/face.In coating operation, with half soft-nip calendering roller by 2 series connection of paper web, every group temperature all maintains 90 ℃, and the pressure of nip maintains 125 and 300kN/m, like this, the sheet gloss of products obtained therefrom is about 50-65 (the glossiness meter by series connection records).Last at coating operation, with remaining coating but half coil paper of press polish is not by separating 3 nips of supercalendering unit, temperature maintenance is at 60 ℃, (except the gravity of calender unit self) is the pressor areas load no longer, and the sheet gloss of products obtained therefrom is about 50-65 (the glossiness meter by series connection records).The press polish of soft nip the results are shown in embodiment 2-4 in the table, 6 and 7.Supercalender the results are shown in embodiment 5.
Figure C20051009394700101
Figure C20051009394700111

Claims (12)

1. coated paper product is characterized in that it contains:
The not coating paper web that contains every ream weight 16-36 pound of ground wood pulp;
Wherein, the two sides of paper web all applies with a kind of water-based paint compositions, and this coating composition comprises:
By per 100 parts of dried total pigment, 0 to 45 part of inorganic pigment,
By per 100 parts of dried total pigment, 55 to 100 parts of polymeric pigment particles with hole, wherein,
Described diameter with particle of hole is 0.2 to 5 μ m, and pore volume accounts for 20-80%, by per 100 parts of dried total pigment, and 10 to 50 parts of starch base or protein-based polymeric binder, wherein,
Each face of the coated paper product of the dry and press polish of every order has the coating composition of 1 to 3 pound of drying, and every to make the weight of paper product be 18 to 40 pounds, and opacity is not higher than 90, and glossiness is 40 to 85, and brightness is 70 to 83.
2, coated paper product as claimed in claim 1 is characterized in that, by per 100 parts of dried total pigment, described paper product also contains 5 to 25 parts composite adhesives.
3. coated paper product as claimed in claim 2 is characterized in that, the granular size with granules of pigments of hole is 0.3-2.0 μ m.
4, coated paper product as claimed in claim 3 is characterized in that, described pore volume with granules of pigments of hole accounts for 40-70%.
5, coated paper product as claimed in claim 4 is characterized in that, described paper product is behind application composition, and its weight is every 24-34 pound that makes.
6, coated paper product as claimed in claim 5 is characterized in that, its opacity is 85-90.
7, coated paper product as claimed in claim 6 is characterized in that, its glossiness is 50-55.
8, a kind of method of producing coated paper product is characterized in that, may further comprise the steps:
Apply a coating composition on the one side at least of the paper web that contains ground wood pulp, the weight of wherein uncoated paper web is whenever to make 16 to 36 pounds, and this coating composition comprises:
By per 100 parts of dried total pigment, 0 to 45 part of inorganic pigment,
By per 100 parts of dried total pigment, 55 to 100 parts of polymeric pigment particles with hole,
Wherein said diameter with particle of hole is 0.2 to 5 μ m, and pore volume accounts for 20-80%,
By per 100 parts of dried total pigment, 10 to 50 parts of starch base or protein-based polymeric binder, and
In total waterborne compositions, moisture is higher than 60%,
Coating composition on the dry paper product, making has 1 to 3 pound dry paint composition still to stay on every each face that makes the dry coating paper product, thereby form the coated paper product that every ream weight amount is 18 to 40 pounds a drying, opacity is not higher than 90, glossiness is 40 to 85, and its brightness is 70 to 83;
And make dry coated paper product by the press polish instrument, wherein the press polish instrument contains 2 rollers and 1 nip at least.
9, method as claimed in claim 8 is characterized in that, in the dry gross weight of coating composition, with every weight applying coating that makes every 1.0-2.5 pound of paper.
10, method as claimed in claim 8 is characterized in that, in the dry gross weight of coating composition, with spraying coating machine, applies coating composition with every weight of every 1.0-2.5 pound of paper that makes.
11, method as claimed in claim 8 is characterized in that, with the soft-nip calendering instrument paper product is carried out press polish, and this instrument contains the roller that is arranged in order, and instrument is heated to 70-200 ℃.
12, method as claimed in claim 8 is characterized in that, with the supercalendering instrument of off-line paper product is carried out press polish, and this instrument contains 3-5 nip, and wherein instrument is heated to 50-150 ℃.
CN200510093947.2A 2004-08-27 2005-08-26 Coated paper product and the method for producing the same Expired - Fee Related CN100593049C (en)

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US20060042768A1 (en) 2006-03-02
CN1740441A (en) 2006-03-01
DE602005014424D1 (en) 2009-06-25

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