CN100587093C - Ni based alloy, component, gas turbine device and application of Pd in the alloy - Google Patents
Ni based alloy, component, gas turbine device and application of Pd in the alloy Download PDFInfo
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 179
- 239000000956 alloy Substances 0.000 title claims abstract description 179
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 29
- 239000001257 hydrogen Substances 0.000 claims abstract description 28
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000007789 gas Substances 0.000 claims abstract description 18
- 238000009434 installation Methods 0.000 claims description 17
- 229910052768 actinide Inorganic materials 0.000 claims description 13
- 150000001255 actinides Chemical class 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 229910052746 lanthanum Inorganic materials 0.000 claims description 13
- 229910052706 scandium Inorganic materials 0.000 claims description 13
- 229910052727 yttrium Inorganic materials 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 229910052726 zirconium Inorganic materials 0.000 claims description 12
- 229910052741 iridium Inorganic materials 0.000 claims description 10
- 229910052762 osmium Inorganic materials 0.000 claims description 10
- 229910052697 platinum Inorganic materials 0.000 claims description 10
- 229910052707 ruthenium Inorganic materials 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 229910052758 niobium Inorganic materials 0.000 claims description 8
- 229910052715 tantalum Inorganic materials 0.000 claims description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 229910052720 vanadium Inorganic materials 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052702 rhenium Inorganic materials 0.000 claims description 6
- 229910052703 rhodium Inorganic materials 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 10
- 238000005275 alloying Methods 0.000 abstract description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 53
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 34
- 239000011651 chromium Substances 0.000 description 20
- 239000010936 titanium Substances 0.000 description 15
- 238000002485 combustion reaction Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 239000013078 crystal Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 229910000601 superalloy Inorganic materials 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 230000002349 favourable effect Effects 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- -1 member Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- LVIYYTJTOKJJOC-UHFFFAOYSA-N nickel phthalocyanine Chemical compound [Ni+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 LVIYYTJTOKJJOC-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000004881 precipitation hardening Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/055—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 20% but less than 30%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/056—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/057—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being less 10%
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Physical Vapour Deposition (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
The invention concerns a Ni based alloy suitable for single 5 crystalline, directionally solidified or polycrystalline components to be used at high temperatures. The alloy is a Ni based gamma/gamma'alloy and consists of different alloying elements within defined ranges. Among other defined ranges of elements, the alloy contains Pd in a significant amount sufficient to 10 provide the alloy with an improved resistance against hydrogen embrittlement. The invention also concerns a component (13, 15) designed for use as a component (13, 15) in a high temperature environment. Furthermore, the invention concerns a gas turbine arrangement. Moreover, the invention concerns the use of Pd for providing an alloy with improved resistance against hydrogen embrittlement.
Description
Invention field
The present invention relates to have the nickel-base alloy that is used for the pyritous excellent specific property.Alloy of the present invention for example can be used for the member of internal combustion turbine.The invention still further relates to the member of making by alloy of the present invention.Moreover, the invention still further relates to gas turbine installation.In addition, the invention still further relates to the application of Pd in alloy.
Background technology
Known have a multiple alloy that high temperature is used that is suitable for.This class alloy is called superalloy.Term " superalloy " be representative based on as nickel, iron and cobalt and contain the complex alloys of interpolation element such as chromium, carbon, aluminium, tungsten, rhenium, titanium, silicon and molybdenum.Term "based" means the element of the maximum weight part of alloy, and its weight % that does not promptly have other in alloy is equal to or higher than the element of the weight % of infrastructure elements.This interpolation element is generally used for giving high values of mechanical strength and the creep resistance under the high temperature, and improves scale resistance and heat/corrosion resistance.To nickel base superalloy, its high-heat strength part is obtained by precipitation hardening by the solid solution hardening of using element such as tungsten or molybdenum and part.This throw out is usually by adding aluminium and titanium to form based on Ni in main material (γ)
3(Ti, intermetallic compound γ ' Al) (" gammaprime ") and making.
File US 6177046 B1 have described γ/γ ' superalloy of a kind of Pd of containing.Adding Pd by this document is for providing improved weldability to this alloy.This document has been listed the very wide content range of alloying element.Gui Ding Pd content is 4-32 weight % in the claims.Press the most preferred alloying element scope of the different embodiment in this document, Pd content should be 5-40 weight % (table 7), 5-45 weight % (table 8) or 8-27 weight % (tables on 17 hurdles).In the specific embodiment of this document, Pd content is very high.The Ni content of suggestion in existing Ni base superalloy up near half should replace (seeing row 9) by Pd.
File US 6007645 describes γ/γ ' nickel base superalloy.The alloy that this document is described has good heat/corrosion resistance, high creep-breaking tenacity and good microstructural stability.This document emphasizes that Cr content should be low.This document has proposed several different alloy composites.Cr content is never greater than 2.9 weight %.File mentions, together with other alloying element, alloy can contain 0-10 weight % one or more be selected from the element of Ru, Rh, Pd, Os, Ir and Pt.And mention that these elements help improving creep-breaking tenacity and scale resistance and erosion resistance.As if this document do not mention the specific embodiment that contains Pd in alloy.
By Liu Yang and Rex B.McLellan at Journal of Materials Research, Vol.11, No.4, in April 1996, " palladium is at the adulterated Ni of B-for the article in the 862-864 page or leaf
3Effect in the hydrogen embrittlement of Al (Effect of palladium on the hydrogen embrittlement of B-doped Ni
3Al) " discussed by adding Pd and can reduce boron-adulterated Ni
3The hydrogen embrittlement of Al.
Known hydrogen can diffuse into alloy, and becomes the reason of the unfavorable characteristic of this alloy thus.For example hydrogen can reduce the ductibility of material, and may be crack reason and make material hardens and crisp.The most important mechanism of these effects is relevant with the reduction of crystal boundary and granule boundary.Also may there be possible disadvantageous synergistic effect in this between H and S, so that forms hydrogen sulfide at crystal boundary and granule boundary.Also known, S helps segregation rather than helps crystal boundary.Even low-down S content also is enough at this crystal boundary place formation hydrogen sulfide layer.When no S, also can produce this problem because of forming nickelous cyanide.Described this class problem can be described as hydrogen embrittlement (HE).
HE can cause because of the existence of hydrogen, but also can take place under wet condition.Alloying element such as Al can consequently form free hydrogen in water oxygenization, referring to early stage mentioned Yang ﹠amp; The article on Scripta Materialia48 (2003) " Environment effects on tensile and low cycle fatiquebehaviour of single crystal nickel base superalloys " of McLellan about people such as the article of γ ' (" gamma prime ") alloy and Nazmy.This hydrogen can diffuse in the alloy and cause HE.
Known Ni base γ/γ ' alloy has excellent high temperature application characteristic, as is used for the member of internal combustion turbine.But reported that also this alloy also has the HE phenomenon, referring to people's such as above mentioned Nazmy article.
Ni base γ/γ ' alloy is very complicated alloy.These alloys have the matrix of γ phase, and this γ is the sosoloid of Ni and other element such as Cr, Co, Fe, W, Mo and Re mutually.In addition, this alloy also contains γ ' phase particle, and this γ ' phase is Ni normally
3The sosoloid of Al and other element such as Ti, Ta and Nb.In addition, this alloy also contains other element, for example for strengthening crystal boundary and/or stable protective oxide layer.Also can mention, different alloying elements often with different concns be present in γ and γ ' mutually in, promptly certain element be easy to attracted to these phases certain mutually in so that the concentration of this element this be higher than in mutually another mutually in.For example once the report, Al often preferred allocation to γ ' mutually in.Also once the newspaper go back, Pd often preferred allocation to γ ' mutually in.In addition, a kind of element is γ and γ ' being distributed in the presence of other element and can having changed in mutually.Notice, add Pd and can produce and make Al be easy to preferred allocation to the effect of γ in mutually.
Summary of the invention
Ni base γ/γ ' alloy components has the protective oxide layer that can prevent hydrogen embrittlement usually.But the inventor notices; also stand the moisture condition if particularly stand as the member of the variation between envrionment temperature and elevated operating temperature and particularly these members; the microstructure of this oxide scales is time to time change, so that this protective oxide layer can unclamp its part provide protection at least or stands mechanical effect and damage its mother metal.The inventor finds, this member is easy to take place hydrogen embrittlement.Because normal air contains a certain amount of humidity, moisture may be a problem in many cases.In addition, the inventor also finds, for example use " wet technology " as the internal combustion turbine of spraying and steam cooling in this hydrogen embrittlement may be a problem.Hydrogen embrittlement can shorten the spendable time of member.For example because internal combustion turbine is expensive device, importantly the member in this class device can move for a long time.
The purpose of this invention is to provide a kind of improved Ni base γ/γ ' alloy, it is applicable to and stands the pyritous member.Therefore special purpose is to provide a kind of alloy with improved soundness and ability hydrogen embrittlement.Particularly the member made from this alloy is in the risk that stands should reduce its hydrogen embrittlement when the small part circulation is the thermal cycling of wet condition.Therefore the purpose of this invention is to provide a kind of alloy that is used for the member that can not damage in long-time running.Another object of the present invention is to provide a kind of member of the member with excellent specific property, particularly anti-hydrogen embrittlement.A purpose provides a kind of gas turbine installation again, and it comprises one or more members that excellent specific property is arranged when high temperature is used.A purpose in addition of the present invention is to use Pd to realize favourable technical effect in Ni base γ/γ ' alloy.
This above-mentioned first purpose is by being suitable for and will realizing that this alloy is γ/γ ' alloy, and be made up of following ingredients (weight %) at single crystalline, Ni directional solidification or many crystalline member base alloy that high temperature uses:
0.5-25 | Cr |
0-25 | Be selected from one or more elements of Co, Fe and Mn |
1-25 | Be selected from one or more elements of Mo, W, Re and Rh |
3-25 | Be selected from one or more elements of Al, Ti, Ta, Nb and V |
0-10 | Be selected from one or more elements of Ru, Os, Ir and Pt |
<4.0 | Pd |
0-3 | Hf |
0-2 | Si |
0-2 | Be selected from one or more elements of B, C, N and Zr |
0-1 | Be selected from one or more elements of Y, La, Sc, actinide elements and Ce and other lanthanon |
0-2 | Be selected from except that Ni and in table one or more of all elements the above-mentioned element add elements |
Rest part | Ni |
Wherein this alloy contains the Pd of obvious amount, to be enough to providing alloy improved hydrogen embrittlement resistance.
Be to be noted that the content of stipulating a group element herein (as is selected from ... one or more elements) time, this content means the total content of all elements that is selected from this group that exists in the alloy.Therefore, if this alloy only contains element in this group, then specified content is the content of this element.
If should be noted also that in this article and do not mention in addition, the content of then different elements or element set is weight %.
Also can be pointed out that, when the scope of content since 0, then the existence of this element or a plurality of coherent elements is chosen wantonly.
The present inventor finds, by can the be improved alloy of type of the different elements of selecting above-mentioned qualification for use.So find particularly to have obtained a kind of improved hydrogen embrittlement resistance.Found the also available low-down Pd concentration of this improved hydrogen embrittlement resistance and realized.Because Pd is a kind of material of costliness, so favourable aspect of the present invention is only to need a little P d.This improved hydrogen embrittlement resistance HE may be because the H that exists on crystal boundary or granule boundary is drawn into γ ' phase because of Pd.As mentioned above, the Pd preferred allocation is to γ ' phase.
In addition, add Pd and also other favourable effect can be arranged.For example report that Pd helps preventing the formation in TCP (topology close-packed) zone.In addition, because Pd is very similar to Ni, so its solvability in Ni is very high.Moreover, because the Pd preferred allocation is to γ ' phase, so at Ni
3Solvability among the Al also is excellent.As described above, report that also the adding of Pd can change the partition ratio of Ni base γ/γ ' alloy so that many slightly Al be assigned to γ mutually in.This meaning can add many slightly Al in alloy to given γ ' content.As if this improved scale resistance and heat/corrosion resistance.In addition, because use a small amount of Pd can be enough to obtain favourable effect, so the significant adverse influence of not mentioned adding Pd (existing report, Pd may cause the relevant problem of heat treatment process and the problem that at high temperature reduces creep strength).
By a kind of embodiment of alloy of the present invention, the content of described interpolation element<1.0, or itself in addition only in the amount of the common acceptable impurity of the alloy of the member that is suitable for used member under the high temperature such as internal combustion turbine.These add element if this alloy only contains on a small quantity (or not containing), and then the characteristic of this alloy is easy to control.
By another embodiment, Pd content>0.05.This Pd content can<2.0, preferred<1.0 and even<0.5.The also available a small amount of Pd in favourable aspect of the present invention reaches required effect.This is a particularly important, because Pd is a kind of expensive material, and because a large amount of Pd has some disadvantageous effect.
By another embodiment, the content of Cr>3.0, preferred>6.0.Can obtain excellent erosion resistance and scale resistance with quite a large amount of Cr.
But by another embodiment, Cr content≤3.0.By this another embodiment, use low Cr content.This can increase the creep-rupture strength of alloy.By selecting other element meticulously for use, even Cr content also can obtain enough corrosion resistant energy property and scale resistance when low.
By an embodiment, be selected from content>3.0 of one or more elements of Co, Fe and Mn.The content of Co for example can>6.0.In addition, the content of Co can>(Fe content+Mn content).Known Co is a kind of this material that class alloy has advantageous feature that provides, and enough hardness is particularly arranged under comparatively high temps.
By another embodiment, be selected from content>3.0 of one or more elements of Mo, W, Re and Rh.By preferred embodiment, the content of W can>content of Mo.In addition, (Re content+Rh content) can<1.0.For example can increase the intensity of alloy with the W of q.s.In addition, also improve creep resistant.
By another embodiment, the content of Al>1.0.For example Al content can>3.0 but<10.0.The molar fraction of Al is preferably greater than the molar fraction of any other element that is selected from Al, Ti, Ta, Nb and V in the alloy.Particularly Al is a kind of advantageous material of the γ of formation ' phase.In addition, Al can improve scale resistance and heat/corrosion resistance.
By another embodiment, be selected from one or more elements of Ru, Os, Ir and Pt content>0.01 but<5.0.Add the element that is selected from this group and can be used for controlling the distribution of other element between γ phase and γ ' phase.
By a kind of embodiment, the content of Hf can>0.05.
By a kind of embodiment, the content of Si can>0.02.Hf and/or Si can be used for promoting to form the protective oxide layer.
Be selected from B, C, N and Zr one or more elements content for example can>0.05 but<0.8.These elements can be used for increasing the intensity at crystal boundary place.
By a kind of embodiment, be selected from this alloy Y, La, Sc, actinide elements and Ce and other lanthanon content can>0.005.These elements can be used in conjunction with S, and it can work to reduce the risk that is formed with harmful hydrogen sulfide.
Content>35 of preferred Ni, more preferably>50.Therefore this alloy preferably contains very a large amount of base element Ni.
By another embodiment, the volume ratio of γ '/γ>0.4 (40%) or even>0.6 (60%).Very high γ ' mark helps the hot strength that provides high.
Press another aspect of the present invention, provide a kind of for being used for the designed member of hot environment, wherein this member be use by the arbitrary alloy in the previous embodiments made.Therefore the advantageous feature described in the relevant embodiment of this alloy above this member has.Particularly this member can at high temperature use, and also has good hydrogen embrittlement resistance.
By a kind of embodiment, this member is the member that is used for gas turbine installation.This member for example can be the part of turning vane or turning vane part or turbine rotor blade or turbine rotor blade.It is particularly advantageous having found to use alloy of the present invention to make these members.This member can use the very long time and not have because of damaged by hydrogen embrittlement.
Gas turbine installation of the present invention comprises the member of at least one above-mentioned definition.Therefore this gas turbine installation will comprise the member with above-mentioned advantageous feature.
By using Pd to realize application of the present invention, it forms the part by the alloy of the above-mentioned arbitrary embodiment that is used to provide described alloy, and it has improved hydrogen embrittlement resistance according to above-mentioned arbitrary embodiment.Therefore the present inventor finds, by can reach technique effect through the meticulous Pd that uses in above-mentioned alloy type.Particularly advantageously be only just to be enough to the advantageous effects that reaches above-mentioned with a small amount of Pd.
Brief description
Fig. 1 is with the very simple indicative icon gas turbine installation with a plurality of members of the present invention of the present invention.
The description of preferred embodiment
List the different embodiment of various alloy compositions of the present invention below.In all the following example, surplus is Ni.The given element, the alloy of these embodiment can contain small amount of impurities in Ni and embodiment, and the concentration of this impurity is used for the alloy of member of the member that will at high temperature use such as internal combustion turbine to this class normally acceptable.In addition, all alloys are Ni-based γ/γ ' alloy.The ratio of this γ '/γ as can be 0.4 (40%) or>0.6 (60%).This ratio is as can be 0.5 (50%).
This first embodiment is a kind of specific embodiment with different elements of specified rate.Each embodiment of embodiment 2-10 defines different elements among a small circle.The alloy of embodiment 2-10 can promptly particularly obtain by adding a small amount of Pd by the composition that changes known alloy slightly.
Alloy is suitable for making the article of monocrystalline or polycrystalline state.
Embodiment 1
12.0 Cr
8.0 Co
2.0 Mo
4.0 W
4.0 Al
2.0 Ti
1.5 Ta
1.5 Nb
0.4 Pd
0.1 Hf
0.1 Si
0.01 B
0.05 C
Embodiment 2
15-17 Cr
8-9 Co
1.5-2.5 Mo
3-4 W
3-4 Al
3-4 Ti
1.5-2.5 Nb
0.1--0.5 Pd
0.05-0.2 C
0.005-0.015 B
0.05-0.015 Zr
Embodiment 3
12-14 Cr
8-10 Co
1.5-2.5 Mo
3-5 W
3-4 Al
3.5-5 Ti
3-5 Ta
1.5-2.5 Nb
0.1-0.5 Pd
0.1-0.3 C
0.015-0.025 B
0.005-0.015 Zr
Embodiment 4
12-14 Cr
8-10 Co
1.5-2.5 Mo
3-5 W
3-4 Al
3.5-4.5 Ti
3-5 Ta
0.1-0.5 Pd
Embodiment 5
7.5-9 Cr
8-11 Co
0.4-0.8 Mo
9-11 W
5-6 Al
0.5-1.5 Ti
2-4 Ta
0.1-0.5 Pd
0.05-0.2 C
0.01-0.02 B
0.005-0.05 Zr
1-2 Hf
Embodiment 6
21-25 Cr
18-20 Co
1-3 W
1.5-2.5 Al
3-4 Ti
1-2 Ta
0.5-1.5 Nb
0.1-0.5 Pd
0.1-0.2 C
0.005-0.015 B
0.05-0.15 Zr
Embodiment 7
21-25 Cr
18-20 Co
1-3 W
2-3 Al
3-4 Ti
1-2 Ta
0.5-1.5 Nb
0.1-0.5 Pd
0.1-0.2 C
0.005-0.015 B
0.05-0.15 Zr
0.5-1.5 Hf
Embodiment 8
8-9 Cr
4-6 Co
1-3 Mo
7-9 W
4.5-5.5 Al
1-2 Ti
5-7 Ta
0.1-0.5 Pd
0.05-0.15 Hf
0.05-0.15 Si
0.005-0.015 C
0.005-0.015 B
Embodiment 9
6-7 Cr
9-11 Co
0.4-0.8 Mo
5-7 W
2.5-3.5 Re
5-6 Al
0.5-1.5 Ti
5-7 Ta
0.1-0.5 Pd
0.05-0.15 Hf
0.005-0.015 Y
Embodiment 10
2.2-2.8 Cr
10-14 Co
8-10 W
6-7 Re
1.5-2.5 Ru
5.5-6.5 Al
5-6 Ta
0.1-0.5 Pd
0.05-0.15 Hf
0.05-0.15 Si
Alloy of the present invention can be prepared by the known method that is used for Ni-based γ/γ ' superalloy of production prior art of this area professional.This alloy can be by the known method manufacture order of this area professional crystalline, directional solidification or many crystalline member.Alloy of the present invention can be used for preparing any member that will at high temperature use or the part of member.
Fig. 1 is with the sectional view of very simple indicative icon typical gas turbine installation part of the present invention.In the embodiment depicted in fig. 1, this gas turbine installation has toroidal combustion chamber 11.The bottom of this combustion chamber 11 only is shown among Fig. 1.This toroidal combustion chamber can center on the symmetry axis of the x-x that marks among Fig. 1 to be settled.This symmetry axis x-x also can constitute the turning axle of the rotor that forms this gas turbine installation part.This combustion chamber 11 is fixed with respect to stator component 14.This gas turbine installation comprises a plurality of turning vanes 13.Two turning vanes 13 shown in Fig. 1.This turning vane 13 is fixed with respect to stator 14.This gas turbine installation also has a plurality of turbine rotor blades 15.Two this spinner blades 15 shown in Fig. 1.This spinner blade 15 constitutes around turning axle x-x and the part of rotating rotor.This gas turbine installation also can comprise other other part known to those skilled in the art certainly.This gas turbine installation for example can have one or more compressor section, also additional turbine stage can be arranged.Different component in gas turbine installation can be with alloy manufacturing of the present invention.For example this turning vane 13 and/or turbine rotor blade 15 can be with alloy manufacturings of the present invention.Alloy of the present invention also can be used for preparing the part of member, for example the protective layer on turning vane 13, turbine rotor blade 15 or other part of internal combustion turbine.
The invention still further relates to the application of Pd.Use by this, Pd for example is used for the alloy of described class with the content of the foregoing description, so that this alloy has improved hydrogen embrittlement resistance.
The present invention is not subject to described embodiment, and it is the interior changes and improvements of scope of claim below.
Claims (94)
1. a single crystalline that is suitable at high temperature using, Ni directional solidification or many crystalline member base alloy, this alloy is γ/γ ' alloy, and is made up of following ingredients (weight %):
Wherein this alloy contains the Pd of obvious amount, and it is enough to make this alloy to have improved hydrogen embrittlement resistance, and Al content>1.0 wherein wherein are selected from content>3.0 of one or more elements of Co, Fe and Mn.
2. the alloy of claim 1, the wherein content of Pd<1.0.
3. the alloy of claim 1, the wherein content of Cr>3.0.
4. the alloy of claim 2, the wherein content of Cr>3.0.
5. the alloy of claim 3, the wherein content of Cr>6.0.
6. the alloy of claim 4, the wherein content of Cr>6.0.
7. the alloy of claim 1, the wherein content of Cr≤3.0.
8. the alloy of claim 2, the wherein content of Cr≤3.0.
9. the alloy of claim 1, the wherein content of Co>6.0.
10. the alloy of claim 1, the wherein content of Co>(Fe content+Mn content).
11. the alloy of claim 9, the wherein content of Co>(Fe content+Mn content).
12. each alloy among the claim 1-11 wherein is selected from content>3.0 of one or more elements of Mo, W, Re and Rh.
13. the alloy of claim 12, wherein W content>Mo content.
14. the alloy of claim 12, wherein (Re content+Rh content)<1.0.
15. the alloy of claim 13, wherein (Re content+Rh content)<1.0.
16. each alloy among the claim 1-11, wherein Al content>3.0 but<10.0.
17. the alloy of claim 12, wherein Al content>3.0 but<10.0.
18. the alloy of claim 13, wherein Al content>3.0 but<10.0.
19. the alloy of claim 14, wherein Al content>3.0 but<10.0.
20. the alloy of claim 16, the molar fraction of Al is greater than the molar fraction of any other element that is selected from Al, Ti, Ta, Nb and V in its interalloy.
21. the alloy of claim 17, the molar fraction of Al is greater than the molar fraction of any other element that is selected from Al, Ti, Ta, Nb and V in its interalloy.
22. the alloy of claim 18, the molar fraction of Al is greater than the molar fraction of any other element that is selected from Al, Ti, Ta, Nb and V in its interalloy.
23. the alloy of claim 19, the molar fraction of Al is greater than the molar fraction of any other element that is selected from Al, Ti, Ta, Nb and V in its interalloy.
24. each alloy among the claim 1-11, wherein be selected from one or more elements of Ru, Os, Ir and Pt content>0.01 but<5.0.
25. the alloy of claim 12, wherein be selected from one or more elements of Ru, Os, Ir and Pt content>0.01 but<5.0.
26. the alloy of claim 13, wherein be selected from one or more elements of Ru, Os, Ir and Pt content>0.01 but<5.0.
27. the alloy of claim 14, wherein be selected from one or more elements of Ru, Os, Ir and Pt content>0.01 but<5.0.
28. the alloy of claim 16, wherein be selected from one or more elements of Ru, Os, Ir and Pt content>0.01 but<5.0.
29. the alloy of claim 20, wherein be selected from one or more elements of Ru, Os, Ir and Pt content>0.01 but<5.0.
30. each alloy among the claim 1-11, the wherein content of Hf>0.05.
31. the alloy of claim 12, the wherein content of Hf>0.05.
32. the alloy of claim 13, the wherein content of Hf>0.05.
33. the alloy of claim 14, the wherein content of Hf>0.05.
34. the alloy of claim 16, the wherein content of Hf>0.05.
35. the alloy of claim 20, the wherein content of Hf>0.05.
36. the alloy of claim 24, the wherein content of Hf>0.05.
37. each alloy among the claim 1-11, the wherein content of Si>0.02.
38. the alloy of claim 12, the wherein content of Si>0.02.
39. the alloy of claim 13, the wherein content of Si>0.02.
40. the alloy of claim 14, the wherein content of Si>0.02.
41. the alloy of claim 16, the wherein content of Si>0.02.
42. the alloy of claim 20, the wherein content of Si>0.02.
43. the alloy of claim 24, the wherein content of Si>0.02.
44. the alloy of claim 30, the wherein content of Si>0.02.
45. each alloy among the claim 1-11, wherein be selected from one or more elements of B, C, N and Zr content>0.05 but<0.8.
46. the alloy of claim 12, wherein be selected from one or more elements of B, C, N and Zr content>0.05 but<0.8.
47. the alloy of claim 13, wherein be selected from one or more elements of B, C, N and Zr content>0.05 but<0.8.
48. the alloy of claim 14, wherein be selected from one or more elements of B, C, N and Zr content>0.05 but<0.8.
49. the alloy of claim 16, wherein be selected from one or more elements of B, C, N and Zr content>0.05 but<0.8.
50. the alloy of claim 20, wherein be selected from one or more elements of B, C, N and Zr content>0.05 but<0.8.
51. the alloy of claim 24, wherein be selected from one or more elements of B, C, N and Zr content>0.05 but<0.8.
52. the alloy of claim 30, wherein be selected from one or more elements of B, C, N and Zr content>0.05 but<0.8.
53. the alloy of claim 37, wherein be selected from one or more elements of B, C, N and Zr content>0.05 but<0.8.
54. each alloy among the claim 1-11 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
55. the alloy of claim 12 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
56. the alloy of claim 13 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
57. the alloy of claim 14 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
58. the alloy of claim 16 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
59. the alloy of claim 20 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
60. the alloy of claim 24 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
61. the alloy of claim 30 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
62. the alloy of claim 37 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
63. the alloy of claim 45 wherein is selected from one or more constituent contents>0.005 of Y, La, Sc, actinide elements and Ce and other lanthanon.
64. each alloy among the claim 1-11, the wherein content of Ni>35.
65. the alloy of claim 12, the wherein content of Ni>35.
66. the alloy of claim 13, the wherein content of Ni>35.
67. the alloy of claim 14, the wherein content of Ni>35.
68. the alloy of claim 16, the wherein content of Ni>35.
69. the alloy of claim 20, the wherein content of Ni>35.
70. the alloy of claim 24, the wherein content of Ni>35.
71. the alloy of claim 30, the wherein content of Ni>35.
72. the alloy of claim 37, the wherein content of Ni>35.
73. the alloy of claim 45, the wherein content of Ni>35.
74. the alloy of claim 54, the wherein content of Ni>35.
75. the alloy of claim 64, the wherein content of Ni>50.
76. each alloy among the claim 1-11, the wherein volume ratio of γ '/γ>0.4 (40%).
77. the alloy of claim 12, the wherein volume ratio of γ '/γ>0.4 (40%).
78. the alloy of claim 13, the wherein volume ratio of γ '/γ>0.4 (40%).
79. the alloy of claim 14, the wherein volume ratio of γ '/γ>0.4 (40%).
80. the alloy of claim 16, the wherein volume ratio of γ '/γ>0.4 (40%).
81. the alloy of claim 20, the wherein volume ratio of γ '/γ>0.4 (40%).
82. the alloy of claim 24, the wherein volume ratio of γ '/γ>0.4 (40%).
83. the alloy of claim 30, the wherein volume ratio of γ '/γ>0.4 (40%).
84. the alloy of claim 37, the wherein volume ratio of γ '/γ>0.4 (40%).
85. the alloy of claim 45, the wherein volume ratio of γ '/γ>0.4 (40%).
86. the alloy of claim 54, the wherein volume ratio of γ '/γ>0.4 (40%).
87. the alloy of claim 64, the wherein volume ratio of γ '/γ>0.4 (40%).
88. the alloy of claim 75, the wherein volume ratio of γ '/γ>0.4 (40%).
89. the alloy of claim 76, the wherein volume ratio of γ '/γ>0.6 (60%).
90. a design is as the member (13,15) in hot environment, wherein said member (13,15) is made by the arbitrary alloy in the aforementioned claim.
91. the member of claim 90 (13,15), wherein said member (13,15) are a kind of members (13,15) that is suitable for gas turbine installation.
92. the member of claim 91 (13,15), wherein said member (13,15) are the part of turning vane (13) or turning vane (13) or the part of turbine rotor blade (15) or turbine rotor blade (15).
93. gas turbine installation, it comprises the member (13,15) of at least a claim 91 or 92.
94.Pd purposes, it constitutes the composition in arbitrary alloy among claim 1-89, so that arbitrary alloy of claim 1-89 has improved hydrogen embrittlement resistance.
Applications Claiming Priority (2)
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SE0403162A SE528807C2 (en) | 2004-12-23 | 2004-12-23 | Component of a superalloy containing palladium for use in a high temperature environment and use of palladium for resistance to hydrogen embrittlement |
SE04031621 | 2004-12-23 |
Publications (2)
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CN101087894A CN101087894A (en) | 2007-12-12 |
CN100587093C true CN100587093C (en) | 2010-02-03 |
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CN200580044306A Expired - Fee Related CN100587093C (en) | 2004-12-23 | 2005-12-21 | Ni based alloy, component, gas turbine device and application of Pd in the alloy |
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US (4) | US20080101981A1 (en) |
EP (1) | EP1825012A1 (en) |
JP (1) | JP2008525634A (en) |
KR (1) | KR20070091350A (en) |
CN (1) | CN100587093C (en) |
BR (1) | BRPI0519432A2 (en) |
CA (1) | CA2592027A1 (en) |
RU (1) | RU2007127852A (en) |
SE (1) | SE528807C2 (en) |
WO (1) | WO2006067189A1 (en) |
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- 2005-12-21 CN CN200580044306A patent/CN100587093C/en not_active Expired - Fee Related
- 2005-12-21 US US11/794,071 patent/US20080101981A1/en not_active Abandoned
- 2005-12-21 RU RU2007127852/02A patent/RU2007127852A/en not_active Application Discontinuation
- 2005-12-21 JP JP2007547519A patent/JP2008525634A/en not_active Abandoned
- 2005-12-21 CA CA002592027A patent/CA2592027A1/en not_active Abandoned
- 2005-12-21 WO PCT/EP2005/057043 patent/WO2006067189A1/en active Application Filing
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- 2005-12-21 KR KR1020077016658A patent/KR20070091350A/en not_active Application Discontinuation
-
2007
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Also Published As
Publication number | Publication date |
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CN101087894A (en) | 2007-12-12 |
US20080101981A1 (en) | 2008-05-01 |
JP2008525634A (en) | 2008-07-17 |
US20070202003A1 (en) | 2007-08-30 |
SE0403162L (en) | 2006-06-24 |
CA2592027A1 (en) | 2006-06-29 |
KR20070091350A (en) | 2007-09-10 |
SE528807C2 (en) | 2007-02-20 |
US20070202002A1 (en) | 2007-08-30 |
WO2006067189A1 (en) | 2006-06-29 |
BRPI0519432A2 (en) | 2009-01-20 |
SE0403162D0 (en) | 2004-12-23 |
EP1825012A1 (en) | 2007-08-29 |
RU2007127852A (en) | 2009-01-27 |
US20070199629A1 (en) | 2007-08-30 |
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