CN100562612C - A kind of antibiotic multifunctional fibre material and preparation method thereof - Google Patents

A kind of antibiotic multifunctional fibre material and preparation method thereof Download PDF

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Publication number
CN100562612C
CN100562612C CNB2006100260521A CN200610026052A CN100562612C CN 100562612 C CN100562612 C CN 100562612C CN B2006100260521 A CNB2006100260521 A CN B2006100260521A CN 200610026052 A CN200610026052 A CN 200610026052A CN 100562612 C CN100562612 C CN 100562612C
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China
Prior art keywords
antibiotic
micro mist
weight
fibre material
multifunctional fibre
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Expired - Fee Related
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CNB2006100260521A
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Chinese (zh)
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CN101063235A (en
Inventor
陈建强
陈颖
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DEBANG NEW MATERIALS CO., LTD.
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EXHIBITION OF SHANGHAI RAISES SCIENCE TECHNOLOGIES Co Ltd
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Priority to CNB2006100260521A priority Critical patent/CN100562612C/en
Publication of CN101063235A publication Critical patent/CN101063235A/en
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Publication of CN100562612C publication Critical patent/CN100562612C/en
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Abstract

The present invention relates to a kind of antibiotic multifunctional fibre material and preparation method thereof, this material is by 80~85: the polypropylene of 15~20 weight ratios and antibiotic multifunction master batch are formed, described antibiotic multifunction master batch comprises following component and percentage by weight thereof: anion micro mist 4%~5%, photocatalysis micro mist 5%~8%, far infrared micro mist 2%~3%, inorganic antibacterial powder 4%~5%, PP (polypropylene) 60%~78%.This material is made the antibiotic multifunction master batch by adopting expressing technique, then with polypropylene and the stirring of antibiotic multifunction master batch, spinning, the stretching of above-mentioned weight ratio, make after twisting, oiling.Antibiotic rate of the present invention reaches in 99%, 2 hour and reaches 80% except that formaldehyde, and the anion release rate is 1000/cm 3

Description

A kind of antibiotic multifunctional fibre material and preparation method thereof
Technical field
The present invention relates to a kind of fibrous material that belongs to the material field, particularly a kind of energy removes formaldehyde, discharges the antibiotic multifunctional fibre material of anion.
Background technology
In the environment that people live, exist various harmful microorganisms, they can produce harmful effect to the mankind's life, especially some moist occasion (as kitchen, toilet etc.) is easier in the domestic environment grows microorganism, causes the dense and dense increase of bacterium article surface of room air bacterium.
Along with improving constantly of people's material and cultural life, people expect health, and the hope of pursuing comfortable life is simultaneously also increasing, and the fiber that therefore has the health care function is one of current relevant researcher direction of endeavouring to study.Have antibiotic, negative ion-releasing function fiber and seem particularly important in medical and health industry, automobile interior trim industry, because employed textiles all might become the communication media of bacterium in the medical medicine industry, cause cross infection, influence patient's rehabilitation, even threat to life.
Summary of the invention
Purpose of the present invention is just providing a kind of antibiotic multifunctional fibre material and preparation method thereof for the defective that overcomes above-mentioned prior art existence.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of antibiotic multifunctional fibre material is characterized in that, this antibiotic multifunctional fibre material by antibiotic multifunction master batch and polypropylene with 15~20: 80~85 weight ratio is formed; Described antibiotic multifunction master batch comprises following component and weight percentage:
Anion micro mist 4%~5%,
Photocatalysis micro mist 5%~8%,
Far infrared micro mist 2%~3%,
Inorganic antibacterial powder 4%~5%,
Inorganic fire-retarded micro mist 5%~10%,
Tissuemat E 1%~2%,
Zinc stearate 0.5%~1%,
Stearic acid 0.5%~1%,
Polypropylene 65%~78%.
Described anion micro mist comprises the tourmaline powder that is rich in boron.
Described photocatalysis micro mist comprises nanoscale TiO 2Micro mist.
Described far infrared micro mist comprises and is selected from ZrO 2, SiO 2In a kind of or two kinds mixture.
Described inorganic antibacterial powder comprises one or more the mixture that is selected from ZnO, CuO, SnO.
Described inorganic fire-retarded micro mist comprises and is selected from Mg (OH) 2, Al 2O 3, CuCl 2In one or more mixture.
A kind of preparation method of antibiotic multifunctional fibre material, it is characterized in that, with photocatalysis micro mist 5~8% weight, far infrared micro mist 2~3% weight, inorganic antibacterial powder 4~5% weight, inorganic fire-retarded micro mist 5~10% weight, Tissuemat E 1~2% weight, zinc stearate 0.5~1% weight, stearic acid 0.5~1% weight, polypropylene 65~78% weight add double screw extruder to be extruded, and the antibiotic multifunction master batch is made in water cooling, pelletizing; Then with 15~20: the antibiotic multifunction master batch of 80~85 weight ratios and polypropylene add mixer, join spinning in the composite spinning machine after stirring again, and spinning is after up-coiler stretches, and twisting after oiling, is made into antibiotic multifunctional fibre material.
The present invention detects through Shanghai City Industry Wei Biological Research Institute inspection center, antibiotic rate reaches 99% (for the examination bacterial classification is Escherichia coli, staphylococcus aureus), detects through Shanghai City environment-friendly products quality supervision and test master station, remove formaldehyde (2 hours) and reach 80%, the anion release rate is 1000/cm 3
The specific embodiment
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1
A kind of antibiotic multifunctional fibre material is made up of the polypropylene and the antibiotic multifunction master batch of 83: 17 weight ratios, and described antibiotic multifunction master batch comprises following component and percentage by weight thereof: be rich in the tourmaline powder 4.5% of boron, nanoscale TiO 26.5%, SiO 22.5%, CuO 4.5%, PP (polypropylene) 69%.
A kind of preparation method of antibiotic multifunctional fibre material: tourmaline powder, the nanoscale TiO that will be rich in boron 2, SiO 2, that CuO, PP (polypropylene) add homogenizer by above-mentioned weight ratio is even, stirs under 90 ℃ of temperature, adds the granulation of double-screw extruding pelletizing machine then, the antibiotic multifunction master batch is made in water cooling, pelletizing; Then the polypropylene and the antibiotic multifunction master batch of 83: 17 weight ratios are put into mixer, join in the composite spinning machine after stirring, spinning, spinning are after there is the group up-coiler to stretch, and twisting after oiling, is made into antibiotic multifunctional fibre material.
Embodiment 2
A kind of antibiotic multifunctional fibre material is made up of the polypropylene and the antibiotic multifunction master batch of 80: 20 weight ratios, and described antibiotic multifunction master batch comprises following component and percentage by weight thereof: be rich in the tourmaline powder 4% of boron, nanoscale TiO 25%, SiO 22%, SnO 4%, PP (polypropylene) 78%, Mg (OH) 28%, Tissuemat E 1%, zinc stearate 0.5%, stearic acid 0.5%.
A kind of preparation method of antibiotic multifunctional fibre material: tourmaline powder, the nanoscale TiO that will be rich in boron 2, SiO 2, SnO, PP (polypropylene), Mg (OH) 2, Tissuemat E, zinc stearate, stearic acid add homogenizer by above-mentioned weight ratio, stirs under 110 ℃ of temperature, adds the granulation of double-screw extruding pelletizing machine then, the antibiotic multifunction master batch is made in water cooling, pelletizing; Then the polypropylene and the antibiotic multifunction master batch of 80: 20 weight ratios are put into mixer, join in the composite spinning machine after stirring, spinning, spinning are after there is the group up-coiler to stretch, and twisting after oiling, is made into antibiotic multifunctional fibre material.
Embodiment 3
A kind of antibiotic multifunctional fibre material is made up of the polypropylene and the antibiotic multifunction master batch of 85: 15 weight ratios, and described antibiotic multifunction master batch comprises following component and percentage by weight thereof: be rich in the tourmaline powder 5% of boron, nanoscale TiO 28%, ZrO 23%, ZnO 5%, PP (polypropylene) 78%, Al 2O 310%, Tissuemat E 2%, zinc stearate 1%, stearic acid 1%.
A kind of preparation method of antibiotic multifunctional fibre material: tourmaline powder, the nanoscale TiO that will be rich in boron 2, ZrO 2, ZnO, PP (polypropylene), Al 2O 3, Tissuemat E, zinc stearate, stearic acid add homogenizer by above-mentioned weight ratio, stirs under 70 ℃ of temperature, adds the granulation of double-screw extruding pelletizing machine then, the antibiotic multifunction master batch is made in water cooling, pelletizing; Then the polypropylene and the antibiotic multifunction master batch of 85: 15 weight ratios are put into mixer, join in the composite spinning machine after stirring, spinning, spinning are after there is the group up-coiler to stretch, and twisting after oiling, is made into antibiotic multifunctional fibre material.

Claims (7)

1. an antibiotic multifunctional fibre material is characterized in that, this antibiotic multifunctional fibre material by antibiotic multifunction master batch and polypropylene with 15~20: 80~85 weight ratio is formed; Described antibiotic multifunction master batch is made up of following component and weight percentage:
Anion micro mist 4%~5%,
Photocatalysis micro mist 5%~8%,
Far infrared micro mist 2%~3%,
Inorganic antibacterial powder 4%~5%,
Inorganic fire-retarded micro mist 5%~10%,
Tissuemat E 1%~2%,
Zinc stearate 0.5%~1%,
Stearic acid 0.5%~1%,
Polypropylene 65%~78%.
2. a kind of antibiotic multifunctional fibre material according to claim 1 is characterized in that, described anion micro mist comprises the tourmaline powder that is rich in boron.
3. a kind of antibiotic multifunctional fibre material according to claim 1 is characterized in that, described photocatalysis micro mist comprises nanoscale TiO 2Micro mist.
4. a kind of antibiotic multifunctional fibre material according to claim 1 is characterized in that, described far infrared micro mist comprises and is selected from ZrO 2, SiO 2In a kind of or two kinds mixture.
5. a kind of antibiotic multifunctional fibre material according to claim 1 is characterized in that, described inorganic antibacterial powder comprises one or more the mixture that is selected from ZnO, CuO, SnO.
6. a kind of antibiotic multifunctional fibre material according to claim 1 is characterized in that, described inorganic fire-retarded micro mist comprises and is selected from Mg (OH) 2, Al 2O 3, CuCl 2In one or more mixture.
7. the preparation method of an antibiotic multifunctional fibre material, it is characterized in that, with photocatalysis micro mist 5~8% weight, far infrared micro mist 2~3% weight, inorganic antibacterial powder 4~5% weight, inorganic fire-retarded micro mist 5~10% weight, Tissuemat E 1~2% weight, zinc stearate 0.5~1% weight, stearic acid 0.5~1% weight, polypropylene 65~78% weight add double screw extruder to be extruded, and the antibiotic multifunction master batch is made in water cooling, pelletizing; Then with 15~20: the antibiotic multifunction master batch of 80~85 weight ratios and polypropylene add mixer, join spinning in the composite spinning machine after stirring again, and spinning is after up-coiler stretches, and twisting after oiling, is made into antibiotic multifunctional fibre material.
CNB2006100260521A 2006-04-26 2006-04-26 A kind of antibiotic multifunctional fibre material and preparation method thereof Expired - Fee Related CN100562612C (en)

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SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Cixi Runxin Electric Appliance Co., Ltd.

Assignor: The Exhibition of Shanghai Raises Science Technologies Co., Ltd.

Contract record no.: 2012310000025

Denomination of invention: Antibiotic multifunctional fibre material and method for making same

Granted publication date: 20091125

License type: Exclusive License

Open date: 20071031

Record date: 20120309

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20160607

Address after: Taizhou City, Zhejiang province 318059 Luqiao Jinqing Juan Qiao Cun

Patentee after: DEBANG NEW MATERIALS CO., LTD.

Address before: 200240 Shanghai city Minhang District Huaning road 191 Lane No. 157 room 304

Patentee before: The Exhibition of Shanghai Raises Science Technologies Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20091125

Termination date: 20170426