CN100559947C - A kind of miticide that contains biomass gasification tar - Google Patents
A kind of miticide that contains biomass gasification tar Download PDFInfo
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- CN100559947C CN100559947C CNB2006100492340A CN200610049234A CN100559947C CN 100559947 C CN100559947 C CN 100559947C CN B2006100492340 A CNB2006100492340 A CN B2006100492340A CN 200610049234 A CN200610049234 A CN 200610049234A CN 100559947 C CN100559947 C CN 100559947C
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- miticide
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- tar
- gasification tar
- mite
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Abstract
The invention discloses a kind of miticide that contains biomass gasification tar.Described a kind of miticide that contains biomass gasification tar contains biomass gasification tar 5-90%.The described miticide that contains biomass gasification tar, good drug efficacy reaches 95.2% to the anti-efficient of insects such as citrus red mite; Good with Environmental compatibility, the safety in production of agricultural product is had important effect; Cost is low.
Description
Technical field
The present invention relates to a kind of miticide, be specifically related to a kind of miticide that contains biomass gasification tar.
Background technology
Biomass gasification tar is the pitchy oily mater that is condensed at normal temperatures by the gas that collection after vegetable material and the industrial wood waste pyrolysis thereof obtains, and main existence is bamboo tar, wood tar and careless tar at present." biomass gasification tar " among the present invention comprises bamboo tar (being the accessory substance that bamboo surplus material of processing obtains through high temperature pyrolysis), wood tar (being the accessory substance that wood machining residues and shell obtain through high temperature pyrolysis) and careless tar (being meant the accessory substance that herbaceous plant, crop stalk and crops husk obtain through high temperature pyrolysis).At present, be processed in the process of corresponding bamboo charcoal, charcoal and the peat composed of rotten mosses at bamboo wood, timber and straw, owing to adopt modern machine to carry out High-efficient Production, accessory substance-the tar of Chan Shenging in process of production, never find its purposes and become refuse, be difficult to again carry out environmental protection treatment, so become the technical barrier of modern production charcoal.Simultaneously, closely for many years, biopesticide is developed to has market-oriented kind seldom, does not satisfy the needs of the production of modern green and organic farm products far away, and especially miticide substantially all is the world of chemical pesticide, the biopesticide that has only a microbial source of Avermectin, but Avermectin is a broad spectrum pesticide, though the mite class there is certain effect,, its effect is nothing like chemical pesticide, so Avermectin can't be as special miticide.With regard to chemical miticide, the main widely used still pyridaben of China before 10 years, but through being extensive use of for many years, the mite class has produced very serious resistance to pyridaben, has been difficult to the mite class is produced certain effect.Therefore, several years ago, the imitated again alkynes mite spy of China agricultural chemicals company, but alkynes mite spy is through being extensive use of in recent years, and resistance is also more and more serious, and therefore, the miticide famine on the China market comprises chemical miticide at present.And also neither one generation and the use of the special miticide of biogenic.
Summary of the invention
For overcoming problems of the prior art, the present invention aims to provide that production cost is low, miticidal effect good, and the miticide that contain biomass gasification tar little to surrounding environment influence.
Described a kind of miticide that contains biomass gasification tar is characterized in that: contain biomass gasification tar 5-90%.
The described miticide that contains biomass gasification tar is characterized in that: contain biomass gasification tar 10-80%.
The described miticide that contains biomass gasification tar is characterized in that: contain biomass gasification tar 20-70%.
The described miticide that contains biomass gasification tar is characterized in that: contain biomass gasification tar 30-50%.
The described miticide that contains biomass gasification tar is characterized in that: also contain known miticide 0.05-70.00%.%。
The described miticide that contains biomass gasification tar is characterized in that: also contain known miticide 0.1-50.0%.
The described miticide that contains biomass gasification tar is characterized in that: also contain known miticide 0.2-30.0%.
The described miticide that contains biomass gasification tar is characterized in that: also contain known miticide 0.2-20.0%.
The described miticide that contains biomass gasification tar, it is characterized in that: described known miticide is Avermectin (Abamectin), more visit rhzomorph (Milbemectin), flucythrinate (Flucythrinate), betacyfluthrin (beta-cyfluthrin), gamma cyhalothrin (lambda-cyhalothrin), smart gamma cyhalothrin (gamma-Cyhalothrin), beta-cypermethrin (beta-cypermethrin), decis (Deltamethrin), sumicidin (Esfenvalerate), flucythrinate (Flucythrinate), alkynes mite spy (propargite), tetradiphon (Tetradifon), capillary (Chlorfenapyr), 4,6-dinitro-o-cresol (DNOC), pyridaben (Pyridaben), fenazaquin (Fenazaquin), azoles mite ester (Fenpyroximate), tebufenpyrad (Tebufenpyrad), pyrimidifen (Pyrimidifen), fluacrypyrim (Fluacrypyrim), rotenone (Rotenone), antimycin (Antimycin) Ya Kun ?(Acequinocyl), fluacrypyrim (Fluacrypyrim), spiral shell mite ester (Spirodiclofen), four mite piperazines (Clofentezine), second mite azoles (Etoxazole), Hexythiazox (Hexythiazox), fluorine mite piperazine (Flufenzine), Citrazon (Benzoximate), dicofol (Dicofol), Chinomethionate (Chinomethionat), pyridalyl (Pyridalyl).
The described miticide that contains biomass gasification tar can be mixed with different formulations such as missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent, suspended emulsion, micro-capsule suspension and sustained release agent.
The described miticide that contains biomass gasification tar, utilize biomass gasification tar to be mixed with pesticidal preparations, carrying out killing laboratory experiment of mite and found that of field control effectiveness test, biomass gasification tar has good acaricidal activity, make this miticide good drug efficacy, the anti-efficient of insects such as citrus red mite is reached 95.2%; Biomass gasification tar itself derives from the natural biology material, thereby described miticide and Environmental compatibility are good, and the safety in production of agricultural product is had important effect; Simultaneously, use biomass gasification tar to belong to twice laid, it is cheap, and cost is about 0.2 yuan/mu, far below existing similar miticide.
Percentage composition is the weight percentage of pure material in the present specification.
Specific embodiment
Now, further specify beneficial effect of the present invention in conjunction with the embodiments of the invention and the test of pesticide effectiveness.
Embodiment 1
Input 180kg emulsifier op-10,120kg emulsifier calcium dodecyl benzene sulfonate, 12kg dimethyl formamide are stirred into compound emulsifying agent in the 500L reactor, and be standby; In the 1000L reactor, drop into bamboo tar 300kg, dimethyl formamide 100kg and stir, after whole dissolvings, slowly drop into the standby compound emulsifying agent of 100kg again, stir, finished product 60% bamboo tar missible oil.
Embodiment 2
In the 1000L reactor, drop into dimethylbenzene 50kg, constantly slowly drop into 450kg wood tar (timber tar) under the condition of stirring, promptly get A liquid up to dissolving fully; Drop into 380kg water in another 1000L reactor, drop into 25kg glycerine, 20kg emulsifier op-10,10kg emulsifier calcium dodecyl benzene sulfonate again, the 3k calcium lignosulfonate fully stirs and promptly gets B liquid; Get B liquid 200kg and become uniform dispersion emulsion, constantly slowly adding 200kgA liquid under the condition of stirring then, and fully stirring through the high-shearing dispersion emulsifying machine dispersion and emulsion, final products 45% wood tar aqueous emulsion.
Embodiment 3
40kg grass tar (paddy stalk), 4kg calcium lignosulfonate, 10kg OP-10,1kg silica, 3kg ethylene glycol adds 42kg water continuously, and being crushed to fineness in wet type colloid mill continuous stirring is 2-5 μ m, existing final products, 40% careless tar water powder.
Embodiment 4
Pyridaben (pyridaben) 30kg, agricultural emulsifier NO 2kg, sodium lignin sulfonate 1kg, SOPA sodium salt 1kg, propane diols 1kg, white carbon 1kg, 64kg water after ball mill is pulverized, re-uses the sand mill pulverizing and is ground to particle diameter less than 3 μ m, obtains suspension liquid A liquid; Wood tar (cathay hickory shell tar) 80kg, dimethylbenzene 10kg, calcium dodecyl benzene sulfonate 7kg, emulsifier op-10 3kg up to complete mixing, obtains B liquid 50-60 ℃ of heated and stirred; A and B liquid are joined high-shearing dispersion emulsifying machine process high speed homogenize and obtain final products according to 2: 3 ratios of weight.60% wood tar pyridaben aqueous suspension emulsion.
Embodiment 5
In the 500L reactor, drop into 180kg water, be heated to 70 ℃, in heating, slowly drop into the 15kg polyvinyl alcohol, after dissolving disperses fully in constantly stirring, stop heating, continue to add 114kg water, 3kgSOPA sodium salt, 3kg ethylene glycol, stir, being cooled to normal temperature, to obtain A liquid standby; In another 500L reactor, drop into benzene 30kg, constantly slowly drop into 160kg grass tar (paddy rice husk) under the condition of stirring, after dissolving fully, add calcium dodecyl benzene sulfonate 12kg, emulsifier op-10 8kg stirs up to complete mixing, and it is standby promptly to get B liquid; A and B liquid are joined high-shearing dispersion emulsifying machine process high speed homogenize and obtain final products, 32% careless tar sustained release agent according to 1: 1 ratio of weight.
Field control effectiveness test and result thereof
1. materials and methods
1.1 reagent agent
The foregoing description 1~5
1.2 contrast medicament
15% aramite missible oil (Nanjing Red Sun Group Co.,Ltd. production, commercially available)
1.3 trial crops and controlling object
Trial crops is a citrus, and kind is the Pon mandarin orange; Controlling object is citrus red mite Panonychus citri (MeGregor)
1.4 experimental scheme and method
1.4.1 field design
Test is carried out in citrus garden, Lishui City Liandu District Wan Ao village, and 12 processing are established in test, and every processing repeats for 3 times, every sub-district 3 strains tree, and guard row is established in the centre, and district's group is arranged at random.Each processing of test is respectively: the valid density of (1)-(10) embodiment 1-5 is respectively 500ppm and 250ppm, 1000 times of (11) 15% aramite missible oil (contrast medicament), the contrast of (12) clear water.
Test in spray medicine September 7 in 2005, medicament shakes up in water and disperses the back even spraying, with till being sprayed onto the blade face and just will having dripped.
1.4.1 efficacy survey and safety are observed
Test 1 young sprout of each mark of 4 orientation, the four corners of the world of setting in every strain before the spray medicine, each young sprout is got 5 blades, and every strain tree is investigated the mite quantity alive on 20 blades altogether.
1,3,7,15 day 4 times each processing of visual observations applying area are to the influence of citrus leaves, growth of young behind medicine, investigate of the safety of this preparation to citrus, and directly observe mite quantity alive on the index blade in 1,3,7,15 usefulness hand magnifiers behind the medicine, calculate go down rate and proofread and correct preventive effect of insect population.Computational methods are as follows:
Insect population borer population * 100 of living before rate (%)=(borer population of living after the borer population-dispenser of living before the dispenser)/dispenser of going down
Proofread and correct preventive effect (%)=(PT-CK)/(100-CK) * 100
In the formula: the PT---chemicals treatment district insect population rate that goes down;
The CK---blank district insect population rate that goes down.
1.5 the weather condition of duration of test (seeing Table 1)
Table 1. duration of test meteorological data
2, result of the test
2.1 safety to citrus
1,3,7,15 day 4 times visual observations behind the medicine do not see that each processing of embodiment 1-5 applying area has a significant effect to citrus leaves, growth of young, has illustrated that this preparation is to citrus safety.
2.2 preventive effect (seeing Table 2) to citrus red mite
Table 2. field control effectiveness test data
Can find out from above-mentioned test data: up to 95.2%, control efficiency is good, and is safe to the anti-efficient of citrus red mite for the described miticide that contains biomass gasification tar.
Claims (9)
1. miticide that contains biomass gasification tar, it is characterized in that: contain the biomass gasification tar of 5-90% weight percentage, described biomass gasification tar is bamboo tar, wood tar or careless tar.
2. the miticide that contains biomass gasification tar as claimed in claim 1 is characterized in that: the biomass gasification tar that contains the 10-80% weight percentage.
3. the miticide that contains biomass gasification tar as claimed in claim 1 is characterized in that: the biomass gasification tar that contains the 20-70% weight percentage.
4. the miticide that contains biomass gasification tar as claimed in claim 1 is characterized in that: the biomass gasification tar that contains the 30-50% weight percentage.
5. the miticide that contains biomass gasification tar as claimed in claim 1 is characterized in that: the known miticide that also contains the 0.05-70.00% weight percentage.
6. the miticide that contains biomass gasification tar as claimed in claim 1 is characterized in that: the known miticide that also contains the 0.1-50.0% weight percentage.
7. the miticide that contains biomass gasification tar as claimed in claim 1 is characterized in that: the known miticide that also contains the 0.2-30.0% weight percentage.
8. the miticide that contains biomass gasification tar as claimed in claim 1 is characterized in that: the known miticide that also contains the 0.2-20.0% weight percentage.
9. as claim 5,6,7 or the 8 described miticides that contain biomass gasification tar, it is characterized in that: described known miticide is Avermectin (Abamectin), more visit rhzomorph (Milbemectin), flucythrinate (Flucythrinate), betacyfluthrin (beta-cyfluthrin), gamma cyhalothrin (lambda-cyhalothrin), smart gamma cyhalothrin (gamma-cyhalothrin), beta-cypermethrin (beta-cypermethrin), decis (Deltamethrin), sumicidin (Esfenvalerate), alkynes mite spy (propargite), trifluoro sulfenone (Tetradifon), capillary (Chlorfenapyr), 4,6-two pin basic orthoresols (DNOC), pyridaben (Pyridaben), fenazaquin (Fenazaquin), azoles mite ester (Fenpyroximate), tebufenpyrad (Tebufenpyrad), pyrimidifen (Pyrimidifen), fluacrypyrim (Fluacrypyrim), rotenone (Rotenone), antimycin (Antimycin), inferior quinone mite (Acequinocyl), spiral shell mite ester (Spirodiclofen), four mite piperazines (Clofentezine), second mite azoles (Etoxazole), Hexythiazox (Hexythiazox), fluorine mite piperazine (Flufenzine), Citrazon (Benzoximate), dicofol (Dicofol), Chinomethionate (Chinomethionat), pyridalyl (Pyridalyl).
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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EP2008517A1 (en) * | 2007-06-29 | 2008-12-31 | Bayer CropScience AG | Acaricide active agent combinations |
CN101263830B (en) * | 2008-04-30 | 2010-09-22 | 浙江林学院 | Multi-effect pesticidal preparations and uses thereof |
CN101584318B (en) * | 2008-05-21 | 2014-01-08 | 山东京博控股股份有限公司 | Insect and acarid killer composition |
CN102265836B (en) * | 2010-06-02 | 2013-09-18 | 南京华洲药业有限公司 | Acaricide composition containing spirodiclofen and etoxazole and application thereof |
CN101990893A (en) * | 2010-11-01 | 2011-03-30 | 吴明龙 | Pesticide composition containing etoxazole and pyridaben |
CN102017960B (en) * | 2011-01-01 | 2013-12-25 | 陕西上格之路生物科学有限公司 | Acaricidal composition containing etoxazole and pyridaben |
CN103300050B (en) * | 2012-03-09 | 2016-04-06 | 陕西韦尔奇作物保护有限公司 | A kind of Pesticidal combination containing fluorine mite piperazine and organic tin |
CN105104407B (en) * | 2012-03-10 | 2017-06-16 | 陕西韦尔奇作物保护有限公司 | A kind of Efficient insecticidal composition |
CN103444726A (en) * | 2013-09-06 | 2013-12-18 | 刘波 | Pesticide acaricide containing flutenzine |
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RU2105549C1 (en) * | 1995-01-23 | 1998-02-27 | Борис Александрович Тимофеев | Acaricide preparation creoquine-leptocide |
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Patent Citations (5)
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RU2105549C1 (en) * | 1995-01-23 | 1998-02-27 | Борис Александрович Тимофеев | Acaricide preparation creoquine-leptocide |
RU2074722C1 (en) * | 1995-05-04 | 1997-03-10 | Акционерное общество открытого типа "Ветеринарные препараты" | Method of preparing acaricide preparation for treatment and prophylaxis of psoroptosis in sheep - phenolless coal creolin |
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