CN100556932C - 一种常压阳离子可染的阻燃共聚酯切片及制造方法 - Google Patents
一种常压阳离子可染的阻燃共聚酯切片及制造方法 Download PDFInfo
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- CN100556932C CN100556932C CNB2005100437527A CN200510043752A CN100556932C CN 100556932 C CN100556932 C CN 100556932C CN B2005100437527 A CNB2005100437527 A CN B2005100437527A CN 200510043752 A CN200510043752 A CN 200510043752A CN 100556932 C CN100556932 C CN 100556932C
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- Prior art keywords
- esterification
- flame
- flame retardant
- dyeable
- copolyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001634 Copolyester Polymers 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000003063 flame retardant Substances 0.000 claims abstract description 38
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 30
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 28
- 230000032050 esterification Effects 0.000 claims abstract description 26
- 238000005886 esterification reaction Methods 0.000 claims abstract description 26
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims abstract description 17
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 13
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 12
- 239000003381 stabilizer Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 238000012661 block copolymerization Methods 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000003446 ligand Substances 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- 229960004249 sodium acetate Drugs 0.000 claims description 2
- 235000017281 sodium acetate Nutrition 0.000 claims description 2
- 239000001632 sodium acetate Substances 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 claims 3
- OSNIIMCBVLBNGS-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-2-(dimethylamino)propan-1-one Chemical compound CN(C)C(C)C(=O)C1=CC=C2OCOC2=C1 OSNIIMCBVLBNGS-UHFFFAOYSA-N 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 15
- 229910052751 metal Inorganic materials 0.000 abstract description 11
- 239000002184 metal Substances 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 9
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract description 8
- 150000001768 cations Chemical class 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 abstract description 5
- 125000002091 cationic group Chemical group 0.000 abstract description 4
- 238000004043 dyeing Methods 0.000 abstract description 4
- 238000009835 boiling Methods 0.000 abstract description 2
- 239000002932 luster Substances 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 description 15
- 239000000835 fiber Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 229920004935 Trevira® Polymers 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 241000876833 Emberizinae Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
实施例 | 1 | 2 | 3 | 4 |
含磷阻燃剂用量,% | 12 | 8 | 4 | 8 |
SIPE用量,% | 3 | 5 | 10 | 5 |
特性粘度(dl/g) | 0.601 | 0.585 | 0.582 | 0.597 |
二甘醇含量(w.t%) | 3.3 | 3.2 | 3.5 | 3.8 |
端羧基含量(mol/t) | 27.6 | 29.1 | 25.3 | 28.4 |
熔点(℃) | 240.75 | 238.18 | 235.71 | 237.54 |
色度b值 | 9.8 | 7.25 | 8.5 | 7.74 |
色度L值 | 66.2 | 64.8 | 65.4 | 65.7 |
热失重(%) | 1.92 | 2.24 | 2.32 | 2.30 |
纺丝操作性 | 好 | 良好 | 一般 | 良好 |
LOI,%(切片酯条) | 28.9 | 27.5 | 27.0 | 28.1 |
纤维日晒牢度(8级制) | 5 | 6 | 6 | 6 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2005100437527A CN100556932C (zh) | 2005-06-16 | 2005-06-16 | 一种常压阳离子可染的阻燃共聚酯切片及制造方法 |
Applications Claiming Priority (1)
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CNB2005100437527A CN100556932C (zh) | 2005-06-16 | 2005-06-16 | 一种常压阳离子可染的阻燃共聚酯切片及制造方法 |
Publications (2)
Publication Number | Publication Date |
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CN1880357A CN1880357A (zh) | 2006-12-20 |
CN100556932C true CN100556932C (zh) | 2009-11-04 |
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CNB2005100437527A Expired - Fee Related CN100556932C (zh) | 2005-06-16 | 2005-06-16 | 一种常压阳离子可染的阻燃共聚酯切片及制造方法 |
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CN (1) | CN100556932C (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080167440A1 (en) * | 2007-01-10 | 2008-07-10 | Pickel Deanna L | Use of copolymerizable sulfonate salts to promote char formation in polyesters and copolyesters |
CN102352027B (zh) * | 2011-08-08 | 2013-02-06 | 张大省 | 一种阳离子染料可染的聚酯及其超细纤维 |
CN102677298A (zh) * | 2012-05-29 | 2012-09-19 | 蔡紫林 | 纺织布 |
CN108166094A (zh) * | 2017-12-28 | 2018-06-15 | 宁波三同编织有限公司 | 一种易染、阻燃阳离子聚酯纤维面料及其制备方法 |
CN110644123B (zh) * | 2018-04-04 | 2021-03-09 | 南京边城体育用品股份有限公司 | 一种持久抗菌的易染亲水聚酯纤维面料 |
CN108624010A (zh) * | 2018-06-07 | 2018-10-09 | 广东轻工职业技术学院 | 一种静电耗散性高透明度聚酯及其制备方法 |
CN115821418B (zh) * | 2022-10-18 | 2024-04-05 | 浙江恒逸石化研究院有限公司 | 一种基于自催化制备高磺酸盐含量抗菌阻燃阳离子染料可染聚酯纤维的方法 |
-
2005
- 2005-06-16 CN CNB2005100437527A patent/CN100556932C/zh not_active Expired - Fee Related
Non-Patent Citations (3)
Title |
---|
磷系阻燃共聚酯的合成和性能. 王国德.聚酯工业,第12卷第2期. 1999 * |
纳米阻燃-阳离子染料可染聚酯切片的研制. 边树昌等.聚酯工业,第17卷第2期. 2004 * |
阻燃-阳离子染料易染涤纶短纤维的研制. 洪剑桥.聚酯工业,第14卷第2期. 2001 * |
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CN1880357A (zh) | 2006-12-20 |
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Effective date of registration: 20090626 Address after: Fujian Haicang investment zone of Xiamen City, Ma Qing Road, No. 1268 post encoding: 361026 Applicant after: XIAMEN XIANGLU CHEMICAL FIBER CO.,LTD. Co-applicant after: Dragon Special Resin (Xiamen) Co.,Ltd. Address before: Fujian Haicang investment zone of Xiamen City, Ma Qing Road, No. 1268 post encoding: 361026 Applicant before: XIAMEN XIANGLU CHEMICAL FIBER CO.,LTD. |
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Assignee: Dragon Special Resin (Xiamen) Co.,Ltd. Assignor: XIAMEN XIANGLU CHEMICAL FIBER CO.,LTD.|Dragon Special Resin (Xiamen) Co.,Ltd. Contract fulfillment period: 2009.9.25 to 2014.9.25 Contract record no.: 2009351000074 Denomination of invention: Normal atmosphere cation-dyeable flame-proof copolyester slice and its production method Granted publication date: 20091104 License type: Exclusive license Record date: 20091102 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.9.25 TO 2014.9.25; CHANGE OF CONTRACT Name of requester: TENGLONG SPECIAL RESIN (XIAMEN) CO., LTD. Effective date: 20091102 |
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