CN100534613C - 一种钴钼系一氧化碳耐硫变换催化剂及其制备方法 - Google Patents
一种钴钼系一氧化碳耐硫变换催化剂及其制备方法 Download PDFInfo
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- CN100534613C CN100534613C CNB200510063573XA CN200510063573A CN100534613C CN 100534613 C CN100534613 C CN 100534613C CN B200510063573X A CNB200510063573X A CN B200510063573XA CN 200510063573 A CN200510063573 A CN 200510063573A CN 100534613 C CN100534613 C CN 100534613C
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- catalyst
- cobalt
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- oxide
- molybdenum
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- 239000003054 catalyst Substances 0.000 title claims abstract description 125
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 14
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 12
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000010941 cobalt Substances 0.000 claims abstract description 8
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 7
- 239000011733 molybdenum Substances 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 22
- 230000000694 effects Effects 0.000 claims description 15
- 238000001125 extrusion Methods 0.000 claims description 14
- 230000009466 transformation Effects 0.000 claims description 14
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 12
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 claims description 12
- 238000005520 cutting process Methods 0.000 claims description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- 150000001340 alkali metals Chemical class 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 244000275012 Sesbania cannabina Species 0.000 claims 1
- 150000001339 alkali metal compounds Chemical class 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052759 nickel Inorganic materials 0.000 abstract description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052721 tungsten Inorganic materials 0.000 abstract description 4
- 239000010937 tungsten Substances 0.000 abstract description 4
- 238000006555 catalytic reaction Methods 0.000 abstract description 2
- -1 cobalt-molybdenum series carbon monoxide Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 10
- 238000005299 abrasion Methods 0.000 description 9
- 239000007789 gas Substances 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 241000219782 Sesbania Species 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000004898 kneading Methods 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 230000001404 mediated effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 238000002803 maceration Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- PMTRSEDNJGMXLN-UHFFFAOYSA-N titanium zirconium Chemical compound [Ti].[Zr] PMTRSEDNJGMXLN-UHFFFAOYSA-N 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- 101000767534 Arabidopsis thaliana Chorismate mutase 2 Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 101000986989 Naja kaouthia Acidic phospholipase A2 CM-II Proteins 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
Abstract
Description
催化剂 | 强度N/cm | 磨耗% | 400℃加压活性XCO% |
C-1 | 172 | 0.9 | 87 |
C-2 | 159 | 1.1 | 89 |
C-3 | 162 | 1.2 | 87 |
C-4 | 170 | 1.0 | 88 |
C-5 | 168 | 1.3 | 87 |
自制球型催化剂 | 69,N/颗 | 1.7 | 83 |
自制条型催化剂 | 159 | 3.6 | 82 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB200510063573XA CN100534613C (zh) | 2005-04-13 | 2005-04-13 | 一种钴钼系一氧化碳耐硫变换催化剂及其制备方法 |
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CNB200510063573XA CN100534613C (zh) | 2005-04-13 | 2005-04-13 | 一种钴钼系一氧化碳耐硫变换催化剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1692981A CN1692981A (zh) | 2005-11-09 |
CN100534613C true CN100534613C (zh) | 2009-09-02 |
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CNB200510063573XA Active CN100534613C (zh) | 2005-04-13 | 2005-04-13 | 一种钴钼系一氧化碳耐硫变换催化剂及其制备方法 |
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CN (1) | CN100534613C (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100462143C (zh) * | 2006-04-03 | 2009-02-18 | 厦门大学 | 一种耐硫的一氧化碳变换催化剂及其制备方法 |
CN103769166B (zh) * | 2012-10-22 | 2015-10-21 | 中国石油化工股份有限公司 | 废旧钴钼耐硫变换催化剂中钴的回收利用方法 |
CN104248961A (zh) * | 2013-06-25 | 2014-12-31 | 中国石油化工股份有限公司 | 耐硫变换催化剂及其制备方法 |
CN103495422A (zh) * | 2013-09-29 | 2014-01-08 | 大连瑞克科技有限公司 | 一种钴钼耐硫变换催化剂的制备方法 |
CN104741110A (zh) * | 2015-03-25 | 2015-07-01 | 襄阳市精信催化剂有限责任公司 | 二氧化硫氧化制备硫酸催化剂的工艺 |
CN106552634A (zh) * | 2015-09-30 | 2017-04-05 | 中国石油化工股份有限公司 | 铝锆炭复合载体耐硫变换催化剂及制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0096322A2 (de) * | 1982-06-08 | 1983-12-21 | BASF Aktiengesellschaft | Katalysator zur Umwandlung von Kohlenmonoxid und Wasserdampf in schwefelhaltigen Gasen, Verfahren zur Herstellung des Katalysators und Anwendung desselben |
CN1128680A (zh) * | 1995-02-09 | 1996-08-14 | 中国石化齐鲁石油化工公司 | 一氧化碳耐硫变换催化剂的再生方法 |
CN2286649Y (zh) * | 1997-03-21 | 1998-07-29 | 化学工业部西南化工研究院 | 异形催化剂 |
CN1219500A (zh) * | 1997-12-07 | 1999-06-16 | 中国石化齐鲁石油化工公司 | 新型co耐硫变换催化剂及制备方法 |
CN1242410A (zh) * | 1998-07-17 | 2000-01-26 | 中国石化齐鲁石油化工公司 | 具有催化和分馏功能的选择加氢催化剂 |
-
2005
- 2005-04-13 CN CNB200510063573XA patent/CN100534613C/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0096322A2 (de) * | 1982-06-08 | 1983-12-21 | BASF Aktiengesellschaft | Katalysator zur Umwandlung von Kohlenmonoxid und Wasserdampf in schwefelhaltigen Gasen, Verfahren zur Herstellung des Katalysators und Anwendung desselben |
CN1128680A (zh) * | 1995-02-09 | 1996-08-14 | 中国石化齐鲁石油化工公司 | 一氧化碳耐硫变换催化剂的再生方法 |
CN2286649Y (zh) * | 1997-03-21 | 1998-07-29 | 化学工业部西南化工研究院 | 异形催化剂 |
CN1219500A (zh) * | 1997-12-07 | 1999-06-16 | 中国石化齐鲁石油化工公司 | 新型co耐硫变换催化剂及制备方法 |
CN1242410A (zh) * | 1998-07-17 | 2000-01-26 | 中国石化齐鲁石油化工公司 | 具有催化和分馏功能的选择加氢催化剂 |
Also Published As
Publication number | Publication date |
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CN1692981A (zh) | 2005-11-09 |
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Owner name: QINGDAO LIANXIN CATALYTIC MATERIALS CO., LTD. Free format text: FORMER OWNER: LIANXIN CHEMICAL CO., LTD., QINGDAO Effective date: 20120625 |
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Effective date of registration: 20120625 Address after: 266300 Jiaozhou Bay Industrial Park, Qingdao, Shandong, China, Jiaozhou Patentee after: QINGDAO LIANXIN CHEMICAL CO., LTD. Address before: 266300 Yunxi five road, Jiaozhou Economic Development Zone, Qingdao Patentee before: Lianxin Chemical Co., Ltd., Qingdao |