CN100525746C - Toothpaste of pearl for beautification and white - Google Patents
Toothpaste of pearl for beautification and white Download PDFInfo
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- CN100525746C CN100525746C CNB2004100613312A CN200410061331A CN100525746C CN 100525746 C CN100525746 C CN 100525746C CN B2004100613312 A CNB2004100613312 A CN B2004100613312A CN 200410061331 A CN200410061331 A CN 200410061331A CN 100525746 C CN100525746 C CN 100525746C
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Abstract
A beautifying-whitening pearl tooth-paste contains proportionally pearl powder or hydrolytic pearl liquid, water, and basic tooth-paste materials including wetting agent, adhesive, friction agent, foaming agent, flavouring, sweetening agent, buffering agent and antiseptic.
Description
Technical field
The present invention relates to a kind of whitening toothpaste that contains pearl composition.
Background technology
The toothpaste that contains pearl composition has certain whitening effect becomes known technology, but the whitening effect of Margarita will be used with suitable abrasive effect is preferably just arranged.What in the toothpaste tartar of tooth is played the cleaning souring after all mainly is abrasive.The whiten sodium fluoride of a employing 0.321% in the serial toothpaste and 20% abrasive silicon dioxide of Colgate-Palmolive for example.
The abrasive of existing toothpaste mainly is divided into four kinds: calcium hydrogen phosphate, silicon dioxide, calcium carbonate, aluminium hydroxide.Wherein calcium carbonate, aluminium hydroxide account for 80% of the market share because of the cheap domestic market that has occupied suitable share.The ultrastructure surface of the crystalline particle of calcium carbonate has the ultrastructure protrusion of surface of the crystalline particle of acute angle, aluminium hydroxide to be 120 degree more, can scratch the glaze of tooth.From the angle of protection consumer, under the prerequisite that guarantees cleaning teeth, should avoid using calcium carbonate and aluminium hydroxide as far as possible.And thinner calcium hydrogen phosphate, the silicon dioxide of granule is high-end abrasive, the price height, quality better, the ultrastructure surface of the crystalline particle of calcium hydrogen phosphate, silicon dioxide is the circular aggregated particles that is full of the honeycomb space, damage to tooth is little, and external toothpaste generally uses calcium hydrogen phosphate, silicon dioxide.That for example adopts calcium hydrogen phosphate, silicon dioxide in U.S.'s formulation of tooth-paste accounts for 97%.External toothpaste generally uses the tiny calcium hydrogen phosphate of granule, silicon dioxide, overseas enterprise's Chinese patent report in this respect has 01810803,02155841,94194690,95120328,97195269,97196178 etc., these calcium hydrogen phosphate, silicon dioxide have also passed through special processing sometimes, and 97195269,97196178 provide the abrasive silica that is used for toothpaste.
Sodium bicarbonate has sterilization and whitening function preferably as special abrasive, report is also arranged, for example " analysis of whitening toothpaste mentality of designing " (Zhang Zhifeng/toothpaste industry .2003 (2) .-32-33) affirmed the whitening function of sodium bicarbonate, points out that simultaneously sodium bicarbonate adds back toothpaste and has stability problem.
Summary of the invention
The purpose of this invention is to provide a kind of whitening toothpaste that contains pearl composition.
Technical scheme of the present invention is:
A kind of pearl whitening toothpaste comprises pearl composition 1-10 part by weight ratio, water 8-25 part, some parts of toothpaste base material; The toothpaste base material comprises: wetting agent 15-25 part, adhesive 0.3-1.0 part, abrasive 35-44 part, washing foaming agent 1.5-3 part, flavouring agent 0.1-1.4 part, sweeting agent 0.2-0.3 part, buffer agent 0.3-0.6 part, antiseptic 0.05-0.3 part.
Wherein: pearl composition is Margarita powder or Margarita hydrolyzed solution.
Adhesive is a locust bean gum.Or also contain other glue.
Pearl whitening toothpaste, wherein: abrasive is the mixture of silicon dioxide 30-35 part and sodium bicarbonate 5-9 part.
Pearl whitening toothpaste, wherein: silicon dioxide is that RDA grinding value is 75-85, and mean diameter is the silicon dioxide of 12-18 μ m.
Pearl whitening toothpaste also is added with methyl salicylate 0.001-0.01 part.
The RDA grinding value of silicon dioxide is less, is the abrasive less to injury of teeth of generally acknowledging.
The RDA method claims the radioactive dentin abrasion method again, and the RDA value is a kind of index of estimating abrasive grinding value that domestic and international dental industry is generally acknowledged." cleaning action of toothpaste abrasive and tooth wear---toothpaste abrasive is to the influence and progress II Wang Yi great waves [1] Li Gangs [2] the tooth body dental pulp periodontal magazine 2003 of tooth wear and cleaning effect " provides the simple computation method of RDA value.
Basic design scheme of the present invention is that the employing abrasive is the mixture of silicon dioxide and sodium bicarbonate, and preferably RDA grinding value is 75-85, and mean diameter is the silicon dioxide of 12-18 μ m.The grinding value of calcium hydrogen phosphate is 100 in contrast.Utilizing the grinding value to be lower than 100 silicon dioxide mainly is to consider to reduce friction the damage of agent to tooth, but the grinding value is lower, its to the cleaning rubbing souring of tartar also a little less than, and sodium bicarbonate can remedy the deficiency of this respect, and by the whitening function of sodium bicarbonate and Margarita.The sodium bicarbonate instability is easily decomposed and is emitted carbon dioxide, if do not select suitable stabilizers, sodium bicarbonate may go bad in lotion of toothpaste production with between the storage life and emit bubble, influences the presentation quality of toothpaste.
Studies show that according to other one of the applicant locust bean gum is obvious to the toothpaste stability action of silicon dioxide and Chinese herbal medicine system, the present invention is diverted to the toothpaste of silicon dioxide and Margarita, sodium bicarbonate system with locust bean gum, and stabilizing effect is also better.
Pearl composition involved in the present invention is Margarita powder or Margarita hydrolyzed solution, obtain by following method: Margarita grinds to form fine powder and promptly obtains Margarita powder, and Margarita hydrolyzed solution is open by CN97108043, CN95113369, CN97108043, CN97116731 as prior art.
The base material of pearl composition and toothpaste, water mix homogeneously are made corresponding compound recipe toothpaste.
Toothpaste advantage of the present invention is: 1, kept Chinese traditional pearl whitening composition.2, select locust bean gum for use,, can overcome the sodium bicarbonate instability, easily discharge bubble, influence shortcoming attractive in appearance as very good thickening stabilizing agent.3, the mixture of high-grade abrasive silicon dioxide and sodium bicarbonate is taken into account and is reduced toothpaste to the damage of tooth and the balance between the good whitening function of toothpaste.
The test example:
Matched group 1 precentagewise Margarita powder 5%, adhesive locust bean gum 0.5%; Abrasive is a calcium carbonate 35%; All the other are conventional toothpaste base material.Experiment number 14 people.
Matched group 2 precentagewise Margarita powder 5%, adhesive locust bean gum 0.5%; Abrasive is a silicon dioxide 35%; All the other are conventional toothpaste base material.Experiment number 27 people.
Experimental group precentagewise Margarita powder 5%, adhesive locust bean gum 0.5%; Abrasive is a silicon dioxide 26%; The mixture of part and sodium bicarbonate 9%; All the other are conventional toothpaste base material.Experiment number 36 people.
Matched group 1, matched group 2, the abrasive of experimental group is had any different, and all the other are identical.
Adopt " whitening toothpaste is removed the clinical effectiveness of dental exogenous mottle and observed " (Guangdong dental prevention .2001,9 (3) .-169-171) the dental exogenous mottle clinical experiment method that provides is investigated abrasive silicon dioxide, sodium bicarbonate to removing the effect of exogenous mottle.
The result: experimental group reduces 26.2% than the dental exogenous mottle area of matched group 1, and experimental group reduces 10.4% than the dental exogenous mottle area of matched group 1.
The specific embodiment
Embodiment 1, the multiple toothpaste of selection are stable contrast experiment:
A kind of pearl whitening toothpaste comprises 5 parts of Margarita powder by weight ratio, some parts of conventional toothpaste base material, 25 parts in water; Conventional toothpaste base material is: wetting agent is 5 parts of glycerol, 15 parts of sorbic acid; Some parts of adhesive; Abrasive is the mixture of 6 parts of 32 parts of silicon dioxide and sodium bicarbonate; 3 parts of washing foaming agent sodium lauryl sulfates; Each 0.2 part of flavouring agent Oleum menthae, Fructus Citri Limoniae oil; 0.3 part of sweeting agent aspartame, 0.3 part of buffer agent tetrasodium pyrophosphate; 0.05 part of preservative sodium benzoate.
Water as raw material is handled through deionization, can better guarantee product quality.
Preparation method: sweeting agent, buffer agent, the component premixing that antiseptic equivalent is few evenly place first barrel stand-by; Wetting agent, adhesive premixing evenly place second barrel stand-by; Abrasive, washing foaming agent and Margarita powder, flavouring agent add deionized water, and add in first and second bucket stand-by material make cream under vacuum condition, and mastic grind to stir 1 hour, went out cream, form.
The selection of adhesive to the influence of stability shown in form.
The RDA=80 of abrasive selective precipitation method preparation; Mean diameter is the precipitated silica of 15 μ m.Precipitated silica is a kind of mature technique.Precipitated silica can be provided by Rhodia Chimie, or provides by the method for CN97196178, CN97195269 record.
Stability range estimation effect expedition is as follows: with the toothpaste of different formulations with hose packing after, places after 3 months, extrude mastic and leave on the glass plate, mastic inspection mastic inside is stirred with Glass rod in visual inspection mastic surface.Observe inside and outside level and smooth, the no crafters of mastic, some parts of adhesive is as follows to the influence of stability:
| Locust bean gum consumption (part) | Xanthan gum consumption (part) | Carrageenan consumption (part) | Guar gum consumption (part) | Bubbles volume | The inside and outside smoothness of mastic | |
| Abrasive is the mixture of 6 parts of 32 parts of silicon dioxide and sodium bicarbonate | 0.3 | 0.2 | No bubble | Smoothly | ||
| Abrasive is 32 parts of silicon dioxide | 0.5 | No bubble | Smoothly |
| Mixture with 6 parts of sodium bicarbonate | ||||||
| Abrasive is the mixture of 6 parts of 32 parts of silicon dioxide and sodium bicarbonate | 0.5 | A small amount of bubble | Smoothly | |||
| Abrasive is the mixture of 6 parts of 32 parts of silicon dioxide and sodium bicarbonate | 0.5 | A large amount of bubbles | Coarse | |||
| Abrasive is the mixture of 6 parts of 32 parts of silicon dioxide and sodium bicarbonate | 0.5 | A small amount of bubble | Smoothly | |||
| Abrasive is the mixture of 9 parts of 30 parts of silicon dioxide and sodium bicarbonate | 0.5 | No bubble | Smoothly | |||
| Abrasive is the mixture of 9 parts of 30 parts of calcium carbonate and sodium bicarbonate | 0.5 | No bubble | Smoothly | |||
| Abrasive is the mixture of 9 parts of 30 parts of calcium hydrogen phosphate and sodium bicarbonate | 0.5 | No bubble | Smoothly | |||
| Abrasive is 39 parts of sodium bicarbonate | 0.5 | A small amount of bubble | Smoothly |
Locust bean gum is in the nature and function of Applications in Food Industry: colourless, tasteless albumen is made with extra care polysaccharide, mainly contains mannose and gala is warded off, and molecular weight is approximately 300,000 dalton, is very good thickening stabilizing agent.Locust bean gum and silicon dioxide, sodium bicarbonate, pearl composition compatibility are coordinated good stability.
Embodiment 2, a kind of pearl whitening toothpaste comprise 10 parts of Margarita powder by weight ratio, 20 parts in water, some parts of toothpaste base material; The toothpaste base material comprises: 10 parts of wetting agent glycerol, 15 parts of sorbic acid, 1.0 parts of adhesive locust bean gums, 44 parts of abrasive silicon dioxide, 3 parts of washing foaming agent, 1.4 parts of flavouring agent Fructus Citri Limoniae oil, 0.3 part of sweeting agent acesulfame potassium, 0.6 part of buffer agent tetrasodium pyrophosphate, 0.3 part of preservative sodium benzoate.All the other are with embodiment 1.
Embodiment 3, a kind of pearl whitening toothpaste comprise 1 part of Margarita powder by weight ratio, some parts of conventional toothpaste base material, 8 parts in water; Conventional toothpaste base material is: wetting agent is 10 parts of glycerol, 3 parts of sorbic acid, 2 parts of malonic acid; 0.3 part of adhesive locust bean gum; 35 parts of abrasive silicon dioxide; 1.5 parts of washing foaming agent sodium lauryl sulfates; Each 0.05 part of flavouring agent Oleum menthae, Fructus Citri Limoniae oil; 0.2 part of sweeting agent aspartame, 0.3 part of buffer agent tetrasodium pyrophosphate; 0.05 part of preservative sodium benzoate.All the other are with embodiment 1.
Embodiment 4, a kind of pearl whitening toothpaste comprise 1 part of Margarita hydrolyzed solution by weight ratio; Adhesive is 0.3 part of locust bean gum, 0.3 part of guar gum, and abrasive is that RDA grinding value is 70, and mean diameter is the silicon dioxide of 12 μ m.All the other are with embodiment 1.
Embodiment 5, a kind of pearl whitening toothpaste comprise 10 parts of Margarita hydrolyzed solutions by weight ratio; Abrasive is that RDA grinding value is 75, and mean diameter is the silicon dioxide of 18 μ m.All the other are with embodiment 2.
Embodiment 6, a kind of pearl whitening toothpaste comprise 6 parts of Margarita hydrolyzed solutions by weight ratio; Also contain conventional toothpaste base material, conventional toothpaste base material comprises: 19 parts of wetting agent, 0.7 part of adhesive, 37 parts of abrasives, 2 parts of washing foaming agent, 0.6 part of flavouring agent, 0.25 part of sweeting agent, 0.4 part of buffer agent, 0.2 part of antiseptic, wherein adhesive is a locust bean gum, and abrasive is that RDA grinding value is 85, and mean diameter is the silicon dioxide of 15 μ m.All the other are with embodiment 3.
Embodiment 7, a kind of pearl whitening toothpaste, wetting agent are 10 parts of glycerol, 5 parts of sorbic acid, 5 parts of malonic acid; 20 parts of abrasive calcium carbonate, 0 part of silica 1,20 parts of titanium dioxides; 3 parts of washing foaming agent sodium lauryl sulfates; The flavouring agent Oleum Menthae Rotundifoliae, respectively 0.2 part of Oleum menthae, Fructus Citri Limoniae oil, citrus oils; 0.3 part of sweeting agent aspartame, 0.3 part of buffer agent tetrasodium pyrophosphate; 0.05 part of preservative sodium benzoate, wherein adhesive also increases by 0.1 part of sodium alginate.All the other are with embodiment 3.
Embodiment 8, a kind of pearl whitening toothpaste are replaced Margarita powder for 5 parts with Margarita hydrolyzed solution.All the other are with embodiment 1.And do stability experiment by the method for embodiment 1.
| Locust bean gum consumption (part) | Xanthan gum consumption (part) | Carrageenan consumption (part) | Guar gum consumption (part) | Bubbles volume | The inside and outside smoothness of mastic | |
| Abrasive is the mixture of 6 parts of 32 parts of silicon dioxide and sodium bicarbonate | 0.5 | No bubble | Smoothly | |||
| Abrasive is the mixture of 6 parts of 32 parts of silicon dioxide and sodium bicarbonate | 0.3 | 0.2 | No bubble | Smoothly | ||
| Abrasive is the mixture of 8 parts of 30 parts of silicon dioxide and sodium bicarbonate | 0.3 | 0.2 | No bubble | Smoothly | ||
| Abrasive is the mixture of 6 parts of 32 parts of silicon dioxide and sodium bicarbonate | 0.5 | A large amount of bubbles | Coarse |
Embodiment 9, a kind of pearl whitening toothpaste also are added with 0.001 part of methyl salicylate, and wherein adhesive also increases by 0.2 part of carrageenan.All the other are with embodiment 3.
Embodiment 10, a kind of pearl whitening toothpaste also are added with 0.01 part of methyl salicylate, and wherein adhesive also increases by 0.3 part of xanthan gum.All the other are with embodiment 3.
Embodiment 11, a kind of pearl whitening toothpaste also are added with 0.008 part of methyl salicylate, and wherein adhesive also increases by 0.1 part of sodium alginate.All the other are with embodiment 3.
Claims (1)
1, a kind of pearl whitening toothpaste is characterized in that: be made up of for 25 parts by weight ratio each 0.2 part of 3 parts of 6 parts of 32 parts of 0.2 part of 0.3 part of 15 parts of 5 parts of 5 parts of Margarita powder, glycerol, sorbic acid, locust bean gum, guar gum, silicon dioxide, sodium bicarbonate, sodium lauryl sulfates, flavouring agent Oleum menthae, Fructus Citri Limoniae oil, 0.3 part of aspartame, 0.3 part of tetrasodium pyrophosphate, 0.05 part of sodium benzoate and water.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100613312A CN100525746C (en) | 2004-12-10 | 2004-12-10 | Toothpaste of pearl for beautification and white |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100613312A CN100525746C (en) | 2004-12-10 | 2004-12-10 | Toothpaste of pearl for beautification and white |
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| CN1660035A CN1660035A (en) | 2005-08-31 |
| CN100525746C true CN100525746C (en) | 2009-08-12 |
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| CNB2004100613312A Expired - Fee Related CN100525746C (en) | 2004-12-10 | 2004-12-10 | Toothpaste of pearl for beautification and white |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100444827C (en) * | 2005-12-02 | 2008-12-24 | 冯真 | Tooth-cleaning composition |
| CN1899261B (en) * | 2006-07-26 | 2010-05-12 | 广州立白企业集团有限公司 | Baking soda toothpaste with salty taste |
| CN102078277A (en) * | 2010-12-28 | 2011-06-01 | 海南京润珍珠生物技术股份有限公司 | Sun screen cream added with silicon-treated pearl powder |
| CN105168019A (en) * | 2015-10-26 | 2015-12-23 | 青岛高新区尚达医药研究所 | Chitin toothpaste and preparation method thereof |
| CN106038334A (en) * | 2016-06-23 | 2016-10-26 | 海南热带海洋学院 | Bacterium-inhibiting and odor-removing toothpaste containing ilex latifolia thunb extract |
| CN108904344A (en) * | 2017-12-26 | 2018-11-30 | 李文婷 | A kind of oral cavity nursing agent with brilliant white function |
| CN109044940A (en) * | 2017-12-26 | 2018-12-21 | 李文婷 | A kind of oral cavity nursing agent with whitening hemostatic function |
| CN109223629A (en) * | 2017-12-26 | 2019-01-18 | 李文婷 | A kind of whitening oral cavity nursing agent |
| CN109528578A (en) * | 2017-12-26 | 2019-03-29 | 李文婷 | A kind of whitening hemostasis oral cavity nursing agent |
-
2004
- 2004-12-10 CN CNB2004100613312A patent/CN100525746C/en not_active Expired - Fee Related
Non-Patent Citations (2)
| Title |
|---|
| 营养型亮白粒子牙膏的研制. 梁华等.牙膏工业，第4期. 2004 |
| 营养型亮白粒子牙膏的研制. 梁华等.牙膏工业，第4期. 2004 * |
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| CN1660035A (en) | 2005-08-31 |
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