CN100516261C - Method for changing A356 alloy primary aluminum liquid using cerium-enriched mixing rare earth - Google Patents

Method for changing A356 alloy primary aluminum liquid using cerium-enriched mixing rare earth Download PDF

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Publication number
CN100516261C
CN100516261C CNB2007101265832A CN200710126583A CN100516261C CN 100516261 C CN100516261 C CN 100516261C CN B2007101265832 A CNB2007101265832 A CN B2007101265832A CN 200710126583 A CN200710126583 A CN 200710126583A CN 100516261 C CN100516261 C CN 100516261C
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China
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time
cerium
refining
aluminum liquid
alloy
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Expired - Fee Related
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CNB2007101265832A
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Chinese (zh)
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CN101086041A (en
Inventor
王云利
赵洪生
栗争光
张军
郭有军
降虹
何建丽
赵亚平
于水
翟宝辰
龚献忠
李宏林
姚巍
赵海龙
周海兰
潘丽红
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Baotou Aluminum Co., Ltd.
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BAOTOU ALUMINUM Co Ltd
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Abstract

The invention relates to a method for preparing A356 alloy original aluminum liquid by using cerium- rich mixed rare earth. It comprises following steps: (1)melting A356 alloy original aluminum liquid in industrial mixed furnace, controlling temperature between 710 Deg. C and 740 Deg. C, melting time is 90-150min, the time of first magnetic stirring is 20-40min, the temperature and time for first refining is 680-700Deg. C and 30-60min; (2) the aluminium -mischmetal master alloy is employed as alterant: Al-6-7wt%RE, mixed rare earth is cerium- rich mixed rare earth, and the content of Ce is more than 70wt%; the original metamorphic materials is A356 alloy original aluminum liquid; (3)adding cerium- rich mixed rare earth to A356 alloy original aluminum liquid after the first refining slag skimming, the additional content of cerium-rich mischmetal between 0.03wt% and 0.1wt%; (4) the temperature of metamorphicing is 720-735 Deg. C; (5) the deteriorate time is 10-30min; (6) the magnetic stirring for the second time is 5-15min; (7) carrying out the second refining, and temperature and time is 670-690Deg. C and 20-50min; (8)stewing and pouring, controlling the temperature between 650 Deg. C and 680Deg. C. The invention is characterized by good metamorphic effect, less burning loss, good hereditary and low cost.

Description

Method with changing A 356 alloy primary aluminum liquid using cerium-enriched mixing rare earth
One, technical field
The present invention relates to a kind of method, belong to the rotten Technology field of aluminium alloy with changing A 356 alloy primary aluminum liquid using cerium-enriched mixing rare earth.
Two, technical background
A356 alloy modification element is more, as sodium, strontium, rare earth etc.Now, strontium modification process technology commonly used on industrial production, but, because there is poor, the shortcoming such as air-breathing easily of the easy scaling loss of strontium, heredity in strontium modification process technology, so enterprise and user need seek and a kind ofly new can be used for the industrial element that directly A356 alloy primary aluminum liquid is gone bad.Through laboratory study, find that rare earth is the ideal alterant element.But, also do not find to use the directly rotten A356 alloy primary aluminum liquid of cerium-rich mischmetal to carry out the industrialization production technology industrial.
Three, summary of the invention
The purpose of this invention is to provide a kind of employing mix-melting method, on industrial production, use the directly rotten A356 alloy primary aluminum liquid of cerium-rich mischmetal, and form industrialization quantity-produced method.
Concrete technical scheme is as follows:
(1) A356 alloy primary aluminum liquid melts in industrial holding furnace and joins, smelting temperature is controlled at 710-740 ℃, smelting time is controlled at 90-150min, in fusion process, carry out the magnetic agitation first time, churning time is controlled at 20-40min, carry out the refining first time after the melting, refining temperature is controlled at 680-700 ℃ for the first time, and refining time is controlled at 30-60min for the first time;
(2) alterant adopts aluminium-mishmetal master alloy: Al-6~7wt%RE, and mishmetal is a cerium-rich mischmetal, and wherein cerium content is greater than 70wt%; Treat that rotten material is an A356 alloy primary aluminum liquid;
(3) after the first time, refining was skimmed, in A356 alloy primary aluminum liquid, add aluminium-cerium-rich mischmetal master alloy, cerium-rich mischmetal add-on minimum is not less than 0.03wt%, and maximum is not more than 0.1wt%, and optimal addn is 0.06wt%;
(4) deterroration is 720-735 ℃;
(5) deteriorating time is 10-30min;
(6) carry out the magnetic agitation second time, churning time 5-15min in the process on the turn;
(7) reach after the deteriorating time, carry out the refining second time, refining temperature is at 670-690 ℃ for the second time, and refining time is controlled at 20-50min for the second time;
(8) leave standstill the back cast, teeming temperature is controlled at 650-680 ℃.
Advantage of the present invention is: modification effect is good, scaling loss is little, heredity is good, cost is low.
Four, description of drawings
Fig. 1 is a process flow sheet of the present invention.
Five, embodiment
In aluminium alloy casting workshop industry holding furnace (16t), add 0.8t solid metal silicon grain earlier; Add 10t molten aluminium and 1.75t titaniferous primary aluminum liquid then; And then adding 44kg pure metal magnesium; Carry out melting and refining after the batching; After refining has been skimmed, add 61kg cerium-rich mischmetal master alloy (Al-6.78%wtRE).
Concrete processing parameter is as follows:
Smelting temperature: 736 ℃
Smelting time: 120min
Churning time: 30min for the first time
Refining temperature for the first time: 689 ℃
Refining time: 40min for the first time
Refining agent consumption: 72kg
Deterroration: 736 ℃
Deteriorating time: 10min
Churning time: 10min for the second time
Refining temperature for the second time: 689 ℃
Refining time: 40min for the second time
Time of repose: 40min
Casting temp: 677 ℃.

Claims (1)

1, a kind of method with changing A 356 alloy primary aluminum liquid using cerium-enriched mixing rare earth, it is characterized in that: concrete steps are as follows:
(1) A356 alloy primary aluminum liquid melts in industrial holding furnace and joins, smelting temperature is controlled at 710-740 ℃, smelting time is controlled at 90-150min, in fusion process, carry out the magnetic agitation first time, churning time is controlled at 20-40min, carry out the refining first time after the melting, refining temperature is controlled at 680-700 ℃ for the first time, and refining time is controlled at 30-60min for the first time;
(2) alterant adopts aluminium-mishmetal master alloy: Al-6~7wt%RE, and mishmetal is a cerium-rich mischmetal, and wherein cerium content is greater than 70wt%; Treat that rotten material is an A356 alloy primary aluminum liquid;
(3) after the first time, refining was skimmed, in A356 alloy primary aluminum liquid, add aluminium-cerium-rich mischmetal master alloy, cerium-rich mischmetal add-on minimum is not less than 0.03wt%, and maximum is not more than 0.1wt%;
(4) deterroration is 720-735 ℃;
(5) deteriorating time is 10-30min;
(6) carry out the magnetic agitation second time, churning time 5-15min in the process on the turn;
(7) reach after the deteriorating time, carry out the refining second time, refining temperature is at 670-690 ℃ for the second time, and refining time is controlled at 20-50min for the second time;
(8) leave standstill the back cast, teeming temperature is controlled at 650-680 ℃.
CNB2007101265832A 2007-06-21 2007-06-21 Method for changing A356 alloy primary aluminum liquid using cerium-enriched mixing rare earth Expired - Fee Related CN100516261C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2007101265832A CN100516261C (en) 2007-06-21 2007-06-21 Method for changing A356 alloy primary aluminum liquid using cerium-enriched mixing rare earth

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2007101265832A CN100516261C (en) 2007-06-21 2007-06-21 Method for changing A356 alloy primary aluminum liquid using cerium-enriched mixing rare earth

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CN101086041A CN101086041A (en) 2007-12-12
CN100516261C true CN100516261C (en) 2009-07-22

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103866166A (en) * 2014-03-05 2014-06-18 中信戴卡股份有限公司 Preparation process of aluminum alloy
CN111041254A (en) * 2019-11-28 2020-04-21 宝胜(宁夏)线缆科技有限公司 Furnace-front production process of electrical round aluminum rod
CN110964936B (en) * 2019-12-16 2021-04-02 金联电力设备有限公司 Production process of high-strength corrosion-resistant aluminum alloy for power line hardware

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