CN100509952C - Transparent epoxy nano composite material and preparation method and application thereof - Google Patents
Transparent epoxy nano composite material and preparation method and application thereof Download PDFInfo
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- CN100509952C CN100509952C CNB2006100809666A CN200610080966A CN100509952C CN 100509952 C CN100509952 C CN 100509952C CN B2006100809666 A CNB2006100809666 A CN B2006100809666A CN 200610080966 A CN200610080966 A CN 200610080966A CN 100509952 C CN100509952 C CN 100509952C
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- nano
- epoxy
- composite material
- particle
- transparent epoxy
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- 239000004593 Epoxy Substances 0.000 title claims abstract description 114
- 239000000463 material Substances 0.000 title claims abstract description 77
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 69
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 51
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 32
- 239000002131 composite material Substances 0.000 claims abstract description 28
- 239000011256 inorganic filler Substances 0.000 claims abstract description 6
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims description 60
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 33
- 239000004408 titanium dioxide Substances 0.000 claims description 23
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 21
- 239000003822 epoxy resin Substances 0.000 claims description 19
- 229920000647 polyepoxide Polymers 0.000 claims description 19
- 239000004848 polyfunctional curative Substances 0.000 claims description 19
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 229960001866 silicon dioxide Drugs 0.000 claims description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 12
- 235000012239 silicon dioxide Nutrition 0.000 claims description 12
- 150000001412 amines Chemical group 0.000 claims description 11
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 238000005538 encapsulation Methods 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 9
- 239000002244 precipitate Substances 0.000 claims description 9
- 150000002460 imidazoles Chemical class 0.000 claims description 8
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical group C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 claims description 8
- 239000012764 mineral filler Substances 0.000 claims description 8
- 238000005119 centrifugation Methods 0.000 claims description 7
- 239000003495 polar organic solvent Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 150000008065 acid anhydrides Chemical class 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- MUTGBJKUEZFXGO-UHFFFAOYSA-N hexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21 MUTGBJKUEZFXGO-UHFFFAOYSA-N 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 229940015043 glyoxal Drugs 0.000 claims description 2
- 239000002798 polar solvent Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 abstract description 21
- 239000002105 nanoparticle Substances 0.000 abstract description 17
- 230000032683 aging Effects 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 10
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 239000004065 semiconductor Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 description 23
- 239000011257 shell material Substances 0.000 description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 14
- 238000002834 transmittance Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 12
- 239000011246 composite particle Substances 0.000 description 7
- 229920002521 macromolecule Polymers 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000011787 zinc oxide Substances 0.000 description 7
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 description 6
- 239000004567 concrete Substances 0.000 description 5
- TVUBDAUPRIFHFN-UHFFFAOYSA-N dioxosilane;oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4].O=[Si]=O TVUBDAUPRIFHFN-UHFFFAOYSA-N 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 238000001132 ultrasonic dispersion Methods 0.000 description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- -1 silicon-dioxide-titanium dioxide-gold Chemical compound 0.000 description 2
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 206010051246 Photodermatosis Diseases 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004100 electronic packaging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000008845 photoaging Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
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CNB2006100809666A CN100509952C (en) | 2006-05-26 | 2006-05-26 | Transparent epoxy nano composite material and preparation method and application thereof |
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CNB2006100809666A CN100509952C (en) | 2006-05-26 | 2006-05-26 | Transparent epoxy nano composite material and preparation method and application thereof |
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CN101077923A CN101077923A (en) | 2007-11-28 |
CN100509952C true CN100509952C (en) | 2009-07-08 |
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CNB2006100809666A Expired - Fee Related CN100509952C (en) | 2006-05-26 | 2006-05-26 | Transparent epoxy nano composite material and preparation method and application thereof |
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Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2009069429A1 (en) * | 2007-11-29 | 2011-04-07 | 日産化学工業株式会社 | Silica-containing epoxy curing agent and epoxy resin cured product |
CN101661983B (en) * | 2008-08-26 | 2012-03-14 | 富准精密工业(深圳)有限公司 | Light emitting diode (LED) and preparation method thereof |
CN101974245B (en) * | 2010-09-29 | 2013-07-03 | 北京化工大学 | High-transparent ultraviolet-blocking energy-saving membrane and solution phase transfer preparation method |
CN102816402B (en) * | 2011-06-09 | 2015-08-05 | 北京化工大学 | A kind of highly-transparent ultraviolet-resistant imitates ceramic flexible nano composite film material and preparation method thereof |
CN102286260A (en) * | 2011-06-28 | 2011-12-21 | 上海景涵实业有限公司 | Non-yellowing high-transmittance insulated epoxy adhesive for light emitting diode (LED) and preparation method and use thereof |
CN102408681B (en) * | 2011-09-10 | 2014-07-23 | 广东东阳光铝业股份有限公司 | Composite material for packaging and preparation method thereof |
JP5756054B2 (en) * | 2012-04-16 | 2015-07-29 | 信越化学工業株式会社 | Thermosetting resin composition for LED reflector, LED reflector and optical semiconductor device using the same |
CN102926273B (en) * | 2012-10-26 | 2014-12-31 | 方少彬 | Nanoparticle-reinforced wallpaper paste and preparation method thereof |
CN104118066B (en) * | 2014-08-29 | 2016-07-27 | 河南易成新能源股份有限公司 | The manufacture method of nano hybridization resin-diamond line |
CN105694362B (en) * | 2014-11-27 | 2018-01-02 | 中国科学院化学研究所 | Light-shielding polymer nano composite material |
CN104559422B (en) * | 2014-12-18 | 2016-08-17 | 益阳市资阳区明乐士涂料厂 | A kind of similar immiscible particle for ornament materials and preparation method thereof |
CN106876145A (en) * | 2017-03-24 | 2017-06-20 | 湖北大学 | A kind of solar cell TiO2/SiO2Core shell structure light anode and preparation method thereof |
CN108047499A (en) * | 2017-12-18 | 2018-05-18 | 苏州亿沃光电科技有限公司 | LED encapsulation nucleocapsid particles, epoxy composite material and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1189459A (en) * | 1998-01-09 | 1998-08-05 | 中国科学院固体物理研究所 | Nanometre titanium dioxide/silicon dioxide mesic hole compound and prepn. thereof |
CN1244516A (en) * | 1999-08-10 | 2000-02-16 | 复旦大学 | Preparation of composite nanometer titania-silica material |
US20020197475A1 (en) * | 2001-03-30 | 2002-12-26 | Degussa Ag | Organosilicon nano/microhybrid or microhybrid system composition for scratch and abrasion resistant coatings |
CN1631995A (en) * | 2003-12-23 | 2005-06-29 | 中国科学院理化技术研究所 | Spherical zinc oxide and titanium dioxide composite particles with particle structures on surfaces, and preparation method and application thereof |
CN1663388A (en) * | 2004-03-03 | 2005-09-07 | 中国科学院理化技术研究所 | Tourmaline and titanium dioxide particle composite coated with micro mesoporous silicon dioxide on surface and preparation method and application thereof |
-
2006
- 2006-05-26 CN CNB2006100809666A patent/CN100509952C/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1189459A (en) * | 1998-01-09 | 1998-08-05 | 中国科学院固体物理研究所 | Nanometre titanium dioxide/silicon dioxide mesic hole compound and prepn. thereof |
CN1244516A (en) * | 1999-08-10 | 2000-02-16 | 复旦大学 | Preparation of composite nanometer titania-silica material |
US20020197475A1 (en) * | 2001-03-30 | 2002-12-26 | Degussa Ag | Organosilicon nano/microhybrid or microhybrid system composition for scratch and abrasion resistant coatings |
CN1631995A (en) * | 2003-12-23 | 2005-06-29 | 中国科学院理化技术研究所 | Spherical zinc oxide and titanium dioxide composite particles with particle structures on surfaces, and preparation method and application thereof |
CN1663388A (en) * | 2004-03-03 | 2005-09-07 | 中国科学院理化技术研究所 | Tourmaline and titanium dioxide particle composite coated with micro mesoporous silicon dioxide on surface and preparation method and application thereof |
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CN101077923A (en) | 2007-11-28 |
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Assignee: GUANGDONG ZHONGKE SHUNWEI NEW MATERIAL TECHNOLOGY DEVELOPMENT Co.,Ltd. Assignor: Technical Institute of Physics and Chemistry Chinese Academy of Sciences Contract record no.: 2012440000368 Denomination of invention: Transparent epoxy nano composite material and its preparation method and use Granted publication date: 20090708 License type: Exclusive License Open date: 20071128 Record date: 20120706 |
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Owner name: GUANGDONG CAS.SUNWILL NEW MATERIAL CO., LTD. Free format text: FORMER OWNER: TECHNICAL INSTITUTE OF PHYSICS AND CHEMISTRY, CAS Effective date: 20121126 |
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Free format text: CORRECT: ADDRESS; FROM: 100080 HAIDIAN, BEIJING TO: 523000 FOSHAN, GUANGDONG PROVINCE |
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Effective date of registration: 20121126 Address after: 523000 Guangdong city of Foshan province Shunde high tech Development Zone (Ronggui) Keyuan Road No. six of Patentee after: GUANGDONG ZHONGKE SHUNWEI NEW MATERIAL TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: 100080 No. 2, north of Haidian District, Beijing, Zhongguancun Patentee before: Technical Institute of Physics and Chemistry Chinese Academy of Sciences |
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