CN100496455C - Personal care composition containing a cleansing phase and a benefit phase - Google Patents

Abstract

A personal care composition comprising a cleansing phase, and at least one benefit phase selected from the group consisting of a fatty compound gel network, a hydrophobic gel network, a hydrophobic gel network in a fatty compound gel network, a fatty compound gel network in a hydrophobic gel network, or a silicone or silicone gel. These products are intended to provide a multi-phase cleansing composition that is packaged in physical contact while remaining stable and providing improved in-use and after-use hair and skin benefits. The present invention is further directed to a method of using the multi-phase personal care composition.

Description

Comprise cleansing phase and useful personal care composition mutually

Invention field

The present invention relates to be applicable to the personal care composition of mammal skin and hair.These compositionss comprise cleansing phase and at least a useful (benefit phase) mutually, described useful organophilic gel network, the aliphatic compound gel network in the organophilic gel network or siloxanes or the silicone gel that is selected from mutually in aliphatic compound gel network (fatty compound gel network), organophilic gel network, the aliphatic compound gel network.These products are used to provide a kind of heterogeneous Cleasing compositions, and described compositions is packed in the mode of actual contact, keep stable simultaneously, and provide the use neutralization of improvement to use back hair and skin beneficiating effect.

Background of invention

Known in the art, can comprise detersive surfactant and cationic polymer and nurse one's health the deposition of oil, thereby can give the Cleasing compositions of conditioning or smooth character for the surface of its processing as silicone oil to improve.Yet these conditioning oil are restricted in the scope of physics, optics and aesthstic beneficial effect that they provided.The washing-off type care composition that comprises cationic surfactant and aliphatic alcohol also is known.These compositionss also comprise various oil and silicone compounds is controlled and the neat beneficial effect of hair so that surface flatness, curly hair to be provided.The conditioner that is used for hair has the required particular viscosity of this product.These products are based on the combination of surfactant (being generally quaternary ammonium compound) and aliphatic alcohol.This combination results gel network structure, this structure provides required rheological behavior to compositions.

Usually, the people that hair-conditioning is had relatively high expectations uses independent shampoo and conditioner product.By conditioning-shampoo, being commonly referred to 2, to close the hair-conditioning beneficial effect that 1 shampoo provides always not enough.Handle moistening and the dry hair-conditioning beneficial effect that provides excellent with independent conditioner.The gel network structure of hair conditioner can produce unique use neutralization and use back moistening hair-conditioning beneficial effect.

For a long time, need send conditioner gel network beneficial effect by one bottle of hair cleaning-care composition always.Typically, in the time will nursing one's health gel network and add in the hair Cleasing compositions comprise decontamination/anion surfactant, rheological behavior of this conditioning gel network and Cleasing compositions is all destroyed.The foaming effect of this unwelcome interaction partners product between anion cleansing phase and the conditioning gel network has adverse effect.

Hair-conditioning and cleaning beneficial effect are being provided by personal cleansing product, and keeping a kind of trial of gel network structure and foaming characteristic aspect simultaneously is dual compartment package.These packings comprise isolating Cleasing compositions and care composition, and can both are divided into one or bifilar mode to join.Isolating conditioning and Cleasing compositions during prolonged storage and before being about to use remain on entity separation and steady statue, then in minute timing or distribute the back to mix, provide conditioning and cleaning beneficial effect by the system of physically stable.Though compare the conditioning beneficial effect that this pair of chamber delivery system can provide improvement with using conventional system, be difficult to obtain a performance of making peace homogeneous usually, because inhomogeneous from the cleansing phase and the distribution ratio between the useful phase of these dual compartment packages.In addition, these packaging systems have increased sizable cost to finished product.

Therefore, still need a kind of like this personal cleaning compositions, said composition can provide the cleaning of being sent by a kind of product and the hair-conditioning beneficial effect of improvement.Also still need a kind ofly to comprise biphase personal cleaning compositions in the actual contact mode, described compositions can keep stable for a long time.Therefore, an object of the present invention is to provide a kind of comprise cleansing phase with useful mutually (for example, conditioning, typing, increase hair brightness, coloring hairs, hair and preserve moisture, strengthen hair health etc.) heterogeneous hair Cleasing compositions, described compositions is packed in the mode of actual contact, keep stable simultaneously, wherein said compositions provides the use neutralization of improvement to use back hair benefit effect.

Summary of the invention

The present invention relates to comprise cleansing phase and at least one useful multi phase personal care composition mutually, described useful organophilic gel network, the aliphatic compound gel network in the organophilic gel network or siloxanes or the silicone gel that is selected from mutually in aliphatic compound gel network, organophilic gel network, the aliphatic compound gel network.These products are used to provide heterogeneous Cleasing compositions, and described heterogeneous compositions is packed in the actual contact mode, keep stable simultaneously, and provide the use neutralization of improvement to use back hair and skin beneficiating effect.In the present invention, cleansing phase, useful phase or cleansing phase and useful phase both can be visually-clear.

The invention still further relates to a kind of method of using described multi phase personal care composition.

Detailed Description Of The Invention

What the present invention relates to be applicable to mammalian hair or skin comprises cleansing phase and useful multi phase personal care composition mutually.Have surprisingly been found that, can prepare and comprise cleansing phase and additional useful multi-phase fluid Cleasing compositions mutually, so that the hair benefit effect of improvement to be provided after using in the application neutralization, also provide fabulous hair-conditioning and cleaning beneficial effect simultaneously, wherein said cleansing phase and additional usefully pack and keep simultaneously stablizing in the actual contact mode.Found that above-mentioned composition can be with enough high-load beneficial agent preparations, and can not influence the foaming effect and the stability of product.Having found can be by cleansing phase and useful density matching mutually, and mixes structuring reagent (structurant) and can prepare stable enhanced multi phase personal care composition in cleansing phase.

Below narrated the solvent of described multi phase personal care composition.Also comprise the non-removing property description that can be used for the various optional and preferred ingredient in the embodiment of the present invention.Though this description with particularly point out and clearly claimed claims of the present invention as conclusion, it is believed that by following explanation and can understand the present invention better.

Except as otherwise noted, all percentage ratio, umber and ratio are all in the gross weight of the present composition.The all wt of relevant ingredients listed therefore except as otherwise noted, does not comprise the solvent or the by-product that may be included in the commercially available material all based on content of active substance.Herein, term " percentage by weight " can be expressed as " wt.% ".

Except as otherwise noted, all used among the present invention molecular weight are weight average molecular weight, represent with gram/mole.

Term used herein " charge density " relates to the ratio of positive changes and the molecular weight of described monomeric unit on the monomeric unit that constitutes polymer.Charge density multiply by polymer molecular weight and determines sites of positive charge number on the given polymer chain.

Herein, " comprise " and be meant and add other step of not influencing final result and other composition.This term comprise term " by ... form " and " basically by ... composition ".The compositions and methods of the invention/technology can comprise, by or form by basis of the present invention and restrictive condition and any additional or optional member, component, step or restrictive condition as herein described basically.

Term used herein " visually completely different " is meant that each mutually occupied zone can be identified by human eye separately when obvious separate areas contacts (that is, they are not less than about 100 microns emulsion or particle dispersion) each other.

The absorbance that term used herein " visually transparent " is meant compositions is preferably greater than 80% greater than 60%.The transparency of compositions uses ultraviolet (UV/VIS) spectrophotometry, and it is by the absorption and the transmission of sampling determination UV/VIS light.Confirm that the optical wavelength of 600nm is enough to the transparency of characterization cosmetic compositions.Typically, preferably according to the relevant detailed directions explanation of used concrete spectrophotometer.Usually, measure the process of percentage transmission from spectrophotometer is set at 600nm.Then, operation calibration " blank " calibrates to 100% absorbance with readout.Then specimen is placed to be designed to be fit to this concrete spectrophotometric cuvette, at 600nm place spectrophotometer measurement percentage transmission.

Term used herein " heterogenetic " and " heterogeneous " are meant biphase at least occupy separately and distinct real space, still directly contact (that is, they are not separated by interlayer, and they are not emulsified) each other in the packing that stores them.In a preferred embodiment of the invention, comprising biphase at least " heterogeneous " personal care composition is present in the container with distinct pattern visually.This pattern is produced by the mixing or the homogenize of " heterogeneous " compositions.These patterns include but not limited to the following example: striated, marblized, collinear, the striped that interrupts, crackle is arranged, mottled, veined, bunch shape, spotted, geometry, speckle, zonal, spiral helicine, gyrate, marshalling, raggle-taggle, veined, fluted, ridged, wavy, sinusoidal, helix, twisting, crooked, cyclic, band, slice is arranged, contour wire, heterogeneous, lacelike, interweave or weave, the basket weave shape, spotted and tessellated.Preferably, described pattern is selected from striated, geometry, marblized and their combination.In a preferred embodiment, the striated pattern can be in whole range of packages relatively all even unanimity.Alternatively, the striated pattern can be uneven, and is promptly wavy, perhaps inhomogeneous within the specific limits.The striated pattern needn't extend in the whole range of packages.These can be various different colours mutually, or comprise granule, glitter or Margarita powder.

Term used herein " water miscible " is meant in this compositions in the component water soluble.Usually, in the time of about 25 ℃, by the weight of described aqueous solvent, this component should be with about 0.1%, and is preferred about 1%, and more preferably from about 5%, even more preferably from about 15% concentration dissolving.

Except as otherwise noted, term used herein " anhydrous " relates to those and comprises by weight less than about 10%, be more preferably less than about 5%, even be more preferably less than about 3%, even the more preferably compositions or the material of 0% water.

Except as otherwise noted, term used herein " environmental condition " relates to the ambient conditions of 101kPa ((a 1) atmospheric pressure), 50% relative humidity and 25 ℃.

Except as otherwise noted, term used herein " stable " relates to when placing at least about time of 180 days under environmental condition in the actual contact mode, the visible pattern of the phase of diverse location or arrange not the compositions of significant change in time in the packing.In addition, it is meant and cream shape or precipitation do not occur separating, being." separation " is meant that visually the intact distribution of completely different phase is destroyed, makes the big zone of at least one phase produce to assemble until two or more compositionss destroyed with respect to the balance distribution ratio between mutually.

Except as otherwise noted, term used herein " personal care composition " relates to compositions of the present invention, wherein said compositions is intended to only comprise that those are locally applied to the compositions of hair or skin, does not comprise that particularly those are primarily aimed at other application (using as hard surface cleaning, fabric or medicated clothing cleaning and similar other) but not mainly are intended to be locally applied to the compositions of hair or skin.

The pH of the present composition is preferably about 2 to about 8.5, and more preferably from about 3 to about 7.5, even preferred about 3.5 to about 6.5.Described cleansing phase is preferably about 10: 1 to about 1:10 with useful ratio mutually.

Described cleansing phase shows to have high viscosity, but it is the high shear dilution.Described cleansing phase and useful viscosity mutually when stress measurement be about 1 during to about 20 Pascals at about 10Pa.s (10,000 centipoise) to about 200,000Pa.s (200,000,000 centipoise) in the scope, more preferably when stress measurement be about 1 to be about 100Pa.s (100 during to about 20 Pascals, 000) to about 100, (000Pa.s 100,000,000 centipoise).Can use Haake RS 150 RheoStress flow graphs to measure the viscosity of described phase.Measurement is carried out to about 500 Pascals' proof stress condition about 1 Pascal.The 60mm parallel-plate that uses a sheet separation to be of a size of about 0.75mm is measured.All measurements are all carried out under about 25 ℃.

Under suitable composition, cleansing phase can constitute stratiform or vesicle structure.Stratiform and vesicle structure all are considered to liquid crystal, and are birefringent.Birefringent material looks like bright between the crossed polarizer under the optical microscope.

A. cleansing phase

Multi phase personal care composition of the present invention comprises the cleansing phase that is suitable for being applied on hair or the skin.The surfactant that is applicable to this paper comprises any known or other effective cleaning surfactant that is suitable for being administered on hair or the skin, and this surfactant also need be compatible with other basis in the composition comprises water cleansing phase.These cleansing surfactants comprise anion surfactant, non-ionic surface active agent, cationic surfactant, amphion or amphoteric surfactant, or their combination.Preferred described cleansing phase is structurized and/or discrete.

The aqueous cleaning of described multi phase personal care composition mutually preferably in by the weight of described aqueous cleaning phase about 1% to about 85%, more preferably from about 3% to about 80%, even more preferably from about 5% to about 70% concentration comprises cleansing surfactants.The preferred pH scope of cleansing phase is about 3 to about 10, preferred about 5 to about 8.

Be applicable to that the anion surfactant in the cleansing phase comprises alkyl sulfate and alkyl ether sulfate.These materials have chemical formula ROSO respectively ₃M and RO (C ₂H ₄O) _xSO ₃M, wherein R is about 8 alkyl or alkenyls to about 24 carbon atoms, and x is 1 to 10, and M is water-soluble cationic such as ammonium, sodium, potassium and triethanolamine.The alkyl ether sulfate typical case can be used as oxirane and contains about 8 condensation products to the monohydric alcohol of about 24 carbon atoms and prepare.Preferably, R has about 10 to about 18 carbon atoms in alkyl sulfate and alkyl ether sulfate.This alcohol can be derived from fat, and for example Oleum Cocois or Adeps Bovis seu Bubali maybe can be synthetic.The preferred lauryl alcohol of this paper and derived from the straight chain alcohol of Oleum Cocois.Above-mentioned alcohol can with about 1 to about 10, preferred about 2 to about 5, the reacting ethylene oxide of 3 mol ratios more preferably from about, and with gained mixture (its molecular species has, for example, average 3 moles of ethylene oxide of every mol of alcohol) through sulfuric acid treatment and neutralization.

The specific embodiment that can be used for the alkyl ether sulfate in the cleansing phase is cocos nucifera oil alkyl 2,2'-ethylenedioxybis(ethanol). ether sodium sulfate salt and ammonium salt, tallow alkyl 2,2'-ethylenedioxybis(ethanol). ether sodium sulfate salt and ammonium salt, and tallow alkyl six ethylene oxide sodium sulfate salt and ammonium salts.Highly preferred alkyl ether sulfate is those of mixture that comprise individualized compound, and the mean alkyl chain length that described mixture has is about 10 to about 16 carbon atoms, and average degree of ethoxylation is about 1 to about 4 moles of ethylene oxide.

Other suitable anion surfactant comprises that general formula is [R ¹-SO ₃-M] the water soluble salt of organic sulfur acid reaction product, R wherein ¹Be selected from and have about 8 to about 24, preferred about 10 straight or branched radical of saturated aliphatic alkyl to about 18 carbon atoms; And M is a cation.Suitable embodiment is the salt of the organic sulfur acid reaction product of methane series hydrocarbon, comprise and have about 8 to about 24 carbon atoms, preferred about 10 different, new, outer (ineso-) and normal paraffin hydrocarbons and sulfonating agents to about 18 carbon atoms, for example, according to the SO of known method of sulfonating (comprise bleaching and hydrolysis) gained ₃, H ₂SO ₄And oleum.Sulfonation C preferably _10-18The alkali metal salt of normal paraffin hydrocarbons and ammonium salt.Other suitable surfactants are described in the Emulsifiersand Detergents of the McCutcheon that M.C.Publishing Co. publishes, in annual in 1989 and the United States Patent (USP) 3,929,678.

The preferred anionic surfactants surfactant that can be used in the cleansing phase comprises: ammonium lauryl sulfate; lauryl polyethenoxy ether sodium sulfate; the lauryl sulfate triethylamine; laureth sulphuric acid triethylamine; triethanolamine lauryl sulfate; laureth sulphuric acid triethanolamine; lauryl sulfate monoethanolamine; laureth sulphuric acid monoethanolamine; lauryl sulfate diethanolamine; laureth sulphuric acid diethanolamine; Glyceryl Monolaurate sodium sulfate; sodium lauryl sulfate; sodium laureth sulfate; laureth ether potassium sulfate; sodium lauryl sarcosinate; sodium lauroyl sarcosine; the sarcosine lauryl; the cocoyl sarcosine; cocoyl ammonium sulfate; lauroyl ammonium sulfate; cocoyl sodium sulfate; lauroyl sodium sulfate; the cocoyl potassium sulfate; lauryl potassium sulfate; cocoyl sulphuric acid monoethanolamine; the tridecyl benzene sulfonic acid sodium salt; dodecylbenzene sodium sulfonate, and their combination.

For example, in some embodiments, preferably has the anion surfactant of branched alkyl chain, as tridecyl polyethenoxy ether sodium sulfate (sodium trideceth sulfate).In some embodiments, can use the mixture of anion surfactant.

Can be incorporated in the cleansing phase compositions being selected from amphoteric surfactant, zwitterionic surfactant, cationic surfactant and/or the nonionic surfactants additional surfactants in not.

Be applicable to that the amphoteric surfactant in the cleansing phase comprises those that extensively are called aliphatic secondary amine and tertiary amines derived thing, wherein aliphatic group can be a straight or branched, and one of them aliphatic substituent group comprise about 8 to about 18 carbon atoms, and an aliphatic substituent group comprises the anionic water-soluble group, as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.The embodiment that belongs to the chemical compound of this definition is: the 3-sodium dodecyl aminopropionitrile; 3-dodecyl amino propane sulfonic acid sodium, sodium lauryl sarcosinate, N-alkyl taurine are (as according to United States Patent (USP) 2; 658; proposed in 072; by lauryl amine and sodium isethionate react and make those), N-senior alkyl aspartic acid is (as according to United States Patent (USP) 2; 438; those that the method that is proposed in 091 makes); and at United States Patent (USP) 2; those products described in 528,378.

Be applicable to that the zwitterionic surfactant in the cleansing phase comprises those that extensively are called aliphatic quaternary ammonium, Phosphonium and sulfonium compound derivant, but aliphatic group straight or branched wherein, and one of them aliphatic substituent group comprise about 8 to about 18 carbon atoms, and an aliphatic substituent group comprises anionic group, as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.Above-mentioned suitable zwitterionic surfactant is shown below:

R wherein ²Comprise alkyl, alkenyl or hydroxyalkyl, this hydroxyalkyl have about 8 to about 18 carbon atoms, 0 to about 10 ethylene oxides part and 0 to about 1 glyceryl; Y is selected from nitrogen, p and s atom; R ³Be to comprise about 1 alkyl or monohydroxyalkyl group to about 3 carbon atoms; When Y was sulphur atom, X was 1, and when Y was nitrogen-atoms or phosphorus atoms, X was 2; R ⁴Be to have about 1 alkylidene or hydroxyl alkylidene, and Z is the group that is selected from carboxylate radical, sulfonate radical, sulfate radical, phosphonate radical and phosphate radical to about 4 carbon atoms.

Other zwitterionic surfactants that are applicable to cleansing phase comprise the betanin that contains the senior alkyl betanin, as cocoyl dimethyl carboxymethyl betaine, cocoamidopropyl, coco betaine, lauramido propyl betaine, the oleyl betanin, the lauryl dimethyl carboxymethyl betaine, lauryl dimethyl-α-carboxyethyl betanin, cetyl dimethyl carboxymethyl betaine, lauryl is two-(2-ethoxy) carboxymethyl betaine, stearyl is two-(2-hydroxypropyl) carboxymethyl betaine, oleyl dimethyl-γ-carboxylic CAB and lauryl be two-(2-hydroxypropyl)-α-carboxyethyl betanin.The representative of sulfobetaines can be cocoyl dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betanin, lauryl two-(2-hydroxyethyl) sulfopropyl betaine or the like; Amido betaine and amino sulfobetaines (RCONH (CH wherein ₂) ₃Group links to each other with nitrogen-atoms in the betanin) also can be used for the present invention, wherein R is an alkyl.

Also can use both sexes acetate and two both sexes acetates.

The both sexes acetate

Two both sexes acetates

Both sexes acetate and two both sexes acetates meet described chemical formula (as above), and wherein R contains 8 aliphatic groups to about 18 carbon atoms of having an appointment.M is the ammonium of cation such as sodium, potassium, ammonium or replacement, and n is about 7 to about 17.In some embodiments, lauryl both sexes sodium acetate (sodiumlauroamphoacetate), cocoyl both sexes sodium acetate, lauryl both sexes acetic acid disodium and cocoyl two both sexes acetic acid disodiums are preferred.

Also can use Marlamid.Preferred alkanolamide comprises CocamideMEA (cocoyl single ethanol amide) and Cocamide MIPA (the single isopropanol amide of cocoyl).The alkanolamide of ethoxylation more preferably.In this embodiment, PPG-2 hydroxyethyl coco base/isostearoyl amine liquid surfactant is preferred.

Cationic surfactant also can be used in the cleansing phase but is more not preferred usually, and by the weight of described cleansing phase compositions, its preferred content is less than about 5%.

Be applicable to that ionic surfactant pack during aqueous cleaning mutually draws together the product of alkylidene oxide group (itself is hydrophilic) and organic hydrophobic compound condensation, this organic hydrophobic compound can reality be aliphatic compounds or Alkylaromatics.

Be not bound by theory, it is believed that in certain embodiments, compositions of the present invention can have layer structure.Compositions of the present invention has the ability (this is the known character of lamellar phase surface activator composition) of runny non newtonian shear thinning performance and suspending components.

Usually, surfactant is sold with the form of aqueous solution or other solvent solutions, these solvents are diluted to active surfactant less than 100% with them, thereby " active surfactant " is meant the actual amount that is delivered to the surfactant in the free flowing composition from commercial surfactant formulations.

Preferred cleansing phase with trade name Miracare SLB-365 available from Rhodia.This cleansing phase is the blend of tridecyl polyethenoxy ether sodium sulfate, lauryl both sexes sodium acetate and coconut oleoyl amine MEA.

All surface activating agent (for example anion surfactant, non-ionic surface active agent, both sexes and/or zwitterionic surfactant, and cationic surfactant) total amount that lumps together is typically about 8% to about 30% active surfactant, and preferred about 10% to about 20% active surfactant.In some embodiments, preferred at least a surfactant has aliphatic chain, and this aliphatic chain can have side chain or degree of unsaturation, or their combination.

B. useful phase

Multi phase personal care composition of the present invention also comprises at least one useful phase, described useful organophilic gel network, the aliphatic compound gel network in the organophilic gel network or siloxanes or the silicone gel that is selected from mutually in aliphatic compound gel network, organophilic gel network, the aliphatic compound gel network.The amount of preferred described useful phase counts about 1% to about 95%, preferred about 5% to about 90% by the weight of described compositions, and more preferably from about 10% to about 80%.Each is useful to can be used as mutually with conditioner or other benefit agent delivery delivery vector to hair, or it self can be used as conditioner or other beneficial agent.

1. aliphatic compound gel network:

Useful phase of the present invention can comprise gel network.Described gel network comprises cationic surfactant, hard fat compounds of group and aqueous carrier.

A. cationic surfactant

Described cationic surfactant can be by weight preferred about 0.1% to about 10%, more preferably from about 1% to about 8%, also more preferably from about 2% to about 5% content is included in the useful combined thing.

Cationic surfactant has formed gel network with aliphatic compound and aqueous carrier hereinafter, and this gel network is suitable for providing various beneficial effects, as flexibility and the wetness sensation on smooth feeling on the wet hair and the dried hair.According to the above-mentioned gel-type vehicle that is provided, comprise cationic surfactant and aliphatic compound with certain content, the mol ratio that makes cationic surfactant and aliphatic compound is at preferred about 1:1 to 1:10, more preferably from about in the scope of 1:2 to 1:6.

Preferred cationic surfactants is that having than long alkyl chain is those of C18-22 alkyl.Above-mentioned cationic surfactant comprises for example INCROQUAT TMC-80 ECONOL TM22 and stearyl trimethyl ammonium chloride, and INCROQUAT TMC-80 ECONOL TM22 more preferably.It is believed that with cationic surfactant and compare that having cationic surfactant than long alkyl chain can provide deposition on the hair of improvement, thereby the conditioning beneficial effect of improvement can be provided, as the flexibility of improving on the dried hair with shorter alkyl chain.It is believed that also with the cationic surfactant that contains shorter alkyl chain and compare that above-mentioned cationic surfactant can reduce zest.

The cationic surfactant that can be used for this paper is those of general molecular formula (I):

R wherein ¹⁰¹, R ¹⁰², R ¹⁰³And R ¹⁰⁴In at least one is selected from and has about 8 to the aliphatic group of about 30 carbon atoms or have aromatics, alkoxyl, polyoxyalkylene, alkyl amido, hydroxyalkyl, aryl or the alkylaryl group of about 22 carbon atoms at most, R ¹⁰¹, R ¹⁰², R ¹³And R ¹⁰⁴In all the other groups be independently selected from and have about 1 to the aliphatic group of about 22 carbon atoms or have aromatics, alkoxyl, polyoxyalkylene, alkyl amido, hydroxyalkyl, aryl or the alkylaryl group of about 22 carbon atoms at most; X ^-Be into salt anionic, as be selected from halide ion (as chloride ion, bromide ion), acetate, citrate, lactate, ethanol acid group, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl azochlorosulfonate those.Except carbon atom and hydrogen atom, aliphatic group also can comprise ehter bond and other group such as amino.Than the aliphatic group of long-chain, according to appointment 12 carbon atoms or more those, can be saturated or unsaturated.R ¹⁰¹, R ¹⁰², R ¹⁰³And R ¹⁰⁴Be independently selected from C ₁To about C ₂₂Be preferred during alkyl.The non-limiting example that can be used for cationic surfactant of the present invention comprises the material with following CTFA name: quaternary ammonium-8, quaternary ammonium-14, quaternary ammonium-18, quaternary ammonium-18 dimethyl sulfate, quaternary ammonium-24, and their mixture.

In the middle of general formula (I) cationic surfactant, preferably comprise the surfactant that at least one has the alkyl of at least 16 carbon atoms in the molecule.The non-limiting example of above-mentioned preferred cationic surfactants comprises: INCROQUAT TMC-80 ECONOL TM22, its with trade name INCROQUATTMC-80 available from Croda and with trade name ECONOL TM22 available from Sanyo Kasei; The cetyl trimethyl ammonium chloride; its for example with trade name CA-2350 available from Nikko Chemical; the hydrogenated tallow alkyl trimethyl ammonium chloride; dialkyl group (14-18) alkyl dimethyl ammonium chloride; two tallow alkyl alkyl dimethyl ammonium chlorides; dihydro tallow alkyl alkyl dimethyl ammonium chloride; VARISOFT TA100; two cetyl alkyl dimethyl ammonium chlorides; two (docosyl/eicosyl) alkyl dimethyl ammonium chloride; two (docosyl) alkyl dimethyl ammonium chloride; the stearyl dimethyl benzyl ammonium chloride, stearyl propylene glycol phosphate ester alkyl dimethyl ammonium chloride, stearyl amido propyl dimethyl benzyl ammonium chloride; stearyl amido propyl dimethyl (acetic acid myristyl ester) ammonium chloride, and N-(stearyl gallbladder carbamyl ylmethyl) pyridinium chloride.

As the cationic surfactant cationic surfactant of hydrophilic replacement further preferably, wherein at least one substituent group contains one or more aromatic series, ether, ester, amide or amino part, described group is as substituent group or as the connecting key in the group chain, wherein R ¹⁰¹To R ¹⁰⁴In the group at least one contains one or more hydrophilic segments, and described hydrophilic segment is selected from alkoxyl (preferred C ₁To C ₃Alkoxyl), polyoxyalkylene (preferred C ₁To C ₃Polyoxyalkylene), alkyl amido, hydroxyalkyl, Arrcostab and their combination.Preferably, the cationic surfactant of this hydrophilic replacement comprises about 2 to about 10 nonionic hydrophilic segments that are positioned at above-mentioned scope.Preferred hydrophilic replacement cationic surfactant comprises those of following chemical formula (II) to (VIII):

Chemical formula (II)

N wherein ¹For about 8 to about 28, m ¹+ m ²For about 2 to about 40, Z ¹Be short-chain alkyl, preferred C ₁-C ₃Alkyl, more preferably methyl or (CH ₂CH ₂O) _M3H, wherein m ¹+ m ²+ m ³For about 10 to about 60, and X ^-For becoming salt anionic as defined above;

Chemical formula (III)

N wherein ²For about 1 to about 5, R ¹⁰⁵, R ¹⁰⁶And R ¹⁰⁷In one or more be C independently ₁-C ₃₀Alkyl, remaining is CH ₂CH ₂OH, R ¹⁰⁸, R ¹⁰⁹And R ¹¹⁰In one or two be C independently ₁-C ₃₀) alkyl, remaining is CH ₂CH ₂OH, and X ^-For becoming salt anionic as defined above;

Chemical formula (IV)

The chemistry formula V

Wherein independently and (V), Z for chemical formula (IV) ²Be alkyl, be preferably C ₁-C ₃Alkyl, more preferably methyl; Z ³Be short chain hydroxyalkyl (C ₁-C ₃), preferred methylol or ethoxy; n ³And n ⁴Be about 2 to about 4 integer (comprising 2 and 4) independently, be preferably for about 2 to about 3 (comprising 2 and 3), more preferably 2; R ¹¹¹And R ¹¹²For that replace or unsubstituted alkyl, be preferably C independently ₁₂To C ₂₀Alkyl or alkenyl; And X ^-For becoming salt anionic as defined above;

Chemical formula (VI)

R wherein ¹¹³Be alkyl, preferred C ₁-C ₃Alkyl, more preferably methyl, Z ⁴And Z ⁵Be short-chain hydrocarbon group independently, preferred C ₂-C ₄Alkyl or alkenyl, more preferably ethyl, m ⁴For about 2 to about 40, preferred about 7 to about 30, and X ^-For becoming salt anionic as defined above;

Chemical formula (VII)

R wherein ¹¹⁴And R ¹¹⁵Be C independently ₁-C ₃Alkyl, preferable methyl, Z ⁶Be C ₁₂-C ₂₂Alkyl, alkyl carboxyl or alkyl amido, A are protein, preferred collagen protein, keratin, lactoprotein, fibroin, soybean protein, wheat protein or their hydrolysed form; And X ^-For becoming salt anionic as defined above;

Chemical formula (VIII)

N wherein ⁵Be 2 or 3, R ¹¹⁶And R ¹¹⁷Be C independently ₁-C ₃Alkyl, preferable methyl, and X ^-For becoming salt anionic as defined above.The non-limiting example that can be used for the cationic surfactant of hydrophilic replacement of the present invention comprises the material with following CTFA title: quaternary ammonium-16, quaternary ammonium-26, quaternary ammonium-27, quaternary ammonium-30, quaternary ammonium-33, quaternary ammonium-43, quaternary ammonium-52, quaternary ammonium-53, quaternary ammonium-56, quaternary ammonium-60, quaternary ammonium-61, quaternary ammonium-62, quaternary ammonium-70, quaternary ammonium-71, quaternary ammonium-72, quaternary ammonium-75, the collagen protein of quaternary ammonium-76 hydrolysis, quaternary ammonium-77, quaternary ammonium-78, the collagen protein of quaternary ammonium-79 hydrolysis, the keratin of quaternary ammonium-79 hydrolysis, the lactoprotein of quaternary ammonium-79 hydrolysis, the fibroin of quaternary ammonium-79 hydrolysis, the wheat protein of the soybean protein of quaternary ammonium-79 hydrolysis and quaternary ammonium-79 hydrolysis, quaternary ammonium-80, quaternary ammonium-81, quaternary ammonium-82, quaternary ammonium-83, quaternary ammonium-84, and their mixture.

Highly preferred hydrophilic replacement cationic surfactant comprises dialkyl group acylamino-ethyl-hydroxyethyl monomethyl ammonium salt, dialkyl group acylamino-ethyl dimethyl ammonium, two alkanoyl ethyl-hydroxyethyl monomethyl ammonium salts, two alkanoyl ethyl dimethyl ammoniums, and their mixture; For example commercially available with following trade name: VARISOFT 110, VARISOFT 222, VARIQUAT K1215 and VARIQUAT638, available from Witco Chemical; MACKPRO KLP, MACKPRO WLW, MACKPROMLP, MACKPRO NSP, MACKPRO NLW, MACKPRO WWP, MACKPRONLP, MACKPRO SLP are available from McIntyre; ETHOQUAD 18/25, ETHOQUADO/12PG, ETHOQUAD C/25, ETHOQUAD S/25 and ETHODUOQUAD are available from Akzo; DEHYQUAT SP is available from Henkel and ATLAS G265, available from ICIAmericas.

The primary, the salt of the second month in a season and uncle's fatty amine also is suitable cationic surfactants.The alkyl of these amine preferably has about 12 to about 22 carbon atoms, and can be that replace or unsubstituted.Useful especially is uncle's fatty amine that acylamino-replaces.This amine that can be used for this paper comprises the amino propyl group dimethylamine of stearoyl, the amino propyl group diethylamide of stearoyl, the amino ethyl diethylamide of stearoyl, the amino ethyl dimethyl amine of stearoyl, palmityl aminopropyl dimethyl amine, palmityl aminopropyl diethylamide, palmityl amino-ethyl diethylamide, palmityl amino-ethyl dimethyl amine, docosane acylamino-propyl-dimethyl amine, docosane acylamino-propyl group diethylamide, docosane acylamino-ethyl diethylamide, docosane acylamino-ethyl dimethyl amine, eicosane acylamino-propyl-dimethyl amine, eicosane acylamino-propyl group diethylamide, eicosane acylamino-ethyl diethylamide, eicosane acylamino-ethyl dimethyl amine, diethylamino ethyl stearmide.Stearic amine, dihydroxy ethyl stearic amine and the eicosyl docosyl amine that dimethyl stearic amine, dimethyl Semen sojae atricolor amine, Semen sojae atricolor amine, tetradecylamine, tridecyl amine, ethyl stearic amine, N-Adeps Bovis seu Bubali propane diamine, ethoxylation (having 5 moles of ethylene oxide) are arranged of Shi Yonging also.These amine usually and acid unite use so that cationic substance to be provided.The preferred acid that can be used for this paper comprises L-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, L-glutamic acid hydrochloride, L-aspartic acid, and their mixture; More preferably L-glutamic acid, lactic acid and citric acid.Be included in and can be used for the cationic amine surfactant in those of the present invention and be disclosed in United States Patent (USP) 4,275, in 055.

Amine that can be protonated with from the H of acid ⁺Mol ratio be preferably about 1:0.3 to 1:1.2, and more preferably from about 1:0.4 to about 1:1.1.

B. aliphatic compound

The aliphatic compound gel network comprises aliphatic compound mutually, its in by the weight of described aliphatic compound gel network about 0.01% to about 20%, preferred about 0.1% to about 15%, more preferably from about 0.2% to about 10% amount exists.Gel-type vehicle can be formed by aliphatic compound, and/or when forming gel-type vehicle, the cationic surfactant chemical compound can at first mix, be suspended in the water and/or be dissolved in the water with water.

The fusing point that can be used for the aliphatic compound of this paper is 25 ℃ or higher, and is selected from aliphatic alcohol, fatty acid and their mixture.Be appreciated that disclosed chemical compound can belong to more than a kind of classification in some cases in this part of this description, for example some fatty alcohol derivative also can classify as derivative of fatty acid.Yet specified classification is not intended to limit this concrete chemical compound, but for the ease of classification and name.In addition, be appreciated that to have the fusing point that required certain some chemical compound of carbon number purpose may have and be lower than 25 ℃ according to the number of two keys and the length and the position of position and side chain.This low-melting compound will be not included in this part.The non-limiting example of high melting compound is found in " Intemational Cosmetic Ingredient Dictionary ", the 5th edition, 1993; " CTFA Cosmetic Ingredient Handbook ", second edition, 1992.

The aliphatic alcohol that can be used for this paper is to have about 14 to about 30 carbon atoms, and preferred about 16 to those of about 22 carbon atoms.These aliphatic alcohol are saturated, and can be straight chain alcohol or branched-chain alcoho.The non-limiting example of aliphatic alcohol comprises spermol, stearyl alcohol, docosanol and their mixture.

The fatty acid that can be used for this paper is to have about 10 to about 30 carbon atoms, preferably has about 12 to about 25 carbon atoms, more preferably has about 16 to those of about 22 carbon atoms.These fatty acids are saturated, and can be straight-chain acid or branched acids.Also comprise the binary acid, ternary acid and other polyprotic acid that satisfy this paper requirement.This paper also comprises the salt of these fatty acids.The non-limiting example of fatty acid comprises lauric acid, Palmic acid, stearic acid, behenic acid, decanedioic acid and their mixture.

The aliphatic compound of high-purity unification compound is preferred.The unification compound that is selected from the pure fat alcohol of pure spermol, stearyl alcohol and docosanol is preferred." pure " herein is meant that the purity of chemical compound is at least about 90%, preferably at least about 95%.When consumer rinsed described compositions, these highly purified unification compounds can provide rinsability good on the hair.

2. organophilic gel network

Another embodiment of the invention can comprise the organophilic gel network.Anhydrous gel is based on multiple hydrocarbon and ester.Gellant is the combination of ethylene/propene/styrol copolymer and butylene/ethylene/styrene copolymer.Various agglomerative hydrocarbon solvents can be used for conditioning ingredients is delivered on the hair surface.Hydrocarbon solvent can be volatile or nonvolatile.The organophilic gel network can comprise the hydrophobic solvent with polymeric gellant thickening.Suitable hydrocarbon gel can trade name Versagel available from Penereco Corporation.

Embodiment based on the gel of non-volatile solvents is the Versagel material, comprises VersagelM (based on mineral oil), Versagel ME (based on Parleam), Versagel MP (based on isopropyl palmitate), Versagel MC (based on 2-Methylpentadecane).An embodiment of volatile hydrocarbon gel is Versagel MD (based on a Fancol ID).

3. the combination of aliphatic compound gel network and organophilic gel network:

Another embodiment of the invention can comprise aliphatic compound gel network in the organophilic gel network or the organophilic gel network in the aliphatic compound gel network.As mentioned above, the suitable embodiment of this phase is the aliphatic alcohol that comprises hair-conditioning ingredients, and it is dispersed in the organophilic gel network.The organophilic gel network also can comprise hair-conditioning ingredients.The scope of aliphatic compound gel network and the ratio of hydrocarbon gel network is preferably about 95:5 to about 5:95, and more preferably from about 90:10 is to about 10:90, even 80:20 about 20:80 extremely more preferably from about.

4. siloxanes or silicone gel

Another embodiment of the invention can comprise siloxanes or silicone gel.Be described the siloxanes that is used for water-in-oil emulsion be applicable to useful mutually in, as long as they satisfy the viscosity requirement.Because high-molecular weight siloxanes and silicone gum have inherent opsonic action to hair, so can use.The embodiment of high molecular polydimethylsiloxane is Dow Corning 200 fluids (0.06,0.3 and 0.6m ²/ s (60000,300000 and 600000 centistoke)).Low-molecular-weight siloxane can be gelation, adds in the high molecular weight silicone, or both combinations.Suitable siloxanes gelling agent embodiment is a silicone elastomer, as Dow Corning 9040.Siloxanes can be volatile or nonvolatile, and simultaneously preferred siloxanes depends on required beneficial effect.

C. stability enhancer

1. layer structure reagent and polymer architecture reagent

Compositions of the present invention preferably comprises about by weight 0.1% to about 10% structuring reagent in cleansing phase, it works in compositions to form lamellar phase.It is believed that this lamellar phase can strengthen the interface stability between cleansing phase and the useful phase.

Suitable structuring reagent comprises fatty acid or its ester derivant, aliphatic alcohol or three (hydroxy stearic acid) glyceride, and polycare 133.Described structuring reagent is lauric acid or three (hydroxy stearic acid) glyceride more preferably.

In a preferred embodiment of the invention, the surface activator composition that is used for cleansing phase shows to have non newtonian shear thinning behavior (this paper is called free flowing composition).These Cleasing compositions comprise water, at least a anion surfactant, electrolyte and at least a alkanolamide.It is found that, show cleansing phase, can improve the stability of gained personal cleaning compositions with the behavior of non newtonian shear thinning by using.

If present, described alkanolamide has formula:

Wherein R is C ₈To C ₂₄Or preferred in some embodiments C _{8 to}C ₂₂Or C in other embodiments _{8 to}C ₁₈Saturated or undersaturated straight or branched aliphatic group, R ₁And R ₂Be identical or different C ₂-C ₄The straight or branched aliphatic group, x=0 to 10; Y=1 to 10, and wherein the summation of x and y is less than or equal to 10.

In the time of in being present in described compositions, the amount of alkanolamide about 0.1% to about 10%, is preferably about by weight 2% to about 5% for by weight in some embodiments.Some preferred alkanolamides comprise Cocamide MEA (cocoyl single ethanol amide) and Cocamide MIPA (the single isopropanol amide of cocoyl).Can randomly mix the cosurfactant that is selected from non-ionic surface active agent, both sexes and/or zwitterionic surfactant or cationic surfactant classification.

In addition, surfactant can comprise polymer and inorganic structure reagent mutually.Anion and nonionic structure reagent are preferred.What can be used for this paper is the crosslinked acrylic acid polymer of polyvinyl such as CTFA carbomer by name, cellulose derivative and modified cellulose polymer such as methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, hydroxypropyl emthylcellulose, NC Nitroncellulose, cellulose sodium sulfate, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, polyvinylpyrrolidone, polyvinyl alcohol, guar gum, karaya, starch-based polymer (Oryza sativa L., corn, Rhizoma Solani tuber osi, Semen Tritici aestivi), carrageenin, pectin, agar, WENBO seeds of trees (Fructus cydoniae oblongae), alginate jelly (algae extract), microbial polymer such as glucosan, succinoglucan, Pullulan, polymer such as carboxymethyl starch based on starch, the methyl hydroxypropyl starch, polymer such as sodium alginate based on alginic acid, the alginic acid propylene glycol ester, acrylate polymer such as sodium polyacrylate, polymethacrylates, polyacrylamide, polymine and inorganic water-soluble substances such as speckle take off bentonite, Magnesiumaluminumsilicate, LAPONITE, Strese Hofmann's hectorite. and anhydrous silicic acid.

The commercially available viscosity modifier that highly can be used for this paper comprises carbomer, commodity are called Carbopol934, Carbopol 940, Carbopol 950, Carbopol 980 and Carbopol 981, it is all available from B.F.Goodrich Company, acrylate/stearyl polyethenoxy ether metacrylic acid ester copolymer, commodity are called Aculyn (especially Aculyn 46) available from Rohm and Hass, oxygen base in the ninth of the ten Heavenly Stems (nonoxynyl) hydroxyethyl-cellulose, commodity are called AMERCELL POLYMER HM-1500, available from Amerchol, methylcellulose, commodity are called BENECEL, hydroxyethyl-cellulose, and commodity are called NATROSOL, hydroxypropyl cellulose, commodity are called KLUCEL, the cetyl hydroxyethyl-cellulose, and commodity are called POLYSURF 67, all provide by Hercules, oxirane and/or based on the polymer of expoxy propane, commodity are called CARBOWAX PEGs, POLYOX WASRs and UCON FLUIDS are all provided by Amerchol.

Other optional structuring reagent comprises crystallizing agent, and it can be classified as acyl derivative, long-chain amine oxide and their mixture.These structuring reagent are described in United States Patent (USP) 4,741, in 855.These preferred construction reagent comprise preferably having about 16 ethylene glycol fatty acids to about 22 carbon atoms.Other long acyl derivant comprises the long-chain ester (for example stearic acid stearyl, cetin etc.) of long-chain fatty acid; The long-chain ester of long chain alkanol amide (for example stearoyl diethanolamine distearate, stearoyl monoethanolamine stearate); And glyceride (for example glycerol distearate, trihydroxy stearin, three mountain Yu essences (tribehenin)), its a commercially available embodiment is Thixin R, available from Rheox, and Inc..Except the preferred substance of listing above, long acyl derivant, long-chain carboxylic acid's glycol ester, long-chain amine oxide and long-chain carboxylic acid's alkanolamide also can be used as structuring reagent.

Be suitable for other long acyl derivant of making structuring reagent and comprise N, N-dialkyl acylamino-benzoic acid and water soluble salt thereof (for example Na, K), the especially N of this class, N-two (hydrogenation) C ₁₆, C ₁₈With Adeps Bovis seu Bubali acylamino-benzoic acids, it can be available from Stepan Company.

The embodiment that is suitable for the long-chain amine oxide of making structuring reagent comprises alkyl (C ₁₆-C ₂₂) dimethyl amine oxide, for example stearyl dimethyl amine oxide.Other suitable structuring reagent comprises the primary amine that has at least about the fatty alkyl part of 16 carbon atoms, embodiment comprises palmitamide or 18-amine., with have two secondary amine that have respectively at least about the fatty alkyl of 12 carbon atoms part, embodiment comprises two palmityl amines or two (h-tallow base) amine.Other suitable structuring reagent also comprises two (h-tallow base) phthalic amides and crosslinked maleic anhydride-methyl ethylene ether copolymer.

Electrolyte (if you are using) itself can be joined in the described compositions, maybe can form electrolyte on the spot by the counter ion counterionsl gegenions that are included in a kind of raw material.Electrolyte preferably includes anion (comprising phosphate radical, chloride ion, sulfate radical or citrate) and cation (comprising sodium ion, ammonium ion, potassium ion, magnesium ion or their mixture).Some preferred electrolyte are sodium chloride or ammonium chloride or sodium sulfate or ammonium sulfate.

Electrolyte should exist with the content that helps forming free flowing composition.Usually, this amount for by weight about 0.1% to about 15%, preferably by the weight of described cleansing phase about 1% to about 6%, but if necessary, can change.

2. density adjuster

In order further to improve stability down in stress state (as high temperature and vibration), preferably regulate the density of each phase, they are equal to substantially.This is called as density matching.In order to realize density matching, low density microspheres can be joined composition density bigger mutually in.The low density microspheres that is used for reducing the cleansing phase total body density is a granule, and its density is lower than about 0.7g/cm ³, preferably be lower than about 0.2g/cm ³, more preferably less than about 0.1g/cm ³, even more preferably less than about 0.05g/cm ³Described low density microspheres general diameter to about 100 μ m, even is more preferably less than about 40 μ m less than about 200 μ m.Preferably, the density contrast between cleansing phase and the useful phase is less than about 0.30g/cm ³, preferably less than about 0.15g/cm ³, more preferably density contrast is less than about 0.10g/cm ³, even more preferably density contrast less than about 0.05g/cm ³, and even more preferably density less than about 0.01g/cm ³

Microsphere uses compatiblely on skin by any, and promptly non-irritating and avirulent suitable inorganic or organic material are made.

The microsphere of being made by thermoplastic sent out is known, and can be according to for example patent and patent application EP-56219, EP-348372, EP-486080, EP-320473, EP-112807 and United States Patent (USP) 3,615, and the method described in 972 obtains.

Can send out the inner chamber air inclusion of hollow microspheres, this gas can be hydrocarbon, as iso-butane or isopentane, or alternatively is air.In spendable hollow microspheres, should mention with trade mark especially

(thermoplasticity can be sent out microsphere) is commercially available in those of Akzo Nobel Company, especially those of DE (dry state) or WE (hydrated state) level.Embodiment comprises:

091 DE 40d30,

091 DE, 80 d30,

051 DE, 40 d60,

091 WE40 d24,

053 DE, 40 d20.

Representative microsphere derived from inorganic substances comprises, for example "

Hollow microspheres " and " EXTENDOSPHERES ^TMThe pottery hollow sphere ", both are all available from PQ Corporation.Embodiment is:

300,

6019,

6042S.

Improve in mutually the stability of vibration as low density microspheres being joined density of the present invention, high density material can be joined density less mutually in increasing its density, and density has same influence to stability.

The density of every phase is measured with gravimeter.Density is that unit calculates with g/cc.When coupling during density, biphase density needn't be different substantially, and should be preferably in+/-15% scope, more preferably in+/-10% scope, even more preferably in+/-5% scope.

D. aqueous carrier

Compositions of the present invention can comprise aqueous carrier.They preferably comprise about by weight 50% to about 99.8% water.Water can randomly comprise other liquid, can with water miscible or water miscible solvent such as lower alkyl alcohol, for example C ₁-C ₅Alkyl monocarbon alcohol, preferred C ₂-C ₃Alkylol.Yet liquid aliphatic alcohol must be miscible in the aqueous phase that contains of compositions.Described aliphatic alcohol is can be natural miscible in containing aqueous phase, or by using cosolvent or surfactant to make it have compatibility.

E. annexing ingredient

This paper compositions can comprise multiple be suitable for making said composition beauty treatment or aesthetic easilier be accepted or provide the annexing ingredient of extra use beneficial effect to them.Supplementary element can be present in cleansing phase or useful mutually in.

1. wetting agent and solute

Suitable beneficial agent is one or more wetting agents and solute.Can use multiple wetting agent and solute, and the amount that can exist is by the weight of nonvolatile organic compound about 0.1% to about 50%, preferred about 0.5% to about 35%, and more preferably from about 2% to about 20%, and the dissolubility of described nonvolatile organic compound is in 10 parts of water at least 5 parts.Preferred water soluble organic substance is selected from the polyhydric alcohol with following structure:

R1-O(CH ₂-CR2O) _nH

Wherein R1=H, C1-C4 alkyl; R2=H, CH ₃, and n=1 to 200; Derivant (as oxyalkylated glucose), pantothenylol (comprising D-, L-and D, the L-configuration), 2-pyrrolidone-5-carboxylic acid, hyaluronic acid, lactamide monoethanolamine, acetamide monoethanolamine, the carbamide of C2-C10 alkanediol, guanidine, glycolic and glycollate (as ammonium salt and tetraalkylammonium salt), lactic acid and lactate (as ammonium salt and tetraalkylammonium salt), polyhydroxy-alcohol (as sorbitol, glycerol, hexanetriol, propylene glycol, hexanediol etc.), Polyethylene Glycol, sugar and starch, sugar and starch and to have general formula be (HOCH ₂CH ₂) _xNH _yEthanolamine (x=1-3 wherein; Y=0-2, and x+y=3) and composition thereof.Preferred polyhydric alcohols is selected from glycerol, polyoxypropylene (1) glycerol and polyoxypropylene (3) glycerol, sorbitol, butanediol, propylene glycol, sucrose, carbamide and triethanolamine.

2. water-soluble nonionic polymer

Compositions of the present invention can comprise about by weight 0.1% to about 10%, and more preferably from about 0.2% to about 5%, and even 0.5% to about 3% water-soluble nonionic polymer more preferably from about.

Polymer of the present invention is characterised in that following general formula:

Wherein R is selected from H, methyl and their mixture.When R was H, these materials were polymers of ethylene oxide, were also referred to as poly(ethylene oxide), polyoxyethylene and Polyethylene Glycol.When R was methyl, these materials were the polymer of expoxy propane, were also referred to as poly(propylene oxide), polyoxypropylene and polypropylene glycol.When R is methyl, will also be understood that all places isomer that can have resulting polymers.In said structure, the meansigma methods of n is about 2,000 to about 14,000, preferred about 5,000 to about 9,000, more preferably from about 6,000 to about 8,000.

The polyethylene glycol polymer that can be used for this paper is PEG-2M especially preferably, and wherein R is H, and the meansigma methods of n is that about 2,000 (PEG 2-M is also referred to as Polyox N-10 available from UnionCarbide, is also referred to as PEG-2,000); PEG-5M, wherein R is H, the meansigma methods of n is that about 5,000 (PEG 5-M is also referred to as Polyox N-35 and Polyox N-80 all available from Union Carbide, is also referred to as PEG-5,000 and Polyethylene Glycol 300,000); PEG-7M, wherein R is H, the meansigma methods of n is that about 7,000 (PEG7-M is also referred to as Polyox N-750 is available from Union Carbide); PEG-9M, wherein R is H, the meansigma methods of n is that about 9,000 (PEG 9-M is also referred to as Polyox N-3333 is available from UnionCarbide); PEG-14M, wherein R is H, the meansigma methods of n is that about 14,000 (PEG 14-M is also referred to as Polyox N-3000 is available from Union Carbide).Other useful polymer comprises polypropylene glycol and blended polyethylene/polypropylene glycol.

3. styling polymer

Compositions of the present invention can comprise styling polymer.This paper compositions comprises by described composition weight meter about 0.1% usually to about 15%, preferred 0.5% to about 8%, more preferably from about 1% to about 8% styling polymer.As long as its effective dose is used to compositions to provide bonding or film forming character and said composition can and be used for its set purpose effectively by preparation, then do not get rid of the polymer that uses higher or lower content.

These styling polymers are by providing polymer deposition to provide the Hairsetting performance for the present composition on hair after using.As is known to the person skilled in the art, the polymer that is deposited on the hair has viscosity and cohesive strength and mainly implements typing by form bonding after the drying between hair fiber.

Many this polymer are known in the art, comprise water solublity and water-insoluble organic polymer and water-insoluble silicone grafted polymers, all these is applicable to the present composition, and precondition is that they also have hereinafter described indispensable feature or characteristic.This polymer can by routine well known in the art or other known polymerization technique prepare, one of embodiment comprises radical polymerization.

The weight average molecular weight of styling polymer should be at least about 20,000, be preferably greater than about 25,000, more preferably greater than about 30,000, most preferably greater than about 35,000.Except for actual cause, limit outside the practicality of the present invention as processing, aesthetic features, preparation performance etc., molecular weight does not have the upper limit.Usually, described weight average molecular weight will be less than about 10,000,000, and more generally less than about 5,000,000, the typical case is less than about 2,000,000.Weight average molecular weight is preferably between about 20,000 and about 2,000, between 000, more preferably between about 30,000 and about 1,000, between 000, most preferably between about 40,000 and about 500,000.

The silicone grafted polymers that is fit to also is disclosed in people such as Hayama as european patent application 0

The european patent application 90307528.1 that 408311A2 announced on January 11st, 1991, be published in the people's such as Suzuki on October 29th, 1991 United States Patent (USP) 5,061,481, be published in the people's such as Bolich on April 21st, 1992 United States Patent (USP) 5,106,609, be published in the people's such as Bolich on March 31st, 1992 United States Patent (USP) 5,100,658, be published in the people's such as Ansher-Jackson on March 31st, 1992 United States Patent (USP) 5,100,657, be published in the people's such as Bolich on April 14th, 1992 United States Patent (USP) 5,104,646, be filed in the people's such as Bolich on August 27th, 1991 United States serial 07/758,319 and be filed in the people's such as Torgerson on August 27th, 1991 United States serial 07/758,320.

Suitable cationic polymers comprises polyquaternary ammonium salt-4 (Celquat H-100; L200-supplier National Starch); Polyquaternary ammonium salt-10 (Celquat SC-240C; SC-230 M-supplier National Starch); (UCARE series of polymers-JR-125, JR-400, LR-400, LR-30M, LK, supplier Amerchol); (Gafquat 734 for polyquaternary ammonium salt-11; 755N-supplier ISP); Polyquaternary ammonium salt-16 (Luviquat FC 370; FC550; FC905; HM-552 supplier BASF); PVP/ dimethylamino methyl ethyl acrylate (copolymer 845; 937; 958-ISP supplier); Caprolactam/PVP/ dimethylamino methyl ethyl acrylate copolymer (Gaffix VC-713; H2OLD EP-1-supplier ISP); Chitosan (Kytamer L; Kytamer PC-supplier Amerchol); Polyquaternary ammonium salt-7 (Merquat 550-supplier Calgon); Polyquaternary ammonium salt-18 (Mirapol AZ-1 is provided by Rhone-Poulenc); Polyquaternary ammonium salt-24 (Quatrisoft polymer LM-200-supplier Amerchol); Polyquaternary ammonium salt-28 (Gafquat HS-100-supplier ISP); Polyquaternary ammonium salt-46 (Luviquat Hold-supplier BASF); With chitosan ethyl glycolate (HydagenCMF; CMFP-supplier Henkel); Hydroxyethyl cetyl di-basic ammonium phosphate (Luviquat MonoCP-supplier BASF); With melon ear hydroxypropyl chlorination three ammoniums (Jaguar C series-13S ,-14S ,-17,162 ,-2000, Hi-CARE 1000-supplier

-Poulenc).

Suitable amphiphilic polymers comprises 1-Octyl acrylate/acrylate/butyl amino-ethyl methacrylate copolymer (Amphomer 28-4910; Amphomer LV-7128-4971; Lovocryl-4728-4947-National Starch provides); with methacryl ethyl betanin/methacrylate copolymer (Diaformer series, supplier Mitsubishi).

Part also is available for zwitterionic polymer.They have positive charge but comprise the acidic-group that only is negative charge in alkaline pH in very wide pH scope.Polymer is positive charge under low pH and is neutral (having negative charge and positive charge concurrently) under higher pH.Amphoteric ion polymer can be selected from cellulose derivative, Semen Tritici aestivi derivant and chitin derivatives as known in the art.The non-limiting example that can be used for the amphoteric ion polymer of this paper comprises polyquaternary ammonium salt-47 (Merquat2001-supplier Calgon (acrylic acid, the amphoteric ion copolymer of methacryl amido propyl trimethyl ammonium chloride and acrylic acid methyl ester .)); Carboxybutyl chitosan (Chitolam NB/10l-is sold by Pilot Chemical Company, is made by Lamberti); With dicarboxyl ethyl chitosan (N-[(3 '-hydroxyl-2 ', 3 '-dicarboxyl) ethyl]-β-D-(1,4)-glucamine) (available from Amerchol, as CHITOLAM NB/101).

Useful non-ionic polymers comprises PVP or polyvinylpyrrolidone (PVP K-15, K-30, K-60, K-90, K-120-supplier ISP) (Luviskol K series 12,17,30,60,80 ， ﹠amp; 90-supplier BASF); PVP/VA (PVP/VA series S-630; 735,635,535,335,235-supplier ISP) (Luviskol VA) PVP/DMAPA acrylate copolymer (Styleze CC-10-supplier ISP); PVP/VA/ vinyl propionate ester copolymer (Luviskol VAP 343 E, VAP 343 I, VAP343 PM-supplier BASF); Hydroxyethyl-cellulose (Cellosize HEC-supplier Amerchol); With hydroxypropyl melon ear resin (Jaguar HP series-8 ,-60 ,-105 ,-120-supplier

-Poulenc).

Natural, the half-natural and synthetic styling polymer of many kinds can be used for this paper, referring to encyclopedia of polymers and thickeners, Cosmetic ﹠amp; Toiletries, the 117th volume, the 12nd phase, in December, 2002, suitable styling polymer in the 67-120 page or leaf.

4. the pure and mild fatty acid of liquid aliphatic

The liquid aliphatic alcohol that can be used for this paper comprise have about 10 to about 30 carbon atoms, preferred 12 to about 25 carbon atoms, more preferably from about 16 to those of about 22 carbon atoms.These liquid aliphatic alcohol can be straight or branched alcohol, and can be saturated or unsaturated alcohols.Solid fatty compound is to be solid those aliphatic alcohol when being in basic pure state for 25 ℃ when it, and liquid aliphatic alcohol is to be those aliphatic alcohol of liquid at 25 ℃.The limiting examples of these chemical compounds comprises oleyl alcohol, Palmitoleyl alcohol, isooctadecanol, different spermol and their mixture.Though poly-aliphatic alcohol can be used for this paper, single aliphatic alcohol is preferred.

The fatty acid that can be used for this paper comprise have about 10 to about 30 carbon atoms, preferred about 12 to about 25 carbon atoms, more preferably from about 16 to those of about 22 carbon atoms.These fatty acids can be straight or branched acid, and can be saturated or undersaturated.Suitable fatty acids comprises for example oleic acid, linoleic acid, isostearic acid, linolenic acid, ethyl linolenic acid, arachidonic acid, castor oil acid and their mixture.

Derivative of fatty acid and fatty alcohol derivative define in this article to comprise for example ester, oxyalkylated aliphatic alcohol and their mixture of fatty acid.The non-limiting example of derivative of fatty acid and fatty alcohol derivative comprises, for example, methyl linoleate, Ethyl linoleate, the linoleic acid isopropyl ester, Ceraphyl 140A, acid isopropyl, ethyl oleate, oleic acid octyl group dodecyl ester, Cetiol, decyl oleate, butyl oleate, methyl oleate, stearic acid octyl group dodecyl ester, isostearic acid octyl group dodecyl ester, different Palmic acid octyl group dodecyl ester, different octyl pelargonate, octyl pelargonate, isostearic acid is ester, the isostearic acid isopropyl ester, different isodecyl pelargonate, the isostearic acid isopropyl ester, the isostearic acid ethyl ester, isostearic acid methyl ester and oil base polyoxyethylene ether-2.

Pure and mild its derivant of commercially available liquid aliphatic that can be used for this paper comprises oleyl alcohol, commodity are called UNJECOL 90BHR, available from Shin-nihon Rika, various liquid ester, commodity are called SCHERCEMOL series, available from Scher, isostearic acid is ester, commodity HIS by name and isostearic acid isopropyl ester, commodity are called ZPIS, available from Kokyu Alcohol.

5. cationic polymer conditioner

The present composition also can comprise one or more cationic polymer conditioners.The cationic polymer conditioner is preferably water miscible.The scope of application of cationic polymer is typically identical with above-mentioned disclosed cationic surfactant.

Term " water solublity " cationic polymer is meant in the time of 25 ℃ fully soluble in water, forms concentration in the water (distilled water or equivalent) and is 0.1% naked eyes and look and be the polymer of settled solution substantially.It is 0.5% basic settled solution that preferred polymers will fully be dissolved to form concentration, and more preferably concentration is 1.0%.

The cationic polymer of this paper has at least about 5,000 usually, the typical case is at least about 10,000, and less than about 1,000 ten thousand weight average molecular weight.Preferred molecular weight is about 100,000 to about 200 ten thousand.Cationic polymer has usually-and the cationic nitrogenous part is as quaternary ammonium or cation amino part, and their mixture.

Cationic charge density is preferably the gram at least about 0.1meq/, more preferably at least about the 0.5meq/ gram, even more preferably at least about the 1.1meq/ gram, even more preferably restrain at least about 1.2meq/.The mean molecule quantity of this suitable cation polymer is usually between about 10,000 and about 1,000 ten thousand, preferably between about 50,000 and about 500 ten thousand, more preferably between about 100,000 and about 300 ten thousand.Person of skill in the art will appreciate that the charge density that comprises amino polymer can be dependent on pH and amino isoelectric point, IP and changes.Charge density should be in the above-mentioned pH limited field that will use.

Any anionic counter-ion can be used for this cationic polymer, as long as it can satisfy the water solubility standard.Suitable counter ion counterionsl gegenions comprise halide ion (for example Cl, Br, I or F, preferably Cl, Br or I), sulfate radical and methyl ester sulfate radical.Because this tabulation is not unique, therefore can also use other counter ion counterionsl gegenions.

Cationic nitrogenous part is present on the part of total monomer units of cation hair-conditioning polymer with the substituent group form usually.Therefore, cationic polymer can comprise the copolymer, terpolymer of quaternary ammonium or cationic amine substituted monomer unit and other non-cationic unit (being referred to herein as the spacer monomers unit) etc.These polymer are known in the art, and at CTFA Cosmetic IngredientDictionary, the 3rd edition, Estrin, Crosley and Haynes compile, (The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C., can find its multiple variant 1982).

Suitable cationic polymers comprises, for example, have the vinyl monomer of cationic amine or quaternary ammonium functional group and the copolymer of water solublity spacer monomers, described water solublity spacer monomers is acrylamide, Methacrylamide, alkyl and dialkyl group acrylamide, alkyl and dialkyl methyl acrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and vinyl pyrrolidone for example.The monomer that alkyl and dialkyl group replace preferably has C ₁-C ₇Alkyl, more preferably C ₁-C ₃Alkyl.Other suitable interval monomer comprises vinyl acetate, vinyl alcohol (being made by the polyvinyl acetate hydrolysis), maleic anhydride, propylene glycol and ethylene glycol.

According to the concrete kind and the pH value of compositions, cationic amine can be primary, the second month in a season or tertiary amine.Usually, preferred secondary amine and tertiary amine, especially preferred tertiary amine.

The vinyl monomer that amine replaces can randomly be converted into ammonium by quaterisation then with the polymerization of amine form.Amine also can be quaternized similarly after forming polymer.For example, tertiary amine functional group is by by quaternized, wherein R ' is a short-chain alkyl with the reactant salt of formula R ' X, preferred C ₁-C ₇Alkyl, more preferably C ₁-C ₃Alkyl, and X is anion, itself and quaternary ammonium form water soluble salt.

Suitable cation amino and quaternary ammonium monomer comprise, for example use propenoic acid dialkyl aminoalkyl ester, the methacrylic acid dialkyl aminoalkyl ester, acrylic acid one alkylaminoalkyl, methacrylic acid one alkylaminoalkyl, trialkyl methacryloxy alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, the vinyl compound that the diallyl quaternary ammonium salt replaces, with have the ring-type cation and contain azo-cycle such as pyridine, the vinyl quaternary ammonium monomer of imidazole salts and quaternized ketopyrrolidine, for example alkyl vinyl imidazole salts, alkylvinylpyridines, alkyl vinyl ketopyrrolidine salt.These monomeric moieties are preferably low alkyl group such as C ₁-C ₃Alkyl, more preferably C ₁And C ₂Alkyl.Suitable amine-substituted ethylene base the monomer that is used for this paper comprises propenoic acid dialkyl aminoalkyl ester, methacrylic acid dialkyl aminoalkyl ester, dialkyl aminoalkyl acrylamide and dialkyl aminoalkyl Methacrylamide, and wherein alkyl is preferably C ₁-C ₇Alkyl, more preferably C ₁-C ₃Alkyl.

Cationic polymer of the present invention can comprise derived from amine and/or quaternary ammonium-substituted monomer and/or the monomeric monomeric unit mixture of compatible spacer.

Suitable cation hair-conditioning polymer for example comprises: l-vinyl-2-pyrrolidone and the 1-vinyl-the 3-methylimidazole salt (for example, chloride salt) copolymer is (in this area, by Cosmetic, Toiletry, and Fragrance Association, " CTFA " called after Onamer M 6), as with trade name LUVIQUAT (as, LUVIQUAT FC 370) available from those of BASF Wyandotte Corp.; The copolymer of l-vinyl-2-pyrrolidone and dimethylamino methyl ethyl acrylate (being referred to as Onamer M 1 by CTFA) in this area, as with trade name GAFQUAT (as, GAFQUAT 755N) available from Gaf Corporation; The polymer that comprises cation diallyl quaternary ammonium comprises for example copolymer of dimethyl diallyl ammonium chloride homopolymer and acrylamide and dimethyl diallyl ammonium chloride, and (CTFA) is called as polyquaternary amine 6 and polyquaternary amine 7 respectively in this area; And the mineral acid salt of the aminoalkyl ester of the homopolymer of unsaturated carboxylic acid and copolymer, it has about 3 to about 5 carbon atoms, and as United States Patent (USP) 4,009,256 is described.

Spendable other cationic polymer comprises polysaccharide polymer, as cationic cellulose derivative and cationic starch derivative.

The cationic polysaccharide polymer that is applicable to this paper comprises those with following chemical formula:

Wherein: A is the anhydroglucose residue, as starch or cellulose anhydroglucose residue; R is alkylidene oxyalkylene, polyoxyalkylene or hydroxy alkylidene or their combination; R ₁, R ₂And R ₃Be alkyl, aryl, alkylaryl, aryl alkyl, alkoxyalkyl or alkoxy aryl independently, each group comprises about 18 carbon atoms at most, and the total number of carbon atoms of each cationic moiety (is R ₁, R ₂And R ₃In the carbon number sum) be preferably about 20 or still less; And X is an anionic counter-ion.Suitable counter ion counterionsl gegenions comprise halide ion (for example Cl, Br, I or F, preferably Cl, Br or I), sulfate radical and methyl ester sulfate radical.Because this tabulation is not unique, therefore can also use other counter ion counterionsl gegenions.

Cationic cellulose can its Polymer With

Series polymer is available from AmercholCorp., and it is the epoxide reactive salt that hydroxyethyl-cellulose and trimethyl ammonium replace, and (CTFA) is called polyquaternary amine 10 in this area.The cationic cellulose of another type comprises the epoxide reactive polymer quaternary ammonium salt that hydroxyethyl-cellulose and lauryl dimethyl ammonium replace, and (CTFA) is called polyquaternary amine 24 in this area.These materials are with trade name Polymer

Available from Amerchol Corp..

Operable other cationic polymer comprises the cationic guar gum derivant, as guar gum hydroxypropyl trimethyl ammonium chloride (with its Jaguar R series available from Celanese Corp.).Other material comprises the cellulose ether (as United States Patent (USP) 3,962, described in 418) that contains quaternary nitrogen and the copolymer (as United States Patent (USP) 3,958, described in 581) of etherified cellulose and starch.

As discussed above, cationic polymers hereof is water miscible.But this does not mean that it must be dissolved in the compositions.Yet this cationic polymer preferably dissolves in the compositions, or dissolve in by the complex coacervate in this cationic polymer and the compositions that anionic species forms mutually in.Cationic polymer can form complex coacervate with optional anion surfactant or the anionic polymer (for example kayexalate) that adds in this paper compositions.

6. silicone conditioning agent

The present composition also can comprise nonvolatile soluble or undissolved silicone conditioning agent." soluble " is meant that the aqueous carrier of silicone conditioning agent and compositions is miscible, to become the part in the phase homophase." undissolved " be meant siloxanes by aqueous carrier form independently, discontinuous phase, as be the form of the suspension of emulsion or siloxanes droplet.

The siloxanes hair conditioner that is used for the present composition in by the weight of described compositions about 0.05% to about 10%, preferred about 0.1% to about 6%, more preferably from about 0.3% to about 5%, even more preferably from about 0.5% to about 3% amount exists.

Soluble siloxanes comprises silicone copolyol such as dimethicone copolyol, the polymer of polyether silicone modification for example, as the polydimethylsiloxane of poly(propylene oxide), poly(ethylene oxide) modification, wherein the content of oxirane and/or expoxy propane is enough to provide its dissolubility in compositions.

Yet, preferred undissolved siloxanes.Can be used for this paper do not dissolve preferred 25 ℃ of siloxanes hair conditioner the time viscosity that has be about 0.001 to about 2m ²/ s (about 1,000 to about 2,000,000 centistoke), more preferably from about 0.01 to about 1.8m ²/ s (about 10,000 to about 1,800,000), even more preferably from about 0.1 to about 1.5m ²/ s (about 100,000 to about 1,500,000).Viscosity can be measured according to disclosed glass capillary tube viscometer method among July in 1970 Dow Corning on the 20th Corporate Test Method CTM0004.

The suitable non-volatile siloxane liquid that do not dissolve comprises poly-alkylsiloxane, poly-aryl siloxanes, polyoxyethylene alkyl aryl radical siloxane, polyether siloxane copolymer, and their mixture.That can use also that other has hair-conditioning character does not dissolve non-volatile siloxane liquid.Term used herein " nonvolatile " is meant that the boiling point of siloxanes is at least about 260 ℃, preferably at least about 275 ℃, more preferably at least about 300 ℃.These materials show to have low-down or do not have significant vapour pressure under environmental condition.Viscosity was less than about 1m when term " polysiloxane fluid " was meant 25 ℃ ²The flowed silicone materials of/s (1,000,000 centistoke).Usually, fluidic viscosity will be between about 5 x 10 25 ℃ the time ^-6To about 1m ²Between/the s (about 5 to about 1,000,000 centistoke), preferably between about 1 x 10 ^-5To about 0.3m ²Between/the s (about 10 to about 300,000 centistokes).

The siloxanes fluids of this paper also comprises poly-alkyl or the poly-aryl siloxanes with following array structure:

Wherein R is an alkyl or aryl, and x is about 7 to about 8,000 integer.The group of " A " representative sealing siloxane chain end.

Go up or can have arbitrary structures at siloxane chain (R) at the alkyl or aryl that the end of siloxane chain (A) replaces, as long as the gained siloxanes at room temperature remains fluid, be hydrophobic, there is not zest in the time of on being administered to hair, nontoxic, also harmless, with other component compatibility of compositions, under normal use and condition of storage is chemically stable, and can deposit on the hair and conditioning hair.

The A group that is fit to comprises methyl, methoxyl group, ethyoxyl, propoxyl group and aryloxy group.Two R groups on silicon atom can be represented identical group or different groups.Preferred two R groups are represented identical group.The suitable R group comprises methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl.Preferred siloxanes is polydimethylsiloxane, poly-di-ethyl siloxane and PSI.Especially preferred polydimethylsiloxane.

Operable non-volatile poly-alkylsiloxane fluid comprises for example polydimethylsiloxane.These siloxanes can be for example with Viscasil R and SF96 series available from General ElectricCompany, with Dow Corning 200 series available from Dow Corning.

Operable polyoxyethylene alkyl aryl radical siloxane fluid also comprises PSI.These siloxanes can, for example, derive from General Electric Company, or derive from Dow Corning with 556 Cosmetic Grade Fluid with SF 1075 aminomethyl phenyl fluids.

For the glossiness of enhanced hair, especially preferred is the siloxanes of height arylation, and as the poly-ethylsiloxane chemical compound of height phenylating, its refractive index is about 1.46 or higher, especially about 1.52 or higher.When using these high index of refraction siloxanes, they should mix with spreading agent (as surfactant or silicone resin as mentioned below), to reduce the film forming ability of surface tension and enhancing substance.

Spendable polyether siloxane copolymer comprises the polydimethylsiloxane (for example, Dow Corning DC-1248) of for example poly(propylene oxide) modification, also can use the mixture of oxirane or oxirane and expoxy propane.The content of oxirane and poly(propylene oxide) should be enough low, to prevent the dissolving in compositions.

The list of references that discloses suitable polysiloxane fluid comprises United States Patent (USP) 2,826,551, United States Patent (USP) 3,964,500, United States Patent (USP) 4,364,837 and British patent 849,433.By Petrarch Systems, Inc., 1984 silicone compounds that distribute provide suitable rough (although not unique) inventory of polysiloxane fluid.

Especially other siloxanes hair-conditioning material that can be used for silicone conditioning agent is undissolved silicone gum.Term used herein " silicone gum " is meant that viscosity in the time of 25 ℃ is more than or equal to 1m ²The polysiloxane material of/s (1,000,000 centistoke).Silicone gum is described by Petrarch and other people, comprises United States Patent (USP) 4,152,416, and Noll, " the Chemistry andTechnology of Silicones " of Walter, New York:Academic Press 1968.That describe silicone gum equally is General Electric Silicone Rubber Product Data Sheets SE 30, SE33, SE 54 and SE 76.It is about 200,000 that the weight average molecular weight of " silicone gum " typical case surpasses, usually between about 200,000 and about 1,000, between 000.Instantiation comprises polydimethylsiloxane, (polydimethylsiloxane) (ethylene methacrylic radical siloxane) copolymer, poly-(dimethyl siloxane) (diphenyl siloxane) (ethylene methacrylic radical siloxane) copolymer and their mixture.

Preferred siloxanes hair conditioner comprises polydimethylsiloxane natural gum, and (its viscosity is greater than about 1m ²/ s (1,000,000 centistoke)) and polydimethylsiloxane fluid (its viscosity is about 1 x 10 ^-5m ²/ s (10 centistoke) is to about 0.1m ²/ s (100,000 centistoke)) mixture, wherein natural gum is extremely about 70:30 of about 30:70 with the ratio of fluid, preferably about 40:60 is to about 60:40.

The optional member that can be included in the described silicone conditioning agent is a silicone resin.This silicone resin is highly cross-linked polysiloxanes system.Described crosslinkedly introduce by trifunctional and four functional silanes being mixed with simple function or difunctional silane or the two at the silicone resin production period.Understand as this area,, will change according to the specific silane unit that mixes in the silicone resin for obtaining the required degree of cross linking of silicone resin.Usually, have the trifunctional of q.s and four functional silicone monomeric units (therefore, having enough crosslinked levels) thus the polysiloxanes material that when drying, forms rigidity or hard film be considered to polyorganosiloxane resin.The ratio of oxygen atom and silicon atom is the indication of the specific crosslinked level of silicone compositions.Silicone resin of the present invention normally each silicon atom has silicone compositions at least about 1.1 oxygen atoms.The preferred oxygen atom: the ratio of silicon atom is at least about 1.2:1.0.The silane that is used to prepare silicone resin comprise monomethyl-, dimethyl-, trimethyl-, a phenyl-, diphenyl-, aminomethyl phenyl-, a vinyl-, methyl ethylene-chlorosilane, and tetrachloro silicane, the silane of methyl-replacement is the most frequently used.Preferred resin is GESS4230 and the SS4267 by General Electric supply.Commercially available silicone resin normally provides with the dissolved form in low viscous volatility or non-volatile siloxane fluid.Be applicable to that silicone resin of the present invention should provide with such dissolved form and be incorporated in the present composition, this it will be apparent to those skilled in the art that.Silicone resin can strengthen the deposition of siloxanes on hair, and can strengthen the glossiness of the hair with high index of refraction volume.

The relevant background information of preparation that comprises siloxanes that siloxanes fluids, siloxane glue and each chapters and sections of silicone resin are discussed and siloxanes can be referring to Encyclopaedia of Polymer Science andEngineering, the 15th volume, the 2nd edition, 204-308 page or leaf, John Wiley ﹠amp; Sons, Inc., 1989.

Polysiloxanes material and especially polyorganosiloxane resin can be easily according to shorthand naming systems well known to those skilled in the art, i.e. " MDTQ " nomenclature identification.Under this system, siloxanes is described according to the various siloxanyl monomers unit of existing composition siloxanes.Briefly, symbol M is represented a functional unit (CH ₃) ₃SiO _0.5D represents two functional unit (CH ₃) ₂SiO; T represents trifunctional units (CH ₃) SiO _1.5Q represents quadruple or four functional unit SiO ₂Major part in the unit symbol such as M ', D ', T ' and the substituent group of Q ' expression except that methyl have specific definitions to each situation.Typical other substituent group comprises the group such as vinyl, phenyl, amino, hydroxyl etc.Each unitary mol ratio, or represent the sum (or its average) of each type units in the polysiloxanes, or show with the ratio and the binding molecule scale of concrete expression with the symbol subscript, thus realize description according to the MDTQ system to the polysiloxanes material.In silicone resin, with respect to D, D ', M and/or M ', the T of higher molar amounts, Q, T ' and/or Q ' mean the degree of cross linking of higher level.Yet total crosslinking degree can also be by the expression recently of oxygen and silicon.

The silicone resin that can be used for this paper is MQ, MT, MTQ, MQ and MDTQ resin preferably.Therefore, preferred siloxanes substituent group is a methyl.Especially preferred is the MQ resin, and wherein the M:Q ratio is extremely about 1.5:1.0 of about 0.5:1.0, and the mean molecule quantity of this resin is about 1000 to about 10,000.

7. dandruff agent

The present composition also can comprise the dandruff agent.The particulate non-limiting example of suitable anti-dandruff comprises: pyrithione, pyrroles, selenium sulfide, climbazole, granule sulfur and their mixture.Pyrithione preferably.Above-mentioned anti-dandruff granule should be at physics and chemically compatible with the solvent of compositions, and should not destroy stability, aesthetic property or the performance of product undeservedly.

Pyrithione anti-dandruff granule, especially 1-hydroxyl-2-pyrithione are the highly preferred dandruff removing agent granules that is used for the present composition.The particulate concentration of pyrithione dandruff is typically by described composition weight meter about 0.1% to about 4%, and preferred about 0.1% to about 3%, and more preferably from about 0.3% to about 2%.Preferred pyrithione comprises by heavy metal such as zinc, stannum, cadmium, magnesium, aluminum and zirconium, those that preferred zinc forms, the more preferably zinc salt of 1-hydroxyl-2-pyrithione (being called " Zinc Pyrithione " or " ZPT "), more preferably scutellate 1-hydroxyl-2-pyrithione, wherein said particulate average-size is about 20 μ to the maximum, preferably be about 5 μ to the maximum, more preferably be about 2.5 μ to the maximum.The salt that is formed by other cation such as sodium also is suitable.The agent of pyrithione dandruff is described in, for example, and United States Patent (USP) 2,809,971, United States Patent (USP) 3,236, and 733, United States Patent (USP) 3,753,196, United States Patent (USP) 3,761,418, United States Patent (USP) 4,345, and 080, United States Patent (USP) 4,323,683, United States Patent (USP) 4,379,753 and United States Patent (USP) 4,470,982 in.It is contemplated that growth or regeneration when ZPT during as the dandruff granule in this paper compositions, can being stimulated or regulate (or stimulate simultaneously and regulate) hair perhaps can reduce or suppress trichomadesis, perhaps hair will seem denser or more plentiful.

Except the anti-dandruff active substance of the multivalent metal salt of selected from mercapto pyridine-N-oxide, the present invention also can comprise one or more antifungals or the antimicrobial active substance except that metal hydrosulfide yl pyridines oxide salt active substance.Suitable anti-microbial active matter comprises coal tar, sulfur, U.S.A reaches whitfield ointment, the pigment of castellani, aluminum chloride, Gentian Violet, Octopirox (Octopirox ethanolamine), encircle pyrrone oxyethylamine ketone, 9-undecylenic acid and slaine thereof, potassium permanganate, selenium sulfide, sodium thiosulfate, propylene glycol, bitter orange oil, Carmol, griseofulvin, the oxine clioquinol, sulfo-bendazol, thiocarbamate, haloprogin, polyene, pyridone ketone, morpholine, benzylamine, allylamine (as terbinafine), tea tree oil, Folium Caryophylli oil, Herba Coriandri, Cymbopogon martini, berberine, Herba thymi vulgaris is red, Oleum Cinnamomi, cinnamic aldehyde, citronellic acid, hinokitol, ichthyol is white, Sensiva SC-50, Elestab HP-100, Azelaic Acid, lyase, iodo propinyl butyl carbaminate (IPBC), isothiazolone such as octyl group isothiazolone and azole, and their combination.Preferred antimicrobial comprises itraconazole, ketoconazole, selenium sulfide and coal tar.

The azoles antimicrobial comprises imidazoles such as benzimidazole, benzothiazole, bifonazole, butunazole nitrate, climbazole, clotrimazole, Crewe health azoles, eberconazole, econazole, Elubiol, fenticonazole, fluconazol, flutrimazole, isoconazole, ketoconazole, Lan Nuokang azoles, metronidazole, miconazole, neticonazole, omoconazole, oxiconazole nitrate, Sertaconazole, sulconazole nitrate, tioconazole, thiazole and triazole such as terconazole (triaconazole) and itraconazole, and their combination.In the time of in being present in compositions, the content of azole anti-microbial active matter is by described composition weight meter, for about 0.01% to about 5%, preferred about 0.1% to about 3%, and more preferably from about 0.3% to about 2%.This paper is especially preferred to be ketoconazole.

Selenium sulfide is the graininess dandruff removing agent that is applicable to antimicrobial compositions of the present invention, and about 0.1% to about 4% scope, preferred about 0.3% to about 2.5% by the weight of described compositions for its valid density, more preferably from about 0.5% to about 1.5%.Selenium sulfide is considered to have the chemical compound of one mole of selenium and two molar sulphur usually, although it also can be general molecular formula Se _xS _yCirculus, x+y=8 wherein.Survey (for example Malvern3600 instrument) as preposition laser light scattering device, the mean diameter of selenium sulfide typically is lower than 15 μ m, preferably is lower than 10 μ m.The selenium sulfide chemical compound for example is disclosed in United States Patent (USP) 2,694, and 668, in United States Patent (USP) 3,152,046, United States Patent (USP) 4,089,945 and the United States Patent (USP) 4,885,107.

Sulfur also can be as the graininess antimicrobial/dandruff removing agent in the antimicrobial compositions of the present invention.The valid density of granule sulfur typically is about 1% to about 4% by the weight of described compositions, is preferably about 2% to about 4%.

The present invention also can comprise one or more keratolytic agents such as salicylic acid.

The other anti-microbial active matter of the present invention can comprise melaleuca (Camellia sinensis) extract and Linesless charcoal.The present invention also can comprise the combination of anti-microbial active matter.This combination can comprise Octopirox and 1-oxygen-2-mercaptopyridine zinc combination, pine tar and sulfur combination, salicylic acid and 1-oxygen-2-mercaptopyridine zinc combination, Octopirox and climbazole combination, and salicylic acid and Octopirox combination, and their mixture.Sulfur is typically about 1% to about 4%, preferred about 2% to about 4%.

8. granule

Personal care composition of the present invention can comprise granule.The water insoluble solid granule of different shape and density is available.Particle grain size of the present invention (based on the volume averaging value of hereinafter described grain diameter measurement) is less than about 100 μ m, preferably less than about 60 μ m, and more preferably particle diameter less than about 30 μ m.

The granule that can be present among the present invention can be natural, synthetic or semisynthetic.In addition, also can there be hybrid particles.Synthetic granule can be made by cross linked polymer or non-cross-linked polymer.Granule among the present invention can have surface charge or their surperficial available organic or inorganic material such as surfactant, polymer and inorganic substances modification.Also can there be particle composites.

Synthetic particulate non-limiting example comprises nylon, silicone resin, poly-(methyl) acrylate, polyethylene, polyester, polypropylene, polystyrene, polyurethane, polyamide, epoxy resin, urea resin and acrylic clear powder.Useful particulate non-limiting example is Microease 110S, 114S, 116 (micronization synthetic wax), Micropoly 210,250S (micronization polyethylene), Microslip (micronization politef) and Microsilk (combination of polyethylene and politef), all granules are all available from Micro Powder, Inc..Other embodiment comprises Luna (slick silica dioxide granule) granule available from Phenomenex, MP-2200 (polymethyl methacrylate), EA-209 (ethene/acrylic ester copolymer), SP-501 (PA-12), ES-830 (polymethyl methacrylate), available from Kobo Products, the BPD-800 of Inc., BPD-500 (polyurethane) granule and with the silicone resin of trade name Tospearl granule available from GESilicones.Ganzpearl GS-0605 crosslinked polystyrene (available from Presperse) also is useful.

The limiting examples of hybrid particles comprises Ganzpearl GSC-30SR (sericite and crosslinked polystyrene mixed-powder) and SM-1000, SM-200 (Muscovitum and silicon dioxide mixed-powder are available from Presperse).

Coated interference pigment of the present invention is the strip granule.The particulate thickness of the strip of multi phase personal care composition preferably is no more than about 5 μ m, more preferably no more than about 2 μ m, also more preferably no more than about 1 μ m.The particulate thickness of the strip of multi phase personal care composition is preferably at least about 0.02 μ m, more preferably at least about 0.05 μ m, even more preferably at least about 0.1 μ m, also more preferably at least about 0.2 μ m.

The coated interference pigment of multi phase personal care composition comprises multiple structure.Particulate central authorities are that refractive index (RI) is usually less than 1.8 flat substrate.Various particle matrixs can be used for this paper.Non-limiting example is natural mica, synthetic mica, graphite, Talcum, Kaolin, alumina wafer, bismuth oxychloride, silicon dioxide thin slice, glass flake, pottery, titanium dioxide, CaSO ₄, CaCO ₃, BaSO ₄, borosilicate, and their mixture, preferred Muscovitum, silicon dioxide and alumina wafer.

Can on the surface of above-mentioned substrate, apply single thin film or plural layers.Thin film is made by high-refraction material.The refractive index of these materials is usually more than 1.8.

There are various thin film to can be used for this paper.Non-limiting example is TiO ₂, Fe ₂O ₃, SnO ₂, Cr ₂O ₃, ZnO, ZnS, ZnO, SnO, ZrO ₂, CaF ₂, Al ₂O ₃, BiOCl, and their mixture, or be the form of stratum disjunctum, preferred TiO ₂, Fe ₂O ₃, Cr ₂O ₃, SnO ₂For multiple structure, thin film can be made up of all high-index materials, or alternately is made up of the thin film with high and low RI material, and with high RI thin film as top layer.

The non-limiting example that can be used for the coated interference pigment of this paper comprises with trade name

By Persperse, those that Inc. provides; With trade name

With

By EMD Chemicals, those that Inc. provides; And with trade name

Those that provide by Engelhard Co..

In embodiments of the invention, the coated interference pigment surface is hydrophobic or hydrophobically modified.Use is filed in the contact angle that the Particle Contact Angle Test described in the common unsettled application sequence number 60/469,075 on May 8th, 2003 measures coated interference pigment.Contact angle is big more, and the hydrophobicity of coated interference pigment is big more.The contact angle that coated interference pigment of the present invention has is at least 60 degree, more preferably greater than 80 degree, even more preferably greater than 100 degree, also more preferably greater than 100 degree.

The non-limiting example that can be used for the hydrophobic surface treatments thing of this paper comprises siloxanes, acrylate silicone copolymers, acrylate polymer, alkyl silane, isopropyl three isostearic acid titaniums, sodium stearate, magnesium myristate, perfluor alcohol phosphate ester, the poly-methyl isopropyl ether of perfluoro, lecithin, Carlow crust wax, polyethylene, chitosan, lauroyl lysine, cerolipoid extract, and their mixture, preferred siloxanes, silane and stearate.Surface disposal facility comprises USCosmetics, KOBO Products Inc. and Cardre Inc..

9. crosslinked silicone elastomer

Personal care composition of the present invention can comprise crosslinked silicone elastomer.The amount that crosslinked siloxane elastomer exists for by the weight of described compositions about 0.01% to about 15%, preferred about 0.1% to about 10%, even more preferably from about 1% to about 5%.These beneficial agents provide hair alignment and flexibility (emollient) beneficial effect for hair.Preferred compositions is the Dimethicone/Vinyl Dimethicone cross linked polymer.This Dimethicone/Vinyl Dimethicone cross linked polymer is provided by a plurality of suppliers, comprise Dow Corning (DC 9040 and DC 9041), GeneralElectric (SFE 839), Shin Etsu (KSG-15,16,18[polydimethylsiloxane/phenyl vinyl polydimethylsiloxane cross linked polymer]), Grant Industries (Gransil ^TMRaw material series), and lauryl Dimethicone/Vinyl Dimethicone cross linked polymer provide by Shin Etsu (for example, KSG-31, KSG-32, KSG-41, KSG-42, KSG-43 and KSG-44).The cross-lined organic polyorganosiloxane elastomer and their method of preparation that can be used for this paper are further described in United States Patent (USP) 4,970, and 252, United States Patent (USP) 5,760,116, United States Patent (USP) 5,654, and 362 and transfer among the Japanese patent application JP61-18708 of Pola KaseiKogyo KK.United States Patent (USP) 5,412,004,5,837,793 and 5,811, the silicone elastomer of type described in 487 also can be used for this paper.Elastomer of the present invention preferably solidifies under anhydrous condition or in water-less environment.

10. high alkylidene (Peralkylene) hydrocarbon

The present invention can comprise high alkylidene hydrocarbon (peralkylene hydrocarbon) material.These materials are the basic material of alkane (alkene) of side chain, and its side group is-H, C _1-4Alkane (alkene) base or (H or C _1-4Alkane (alkene) base) the saturated or unsaturated cyclic hydrocarbon of Qu Daiing, and wherein the side group number at least 10% be not-H more preferably 25% to 75%, most preferably 40% to 60%.Preferred pendent alkyl groups is a methyl.

The weight average molecular weight of the basic hydrocarbon materials of preferred high alkane (alkene) is preferably about 180 to about 2500 less than about 4200.The basic hydrocarbon materials of these low-molecular-weight height-alkane (alkene) for example can trade name Indopol available from BP, with trade name Solanes available from Soltex and with trade name Oronite OLOA available from Chevron.

Control the granularity of the basic hydrocarbon materials of high alkane (alkene) also advantageously, so that keep the suitable conditioning characteristic of described compositions.To be about 0.01 μ can make the conditioning aspect of this prescription be controlled and at specific colony of consumer to the combination of the basic hydrocarbon materials of high alkane (alkene) of about 40 μ and cationic deposition polymer (especially cellulose) to granularity. by using the basic hydrocarbon materials of low-molecular-weight high alkane (alkene), demand to a large amount of expensive conditioning oil significantly reduces, and has reduced the tradition consumption relevant with styling shampoos.

The basic hydrocarbon materials of preferred high alkane (alkene) is butylene, isoprene, terpenes and cinnamic polymer, copolymer with any of these combination of monomers, as butyl rubber (polymethyl-be total to-isoprene), natural rubber (cis-1, the 4-polyisoprene) and hydrocarbon resin, as the Encyclopedia of Chemical Technology of Kirk and Ohmer (the 3rd edition, the 8th the volume, the 852-869 page or leaf) in provided those, for example aliphatic series and aromatic petroleum resin, terpene resin etc.The especially preferred polymer that dissolves in the basic hydrocarbon materials of the high alkane of low-molecular-weight (alkene) or other solvent or carrier (if you are using) that is to use.

Especially preferred is the basic hydrocarbon materials of high alkane (alkene) with following chemical formula:

Wherein: n=0-3, preferred 1;

The m=integer makes the weight average molecular weight of this hydrocarbon be less than or equal to 4200.

R ¹For--H or C _1-4Alkyl; Preferable methyl;

R ²Be C _1-4Alkyl; Preferable methyl;

R ³For--H or C _1-4Alkyl; Preferably--H or methyl

Or

Especially preferred is the polybutene material with following chemical formula:

R wherein ⁴For

Or

These materials with trade name Permethyl available from Presperse Inc..The total content of the basic hydrocarbon of high alkane (alkene) is preferably by described composition weight meter about 0.01% to about 10% in the Hairsetting compositions, and more preferably from about 0.2% to about 5%, even more preferably from about 0.2% to about 2%.

11. hair dyeing profit/dyestuff

Compositions of the present invention also can comprise hair dye/dyestuff.Hair dye/the dyestuff that can be used for this paper comprises anthraquinone, azo, nitro, alkali, triarylmethane or disperse dyes, or their any combination.Direct dyes in the certain limit comprises basic stain and neutral dye, also can be used for this paper.The dyestuff that is suitable for is described in United States Patent (USP) 5,281,240 and United States Patent (USP) 4,964,874 in.

12. other composition

This paper compositions can comprise multiple other be suitable for making said composition the beauty treatment or aesthetic the easier optional components that is accepted or makes it to have extra use beneficial effect.These conventional optional members are that those skilled in the art is known.Supplementary element can be present in cleansing phase or useful mutually in.

Multiple additional composition can be formulated in the present composition.These components comprise: other conditioner; The hair that is used for various approved products (being hair jelly, mousse, gel etc.) keeps polymer with ability that strengthens shaping hair and the durability that Hairsetting is provided; Detersive surfactant such as anion, nonionic, both sexes and zwitterionic surfactant; Additional thickener and suspending agent such as xanthan gum, guar gum, hydroxyethyl-cellulose, methylcellulose, hydroxyethyl-cellulose, starch and starch derivatives; The methanol amide of viscosity modifier such as long-chain fatty acid such as cocoyl single ethanol amide; Crystalline suspending agent; Pearlescent additive such as glycol distearate; Antiseptic such as benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; Polyvinyl alcohol; Ethanol; The pH regulator agent is as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is usually as potassium acetate and sodium chloride; Coloring agent is as any FD﹠amp; C or D﹠amp; The C dyestuff; Hair oxidation (bleaching) agent is as hydrogen peroxide, perborate and persulfate; The hair Reducing agent is as thioglycolate salt; Spice; Sequestering agent is as disodiumedetate; Polymeric plasticizer is as glycerol, adipic acid diisobutyl ester, butyl stearate and propylene glycol.Other non-limiting examples of these optional members comprise: vitamin and derivant thereof are (as ascorbic acid, vitamin E, tocopherol acetas etc.), sunscreen, thickening agent is (as the polyhydric alcohol alkoxy ester, with trade name Crothix available from Croda), the antiseptic of compositions antimicrobial integrity is used to keep clean, anti-acne medicament (resorcinol, salicylic acid etc.), antioxidant, skin console and rehabilitation agent (as Aloe extract, allantoin etc.), chelating agen and sequestering agent, and be suitable for aesthetic purposes reagent (as aromatic, quintessence oil, the skin sensitizer, pigment, pearling agent (as Muscovitum and titanium dioxide), the color lake, coloring agent, or the like (as Oleum Caryophylli, menthol, Camphora, Eucalyptus oil and acetaminol)).The non-limiting example of suitable carboxyl copolymer, emulsifying agent, emollient and other supplementary element is disclosed in United States Patent (USP) 5,011, in 681.These optional members usually separately with by described composition weight meter about 0.01% to about 10.0%, preferred about 0.05% to about 5.0% content uses.

Using method

Use multi phase personal care composition of the present invention so that conditioning and other beneficial effect to be provided in the mode of routine.These usings method depend on the type of compositions for use, but the product that generally includes effective dose is applied on hair or the skin, can rinse (under the situation of hair rinsing) from hair or skin then, or allow it be retained in (under the situation of gel, Emulsion and cream) on hair or the skin." effective dose " is meant is enough to provide the amount of doing the combing beneficial effect.Usually will about 1g be applied on hair, skin or the scalp to about 50g.Typically, by friction or massage hair, scalp or skin, compositions is distributed on whole hair or the skin.Preferably before with trichoxerosis, compositions is applied on the hair of moistening or humidity.After being applied to such compositions on the hair, according to the hobby of user with trichoxerosis and typing.Replacedly, compositions is applied to dried hair, then according to the hobby of user with hair combing and typing.Described compositions by local application effective dose on hair or skin, the water flushing is removed described compositions from described hair or skin then, described multi phase personal care composition can be used for the conditioning beneficial effect is delivered to hair or skin, and/or the Hairsetting beneficial effect is delivered to hair or skin, and/or the coloring hairs beneficial effect is delivered to hair or skin.

Preparation method

Multi phase personal care composition of the present invention can be suitable for making and preparing the preparation of the known of required heterogeneous product form or other effective technologies by any.It is especially effective that the dentifrice tube filling technique is combined with the turntable design.When they were applied to specific embodiments of the present invention, the concrete non-limiting example of these class methods was narrated in following embodiment.

Non-limiting example

The compositions that illustrates in following examples is for example understood the specific embodiments of the present composition, but is not intended to it is limited.Under the condition that does not deviate from spirit and scope of the invention, the technical staff can carry out other change.These exemplary of the present composition provide because enhanced coacervate forms the enhanced multi phase personal care composition deposition that is produced.

The compositions that illustrates among the following embodiment has been described one of them embodiment above by conventional formulation and mixed method preparation.Except as otherwise noted, the amount of all examples is listed with percentage by weight, except microcomponent, as diluent, antiseptic, colored solutions, imaginary composition, medicinal plants etc.

Not only comprise cleansing phase but also comprised the two-phase compositions of additional (conditioning) phase

	Embodiment 1	Embodiment 2	Embodiment 3	Embodiment 4
					Composition	Percentage by weight	Percentage by weight	Percentage by weight	Percentage by weight
The cleansing phase compositions
					Laureth-3 ammonium sulfate	3.0	3.0	3.0	-
Lauryl both sexes sodium acetate (Miranol L-32 Ultra is available from Rhodia)	16.7	16.7	16.7	-
					Surfactant blend (Miracare SLB-365 is available from Rhodia)	-	-	-	23.7
Ammonium lauryl sulfate	1.0	1.0	1.0	3.3
					Lauryl polyethenoxy ether sodium sulfate				0.42
Lauric acid (Emry 625)	0.9	0.9	0.9	2.0
					Three (hydroxy stearic acid) glyceride (Thixcin R)	2.0	2.0	2.0	-
Rhaball Gum CG-M 8M (N-Hance 3196, derive from Aqualon)	0.17	0.75	0.75	0.7
					Rhaball Gum CG-M 8M (Jaguar C-17 is available from Rhodia)	0.58	-	-	-
Polyquaternary amine 10 (UCARE polymer JR-30M is available from Amerchol)	0.45	-	-	-
					PMAm oxypropyl trimethyl ammonium chloride (Polycare 133, available from Rhodia)	-	0.24	-	0.13
Polyquaternary amine-39 (Merqurt Plus 3300 is available from Calgon)	-	0.81	-	-
					PEG 90M (Polyox WSR 301 is available from Union Carbide)	0.25	-	-	-
PEG-14M (Polyox WSR N-3000 H is available from Union Carbide)	0.45	2.45	2.45	-
					Inferior oleamide propyl group pg dimonium chloride phosphorus	-	1.0	4.0	-

Acid esters polydimethylsiloxane (Monasil PLN is available from Uniqema)
					Polydimethylsiloxane (Viscasil 330M is available from General Electric)	-	-	-	4.2
Glycol distearate				1.5
					Glycerol	1.4	4.9	4.9	-
Sodium chloride	0.3	0.3	0.3	2.84
					Sodium benzoate	0.25	0.25	0.25	-
Disodiumedetate (Hampene NA2/Dissolvine NA-2X)	0.13	0.13	0.13	0.05
					1,3-dihydroxymethyl-5,5-dimethyl hydantoin	0.37	0.37	0.37	-
DMDM Hydantoin (Lonza)	-	-	-	0.37
					The red #30 Talcum of D﹠C color lake	-	-	-	0.05
Citric acid	1.6	0.95	0.95	0.64
					Titanium dioxide	0.5	0.5	0.5	-
Spice	0.5	0.5	0.5	0.25
					Water	In right amount	In right amount	In right amount	In right amount
Expancel 091-DE-40-D30(Expancel Corp.)	0.00001	0.00001	0.00001	0.000015
					Useful combined thing
The amino propyl group dimethylamine (1) of stearoyl	2.00	1.60	2.00	3.0
					The amino ethyl diethylamide (2) of stearoyl
INCROQUAT TMC-80 ECONOL TM22 (3)	-	3.4	-	-
					L-glutamic acid (4)	0.64	0.51	0.64	0.96
Spermol (5)	2.50	2.32	3.75	3.75
					Stearyl alcohol (6)	4.50	4.2	6.75	6.75
Oleyl alcohol (7)	-	-	-	-
					Mineral oil (8)		-	-	-
Polydimethylsiloxane blend (9)	-	4.2
					Siloxane emulsion (10)				6.3

Polydimethylsiloxane polysiloxane fluid blend (11)	4.2	-	4.2
					Benzylalcohol	0.40	0.40	0.40	0.40
EDTA	0.10	0.13	0.10	0.10
					Kathon CG(12)	0.03	0.03	0.03	0.03
Methyl parahydroxybenzoate
					Propyl p-hydroxybenzoate
General basic ether	0.05	0.1		0.06
					Pantothenylol	0.09	0.09		0.05
Sodium chloride	-	0.01	-	-
					Spice	0.25	0.20	0.20	0.25
Water	In right amount	In right amount	In right amount	In right amount
					The ratio of cleansing phase/useful phase	40/60	70/30	70/30	70/30

(1) the amino propyl group dimethylamine of stearoyl: AMIDOAMINE MPS, available from Nikko

(2) the amino ethyl diethylamide of stearoyl: AMIDOAMINE S, available from Nikko

(3) INCROQUAT TMC-80 ECONOL TM22, with Genamin KDMP available from Clariant

(4) L-glutamic acid: L-glutamic acid (beauty treatment level), available from Ajinomoto

(5) spermol: KONOL series, available from New Japan Chemical

(6) stearyl alcohol: KONOL series, available from New Japan Chemical

(7) oleyl alcohol: UNJECOL90BHR is available from New Japan Chemical

(8) mineral oil: BENOL is available from Witco

(9) 60% 0.00035m ²/ s (350 centistoke) and 40% 18m ²The polydimethylsiloxane fluid blend of/s (18,000,000 centistoke) is available from General Electric Silicones Products.

(10) Dow Cornining HMW 2220 non-ionic emulsions

(11) polydimethylsiloxane fluid blend (0.5MM centistoke/0.0002m ²/ s (200 centistoke) [15/85v/v%]), available from General Electric Silicones Products.

(12) Kathon CG: the mixture of methyl chloride isothiazoline and methyl isothiazoline, available from Rohm ﹠amp; Hass Co..

Embodiment

Embodiment 6

Embodiment

Embodiment 8

Embodiment 9

Composition	Percentage by weight	Percentage by weight	Percentage by weight	Percentage by weight	Percentage by weight
						The cleansing phase compositions
Laureth-3 ammonium sulfate	3.0	3.0	3.0	-	3.0
						Lauryl both sexes sodium acetate (Miranol L-32 Ultra is available from Rhodia)	16.7	16.7	16.7	-	16.7
Surfactant blend (Miracare SLB-365 is available from Rhodia)	-	-	-	23.7	-
						Ammonium lauryl sulfate	1.0	1.0	1.0	3.3	1.0
Lauryl polyethenoxy ether sodium sulfate				0.42
						Lauric acid (Emry 625)	0.9	0.9	0.9	2.0	0.9
Three (hydroxy stearic acid) glyceride (Thixcin R)	2.0	2.0	2.0	-	2.0
						Rhaball Gum CG-M 8M (N-Hance 3196, derive from Aqualon)	0.17	0.75	0.75	0.7	0.17
Rhaball Gum CG-M 8M (Jaguar C-17 is available from Rhodia)	0.58	-	-	-	0.58
						Polyquaternary amine 10 (UCARE polymer JR-30M is available from Amerchol)	0.45	-	-	-	0.45
PMAm oxypropyl trimethyl ammonium chloride (Polycare 133, available from Rhodia)	-	0.24	-	0.13	-
						Polyquaternary amine-39 (Merqurt Plus 3300, available from	-	0.81	-	-	-

Calgon)
						PEG 90M (Polyox WSR 301 is available from Union Carbide)	0.25	-	-	-	0.25
PEG-14M (Polyox WSR N-3000H is available from Union Carbide)	0.45	2.45	2.45	-	0.45
						Inferior oleamide propyl group pg dimonium chloride phosphate ester polydimethylsiloxane (Monasil PLN is available from Uniqema)	-	1.0	4.0	-	-
Polydimethylsiloxane (Viscasil 330M is available from General Electric)	-	-	-	4.2	-
						Glycol distearate				1.5
Glycerol	1.4	4.9	4.9	-	1.4
						Sodium chloride	0.3	0.3	0.3	2.84	0.3
Sodium benzoate	0.25	0.25	0.25		0.25
						Disodiumedetate (Hampene A2/Dissolvine NA-2X)	0.13	0.13	0.13	0.05	0.13
1,3-dihydroxymethyl-5,5-dimethyl hydantoin	0.37	0.37	0.37	-	0.37
						DMDM Hydantoin (Lonza)	-	-	-	0.37	-
The red #30 Talcum of D﹠C color lake	-	-	-	0.05	-
						Citric acid	1.6	0.95	0.95	0.64	1.6
Titanium dioxide	0.5	0.5	0.5	-	0.5
						Spice	0.5	0.5	0.5	0.25	0.5
Water	In right amount	In right amount	In right amount	In right amount	In right amount
						Expancel 091-DE-40-D30	0.00001	0.00001	0.00001	0.000015	0.00001

(Expancel Corp.)
						Useful combined thing
Versagel MD 500	72.3	91.6	-	-	-
						Versagel ME 1600	-	-	-	72.3	-
Versagel MP 1600	-	-	96.0	-	-
						Versagel M1600	-	-	-	-	-
Spermol	5.0	-	-	5.0	-
						Stearyl alcohol	9.0	-	-	9.0	-
L-glutamic acid	1.3	-	-	1.3	-
						The amino propyl group dimethylamine of stearoyl	4.0	-	-	4.0	-
Polydimethylsiloxane blend (1)	8.4	84	-	8.4
						Polydimethylsiloxane (2)	-	-	-	-	100
Amino silicone	-	-	4.0	-	-
						The ratio of cleansing phase/useful phase	80/20	80/20	80/20	70/30	96/4

(1) 60% 0.00035m ²/ s (350 centistoke) and 40% 18m ²The polydimethylsiloxane fluid blend of/s (18,000,000 centistoke) is available from General Electric Silicones Products.

(2) high molecular polydimethylsiloxane, viscosity is about 0.3m ²/ s (300,000 centistoke).(available from DowCorning)

By at first obtaining the cleansing phase compositions that following pre-composition prepares embodiment 1,5 and 9: citric acid with the ratio of 1:3 in water premix, guar gum polymer and Jaguar C-17 and N-Hance 3196 premix, UCARE and JR-30M are with about 1:30 ratio premix in water in water with about 1:10 ratio, Polyox and PEG-90M and PEG-14M are with about 1:2 ratio premix in glycerol.Then, following ingredients is joined in the main mixer: ammonium lauryl sulfate, laureth-3 ammonium sulfate, citric acid pre-composition, Miranol L-32ultra, sodium chloride, sodium benzoate, disodiumedetate, lauric acid, Thixcin R, melon ear pre-composition, UCARE pre-composition, Polyox pre-composition, and the water of surplus.Then, stir this container of heating down, reach 88 ℃ (190 ℉) until it.It was mixed about 10 minutes.Cool off this batch of material with psychrolusia, slowly stir simultaneously, reach 43 ℃ (110 ℉) until it.Add following composition: 1,3-dihydroxymethyl-5,5-dimethyl hydantoin, spice, titanium dioxide.Stir, until forming homogeneous solution.

By at first obtaining the cleansing phase compositions that following pre-composition prepares embodiment 2 and 6: at water route premix, melon ear polymer and the N-Hance 3196 ratio premix in water with about 1:10, Polyox and PEG-14M are with about 1:2 ratio premix in glycerol with about 1:3 ratio for citric acid.Then, following composition is joined in the main mixer: ammonium lauryl sulfate, laureth-3 ammonium sulfate, citric acid pre-composition, Miranol L-32ultra, sodium chloride, sodium benzoate, disodiumedetate, lauric acid, Thixcin R, melon ear pre-composition, Polyox pre-composition, Polycare 133, Merquat Plus 3300, Monosil PLN, and the water of surplus.Then, stir this container of heating down, reach 88 ℃ (190 ℉) until it.Mixed about 10 minutes.Then, cool off this batch of material, slowly stir simultaneously, reach 43 ℃ (110 ℉) until it with psychrolusia.At last, add following ingredients: 1,3-dihydroxymethyl-5,5-dimethyl hydantoin, spice, titanium dioxide.Stir, until forming homogeneous solution.

By at first obtaining the cleansing phase that following pre-composition prepares embodiment 3 and 7: premix, melon ear polymer and N-Hance 3196 are with ratio premix in water of about 1:10 in water with about 1:3 ratio for citric acid, and Polyox and PEG-14M are with about 1:2 ratio premix in glycerol.Then, following composition is joined in the main mixer: ammonium lauryl sulfate, laureth-3 ammonium sulfate, citric acid pre-composition, Miranol L-32 ultra, sodium chloride, sodium benzoate, disodiumedetate, lauric acid, Thixcin R, melon ear pre-composition, Polyox pre-composition, Monasil PLN, and the water of surplus.Then, stir this container of heating down, reach 88 ℃ (190 ℉) until it.Mixed this container about 10 minutes.Then, cool off this batch of material, slowly stir simultaneously, reach 43 ℃ (110 ℉) until it with psychrolusia.At last, add following ingredients: 1,3-dihydroxymethyl-5,5-dimethyl hydantoin, spice, titanium dioxide.Stir, until forming homogeneous solution.

By at first obtaining the cleansing phase compositions that following pre-composition prepares embodiment 4 and 8: the siloxanes pre-composition in comprising the water of lauryl polyethenoxy ether sodium sulfate (10:1 ratio), the pre-composition (1:1 ratio) of the pre-composition of glycol distearate and ammonium lauryl sulfate (1:1 ratio) and citric acid and water.Add described composition in the following order: water, Nhance 3196, citric acid, Polycare133, Hampene, ammonium lauryl sulfate, Miracare SLB-365, lauric acid.Be heated to 150 ℃, and stirred 15 minutes, slowly cool to 60 ℃, add sodium chloride then, D﹠amp; The red #30 of C.When it reaches 40 ℃, add DMDM Hydantoin, between 5.8 and 6.2, add spice and siloxanes, and stirred 30 minutes with the Fructus Citri Limoniae acid for adjusting pH.The centrifugal back of this batch of material is added Expancel regulate density.

For the useful combined thing of preparation embodiment 1 to 4, the L-glutamic acid of the amino propyl group dimethylamine of water, stearoyl and about 50% is mixed in the temperature more than 70 ℃.Then, stir adding hard fat compounds of group and benzylalcohol down.Be cooled to below 60 ℃, stir the remaining L-glutamic acid of adding and other remaining ingredient down then, be cooled to about 30 ℃ then.

In the useful combined thing of embodiment 5 to 8, the suitable Versagel of weighing aequum is heated to 40 ℃ to 50 ℃ then to container, and the speed with 31.4-53 radian/s (300-500rpm) stirs simultaneously.Then, add other composition up to obtaining uniform mixture.

In the useful combined thing of embodiment 9, use the polydimethylsiloxane of generally acknowledging.

Although illustrated and described the present invention with specific embodiments, it will be apparent to those skilled in the art that many other variations and modifications may be made in the case of without departing from the spirit and scope of protection of the present invention.Therefore, in additional claims, comprise all such changes and modifications in the scope of the invention consciously.

The relevant portion of the document of all references is incorporated herein by reference in background of invention, summary of the invention and the detailed Description Of The Invention; The quoting and may not be interpreted as of any document to its approval as prior art of the present invention.

Claims (16)

1. multi phase personal care composition, described multi phase personal care composition comprises:

A. at least one cleansing phase and

B. at least one useful phase, described useful be selected from mutually aliphatic compound gel network, organophilic gel network and their combination, described aliphatic compound gel network comprises cationic surfactant and hard fat compounds of group and aqueous carrier, the mol ratio of wherein said surfactant and described hard fat compounds of group is 1:2 to 1:6, described organophilic gel network comprises the hydrophobic solvent with polymeric gellant thickening, and wherein said gellant is the combination of ethylene/propene/styrol copolymer and butylene/ethylene/styrene copolymer;

Wherein said cleansing phase with described useful be visually distinct phase mutually, they are packed in the actual contact mode, and the wherein said visually distinct pattern that forms mutually, described pattern is selected from striated, geometry, marble striped and their combination; And

Density contrast between wherein said cleansing phase and the described useful phase is less than 0.30g/cm ³, and keep stable.

2. multi phase personal care composition as claimed in claim 1, wherein said cleansing phase exists in the amount by the weight 1% to 85% of described compositions.

3. multi phase personal care composition as claimed in claim 1, wherein said cleansing phase exists in the amount by the weight 3% to 80% of described compositions.

4. multi phase personal care composition as claimed in claim 1, wherein said usefully exist in amount by the weight 1% to 95% of described compositions.

5. multi phase personal care composition as claimed in claim 1, wherein said usefully exist in amount by the weight 5% to 90% of described compositions.

6. multi phase personal care composition as claimed in claim 1, wherein said cleansing phase are the blend of tridecyl polyethenoxy ether sodium sulfate, lauryl both sexes sodium acetate and coconut oleoyl amine MEA.

7. multi phase personal care composition as claimed in claim 1, described compositions also comprises aqueous carrier.

8. multi phase personal care composition as claimed in claim 1, described compositions also comprises stability enhancer.

9. multi phase personal care composition as claimed in claim 8, wherein said stability enhancer are that thermoplasticity can be sent out microsphere.

10. multi phase personal care composition as claimed in claim 1, wherein said cleansing phase also comprises structuring reagent.

11. multi phase personal care composition as claimed in claim 1, described multi phase personal care composition also comprises annexing ingredient, and described annexing ingredient is selected from wetting agent, solute, water-soluble nonionic polymer, styling polymer, liquid aliphatic alcohol, fatty acid, cationic polymer conditioner, silicone conditioning agent, granule, crosslinked silicone elastomer, high alkylidene hydrocarbon and hair dye and dyestuff.

12. multi phase personal care composition as claimed in claim 1, the density contrast between wherein said cleansing phase and the described useful phase is less than 0.05g/cm ³

13. multi phase personal care composition as claimed in claim 1, wherein said cleansing phase, described useful phase or described cleansing phase are with described useful both visually are transparent mutually.

14. one kind is the method for hair or dermal delivery conditioning beneficial effect, said method comprising the steps of:

A) personal care composition as claimed in claim 1 with effective dose locally applies on described hair or the skin; With

B) by described compositions being removed from described hair or skin with water rinse.

15. one kind is the method for hair or dermal delivery Hairsetting beneficial effect, said method comprising the steps of:

A) personal care composition as claimed in claim 1 with effective dose locally applies on described hair or the skin; With

B) by described compositions being removed from described hair or skin with water rinse.

16. one kind is the method for hair and dermal delivery coloring hairs beneficial effect, said method comprising the steps of:

A) personal care composition as claimed in claim 1 with effective dose locally applies on described hair or the skin; With

B) by described compositions being removed from described hair or skin with water rinse.