CN100469414C - Method for producing a moisture-keeping fresh-keeping healthy material with Vitamin - Google Patents

Method for producing a moisture-keeping fresh-keeping healthy material with Vitamin Download PDF

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Publication number
CN100469414C
CN100469414C CNB2004100510405A CN200410051040A CN100469414C CN 100469414 C CN100469414 C CN 100469414C CN B2004100510405 A CNB2004100510405 A CN B2004100510405A CN 200410051040 A CN200410051040 A CN 200410051040A CN 100469414 C CN100469414 C CN 100469414C
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China
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vitamin
keeping
fresh
healthcare
manufacture method
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CNB2004100510405A
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CN1732788A (en
Inventor
程启进
佐野昌隆
小田岛贞雄
福田文夫
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Ceraft Inc
Nippon Frontier Industrial Co Ltd
Freudenberg Apollo Filtration Technologies Co Ltd
Taiyo Co Ltd
Original Assignee
Ceraft Inc
Nippon Frontier Industrial Co Ltd
Foshan Shunde Apollo Air Cleaner Co Ltd
Taiyo Co Ltd
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Priority to CNB2004100510405A priority Critical patent/CN100469414C/en
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Abstract

Disclosed is a method for producing a moisture-keeping fresh-keeping healthy material with Vitamin, which comprises applying functional substances such as vitamin C onto substrate of porous material, then appending adhesive of inorganic or organic compounds, metallic ions or metallic oxides. The obtained material has water resistance and heat resistance to aqueous vapor.

Description

The preserve moisture manufacture method of fresh-keeping and healthcare material of a kind of vitamin
Technical field
The present invention relates to the preserve moisture manufacture method of fresh-keeping and healthcare material of a kind of vitamin.More specifically to preserve moisture the longer manufacture method of material of fresh-keeping and healthcare of machinery equipments such as refrigerator, air-conditioning, air cleaner, humidifier at normal temperatures.
Background technology
At present, people utilize vitamin C as healthy tonic, pharmaceuticals, cosmetics, underwear or the like always, can drink, can eat, can be coated on the health, can be through on the health and use, and these utilize method is the direct method of utilizing absorbed by the body.And in the refrigerator inside of family, commercial usefulness, mainly be in places such as fruit and vegetable casees, keep freshness with the anion that takes place, with metallic elements such as active carbon or Yong Ba Manganese iron or with natural materials such as catechin wych-elm dish rosemary,, make deodoring materials and remove ethene, methyl mercaptan, trimethylamine etc., can make vegetables, fruit, the flesh of fish etc. can not reduce freshness and oxidation deterioration.And conducts such as air-conditioning, air cleaner, humidifier improve the means of indoor environment, have mainly adopted methods such as generating negative ions, the mist that sprays particulate, corona discharge, ultrasonic wave humidification, have also adopted active carbon, catechin, wych-elm dish etc. as deodoring materials.The problem that above method exists is: 1, the ascorbic fields of existing use such as healthy tonic, pharmaceuticals, cosmetics do not have vitality, one-shot effect.2, the ascorbic acid inductor that adopted such as cosmetics is that magnesium salts, the sodium salt with phosphate is the material of representative, and the long-time stability of these materials had only about several months.3, in esse vitamin C material is soluble in water, and heat resistance is very poor, will divide to take off, dissolve use that cannot be long-term in the steam under the heat of humidifier at once.And vitamin is preserved moisture the fresh-keeping and healthcare material when using as the filter of room conditioning or air cleaner, and discharge the air that contains vitamin, can be in indoor non-oxidizability, moistening effects etc. have this report on the one hand of effect that improves environment but not see.
Summary of the invention
Technical problem to be solved by this invention is to overcome existing deficiency and the manufacture method that provides a kind of manufacture method is simple, technology is easy, the fresh-keeping and healthcare of preserving moisture is effective vitamin to preserve moisture the fresh-keeping and healthcare material.
The present invention can take following technical measures to solve:
A kind of vitamin fresh-keeping and healthcare material of preserving moisture, be on the porous material base material, with cooperating more than a kind or 2 kinds of function vitamin substances such as vitamin C, add more than a kind or 2 kinds of binding of inorganic or organic compound then, add more than a kind or 2 kinds of metal ion or metal oxide.
The above-mentioned vitamin employed vitamin substances of fresh-keeping and healthcare material of preserving moisture mainly is a vitamin C, and ascorbic raw material mainly has been to use the L-ascorbic acid.And auxiliary material mainly is insoluble L-ascorbic acid inductor, and this inductor is meant phosphoric acid and polyphosphate or its metal ester salt.These metal ester salt refer to magnesium, sodium, potassium, calcium, aluminium, iron etc.Vitamin is preserved moisture in the vitamin ingredients in the fresh-keeping and healthcare material except vitamin C, also comprises vitamin D, vitamin E etc.The raw material of vitamin has catechin in green tea, the green tea, the catechin in the persimmon, STEVIA REBAUDIANA or the like.Use the solution that is prepared into more than a kind or 2 kinds of these compositions to be fixed on the surperficial and inner of porous material with methods such as immersion, plating, chemical platings.
Above-mentioned porous material, such as having absorptive material, ceramic material, natural synthetic fibers, paper pulp material etc., ceramic material mainly comprises silicon, aluminium, magnesium, titanium, zirconic single oxide, also has zeolite, Ban Shiyan, sepiolite, attapulgite, sillimanite, kaolin, sericite, diatomite, feldspar, frog order clay, ripple to come silicate compounds such as soil, vermiculite.Natural material then comprises paper pulp fiber, silk floss, wool fiber, flaxen fiber etc.Comprise then that as for synthetic material these materials such as nylon, staple fibre, aminomethyl ester (comprising polyurethane), propylene, polyethylene, polypropylene are as base material.The shape of porous body comprises ojosa, these representative shape of fluxion structure, other tubulose, sheet, rugosity or the like in addition.
About inorganic or organic compound: inorganic compound comprises lithium metasilicate, potassium silicate, sodium metasilicate, zirconium silicate, calcium silicates, alumina silicate, ethyl silicic acid, silica gel, contain silicate such as char combustion silicon, also has phosphate such as phosphoric acid, polyphosphoric acid, super polyphosphoric acid, aluminum phosphate, calcium phosphate, magnesium phosphate.Then comprise methylcellulose, carboxy methyl cellulose, polyvinyl alcohol, ammonia ester emulsion, acrylic acid emulsion, acetate emulsion or the like as for organic compound.Use a kind of of these inorganic or organic compounds or more than 2 kinds.
The function vitamin substances is fixed on the porous material with the binding of inorganic or organic compound, and mixing more than a kind or 2 kinds of metal ion or metal oxide disperseed.
The vitamins composition has the feature of dissolving in the pre-prepd inorganic and organic compound aqueous solution.When the adding rate of the ratio of the composition of selecting vitamins and inorganic and organic compound and metal and metal oxide, according to the difference of use and difference.
Effect of the present invention is:
1, a kind of vitamin of the present invention fresh-keeping and healthcare material of preserving moisture can be in refrigerator, the boxlike part of air-conditioning, air cleaner, humidifier etc. and using above filter, the fan etc.Vegetables in the refrigerator, fruit, the flesh of fish etc. can not gone bad because of oxidation keep freshness deodorizing antibiotic or the like; Can make air-conditioning, air cleaner, humidifier etc. long-term discharge the moistening air that contains vitamin, have non-oxidizability, preserve moisture, deodorizing, aspect such as antibiotic have the effect of improving environment, prevents xerodermatic effect.
2, the vitamin of the present invention fresh-keeping and healthcare material of preserving moisture has resistance to water, the hear resistance of steam, and long-time stability, thereby use porous material as preparing base material in advance, thus make it keep long-term effect.
3, disperseed mixing more than a kind or 2 kinds of metal ion or metal oxide, make it have the effect of mildew-resistant.
The specific embodiment
Embodiment 1
Adjust 55-75 parts of the sepiolite clay of granularity below 325 orders, adjust the cordierite of granule size below 200 orders, 3-8 parts of dry types of methylcellulose are mixed; Add 30-50 parts of Ludox, 10-35 parts of wet types of water are mixing, join then in the vacuum soil refining machine, add and load onto cellular mould extrusion molding.Then at 20-25 ℃, humidity is to place 10-24 hour in 75-85% the no air compartment, ℃ ends from normal temperature to 110 then, with the speed heat drying of 5 ℃ of per minutes.After dry with burning till water absorption rate at about 25%-35% ceramic porous article with 800-1100 ℃ in general electric furnace or the combustion gas kiln.
The vitamin C raw material is 40-100 parts of 20%-40% phosphoric acid solutions, 5-20 parts in ascorbic acid, in 1-3 parts of the magnesium ascorbyl phosphate fully stirring and dissolving be made into the aqueous solution, then the ceramic honey comb base material was flooded one hour in above-mentioned solution, take out the back 90-120 parts of 30%-50% Ludox, 3-5 parts of ethanol, dipping is 5 seconds in 0.5 part of solution that is made into of silver, taking out fast then, is in 70 ℃-100 ℃ the vacuum drier dry about 4-6 hours at design temperature.Then from drying machine, take out cellular material and move in the hydrogen furnace, 100-180 ℃ of following sintering 1-5 hours to make vitamin function material.
Embodiment 2
Staple fibre or the various types of absorptive material that has like paper wood are processed with Foldable device, made it have undulatory structure, and by playing glue or other form support makes it have fixed shape, so that it can be installed on the machinery equipment.
With 70-120 parts of 20-50% phosphoric acid solutions, 10~30 parts of vitamin C raw materials, in 1-10 parts of the L-magnesium ascorbyl phosphate fully stirring and dissolving be made into the vitamin aqueous solution.
To have rugosity ripple staple fibre or the various types of absorptive material that has like paper wood is placed on and flooded in the vitamin solution 0.5-5 hours, take out the back 90-120 parts of 30-50% Ludox, 3-5 parts of ethanol, flooded 5-20 seconds in 0.5-3 parts of synthetic solution of silver, taking out fast then, is in 70-100 ℃ the vacuum drier dry 4-6 hours at design temperature.
Using method:
The vitamin of making is preserved moisture the fresh-keeping and healthcare material according to refrigerator, air-conditioning, air cleaner, machinery equipments such as humidifier require to be processed into filter or appurtenances use.

Claims (8)

1, a kind of vitamin manufacture method of fresh-keeping and healthcare material of preserving moisture, it is characterized in that: be on porous mortgage material base material, with cooperating more than a kind or 2 kinds of function vitamin substances, add more than a kind or 2 kinds of binding of inorganic or organic compound then, add being made more than a kind or 2 kinds of metal ion with mildew-resistant effect or metal oxide.
2, a kind of vitamin according to claim 1 manufacture method of fresh-keeping and healthcare material of preserving moisture, it is characterized in that: the vitamin employed vitamin substances of fresh-keeping and healthcare material of preserving moisture, it mainly is vitamin C, also comprise the vitamin inductor that contains equal composition, use the solution that is prepared into more than a kind or 2 kinds of these compositions to be fixed on the surperficial and inner of porous material with arbitrary method in immersion, plating, the chemical plating method, vitamin substances also comprises vitamin D, vitamin E except vitamin C.
3, a kind of vitamin according to claim 1 manufacture method of fresh-keeping and healthcare material of preserving moisture, it is characterized in that: porous material is ceramic material, natural or synthetic fibers, paper pulp material, these materials are as base material, the shape of porous material comprises ojosa, these representative shape of fluxion structure, other tubulose, sheet, rugosity in addition.
4, a kind of vitamin according to claim 1 manufacture method of fresh-keeping and healthcare material of preserving moisture is characterized in that: about inorganic or organic compound: inorganic compound is silicic acid, phosphate; Organic compound is methylcellulose, polyvinyl alcohol, polyurethane emulsion.
5, a kind of vitamin according to claim 1 manufacture method of fresh-keeping and healthcare material of preserving moisture, it is characterized in that: the function vitamin substances is fixed on the porous material with the binding of inorganic or organic compound, and mixing more than a kind or 2 kinds of metal ion or metal oxide disperseed.
6, a kind of vitamin according to claim 1 manufacture method of fresh-keeping and healthcare material of preserving moisture is characterized in that; The adding rate of the ratio of the composition of vitamins and inorganic or organic compound and metal or metal oxide is according to the difference of use and difference.
7, a kind of vitamin according to claim 2 manufacture method of fresh-keeping and healthcare material of preserving moisture, it is characterized in that: above-mentioned vitamin C raw material is to get 40-100 parts of 20%-40% phosphoric acid solutions, 5-20 parts in ascorbic acid, 1-3 parts of abundant stirring and dissolving of magnesium ascorbyl phosphate are made into the aqueous solution.
8, a kind of vitamin according to claim 1 manufacture method of fresh-keeping and healthcare material of preserving moisture, it is characterized in that: the binding of above-mentioned inorganic or organic compound and metal ion or metal oxide are to get 90-120 parts of 30%-50% Ludox, 3-5 parts of ethanol, 0.5 part of solution that is made into of silver.
CNB2004100510405A 2004-08-11 2004-08-11 Method for producing a moisture-keeping fresh-keeping healthy material with Vitamin Active CN100469414C (en)

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CN100469414C true CN100469414C (en) 2009-03-18

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007009342A1 (en) * 2005-07-19 2007-01-25 Haier Group Corporation A refigerator and freshness maintaining method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5360145A (en) * 1992-07-21 1994-11-01 L'oreal Dispenser for at least one liquid or pasty product comprising a closure system that allows no ingress of air, and preservation process using the said dispenser
US5393809A (en) * 1992-07-21 1995-02-28 L'oreal Polymeric synthetic material which has an antiseptic and/or antioxidant action and process for the manufacture of the said material
JP2925625B2 (en) * 1990-02-15 1999-07-28 クラレケミカル株式会社 Air purification filter
CN2497215Y (en) * 2001-08-29 2002-06-26 广东科龙电器股份有限公司 Air conditioner with air-purifying function
CN2565520Y (en) * 2002-07-10 2003-08-13 广东科龙电器股份有限公司 High efficient air purifier filtering net
CN2615562Y (en) * 2003-02-26 2004-05-12 上海欣誉净化设备有限公司 Nano-laminated filtering domestic air purifier
CN1509794A (en) * 2002-12-23 2004-07-07 ���ǵ�����ʽ���� Filter of applied carbon nanometer tube

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2925625B2 (en) * 1990-02-15 1999-07-28 クラレケミカル株式会社 Air purification filter
US5360145A (en) * 1992-07-21 1994-11-01 L'oreal Dispenser for at least one liquid or pasty product comprising a closure system that allows no ingress of air, and preservation process using the said dispenser
US5393809A (en) * 1992-07-21 1995-02-28 L'oreal Polymeric synthetic material which has an antiseptic and/or antioxidant action and process for the manufacture of the said material
CN2497215Y (en) * 2001-08-29 2002-06-26 广东科龙电器股份有限公司 Air conditioner with air-purifying function
CN2565520Y (en) * 2002-07-10 2003-08-13 广东科龙电器股份有限公司 High efficient air purifier filtering net
CN1509794A (en) * 2002-12-23 2004-07-07 ���ǵ�����ʽ���� Filter of applied carbon nanometer tube
CN2615562Y (en) * 2003-02-26 2004-05-12 上海欣誉净化设备有限公司 Nano-laminated filtering domestic air purifier

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Addressee: Huang Peixian

Document name: patent for invention