CN100462399C - 一种透明聚丙烯的制备方法 - Google Patents
一种透明聚丙烯的制备方法 Download PDFInfo
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- CN100462399C CN100462399C CNB2006100974127A CN200610097412A CN100462399C CN 100462399 C CN100462399 C CN 100462399C CN B2006100974127 A CNB2006100974127 A CN B2006100974127A CN 200610097412 A CN200610097412 A CN 200610097412A CN 100462399 C CN100462399 C CN 100462399C
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- polypropylene
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- -1 polypropylene Polymers 0.000 title claims abstract description 45
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 36
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 38
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 20
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- 238000005469 granulation Methods 0.000 claims abstract description 3
- 230000003179 granulation Effects 0.000 claims abstract description 3
- 239000003112 inhibitor Substances 0.000 claims description 33
- 230000003647 oxidation Effects 0.000 claims description 33
- 238000007254 oxidation reaction Methods 0.000 claims description 33
- 239000008188 pellet Substances 0.000 claims description 28
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 28
- 239000000843 powder Substances 0.000 claims description 28
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 23
- NFWKVWVWBFBAOV-MISYRCLQSA-N dehydroabietic acid Chemical compound OC(=O)[C@]1(C)CCC[C@]2(C)C3=CC=C(C(C)C)C=C3CC[C@H]21 NFWKVWVWBFBAOV-MISYRCLQSA-N 0.000 claims description 20
- QUUCYKKMFLJLFS-UHFFFAOYSA-N Dehydroabietan Natural products CC1(C)CCCC2(C)C3=CC=C(C(C)C)C=C3CCC21 QUUCYKKMFLJLFS-UHFFFAOYSA-N 0.000 claims description 17
- NFWKVWVWBFBAOV-UHFFFAOYSA-N Dehydroabietic acid Natural products OC(=O)C1(C)CCCC2(C)C3=CC=C(C(C)C)C=C3CCC21 NFWKVWVWBFBAOV-UHFFFAOYSA-N 0.000 claims description 17
- 229940118781 dehydroabietic acid Drugs 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 10
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 4
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000019359 magnesium stearate Nutrition 0.000 claims description 3
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 claims description 3
- 229940078456 calcium stearate Drugs 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 claims description 2
- 229940057948 magnesium stearate Drugs 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 229940114930 potassium stearate Drugs 0.000 claims description 2
- 229940080350 sodium stearate Drugs 0.000 claims description 2
- 239000002253 acid Substances 0.000 abstract description 19
- 150000007513 acids Chemical class 0.000 abstract description 17
- 238000000034 method Methods 0.000 abstract description 16
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 14
- 239000000194 fatty acid Substances 0.000 abstract description 14
- 229930195729 fatty acid Natural products 0.000 abstract description 14
- 239000011347 resin Substances 0.000 abstract description 5
- 229920005989 resin Polymers 0.000 abstract description 5
- 238000011065 in-situ storage Methods 0.000 abstract description 4
- 239000003963 antioxidant agent Substances 0.000 abstract description 2
- 230000003078 antioxidant effect Effects 0.000 abstract description 2
- 239000002667 nucleating agent Substances 0.000 abstract 2
- 238000004383 yellowing Methods 0.000 abstract 1
- 239000003595 mist Substances 0.000 description 30
- 238000005453 pelletization Methods 0.000 description 26
- 230000000052 comparative effect Effects 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- ZRIHAIZYIMGOAB-UHFFFAOYSA-N butabarbital Chemical compound CCC(C)C1(CC)C(=O)NC(=O)NC1=O ZRIHAIZYIMGOAB-UHFFFAOYSA-N 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010023126 Jaundice Diseases 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011575 calcium Chemical group 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000011777 magnesium Chemical group 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011591 potassium Chemical group 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000011734 sodium Chemical group 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000011701 zinc Chemical group 0.000 description 1
- 229910052725 zinc Chemical group 0.000 description 1
Images
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
雾度(%) | 光泽度(%) | 拉伸强度(MPa) | 弯曲模量(MPa) |
实施例1 | 10.5 | 133.2 | 40.85 | 1609.9 |
2 | 12.3 | 134.6 | 40.71 | 1791.3 |
3 | 9.9 | 138.9 | 39.14 | 1763.8 |
4 | 9.4 | 139.8 | 39.39 | 1721.1 |
5 | 7.5 | 143.7 | 39.34 | 1755.4 |
6 | 7.6 | 141.7 | 39.73 | 1758.5 |
对比例1 | 45.4 | 103.4 | 37.22 | 1204.6 |
2 | 49.6 | 103.3 | 46.19 | 1218.3 |
3 | 42.5 | 105.9 | 38.28 | 1268.6 |
雾度(%) | 光泽度(%) | 拉伸强度(MPa) | 弯曲模量(MPa) | |
实施例7 | 37.4 | 102.9 | 37.25 | 1904.0 |
8 | 16.7 | 117.9 | 44.35 | 1435.5 |
9 | 17.3 | 120.2 | 36.56 | 1501.0 |
10 | 16.1 | 122.2 | 36.50 | 1512.4 |
雾度(%) | 光泽度(%) | 拉伸强度(MPa) | 弯曲模量(MPa) | |
实施例11 | 41.6 | 102.8 | 40.43 | 1361.1 |
12 | 41.4 | 103.1 | 36.31 | 1403.4 |
13 | 36.5 | 110.6 | 40.37 | 1254.9 |
14 | 32.9 | 114.3 | 37.58 | 1632.8 |
雾度(%) | 光泽度(%) | 拉伸强度(MPa) | 弯曲模量(MPa) | |
实施例15 | 10.8 | 129.2 | 41.29 | 1328.8 |
16 | 6.1 | 140.0 | 40.00 | 1359.3 |
17 | 7.9 | 137.5 | 38.95 | 1429.3 |
18 | 12.3 | 127.05 | 39.51 | 1113.9 |
对比例4 | 30.4 | 113.3 | 39.92 | 875.5 |
5 | 34.0 | 108.2 | 38.19 | 999.7 |
6 | 44.6 | 101.6 | 35.77 | 1043.8 |
7 | 28.0 | 111.5 | 38.76 | 928.0 |
Claims (6)
Priority Applications (1)
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CNB2006100974127A CN100462399C (zh) | 2006-11-07 | 2006-11-07 | 一种透明聚丙烯的制备方法 |
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CNB2006100974127A CN100462399C (zh) | 2006-11-07 | 2006-11-07 | 一种透明聚丙烯的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1948382A CN1948382A (zh) | 2007-04-18 |
CN100462399C true CN100462399C (zh) | 2009-02-18 |
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CNB2006100974127A Expired - Fee Related CN100462399C (zh) | 2006-11-07 | 2006-11-07 | 一种透明聚丙烯的制备方法 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101168609B (zh) * | 2007-09-30 | 2010-05-19 | 广州市合诚化学有限公司 | β成核剂改性无规共聚聚丙烯管材专用料及其制备方法 |
CN103030886B (zh) * | 2012-12-20 | 2014-11-26 | 中国石油天然气股份有限公司 | 一种透明聚丙烯及其制备方法 |
CN111187577A (zh) * | 2020-02-26 | 2020-05-22 | 江苏斯迪克新材料科技股份有限公司 | 可弯折柔性屏保护膜及其制备方法 |
CN111171742A (zh) * | 2020-02-26 | 2020-05-19 | 江苏斯迪克新材料科技股份有限公司 | 折叠屏用可弯折保护膜及其制备方法 |
CN116253950A (zh) * | 2023-01-05 | 2023-06-13 | 科邦石化(连云港)有限公司 | 一种高透明的生物可降解聚丙烯的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10273569A (ja) * | 1997-03-28 | 1998-10-13 | Grand Polymer:Kk | ポリプロピレン系樹脂組成物 |
CN1198766A (zh) * | 1996-08-08 | 1998-11-11 | 新日本理化株式会社 | 松香基分子晶体,聚烯烃树脂用成核剂与聚烯烃树脂组合物及其模塑件 |
CN1415655A (zh) * | 2001-11-02 | 2003-05-07 | 中国科学院化学研究所 | 一种透明聚丙烯的制备方法 |
JP2004231584A (ja) * | 2003-01-31 | 2004-08-19 | Arakawa Chem Ind Co Ltd | 樹脂酸組成物の製造方法、結晶性熱可塑性樹脂用結晶核剤、および結晶性熱可塑性樹脂組成物 |
-
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- 2006-11-07 CN CNB2006100974127A patent/CN100462399C/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1198766A (zh) * | 1996-08-08 | 1998-11-11 | 新日本理化株式会社 | 松香基分子晶体,聚烯烃树脂用成核剂与聚烯烃树脂组合物及其模塑件 |
JPH10273569A (ja) * | 1997-03-28 | 1998-10-13 | Grand Polymer:Kk | ポリプロピレン系樹脂組成物 |
CN1415655A (zh) * | 2001-11-02 | 2003-05-07 | 中国科学院化学研究所 | 一种透明聚丙烯的制备方法 |
JP2004231584A (ja) * | 2003-01-31 | 2004-08-19 | Arakawa Chem Ind Co Ltd | 樹脂酸組成物の製造方法、結晶性熱可塑性樹脂用結晶核剤、および結晶性熱可塑性樹脂組成物 |
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Assignee: NANJING HONGRUI PLASTIC PRODUCTS Co.,Ltd. Assignor: Nanjing Tech University Contract fulfillment period: 2009.2.19 to 2014.2.18 Contract record no.: 2009320001522 Denomination of invention: Preparation method of transparent polypropylene Granted publication date: 20090218 License type: Exclusive license Record date: 20090813 |
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