CN100441343C - Hard alloy vacuum extrusion molding agent and its prepn process - Google Patents

Abstract

The present invention relates to a hard alloy vacuum extrusion molding agent and a preparing method thereof. Components of the molding agent comprise 6 to 10 weight portions of ethyl cellulose, 3 to 7 weight portions of tetralin and 0.01 to 0.04 weight portions of oleic acid which are stirred 5 to 20 minutes at room temperature after dosed and is heated to 30 DEG to 100 DEG, and the molding agent can be manufactured by stirring 15 minutes to 30 minutes. The molding agent can be mixed with carbide W-Co alloy powder thereafter, and hard alloy finished goods can be manufactured by publicly known work procedures and conditions of vacuum extrusion, natural air drying, baking and sinter-roasting. The present invention eliminates a wax component and replaces an imported soybean amine component by domestic oleic acid, can effectively lower the sensitivity of wax to temperature in the process of hard alloy vacuum extrusion molding, is favorable to blank pressing molding, and shortens the period of natural air drying, the first-time qualification rate of the hard alloy can be increased to over 70%, and the length of products is not limited. The present invention has the characteristics of convenient and simple preparation process, fewer devices, low price, easy purchase, high productive efficiency and low cost; furthermore, the raw material is domestically produced.

Description

Hard alloy vacuum extrusion molding agent and preparation method thereof

One. technical field

The present invention relates to the carbide alloy technical field, especially a kind of hard alloy vacuum extrusion molding agent and preparation method thereof.

Two. background technology

The quality of hart metal product quality and the prescription of forming agent have very big relation.General CEMENTED CARBIDE PRODUCTION is to adopt compression molding technology, promptly when compression molding, add rubber or paraffin as forming agent, because contaminating impurity is bigger in the wayward alloy carbon of this class forming agent, the glue, so usually cause dirtyization of carbide alloy, intensity is low, labor productivity is not high, be difficult to the high-quality product of output, with regard to specification, only can bar and length more than the output diameter ￠ 4mm be restricted.

For addressing the above problem, various researchs are all being carried out, and adopt the hard alloy vacuum extrusion molding technology to become the new lover.This technology is that vacuum extrusion molding agent and Wc-Co alloys powder are added extruder material cylinder, vacuumize, extruding, natural air drying, oven dry, sintering circuit form, not only can raise labour productivity significantly, product quality is also more stable, can also output such as high gear products such as little brill, fluted drill, slotting cutter, screw-on cutters, with regard to specification, product length is not limit, can output the I of diameter reach the bar of ￠ 0.6mm.But the vacuum extrusion molding agent of states such as Japan, Sweden is still based on paraffin, thereby exist the technology pressed compact natural air drying time to need more than the week inevitably, and will be under 1200 temperature pre-burning 12 hours, yet paraffin can be separated out in solution at a lower temperature, cause bar carbon skewness, sintering to shrink inconsistent, alloy bar material is flexible, and first-time qualification rate is low, so there are problems such as labor productivity is lower, energy resource consumption is big, percent defective height.The vacuum extrusion molding agent of the U.S. is made up of four kinds of components, be cellulose, soybean amine, naphthane, paraffin composition, though can raise labour productivity preferably, reduce energy resource consumption, first-time qualification rate can bring up to 50%, but because it still contains paraffinic components, actual effect is also unsatisfactory, adds four kinds of component price height that this state produces, also be difficult to import when other countries use, usually do not go up and influence ordinary production owing to raw material supply.

Three. summary of the invention

The object of the present invention is to provide a kind of hard alloy vacuum extrusion molding agent and preparation method thereof, can realize localization of raw material, can raise labour productivity with product quality again, reduce cost and energy resource consumption.

For reaching this purpose, the present invention mainly finishes in the following way:

1. hard alloy vacuum extrusion molding agent, it is to be made by the component of following composition weight proportioning: as the component of binding agent select for use ethyl cellulose, as the component of solvent select for use naphthane, as lubricant component select oleic acid for use, the weight proportion of each component is: 6～10 parts of component ethyl celluloses, 3～7 parts of component naphthanes, 0.01～0.4 part of component oleic acid.

2. the method for preparing above-mentioned hard alloy vacuum extrusion molding agent comprises the processing step and the condition of following order:

A. batching is poured component ethyl cellulose, component naphthane and component oleic acid into container in proportion and is mixed;

B. stir, stirred under the room temperature 5～20 minutes;

C. add thermal agitation, be heated to 30～100 ℃, stirred the output forming agent 15～30 minutes.

Component ethyl cellulose, component naphthane and the component oleic acid that can be used as forming agent of the present invention all is the production domesticization raw material that market is easily purchased.For avoiding the component ethyl cellulose inhomogeneous, component naphthane and component oleic acid should be liquid.

The container of the usefulness that is mixed and the electromagnetic oven of heating also are equipment conventional, that easily purchase.Equipment also should be controlled parameter such as temperature, time and guarantee that forming agent mixes when using, help further and the moulding of Wc-Co alloys powder, and final production goes out hard alloy finished product.

Advantage of the present invention:

1. eliminate paraffinic components and, change four kinds of components of forming agent into three kinds of components, make the forming agent cost reduce by 40% approximately with the soybean amine component of homemade oleic acid substituting import one.

2. ethyl cellulose, naphthane, oleic acid all domesticize, originate wide, inexpensive, easily purchase, save foreign exchange.

3. owing to eliminated paraffin, institute so that in the hard alloy vacuum extrusion molding process sensitiveness reduction to temperature more help moulding, first-time qualification rate can be brought up to more than 70%.

4. natural air drying time weak point has improved production efficiency.

5. the technology of preparation forming agent is simple, equipment is few.

Four. description of drawings

The concrete grammar and the equipment of invention are provided by the following drawings.

Fig. 1 is preparation forming agent and the hard alloy vacuum extrusion molding process chart that proposes according to the present invention.

Each sign expression in the accompanying drawing:

1. ethyl cellulose 2. naphthanes 3. oleic acid 4. forming agents 5. Wc-Co alloys powder 6. are mixed Wc-Co alloys powder 7. pressed compacts 8. carbide alloy semi-finished product 9. hard alloy finished product of forming agent

The present invention is described in further detail below in conjunction with accompanying drawing.

Five. the specific embodiment

Shown in Fig. 1 leading portion, hard alloy vacuum extrusion molding agent, it is to be made by the component of following composition weight proportioning: as the component 1 of binding agent, as the component 2 of solvent, as the component 3 of lubricant, component 1 is a kind of ethyl cellulose, component 2 is a kind of naphthane, component 3 is a kind of oleic acid, and the weight proportion of each component is: component 1 is that 6～10 parts, component 2 are that 3～7 parts, component 3 are 0.01～0.4 part.

Hard alloy vacuum extrusion molding agent, the further preferred weight proportioning of each component are that component 1 is that 7～8 parts, component 2 are that 5～6 parts, component 3 are 0.05～0.2 part.

The method for preparing above-mentioned hard alloy vacuum extrusion molding agent comprises the process and the process conditions of following order:

A. batching is poured component 1, component 2 and component 3 into container in proportion and is mixed;

B. stir, stirred under the room temperature 5～20 minutes;

C. add thermal agitation, be heated to 30～100 ℃, stirred output forming agent 4 15～30 minutes.

The operation of preparation hard alloy vacuum extrusion molding agent and further preferred processing condition: at room temperature stirred after the batching 18～25 minutes, and be heated to 40～60 ℃ again, stirred output forming agent 4 20～25 minutes.

Behind Fig. 1, shown in the hypomere frame of broken lines, hard alloy vacuum extrusion molding technology is known process and condition, be about to prepare described forming agent 4 and mix the back discharging with Wc-Co alloys powder 5 input blenders, the Wc-Co alloys powder 6 that to the mix forming agent extruder of packing into, squeeze out pressed compact 7 after vacuumizing, at room temperature use 3～7 day time natural air drying, air-dry pressed compact 7 is dried again, 4 volatilizations of part forming agent, output carbide alloy semi-finished product 8, at last carbide alloy semi-finished product 8 are carried out sintering, 4 volatilizations of remainder forming agent, output hard alloy finished product 9.

Following table is forming agent formulation examples of the present invention and effect contrast thereof

Example one to 13 all is to carry out under same preparation forming agent that the present invention proposes and hard alloy vacuum extrusion molding process and process conditions in the table, and wherein: example one to seven is most preferred embodiments, and example eight to 13 is better embodiment.Described material is meant the Wc-Co alloys powder 6 of mixing forming agent.

Many group comparative experimental example

Operation and process conditions are only fixed two kinds of components with example one to 13 in turn in described three kinds of components, another component is carried out dosage test, adjust the test example successively and compare, and draw the routine conclusion of following test and eliminate:

The ethyl cellulose weight proportion is higher than 10 parts, expect too dried, can't moulding, very easily split; The ethyl cellulose weight proportion is lower than 6 parts, and adhesion strength is poor, extrudes often and breaks, and often produces crackle in length and breadth.

The naphthane weight proportion is higher than 7 parts, expect too rare, can't moulding, very easily fracture; The naphthane weight proportion is lower than 3 parts, expect too rare, can't moulding.

The oleic acid weight proportion is higher than 0.4 part, expect too rare, can't moulding, very easily fracture; The oleic acid weight proportion is lower than 0.01 part, and lubricity is bad, very easily produces crackle in length and breadth.

Claims (4)

1. hard alloy vacuum extrusion molding agent, it is characterized in that it is to be made by following components in weight percentage: as the component (1) of binding agent, as the component (2) of solvent, as the component (3) of lubricant, component (1) is a kind of ethyl cellulose, component (2) is a kind of naphthane, and component (3) is a kind of oleic acid

The weight proportion of each component is: (1) 6～10 part of component, (2) 3～7 parts of components, (3) 0.01～0.4 parts of components.

2. hard alloy vacuum extrusion molding agent according to claim 1, the weight proportion that it is characterized in that described each component are (1) 7～8 part of component, (2) 5～6 parts of components, (3) 0.05～0.2 parts of components.

3. the method for preparing claim 1 or 2 described hard alloy vacuum extrusion molding agents is characterized in that this method comprises the process and the process conditions of following order:

A. batching is poured component (1), component (2) and component (3) into container in proportion and is mixed;

B. stir, stirred under the room temperature 5～20 minutes;

C. add thermal agitation, be heated to 30～100 ℃, stirred output forming agent (4) 15～30 minutes.

4. the method for preparing claim 1 or 2 described hard alloy vacuum extrusion molding agents is characterized in that this method comprises the process and the process conditions of following order:

A. batching is poured component (1), component (2) and component (3) into container in proportion and is mixed;

B. stir, stirred under the room temperature 8～15 minutes;

C. add thermal agitation, be heated to 40～60 ℃, stirred output forming agent (4) 20～25 minutes.

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