CN100426561C - Battery with vibration-resistant joint between positive electrode and current carrying strap - Google Patents

Battery with vibration-resistant joint between positive electrode and current carrying strap Download PDF

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Publication number
CN100426561C
CN100426561C CNB038143100A CN03814310A CN100426561C CN 100426561 C CN100426561 C CN 100426561C CN B038143100 A CNB038143100 A CN B038143100A CN 03814310 A CN03814310 A CN 03814310A CN 100426561 C CN100426561 C CN 100426561C
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CN
China
Prior art keywords
positive plate
battery
plate
positive
outstanding tab
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Expired - Lifetime
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CNB038143100A
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Chinese (zh)
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CN1663062A (en
Inventor
R·J·奈特
D·克维尔
A·C·罗恩斯
R·库里安
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Enersys European Holding Co
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Enersys European Holding Co
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Publication of CN1663062A publication Critical patent/CN1663062A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • H01M10/128Processes for forming or storing electrodes in the battery container
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/533Electrode connections inside a battery casing characterised by the shape of the leads or tabs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/534Electrode connections inside a battery casing characterised by the material of the leads or tabs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/54Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
    • H01M50/541Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges for lead-acid accumulators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49108Electric battery cell making

Abstract

A method of manufacturing a battery includes as an initial step providing a cell for a battery having alternating positive and negative electrode plates, wherein each of the electrode plates is separated by an electrically insulative separator layer. Each of the positive and negative electrode plates includes a projecting tab extending from an adjacent upper portion thereof, the projecting tabs of the positive plates being generally aligned, and the projecting tabs of the negative plates being generally aligned. Next, the method comprises attaching a conductive connecting strap to the projecting tabs of the positive and negative plates. The method then comprises applying a cap material onto the connecting positive strap and allowing the cap material to spread and drip to the exposed portions of the projecting tabs and the adjacent upper portions of the negative and positive plates and separator material. The cap material is allowed to harden to provide a cap attached to the projecting tabs and the adjacent upper portions of the positive plates and negative plates and separator material.

Description

Between anodal and current-carrying band, has the battery that antivibration is connected
Technical field
The present invention relates generally to battery, and is particularly related to lead-acid battery.
Background technology
Typical battery comprises one or more electrochemical cell that are electrically connected and provide to battery electric power at inside battery.These battery units generally comprise four kinds of basic modules: receive the positive pole (negative electrode when anode during charging and discharge) from the electronics of external circuit when battery unit discharges; When discharging, battery unit discharges the negative pole (anode when negative electrode during charging and discharge) of electronics to external circuit; The electrolyte (being present in usually in solution or the pastel) that provides a kind of mechanism that electric charge is flowed between positive pole and negative pole; And the one or more dividing plates that make positive pole and negative electricity insulation.Because the electrochemical relationship between these assemblies makes this structure can make battery unit produce electric energy.In case the generation electric current, electric current just flow to terminal from positive plate by electrical current carriers, is sent to external circuit from terminal, gets back to battery (generally by another electrical current carriers) by the terminal that is connected with negative plate then.
When the rechargeable character of needs, lead-acid battery receives an acclaim.Because abuse is had high tolerance and relative low manufacturing cost, especially when battery weight was not major consideration, this battery was desirable especially for requiring rechargeable application.Thus, lead-acid battery is often used in to automobile and other vehicles provide power, because these external environments can be very abominable and abuse miscellaneous can be occurred.Lead-acid battery also often is used in when power network can not use and provides in the back-up system of power.
Most of lead-acid batteries mainly utilize identical basic electrochemical reaction to produce electric energy, and generally use identical active material.Electrochemical reaction is as follows:
Negative electrode: PbO 2+ SO 4 -2+ 4H ++ 2e -→ PbSO 4+ 2H 2O
Anode: Pb+SO 4 -2→ PbSO 4+ 2e -
At anode, metallic lead and sulfate ion (SO 4 -2) send out and should generate lead sulfate (PbSO 4).At negative electrode, lead oxide (PbO 2) and sulfate ion (SO 4 -2) reaction also generates lead sulfate.Electronics is provided by anode, and the external circuit of flowing through is received by negative electrode.
In practice, typical lead-acid battery comprises anode layer and the cathode layer that multilayer is stacked.Usually, it is set to a kind of in following two kinds of structures: the rectangular band of laminated plate or screw winding.In arbitrary situation, all to isolate mutually between anode layer and the cathode layer by carrier ring, carrier ring is made by electrical insulating material (glass fibre bedding and padding etc. are typically arranged).The sulfuric acid solution of dilution is used as electrolyte usually provides sulfate ion.
The laminated plate pattern of lead-acid battery generally comprises a plurality of anodes and the negative electrode that alternating sequence is arranged in the lamination of separating by carrier ring.In other words, the typical layout comprises a minus plate, a dividing plate, and a positive plate, another dividing plate, second minus plate, the rest may be inferred.Some lead-acid battery cells comprise 29 stacked by this way minus plates and positive plate.
In order to utilize by the electric energy that electrochemical reaction produced takes place on the battery lead plate, parallel with one another between the minus plate, also parallel with one another between the positive plate.A kind of common technique that connects pole plate is at an edge of each pole plate outstanding tab to be set.Tab is arranged on the identical position of each minus plate, makes can align between the tab when stacked at pole plate.Tab is connected on the conduction connecting band, promptly in turn is connected to battery terminal.Similarly the tab of alignment is given prominence to and is passed through a connecting band from positive plate and connects, but these tabs are set on the different position of positive plate to avoid and the mutual interference mutually of anode connecting band.For example, a example to this structure has been described in the U.S. Patent No. 4383011 of McClelland etc.
Lead-acid battery with this design in use can run into the problem of vibration resistance and durability aspect.As mentioned above, because lead-acid battery is generally very solid, often be used in the rugged environment.Therefore, they to be subjected to strict test, especially impact, bump, collision and vibration repellence (as a typical test, referring to VG96924-2, BS6290 the 4th part, IEC).In some cases, fracture occurs in the tab of positive plate and the junction between the connecting band.This zone of positive plate can since below being used for of taking place of tab surface protected the oxidation reaction of the metallic lead (Pb) of bulk (promptly form PbO 2) and become fragile.PbO 2Layer is more crisp relatively, can cracking under the shear action that applies during the vibration-testing.These cracks can make following metallic lead come out then, and oxidized thereupon.This pattern in generation oxidation behind the cracking constantly repeats to rupture fully from pole plate up to tab.
Summary of the invention
The objective of the invention is to battery unit and Battery And Its Manufacturing Methods, when battery is subjected to vibrating check and the detection of other strict mechanics, help the resistance to fracture of junction between positive plate tab and connecting band.As a first aspect of the present invention, the method for making battery comprises one, and it has positive plate and negative plate alternately for battery provides the initial step of battery unit, wherein between each pole plate insulated carrier ring separately, positive plate and negative plate are stacked mutually.Each positive plate all comprises the tab outstanding from adjacent positive plate top, alignment usually between the tab of positive plate.Each negative plate all comprises outstanding tab, alignment usually between the tab of negative plate.Next, this method comprise with the conduction connecting band be attached on the outstanding tab of positive plate.This method comprises that cladding material is applied to positive plate gives prominence to the tab part top adjacent with positive plate (for example by topple over adhesive material on anodal connecting band then, it is scatter and drip to positive plate, and on the tab and top and dividing plate of common negative plate), cladding material is hardened provides one to be attached at the outstanding tab of positive plate and negative plate and the cover layer on the adjacent upper.This method can provide a kind of battery unit, and wherein hardened and/or prevent oxidation in the junction between positive plate tab and the connecting band, improves the performance in the mechanical test thus.
On the other hand, the objective of the invention is to a kind of battery, it comprises: shell; A plurality of positive plates that replace and negative plate; Two conduction connecting bands; With a cover layer.Separated stacked being placed in the shell between each positive plate and the negative plate by the electric insulation baffle layer.Each positive plate has the outstanding tab that extends out from the adjacent upper of this positive plate, the tab general alignment of positive plate, and each negative plate has outstanding tab, the tab general alignment of negative plate.A conduction connecting band is mutually attached with the outstanding tab of positive plate, and another conduction connecting band is mutually attached with the outstanding tab of negative plate.The adjacent upper of outstanding tab part of cover layer (for example making by adhesive material) covering positive plate and positive plate (and, generally also cover negative plate and dividing plate).
Description of drawings
Figure 1A is the perspective view according to the lamination of the positive plate of battery unit of the present invention and negative plate and dividing plate;
Figure 1B is the decomposition diagram of battery unit shown in Figure 1A;
Fig. 2 A be according to the embodiment of the invention for forming the schematic diagram that connecting band is dipped into battery unit shown in Figure 1A in the melted material;
Fig. 2 B is the profile of the 2B-2B direction along the line of battery unit shown in Fig. 2 A;
Fig. 3 shows and battery unit shown in Fig. 2 A and Fig. 2 B is inserted schematic side view in the battery case according to the embodiment of the invention;
Fig. 4 is the schematic side view that comprises the battery of battery unit shown in a plurality of Fig. 2 A and the 2B of the present invention;
Fig. 5 is the perspective diagram that receives covering layer material according to each battery unit of the battery as shown in Figure 4 of the embodiment of the invention;
Fig. 6 is the perspective view with complete tectal battery as shown in Figure 5; With
Fig. 7 shows the schematic side view of tectal battery shown in Figure 6.
Embodiment
To be described in detail the present invention in conjunction with the accompanying drawings hereinafter, wherein the preferred embodiments of the present invention shown in the accompanying drawing.Yet the form that the present invention can be much different is implemented, and the embodiment that is not limited only to wherein provide; And the purpose that these embodiment are provided is to make the present invention fully, completely openly, makes those skilled in the art can understand scope of the present invention fully.
In the accompanying drawings, for the sake of clarity, the thickness in line, layer and zone may be exaggerated.Be understandable that, if element, for example layer, zone, substrate or panel, be known as another element " on ", it may be to be directly arranged on another element or also to have insertion element so.Opposite, if element is known as " directly " be arranged on another element " on ", then do not have insertion element.Be understandable that equally, if element be " connection " or " attached " on another element, it may be directly to connect or be attached on another element so, perhaps also may have intermediary element.Opposite, if element be " directly connecting " or " directly attached " on another element, then do not have intermediary element.The term of expression direction " makes progress ", " downwards ", " vertically ", " level " or the like here only are to use for illustrative purposes.
Referring now to accompanying drawing, a battery unit is by Reference numeral 10 expressions, as shown in Figure 1A and Figure 1B.Battery unit 10 comprise with replace, pile up, stacked system is arranged a plurality of be substantially the plane positive plate 12 and a plurality of be the negative plate 14 on plane substantially, each is to being separated by dividing plate 16 between adjacent positive plate and the negative plate.Positive plate and negative plate 12,14 and dividing plate 16 can be to well known to a person skilled in the art any material that is applicable to battery unit or battery.In lead-acid battery, positive plate and negative plate 12,14 are made (described " based on lead " material comprises at least 99% lead) here, by the material based on lead.Dividing plate 16 is generally made by glass microfiber or synthetic glass microfibre.The size and the thickness of positive plate and negative plate 12,14 and dividing plate 16 are well known to a person skilled in the art, need not to describe at this.
Still with reference to Fig. 1, each positive plate 12 comprises from the upwardly extending outstanding tab 12a of the top edge of positive plate 12.Tab 12a extends out from the essentially identical position on each positive plate 12, so that tab 12a aligns substantially when positive plate is stacked.Tab 12a helps the electrical connection between all parallel positive plates.Similarly, each negative plate 14 comprises from the upwardly extending outstanding tab 14a of the top edge of negative plate 14, and because tab 14a is positioned at essentially identical position and the basic alignment on each negative plate 14, this helps the electrical connection between the parallel negative plate 14.The concrete structure of tab 12a, 14a can change, but selected structure should fully be extended from the edge of respective electrode plate so that it can be electrically connected.
Be connected to the anodal connecting band 18 of tab 12a by utilization, and be connected to the negative pole connecting band 22 illustratives ground of tab 14a and typically realize interconnecting between positive plate 12 and the negative plate 14 (referring to Fig. 3-6).For example, connecting band 18,22 can obtain in the concave well 28,30 with tab 12a and 14a immersion mould 26 by being inverted battery 10, at this moment comprises melted material 29,32 for example plumbous (seeing accompanying drawing 2A and 2B) in concave well 28,30. Tab 12a, 14a stay in the concave well 28,30 up to melted material 29,32 coolings.The battery unit 10 that is attached with connecting band 18,22 then is raised from mould 26.Those skilled in the art can recognize the other technologies that connecting band 18,22 is attached on tab 12a, the 14a, and for example manual hot weld or other any mechanical connection methods also can be applied among the present invention respectively.
After connecting band 18,22 had been set on the battery unit 10, battery unit 10 can be then be placed in the battery 50 of many battery units (seeing accompanying drawing 3 and 4) with other battery units 10.Battery 50 comprises a plurality of battery units 10 (generally these batteries have the battery unit of similar size) and a compartment formula shell 52, and each compartment 54 of shell comprises insertion battery unit wherein.Battery unit 10 is placed as follows: the plus end 20 of a battery unit is adjacent with the negative terminal 24 of another battery unit 10.
Now referring to accompanying drawing 5, after battery unit 10 is inserted into shell 52, covering layer material 42 (being generally adhesive) is applied on the anodal connecting band 18 of each battery unit 10 (oxidation does not generally take place negative plate 14, aforesaid become fragile and ftracture can not take place) thereon.For example, can covering layer material 42 be deposited on the upper surface 18a of anodal connecting band by distributor mechanism 40.Covering layer material scatter on upper surface 18a, and the side 18b that splashes into anodal connecting band 18 downwards is with top 12e, 14e, the 16e (seeing accompanying drawing 7) of the expose portion that covers tab 12a and adjacent positive plate 12, negative plate 14 and dividing plate 16.The covering layer material 42 general spaces of infiltrating between positive plate and negative plate 12,14 and the dividing plate 16, infiltrate 0.5cm to 1.0cm (size can change according to cell types/size) from top 12e, 14e, the 16e of positive plate 12, negative plate 14 and dividing plate 16, more or less but covering layer material 42 can infiltrate as required.Covering layer material 42 sclerosis then form cover layer 44.
In certain embodiments, cover layer 44 can make the anodal connecting band 18 and the top edge of positive plate, negative plate 12,14 and dividing plate 16 become one, and a kind of structural integrity of battery unit 10 and rigid structure of vibration resistance improved is provided thus.In certain other embodiments, cover layer 44 can also apply the tab 12a of positive plate 12, and the protective layer of anti-tab oxidation is provided.In a further embodiment, cover layer 44 can provide structural integrity, vibration resistance and anti-oxidation protection.
Cover layer 44 can be made by any material of aforesaid flintiness and/or protective value that can provide.Typical covering layer material comprises adhesive, for example epoxies, active crylic acid class or connection compound.In certain embodiments, cover layer 44 can be made by the material with certain viscosity (generally having the viscosity of 19 centipoises under 25 ℃), so that it can be applied on the anodal connecting band 18 as described like that, and be distributed to therefrom on the last and tab 12a of top 12e, the 14e of positive plate 12, negative plate 14, the 14a part.Covering layer material also can be acidproof (especially sulfuric acid, because in its electrolyte solution through being commonly used in lead-acid battery) and anti-80 ℃ of high temperature, can withstand the internal environment of battery.Further, produce pressure for avoiding inside battery, covering layer material can not be the material that can emit a large amount of gases, should adhere at least on the positive plate 12.A kind of typical covering layer material is the S-2470-E epoxy, can be from Britain Structural Adhesives Ltd, and Bushby Brooks Works, 16SpenceStreet, Leicester.LE5 3NW buys.
Those skilled in the art will appreciate that other cover layer 44 can be applied on the anodal connecting band 18 and the top 12e of positive plate 12 on technology can use.For example, cover layer 44 can be applied on the top 12e and tab 12a of positive plate 12 by the mode of spraying or direct injection material.Another example, cover layer 44 also can apply in time around the anodal connecting band 18 in mold position, fill mould and form predetermined shape so that covering layer material 42 flows.
After applying cover layer 44, the positive pole of adjacent cell 10 and negative terminal 20,24 are electrically connected.Battery 50 is capped and fill electrolyte solutions then.Battery after the filling is deflated before use and is sealed.
Those skilled in the art will appreciate that though the cover layer that illustrates and discussed is used to the battery of many battery units, this cover layer also can be used the battery of single cell units here.Further, though what here illustrate and describe is " parallel-plate " battery, cover layer also can be applied in the battery of " screw winding " easily, and wherein positive plate and negative plate are with stacked mode screw winding.In addition, also can comprise cover layer on the top edge of negative pole connecting band and adjacent plate and dividing plate, but optional.
Aforementioned is to illustrate of the present invention, and is not limitation of the present invention.Though the cited embodiment of the invention is described, those skilled in the art are readily appreciated that these embodiment are had many variations, and do not break away from the instruction and the advantage of novelty of the present invention in itself.Therefore, all such variations are included within the scope of the presently claimed invention.The present invention is limited by following claim, and it is suitable with desired protection range.

Claims (19)

1, a kind of method of making battery comprises:
For battery provides an element cell, it has positive plate and negative plate alternately, separated by the carrier ring of electric insulation between each positive plate and the negative plate, positive plate and negative plate are stacked mutually, wherein each positive plate comprises the outstanding tab that extends out from the adjacent top of positive plate, the outstanding tab alignment of described positive plate, and wherein each negative plate comprises outstanding tab, the outstanding tab alignment of described negative plate;
The conduction connecting band is attached on the outstanding tab of positive plate;
Covering layer material is applied on the outstanding tab part and adjacent upper of positive plate; With
Make covering layer material sclerosis so that the outstanding tab that is attached at positive plate and the cover layer on the adjacent upper to be provided.
2, the method for claim 1, wherein said cover layer cover the outstanding tab part and the adjacent upper part of positive plate, and prevent that above-mentioned part is oxidized.
3, the method for claim 1, wherein cover layer is a kind of hard structure that connecting band and positive plate are become one.
4, the method for claim 1, wherein positive plate and negative plate are made by the material based on lead.
5, the method for claim 1 further comprises: after the step of attached conduction connecting band battery unit is inserted battery case.
6, the method for claim 1 further comprises: the step that adds electrolyte solution after applying the step of covering layer material to battery unit.
7, the method for claim 1, the step that wherein applies covering layer material comprises the upper surface that covering layer material is applied to connecting band, and covering layer material is scatter and drips to the outstanding tab of positive plate and the expose portion of adjacent upper.
8, method as claimed in claim 7, wherein covering layer material comprises a kind of adhesive resin.
9, method as claimed in claim 8, wherein said adhesive resin are a kind of epoxy resin.
10, method as claimed in claim 7, wherein covering layer material has the viscosity that under 25 ℃ of conditions size is 19 pools.
11, the method for claim 1, wherein positive plate and negative plate are the plane basically.
12, the method for claim 1, wherein the step of attached connecting band comprises, the outstanding tab of positive plate is immersed in the conduction melt solution that is collected in the mould, and make described melt solution cooling form connecting band, outstanding tab is embedded.
13, method as claimed in claim 12, wherein Dao Dian melt solution comprises the material based on lead.
14, a kind of battery comprises:
Shell;
A plurality of positive plates that replace and negative plate, separated by the carrier ring of electric insulation between each positive plate and the negative plate, positive plate and negative plate be stacked being placed in the shell mutually, wherein each positive plate comprises the outstanding tab that extends out from the adjacent top of positive plate, the outstanding tab alignment of described positive plate, and wherein each negative plate comprises outstanding tab, the outstanding tab alignment of described negative plate;
Be attached at the conduction connecting band on the outstanding tab of positive plate;
Be attached at the conduction connecting band on the outstanding tab of negative plate;
Cover the outstanding tab of positive plate and the cover layer of positive plate adjacent upper part.
15, battery as claimed in claim 14, wherein said cover layer comprises a kind of adhesive resin.
16, battery as claimed in claim 15, wherein said adhesive resin comprise the material that is selected from the material group that comprises epoxies, active crylic acid class and be connected compound.
17, battery as claimed in claim 14, wherein positive plate and negative plate are made by the material based on lead.
18, battery as claimed in claim 14, wherein the outstanding tab and the adjacent upper of negative plate do not have cover layer.
19, battery as claimed in claim 14 further comprises the electrolyte solution that is included in the described shell.
CNB038143100A 2002-04-20 2003-04-15 Battery with vibration-resistant joint between positive electrode and current carrying strap Expired - Lifetime CN100426561C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0209227A GB2387960B (en) 2002-04-20 2002-04-20 Improvements in or relating to batteries
GB0209227.8 2002-04-20

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CN100426561C true CN100426561C (en) 2008-10-15

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EP (1) EP1497874B1 (en)
JP (1) JP4491243B2 (en)
CN (1) CN100426561C (en)
AT (1) ATE316694T1 (en)
DE (1) DE60303369T2 (en)
ES (1) ES2258221T3 (en)
GB (1) GB2387960B (en)
WO (1) WO2003090292A2 (en)

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EP1497874A2 (en) 2005-01-19
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ATE316694T1 (en) 2006-02-15

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