CN100395300C - Natural plant type oil paint and its preparation method - Google Patents
Natural plant type oil paint and its preparation method Download PDFInfo
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- CN100395300C CN100395300C CNB2005101223281A CN200510122328A CN100395300C CN 100395300 C CN100395300 C CN 100395300C CN B2005101223281 A CNB2005101223281 A CN B2005101223281A CN 200510122328 A CN200510122328 A CN 200510122328A CN 100395300 C CN100395300 C CN 100395300C
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- 239000003973 paint Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title abstract description 12
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 30
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000049 pigment Substances 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 16
- 229940087305 limonene Drugs 0.000 claims abstract description 14
- 235000001510 limonene Nutrition 0.000 claims abstract description 14
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 12
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims abstract description 10
- -1 compound rare earth Chemical class 0.000 claims abstract description 10
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940116411 terpineol Drugs 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 229920002521 macromolecule Polymers 0.000 claims description 10
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 229940059574 pentaerithrityl Drugs 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 12
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 5
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
- 150000002894 organic compounds Chemical class 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 230000003068 static effect Effects 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002274 desiccant Substances 0.000 abstract 2
- 229920006254 polymer film Polymers 0.000 abstract 2
- 241000196324 Embryophyta Species 0.000 abstract 1
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 abstract 1
- NAYYNDKKHOIIOD-UHFFFAOYSA-N phthalamide Chemical compound NC(=O)C1=CC=CC=C1C(N)=O NAYYNDKKHOIIOD-UHFFFAOYSA-N 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 150000007519 polyprotic acids Polymers 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 13
- 238000006136 alcoholysis reaction Methods 0.000 description 8
- 238000010792 warming Methods 0.000 description 8
- 239000002994 raw material Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- 239000002966 varnish Substances 0.000 description 5
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 4
- QVYYOKWPCQYKEY-UHFFFAOYSA-N [Fe].[Co] Chemical compound [Fe].[Co] QVYYOKWPCQYKEY-UHFFFAOYSA-N 0.000 description 4
- 239000002320 enamel (paints) Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 206010013082 Discomfort Diseases 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 208000007502 anemia Diseases 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- NJTGANWAUPEOAX-UHFFFAOYSA-N molport-023-220-454 Chemical compound OCC(O)CO.OCC(O)CO NJTGANWAUPEOAX-UHFFFAOYSA-N 0.000 description 1
- 208000002040 neurosyphilis Diseases 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to natural plant type paint and a preparation method thereof. The present invention is characterized in that the paint is mixed up by a high polymer film forming material, a pigment, auxiliary agents and a solvent, wherein the high polymer film forming material is composed of 30 to 40 parts by weight of flax oil which is used as an oil material, 35 to 45 parts by weight of limonene, 5 to 15 parts by weight of polyalcohol, and 8 to 15 parts by weight of phthalic diamide and 2 to 5 parts by weight of trimellitic anhydride which are used as polybasic acid; the pigment is composed of 10 to 20 parts by weight of natural pigment; the auxiliary agents comprise a catalyst and a drying agent, wherein the catalyst is 0.02 to 0.1 parts by weight of lithium hydroxide, and the drying agent is 3 to 10 parts by weight of compound rare earth; the solvent is composed of 5 to 10 parts by weight of turpentine and 5 to 10 parts by weight of terpineol. The paint mixed up by the components not only can reduce the volatilizing amount of organic compounds, but also can reduce the content of heavy metals, and therefore, the paint can reduce pollution effectively, and protect the environment. The paint film of the product has the advantages of rich texture, no static electricity generated by friction, good water resistance, high elasticity, high flexibility, good chemical resistance, good wear resistance, strong adhesive force, high hiding rate, large unit coating area and low operating cost.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of natural plant type oil paint and preparation method thereof.
Background technology
Paint is the basal plane material of buildings and the required coating of all kinds of thing tool.At present, mostly adopt in field such as construction and decoration, decoration is the paint that contains chemical ingredients, after this paint application, can constantly volatilize organic compound and episome, therefore can produce bigger pollution to nature, and can cause the various discomforts of human body, as headache, general paralysis, anaemia, to such an extent as to the generation of diseases such as cancer; Especially preparation produce and use in, the easier infringement that causes operator's health.Therefore, how guaranteeing effectively that paint is environment friendly and pollution-free, and improve inner quality, the reduction of painting and produce and use cost, is one of the current urgency in this field difficult problem to be solved.
Summary of the invention
The objective of the invention is to overcome above-mentioned weak point, natural plant type oil paint that provide that a kind of technology is simple, excellent property, reduction is polluted and preparation method thereof.
The technical solution adopted in the present invention is for achieving the above object: a kind of natural plant type oil paint, this paint is made up of macromolecule filming material, pigment, auxiliary agent and solvent, it is characterized in that counting by weight: the oil plant that adopts in the macromolecule filming material is 30～40 parts of oleum lini, 35～45 parts of limonene, 5～15 parts of polyvalent alcohols, polyprotonic acid is 8～15 parts of Tetra hydro Phthalic anhydrides, 2～5 parts of trimellitic acid 1,2-anhydrides; Pigment is 10～20 parts of natural pigments; Auxiliary agent is 0.02～0.1 part of a catalyzer lithium hydroxide, and siccative is 3～10 parts of compound rare-earths; Solvent is 5～10 parts of 5～10 parts in turps and Terpineol 350s.
Described polyvalent alcohol adopts tetramethylolmethane or glycerol.
The raw material of said ratio is got all the ready, and its preparation method is followed successively by the following step:
(1) oleum lini, the polyvalent alcohol of proportional quantity are inserted in the reactor and stirred, 80～130 rev/mins of stirring velocitys are warming up to 120～150 ℃, the catalyzer lithium hydroxide that adds proportional quantity, continue to be warming up to 230～240 ℃, keep alcoholysis reaction, qualified to alcoholysis;
(2) be cooled to 150～180 ℃, 5～10 parts limonene in polyprotonic acid Tetra hydro Phthalic anhydride, trimellitic acid 1,2-anhydride and the proportional quantity of adding proportional quantity, in 170～220 ℃ of scopes of temperature, keep fatization, 7～10 hours, index request: below the acid number 25mg KOH/g, viscosity is by Ge Shi pipe: 1.8～3s;
(3) be blended into 30～40 parts of the limonene of proportioning surplus, add solvent turps, the Terpineol 350 of proportional quantity, index request: acid number≤20mg KOH/g, viscosity: be coated with-4 glasss, 80～100s, solid part is 55% ± 2, color≤3～No. 8 iron cobalt colorimetric;
(4) the siccative compound rare-earth of adding proportional quantity, stirring and evenly mixing becomes natural plant type varnish;
(5) adding proportional quantity pigment is natural pigment, and mesh-of-grind reaches below the 20 μ m, evenly stirs to keep 1～2 hour, becomes natural plant type enamel paint.
The invention has the beneficial effects as follows:
1, because the selected raw material of product made of the present invention is to extract from natural plant, so this product not only can reduce the volatile quantity of organic compound, and can reduce heavy metal content.Detected result shows and does not contain heavy metals such as Pb, Cr, Cd, Sb, Ba in this product, reduces and pollutes, helps environment protection.
2, the rich texture of this product paint film, friction can not produce static, has excellent water tolerance, elasticity, snappiness, chemical resistant properties, wearability.And strong adhesion, hiding rare height, surface covered are big, and the unit usage quantity reduces, so effective reduction use cost.
3, this product can be used for the finishing of timber, iron material, plastic, paper wood, high-grade coloured furniture, hotel, hospital etc.; To toy for children, health-care hospital equipment, cultural goods, artwork etc. is the coloured healthy paint of ideal.Using in fields such as electric industry, communications industry, electronics industry, precision instruments, is that safe antistatic protection is with coating with lacquer; The scope of application is very extensive.
4, the main raw material of this product employing is the recyclable regenerative resource, and the source is abundant and extensive; Reach the removing source of pollution in utilization of waste material, when turning waste into wealth, effectively implement resource integration.
5, preparation technology of the present invention is simple, easy and simple to handle, and the production environment condition is loose, need not specific equipment and the supporting facility that decontaminates, and has significant practical value and economic benefit.
Embodiment
Below in conjunction with preferred embodiment, to details are as follows according to embodiment provided by the invention:
Embodiment 1
A kind of natural plant type oil paint, this paint is made up of macromolecule filming material, pigment, auxiliary agent and solvent, it is characterized in that the oil plant that adopts in the macromolecule filming material is 35 kilograms of oleum lini, 40 kilograms of limonene, polyvalent alcohol adopts 7.5 kilograms of tetramethylolmethanes, and polyprotonic acid is 11.5 kilograms of Tetra hydro Phthalic anhydrides, 3.5 kilograms of trimellitic acid 1,2-anhydrides; Pigment is 15 kilograms of natural pigments; Auxiliary agent is 0.06 kilogram of a catalyzer lithium hydroxide, and siccative is 6.5 kilograms of compound rare-earths; Solvent is 7.5 kilograms of 7.5 kilograms in turps and Terpineol 350s.
The raw material of said ratio is got all the ready, and its preparation method is followed successively by the following step:
(1) oleum lini, the polyvalent alcohol of proportional quantity are inserted in the reactor and stirred, 80～130 rev/mins of stirring velocitys, be warming up to 120～150 ℃, the catalyzer lithium hydroxide that adds proportional quantity, continue to be warming up to 230～240 ℃, keep alcoholysis reaction, to alcoholysis qualified (promptly 95% ethanol and material are 5: 1, and miscible back is as clear as crystal);
(2) be cooled to 150～180 ℃, the polyprotonic acid that adds proportional quantity, 7.5 kilograms limonene in Tetra hydro Phthalic anhydride, trimellitic acid 1,2-anhydride and the proportional quantity, in 170～220 ℃ of scopes of temperature, keep fatization, 7～10 hours, index request: below the acid number 25mg KOH/g, viscosity is by Ge Shi pipe: 1.8～3s;
(3) be blended into 32.5 kilograms of the limonene of proportioning surplus, add solvent turps, the Terpineol 350 of proportional quantity, index request: acid number≤20mg KOH/g, viscosity (being coated with-4 glasss) 80～100s, solid part is 55% ± 2, color≤3～No. 8 iron cobalt colorimetric;
(4) the siccative compound rare-earth of adding proportional quantity, stirring and evenly mixing becomes natural plant type varnish;
(5) adding proportional quantity pigment is natural pigment, and mesh-of-grind reaches below the 20 μ m, evenly stirs to keep 1～2 hour, becomes natural plant type enamel paint.
Embodiment 2
A kind of natural plant type oil paint, this paint is made up of macromolecule filming material, pigment, auxiliary agent and solvent, it is characterized in that the oil plant that adopts in the macromolecule filming material is 30 kilograms of oleum lini, 35 kilograms of limonene, polyvalent alcohol adopts glycerol (glycerine) 5 kilograms, and polyprotonic acid is 8 kilograms of Tetra hydro Phthalic anhydrides, 2 kilograms of trimellitic acid 1,2-anhydrides; Pigment is 10 kilograms of natural pigments; Auxiliary agent is 0.02 kilogram of a catalyzer lithium hydroxide, and siccative is 3 kilograms of compound rare-earths; Solvent is 5 kilograms of 5 kilograms in turps and Terpineol 350s.
The raw material of said ratio is got all the ready, and its preparation method is followed successively by the following step:
(1) oleum lini, the polyvalent alcohol of proportional quantity are inserted in the reactor and stirred, 80～130 rev/mins of stirring velocitys are warming up to 120～150 ℃, the catalyzer lithium hydroxide that adds proportional quantity, continue to be warming up to 230～240 ℃, keep alcoholysis reaction, qualified to alcoholysis;
(2) be cooled to 150～180 ℃, the polyprotonic acid that adds proportional quantity, 5 kilograms limonene in Tetra hydro Phthalic anhydride, trimellitic acid 1,2-anhydride and the proportional quantity, in 170～220 ℃ of scopes of temperature, keep fatization, 7～10 hours, index request: below the acid number 25mg KOH/g, viscosity is by Ge Shi pipe: 1.8～3s;
(3) be blended into 30 kilograms of the limonene of proportioning surplus, add solvent turps, the Terpineol 350 of proportional quantity, index request: acid number≤20mg KOH/g, viscosity (being coated with-4 glasss) 80～100s, solid part is 55% ± 2, color≤3～No. 8 iron cobalt colorimetric;
(4) the siccative compound rare-earth of adding proportional quantity, stirring and evenly mixing becomes natural plant type varnish;
(5) adding proportional quantity pigment is natural pigment, and mesh-of-grind reaches below the 20 μ m, evenly stirs to keep 1～2 hour, becomes natural plant type enamel paint.
Embodiment 3
A kind of natural plant type oil paint, this paint is made up of macromolecule filming material, pigment, auxiliary agent and solvent, it is characterized in that the oil plant that adopts in the macromolecule filming material is 40 kilograms of oleum lini, 45 kilograms of limonene, polyvalent alcohol adopts 15 kilograms of tetramethylolmethanes, and polyprotonic acid is 15 kilograms of Tetra hydro Phthalic anhydrides, 5 kilograms of trimellitic acid 1,2-anhydrides; Pigment is 20 kilograms of natural pigments; Auxiliary agent is 0.1 kilogram of a catalyzer lithium hydroxide, 10 kilograms of siccative compound rare-earths; Solvent is 10 kilograms of 10 kilograms in turps and Terpineol 350s.
The raw material of said ratio is got all the ready, and its preparation method is followed successively by the following step:
(1) oleum lini, the polyvalent alcohol of proportional quantity are inserted in the reactor and stirred, 80～130 rev/mins of stirring velocitys are warming up to 120～150 ℃, the catalyzer lithium hydroxide that adds proportional quantity, continue to be warming up to 230～240 ℃, keep alcoholysis reaction, qualified to alcoholysis;
(2) be cooled to 150～180 ℃, the polyprotonic acid that adds proportional quantity, 10 kilograms limonene in Tetra hydro Phthalic anhydride, trimellitic acid 1,2-anhydride and the proportional quantity, in 170～220 ℃ of scopes of temperature, keep fatization, 7～10 hours, index request: below the acid number 25mg KOH/g, viscosity is by Ge Shi pipe: 1.8～3s;
(3) be blended into 35 kilograms of the limonene of proportioning surplus, add the solvent turps and the Terpineol 350 of proportional quantity, index request: acid number≤20mg KOH/g, viscosity (being coated with-4 glasss) 80～100s, solid part is 55% ± 2, color≤3～No. 8 iron cobalt colorimetric;
(4) the siccative compound rare-earth of adding proportional quantity, stirring and evenly mixing becomes natural plant type varnish; Also can add 3～8 kilograms of matting agent Ployethylene Wax, Witcodur 272 or aerosils, stir, become the inferior light varnish of natural plant type;
(5) adding proportional quantity pigment is natural pigment, and mesh-of-grind reaches below the 20 μ m, evenly stirs to keep 1～2 hour, becomes natural plant type enamel paint.
The result of this examination and test of products project shown in the table
| Test item | Unit | Measured result |
| Former lacquer outward appearance | Transparent inorganic tool impurity | |
| Paint film color and outward appearance | Smooth smooth | |
| Fineness | μm | 15 |
| Time of drying (surface drying) | min | 90 |
| Time of drying (doing solid work) | h | 5.5 |
| Cross cut test (level) | 1 | |
| Hardness | H | |
| Water tolerance (72h) | Non-foaming, wrinkle resistant, do not come off | |
| Alcohol resistance (volume fraction 50% ethanol) | 8h is non-foaming, wrinkle resistant, the no abnormal variation of paint film | |
| Application property | Brush accessible | |
| Benzene % | Do not detect | |
| Toluene and dimethylbenzene summation % | Do not detect |
Above-mentioned detailed description of the present invention being carried out with reference to embodiment; be illustrative rather than determinate; can enumerate several embodiment according to set of dispense than qualification scope,, should belong within protection scope of the present invention therefore in the variation and the modification that do not break away under the general plotting of the present invention.
Claims (2)
1. natural plant type oil paint, this paint is made up of macromolecule filming material, pigment, auxiliary agent and solvent, it is characterized in that counting by weight: the oil plant that adopts in the macromolecule filming material is 30～40 parts of oleum lini, 35～45 parts of limonene, 5～15 parts of polyvalent alcohols, polyprotonic acid is 8～15 parts of Tetra hydro Phthalic anhydrides, 2～5 parts of trimellitic acid 1,2-anhydrides; Pigment is 10～20 parts of natural pigments; Auxiliary agent is 0.02～0.1 part of a catalyzer lithium hydroxide, and siccative is 3～10 parts of compound rare-earths; Solvent is 5～10 parts of 5～10 parts in turps and Terpineol 350s.
2. natural plant type oil paint according to claim 1 is characterized in that described polyvalent alcohol adopts tetramethylolmethane or glycerol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101223281A CN100395300C (en) | 2005-12-13 | 2005-12-13 | Natural plant type oil paint and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101223281A CN100395300C (en) | 2005-12-13 | 2005-12-13 | Natural plant type oil paint and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1789358A CN1789358A (en) | 2006-06-21 |
| CN100395300C true CN100395300C (en) | 2008-06-18 |
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ID=36787487
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101223281A Expired - Fee Related CN100395300C (en) | 2005-12-13 | 2005-12-13 | Natural plant type oil paint and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100395300C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974376A (en) * | 2010-10-31 | 2011-02-16 | 无锡龙腾画材有限公司 | Adhesive removing soft capsule by extracting limonene from orange peel and preparation method thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286249A (en) * | 2010-06-17 | 2011-12-21 | 葛义谦 | Biological pain and manufacturing method |
| CN102382568B (en) * | 2010-08-31 | 2013-07-17 | 深圳市春来机电工具制造有限公司 | High-temperature-resistant insulating paint |
| CN103740276A (en) * | 2013-09-30 | 2014-04-23 | 罗新平 | Environmental-protection paint |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5478491A (en) * | 1992-07-09 | 1995-12-26 | Specialty Environmental Technologies, Inc. | NMP/d-limonene paint stripper with evaporation inhibitor |
| CN1314443A (en) * | 2001-04-05 | 2001-09-26 | 张昌荣 | Solvent type poisonless health paint |
| US6623554B2 (en) * | 2000-12-20 | 2003-09-23 | Chemtek, Incorporated | Protective coating compositions containing natural-origin materials, and method of use thereof |
| CN1448452A (en) * | 2002-04-02 | 2003-10-15 | 张世刚 | Natural plant paint and its preparation |
| CN1569996A (en) * | 2003-07-25 | 2005-01-26 | 张昌荣 | Solvent type environment friendly paint |
-
2005
- 2005-12-13 CN CNB2005101223281A patent/CN100395300C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5478491A (en) * | 1992-07-09 | 1995-12-26 | Specialty Environmental Technologies, Inc. | NMP/d-limonene paint stripper with evaporation inhibitor |
| US6623554B2 (en) * | 2000-12-20 | 2003-09-23 | Chemtek, Incorporated | Protective coating compositions containing natural-origin materials, and method of use thereof |
| CN1314443A (en) * | 2001-04-05 | 2001-09-26 | 张昌荣 | Solvent type poisonless health paint |
| CN1448452A (en) * | 2002-04-02 | 2003-10-15 | 张世刚 | Natural plant paint and its preparation |
| CN1569996A (en) * | 2003-07-25 | 2005-01-26 | 张昌荣 | Solvent type environment friendly paint |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974376A (en) * | 2010-10-31 | 2011-02-16 | 无锡龙腾画材有限公司 | Adhesive removing soft capsule by extracting limonene from orange peel and preparation method thereof |
| CN101974376B (en) * | 2010-10-31 | 2013-07-03 | 无锡龙腾画材有限公司 | Adhesive removing soft capsule by extracting limonene from orange peel and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1789358A (en) | 2006-06-21 |
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