CN100384002C - Fuel cell device - Google Patents
Fuel cell device Download PDFInfo
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- CN100384002C CN100384002C CNB021257973A CN02125797A CN100384002C CN 100384002 C CN100384002 C CN 100384002C CN B021257973 A CNB021257973 A CN B021257973A CN 02125797 A CN02125797 A CN 02125797A CN 100384002 C CN100384002 C CN 100384002C
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- fuel
- air
- water
- fuel cell
- cell pack
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Abstract
The present invention discloses a fuel cell device which relates to the fuel cell device made from liquid fuel. The present invention comprises a fuel cell pack part, wherein both sides of the fuel cell pack part are provided with a fuel pole and an air pole which are stacked, an electrolyte membrane is put in the middle of the fuel cell pack part, and fuel and air supplied to each pole generates electricity through electrochemical reaction; the fuel pole in the fuel cell pack part is connected to a fuel supply part of a liquid fuel tank through a fuel circulation pipe and a fuel pump; the air pole in the fuel cell pack part is connected to an air supply part through an air compressor; an air moistening part capable of moistening air with a water supply circulation part is arranged between the fuel cell stack part and the air supply part; the electric output end of the fuel cell stack part is connected with an electric energy output part; all the parts are connected with a control part. The present invention has the advantages that the fuel tank and a water tank are arranged in a dismountable mode to form a portable generating set, and the fuel tank and the water tank form a whole, which can be changed as a whole; water circulated through the air pole can be reused for air moistening, which can save energy sources and reduce the loss.
Description
Technical field
What the present invention relates to is the fuel cell that can produce electric energy, and the liquid fuel that is to use is particularly made fuel-cell device.
Background technology
Major part is to obtain from fossil fuel in the human energy that uses.But the use of this fossil fuel is to cause serious baneful influences such as air pollution, acid rain and global greenhouse effect to environment, also has the low problem of energy efficiency simultaneously.
For the problem that the use that solves above-mentioned fossil fuel causes, recent development fuel-cell device.
Fuel cell is to be different from common battery---2 primary cells.It is from the outside to the negative electrode fuel supplying---hydrogen or nitrogenize hydrogen, in fact the battery instrument that generates electricity behind the anode supply oxygen can regard Blast Furnace Top Gas Recovery Turbine Unit (TRT) as.
The electricity-generating method of fuel cell is without the burning (oxidation) of fuel reaction, but causes that through the electrochemical reaction of hydrogen and oxygen the energy difference before and after the reaction is directly changed into the method for electric energy.
This fuel cell is not produce nitrogen oxide (NO
X) and sulfur oxide (SO
X) wait pernicious gas and do not have noise and the clean electricity generation system of vibration; The heat efficiency is to comprise that electric energy output and recuperation of heat amount reach more than 80%.
Original fuel-cell device generates the fuel electrodes 11 of electric energy and the fuel cell pack portion 10 of air pole 12 by possessing the electrochemical reaction of utilizing hydrogen and oxygen as shown in fig. 1; From the fuel liquefied natural gas, make hydrogen H
2After be fed to the fuel supplies 20 of the fuel electrodes 11 of fuel cell pack portion 10; Air supply portion 30 to air pole 12 supply oxygens of fuel cell pack portion 10; The electric energy efferent 40 of the electric energy that produces in the fuel cell pack portion 10 to load supply; The control part (not shown) of suitably adjusting above-mentioned each one 10,20,30,40 constitutes.
This moment, fuel supplies 20 was to have possessed the bigger reformer means 25 of volume ratio between common fuel cell pack portion 10 and the fuel supply source 21.Reformer 25 is by the Desulfurizer 26 of removing sulphur S in the fuel liquefied natural gas; Reformer 27 with water vapour haptoreaction formation hydrogen; Separation of C O in the hydrogen that generates
2, CO, N
2, H
2CO interpreter 28 and the CO remover 29 of O etc. are connected to form side by side.
Undeclared symbol 22 is petrolifts among the figure, the 31st, and compressor, the 32nd, humidifier, the 41st, inverter, the 42nd, load.
Below the course of work of above-mentioned existing fuel-cell device is carried out following explanation:
Control part (not shown) when assigning control command the fuel liquefied natural gas Desulfurizer 26 by being referred to as reformer means 25, reformer 27, CO transducer 28 and CO remover 29 generate H successively
2Be fed to the fuel electrodes 11 of fuel cell pack portion 10.
Meanwhile by the air pole 12 supply air of air supply portion 30, and form oxidation reaction to fuel electrodes 11 supplied fuel and reduction reaction produces electric energy to fuel cell pack portion 10.
Existing fuel-cell device produces the volume macrostructure complexity of the reformer means 25 of hydrogen, so can fixedly mount use in the general home-use electricity generation system, the field is portably used, and acquires a certain degree of difficulty on its volume and the price.In order to address the above problem, just greatly and baroque hydrogen generating unit, can the dismounting form connect the fuel electrodes 11 that is arranged on fuel cell pack portion 10 with the hydrogen high-pressure bottle 50 of compression storage of hydrogen body shown in Figure 2 with volume in original fuel-cell device.
But above-mentioned existing fuel-cell device is difficult to compression with general high voltage and charges into when replacing hydrogen high-pressure bottle 50 or charge into hydrogen again in hydrogen high-pressure bottle 50, and use upward exists dangerous greatly in addition.
Summary of the invention
The objective of the invention is to overcome the deficiency of above-mentioned technology, provide a kind of do not possess reformer means also can security provisions hydrogen and replace portable a kind of fuel-cell device of fuel easily.
The present invention solves the problems of the technologies described above the technical scheme that is adopted: a kind of fuel-cell device, its structure include the fuel electrodes and the air pole centre that have possessed stack in both sides and put into dielectric film and carry out the fuel cell pack portion that electrochemical reaction produces electricity to each utmost point supplied fuel and air; Fuel electrodes in the fuel cell pack portion is connected the fuel supplies of fill liquid fuel tank by fuel recycle pipe, petrolift; The air supply portion that is connected with air pole in the fuel cell pack portion by air supply pipe and air compressor; But in the middle air wetting portion that has water supply circulation portions and humidifying air that is connected of fuel cell pack portion and air supply portion; The electric energy efferent that links to each other with the electric output of fuel cell pack portion; Above-mentioned each one all links to each other with control part.
The invention has the beneficial effects as follows: the present invention charges into the fuel tank of fuel liquid and the water tank of the required water of stored air humidification with detachable form being provided with, and constitutes the portable Blast Furnace Top Gas Recovery Turbine Unit (TRT), and fuel tank and water tank form one, but integral replacing fuel tank and water tank.And the water that cycles through air pole is recycling in air wetting, can save the energy, reduces loss.
Description of drawings
Fig. 1 and Fig. 2 are existing fuel-cell device structure connection diagrams;
Fig. 3 is a fuel-cell device structure connection diagram of the present invention;
Fig. 4 is the generalized section of fuel cell pack;
Fig. 5 is another example structure connection diagram of fuel-cell device of the present invention.
Embodiment
Below in conjunction with accompanying drawing embodiments of the invention are described in further detail:
The present invention is a kind of fuel-cell device, and this fuel-cell device structure includes the fuel electrodes 113 and air pole 114 centres that have possessed stack in both sides and puts into dielectric film 112 and carry out the fuel cell pack portion 110 that electrochemical reaction produces electricity to each utmost point supplied fuel and air; Fuel electrodes 113 in the fuel cell pack portion 110 is connected the fuel supplies 120 of fill liquid fuel tank 121 by fuel recycle pipe 122, petrolift 123; The air supply portion 130 that is connected with air pole 114 in the fuel cell pack portion 110 by air supply pipe 132 and air compressor 131; But in fuel cell pack portion 110 and the 130 middle air wetting portions 140 that have water supply circulation portions 150 and humidifying air that are connected of air supply portion; The electric energy efferent 160 that links to each other with the electric output of fuel cell pack portion 110; Above-mentioned each one all links to each other with control part.
Fuel cell pack portion 110 is formed by a plurality of cell 111 stacks as shown in Figure 4.Every each cell 111 includes dielectric film 112, the fuel electrodes 113 and the air pole 114 of both sides stack; Being superimposed upon fuel electrodes 113 and air pole 114 outsides makes separately fuel contact with air and the separator 115,116 that circulates constitutes.The current-collector 117,118 that superposes separately and formed collecting electrodes in the outside of fuel cell pack portion 110 both sides separators 115,116, more than a plurality of cells and current-collector form above-mentioned fuel cell pack portion 110.
Separator 115,116 has used electrical conductivity well to reach the strong metallicses such as lead powder of corrosion resistance, has formed fuel channel and the air duct that passes through fuel gas with the medial surface separately that fuel electrodes 113 contacts with air pole 114.And the separator 115,116 that is provided with between the cell 111 is that a side forms fuel gas channel and opposite side forms air duct, and the separator 115,116 of the both side ends setting of fuel cell pack 110 has only medial surface to form fuel gas channel and air duct.The fuel gas channel of the separator 115,116 that fuel cell pack 110 middle parts are provided with and air duct are connected separately side by side by house steward.
Current-collector 117,118 is finally obtained electric energy in fuel cell pack 110, preferably adopt the electrical conductors of the copper product be generally used for terminal etc.
Be provided with in fuel recycle pipe 122 or the fuel tank 121 and detect the supply fluid fuel concentration and point out the concentration sensor D of the replacing time of fuel tank.
Be connected with the humidifier 141 of humidification by the air of air supply pipe 132 in the outlet back of air compressor 131; Be provided with the check-valves 134 that prevents air inversion before the inlet of humidifier 141; Its outlet back is provided with air adjustment valve door 135.
Be water on the running water when water source of supply 142 is used for family, be used for present embodiment and carry the time spent for storing a certain amount of water tank formation.
Connect the water tank 142 that can the dismounting form stores certain water gaging in the water supply pipe 143.Water tank 142 in order to replace simultaneously with above-mentioned fuel tank 121, is considered the use amount of fuel and water as shown in Figure 5, and fuel tank 121 and water tank 142 can fuse, and two casees volume ratio is for can change the volume that is complementary simultaneously.
Boiler water circulation portion 150 is by the air pole 114 that connects fuel cell pack portion 110 and the water-circulating pipe 151 of water supply pipe 143; Be arranged on the centre of water-circulating pipe 151 and separate the gas-liquid separator of carrying to humidifier 141 circulations by behind the water in the water and air of fuel cell pack portion 110 152; The water conversion valve 153 of three-way valve that is arranged on the tie point of water supply pipe 143 and water-circulating pipe 151 and changes the service duct of water constitutes.
The level sensor L that connects water tank 142 and water supply pipe 143 according to the water yield by water conversion valve 153 by turns is housed in gas-liquid separator 152.
Below in conjunction with accompanying drawing the course of work of the present invention is described:
After control part (not shown) was assigned enabled instruction, the petrolift 123 of starting fluid supply department 120 was carried liquid fuel, and this fuel is fed to the fuel electrodes 113 of fuel cell pack portion 110 from fuel tank 121 by fuel recycle pipe 122.At this moment, fuel trim valve door the 124, the 125th, Be Controlled portion suitably opens the strength of fluid that utilizes the circulation of concentration sensor D Sustainable Control when liquid fuel is circulated smoothly, when concentration value tells the user to answer refuelling case 121 by display part (not shown) when standard value is following.
Meanwhile starting air compressor 131 carries the air in the atmosphere to supply air by air supply pipe 132 to the air pole 114 of fuel cell pack portion 110.This air becomes the steam state to be fed to air pole 114 by air adjustment valve door 135 through humidifier 141 humidifications in the middle of being, forms electric energy.
Be described in more detail as follows, open air supply portion 130 when liquid fuel is fed to the fuel channel supply of the separator 115,116 that is formed on fuel cell pack portion 110 by fuel recycle pipe 122, make air be fed to the air duct of fuel cell pack portion 110 separators 115,116 by air supply pipe 132.
At this moment, the supply valve 145 of fetching boiling water starts water pump 144, and the water of water tank 142 is fed to humidifier 141 by water supply pipe 143, and these humidifier 141 hollow cyclostrophics change the steam state into and are fed to fuel cell pack portion 110.
Fuel gas channel to separator 115,116 is to contact with air pole 114 with fuel electrodes 113 separately with air duct supplied fuel gas and air, and this moment is by electrochemical reaction generation electric energy and heat energy.
That is, fuel electrodes 113 sides take place from the electrochemical oxidation reactions of the H+ of supply of fuel:
H→2H++2e-
Conduct the ion that oxidation/reduction reaction causes in the dielectric film 112, the electrochemical reducting reaction of air supplied (oxygen) take place in the air pole 114:
4H++O
2+4e-→2H
2O
Electric power has taken place between above-mentioned fuel electrodes 113 and air pole 114, this plays electric power is the two ends of the fuel cell pack portion 110 by 111 stacks of a plurality of cells current-collector 117,118 outputs that are provided with, and the electric current of output is fed to load from current-collector 117,118.
Discharge to gas-liquid separator 152 by water-circulating pipe 151 by the water that mixes in the fuel cell pack portion 110 air pole air, wherein air is directly discharged by blast pipe 154, when water conversion valve 153 is closed water tank 142 and is opened gas-liquid separator 152 simultaneously, to humidifier 141 circulation-supplied water.At this moment, judge the water yield that is stored in the gas-liquid separator 152 by the level sensor L that is arranged in the gas-liquid separator 152, if its water yield is when being able to replace water tank 142 degree, and the water Be Controlled portion in the gas-liquid separator 152 connects conveying separately in humidifier 141.
After this, close fuel trim valve door 124,125 backs when needing refuelling case 121 and water tank 142 fuel tank 121 is replaced by another fresh fuel case 121, when fuel tank 121 and water tank 142 fuse as shown in Figure 5, do not need refuelling case 121 and water tank 142 respectively, but disposable replacing.
So, do not need yet fuel supplying smoothly of reformer, thereby avoided the volume of the system that causes with reformer to increase and the expense increase.
And, because charge and discharge liquid fuel with dismountable fuel tank, thus not only easy to carry, also reduced the danger when using.
For the water of humidifying air except the last water that uses water system, can also replace with dismountable water tank that is easy to carry, particularly be one with water tank and fuel tank, water tank is also changed together when the refuelling case, can be more convenient in the use.
Especially use the water humidifying air of from the air pole of fuel cell pack portion, discharging preheating, when particularly using heated humidifier, can use a spot of heat and obtain good humidification effect, more effective use energy with air.
Claims (4)
1. fuel-cell device, this fuel-cell device structure includes the fuel electrodes (113) and air pole (114) centre that have possessed stack in both sides and puts into dielectric film (112) and carry out the fuel cell pack portion (110) that electrochemical reaction produces electricity to each utmost point supplied fuel and air, and the fuel electrodes (113) in the fuel cell pack portion (110) is connected the fuel supplies (120) of fill liquid fuel tank (121) by fuel recycle pipe (122), petrolift (123); The air supply portion (130) that is connected with air pole (114) in the fuel cell pack portion (110) by air supply pipe (132) and air compressor (131); In the middle of fuel cell pack portion (110) and air supply portion (130), is connected have water supply circulation portions (150) but and above-mentioned each one of electric energy efferent (160) of linking to each other with the electric output of fuel cell pack portion (110) of the air wetting portion (140) of humidifying air all link to each other with control part, it is characterized in that water supplies circulation portions (150) and include gas-liquid separator (152), water supply pipe (143), water-circulating pipe (151) and the water conversion valve (153) that possesses separating cycle water in the water and air of air pole; Gas-liquid separator (152) one ends connect air pole (114) by water-circulating pipe (151), and its other end connects water conversion valve (153) and water supply pipe (143) successively; The other end of water supply pipe (143) connects water tank (142).
2. according to the fuel-cell device described in the claim 1, it is characterized in that the described concentration sensor (D) that detects the supply fluid fuel concentration and point out the replacing time of fuel tank that in fuel recycle pipe (122) or fuel tank (121), is provided with.
3. according to the fuel-cell device described in the claim 1, it is characterized in that the middle connection of water supply pipe (143) can store the water tank (142) of certain water gaging with the dismounting form.
4. according to each described fuel-cell device among the claim 1-3, it is characterized in that fuel tank (121) and water tank (142) fuse, two casees volume ratio is for changing the volume that is complementary simultaneously.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB021257973A CN100384002C (en) | 2002-08-19 | 2002-08-19 | Fuel cell device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB021257973A CN100384002C (en) | 2002-08-19 | 2002-08-19 | Fuel cell device |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1474471A CN1474471A (en) | 2004-02-11 |
CN100384002C true CN100384002C (en) | 2008-04-23 |
Family
ID=34143075
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB021257973A Expired - Fee Related CN100384002C (en) | 2002-08-19 | 2002-08-19 | Fuel cell device |
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Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100529079B1 (en) * | 2004-03-25 | 2005-11-15 | 삼성에스디아이 주식회사 | Fuel cell system |
JP4956187B2 (en) * | 2004-06-25 | 2012-06-20 | 三菱鉛筆株式会社 | Fuel cell |
JP2010238591A (en) * | 2009-03-31 | 2010-10-21 | Toto Ltd | Fuel cell system |
CN102544554B (en) * | 2012-02-13 | 2014-10-29 | 欧阳洵 | Fuel cell system |
CN107091508B (en) * | 2017-03-24 | 2020-01-14 | 西安交通大学 | Distributed air conditioning apparatus and method |
CN106907811B (en) * | 2017-03-24 | 2020-01-14 | 西安交通大学 | Distributed air conditioning device and method |
CN107014110B (en) * | 2017-03-24 | 2020-01-14 | 西安交通大学 | Distributed water vapor cold-heat-electricity combined supply device and method |
CN107084553B (en) * | 2017-03-24 | 2020-01-14 | 西安交通大学 | Distributed combined cooling heating and power water vapor generation device and method |
CN107024028A (en) * | 2017-03-24 | 2017-08-08 | 西安交通大学 | A kind of distributed heat pump installation and method |
CN109921063A (en) * | 2017-12-13 | 2019-06-21 | 郑州宇通客车股份有限公司 | A kind of fuel battery air humidifying system, fuel cell system and vehicle |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001048850A1 (en) * | 1999-12-24 | 2001-07-05 | Sanyo Electric Co., Ltd. | Fuel cell power generating system |
WO2001091216A2 (en) * | 2000-05-23 | 2001-11-29 | Nissan Motor Co., Ltd. | Fuel cell system and method of controlling the same |
-
2002
- 2002-08-19 CN CNB021257973A patent/CN100384002C/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001048850A1 (en) * | 1999-12-24 | 2001-07-05 | Sanyo Electric Co., Ltd. | Fuel cell power generating system |
WO2001091216A2 (en) * | 2000-05-23 | 2001-11-29 | Nissan Motor Co., Ltd. | Fuel cell system and method of controlling the same |
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CN1474471A (en) | 2004-02-11 |
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Granted publication date: 20080423 |