CN100371402C - Infrared resistant coating and preparation process - Google Patents
Infrared resistant coating and preparation process Download PDFInfo
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- CN100371402C CN100371402C CNB2006101496902A CN200610149690A CN100371402C CN 100371402 C CN100371402 C CN 100371402C CN B2006101496902 A CNB2006101496902 A CN B2006101496902A CN 200610149690 A CN200610149690 A CN 200610149690A CN 100371402 C CN100371402 C CN 100371402C
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Abstract
The present invention relates to infrared resisting paint, and is especially one kind of infrared resisting paint and its recipe and preparation process. The infrared resisting paint is compounded with base material in 3-5 weight portions and pigment and stuffing in 3-5 weight portions as main components. The infrared resisting paint can form coating with high infrared reflecting capacity and certain heat insulating performance. It is coated to the surface of building to resist heat effect of sunlight, reduce the effect of sun radiation to the building, lower the temperature of the building, isolate heat and save energy.
Description
Technical field
The present invention relates to a kind of infrared resistant coating, especially relate to the prescription and the preparation technology thereof of infrared resistant coating.
Background technology
Hot summer, how reducing the indoor temperature of top layer is the problem that must consider.At present, regulate room temp by air-conditioning mostly, this need consume a large amount of electric energy.The highest infrared rays of heat energy in the sunlight of sweltering heat in summer is reflected, thereby reduce amount of heat absorption, be undoubtedly the energy-conservation again cool-down method of a kind of convenience.But, how to realize to ultrared reflection it being the problem of a more complicated.In order to address this problem, some producers have released infrared resistant coating, are coated in building surface, and reflected infrared is to reach the purpose that reduces temperature in the buildings.But existing infrared resistant coating exists many defectives, such as: cooling-down effect is good inadequately.For example, " infrared heat proof paint " bought on the market (hereinafter to be referred as " city's coating materials ") is coated in it on white ceramic tile and our coating contrast, 8:30 is exposed to the sun in the sun from the morning, to 12 noon, be coated with the ceramic tile of " city's flooring ", surface temperature is 42.5 degrees centigrade.Poor water resistance.For example, we are coated in " city's coating materials " and our coating on the sheet glass equally, soaked test after the drying, and the foaming phenomenon just took place in 36 hours in " city's coating materials ".
Summary of the invention
In order to solve the above-mentioned defective that existing infrared resistant coating exists, the invention provides a kind of novel anti infra-red paint, be used for effectively reducing the temperature in the buildings.
Technical scheme of the present invention is as follows:
The invention provides a kind of infrared resistant coating, it is characterized in that, is that main component is formulated with 3-5 weight part base-material and 3-5 weight part color stuffing.
Described base-material is: Acrylate copolymer or acid-organosilicon crylic acid multipolymer are preferably AD66 Acrylate copolymer (Dongfang Chemical Plant, Beijing, The East Chemical Plant,Beijing's production) or acid-organosilicon crylic acid multipolymer KD8 acid-organosilicon crylic acid multipolymer (Dongfang Chemical Plant, Beijing, The East Chemical Plant,Beijing's production).
Described color stuffing is: titanium dioxide (Du Pont's product), dicalcium powder (1250 order), wollastonite (800 order), sericite (800 order), process white (800 order), kaolins (1250 order), ceramic fine bead (2500 orders, the inferior nano material of Shanghai Ge Run company limited) or a kind of or its arbitrary combination in the cenosphere (2500 orders, the inferior nano material of Shanghai Ge Run company limited).
In the process for preparation of above-mentioned infrared resistant coating, add in an amount of sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent, the thickening leveling agent one or more as required.Preferred addition is sterilant, wetting agent, dispersion agent, defoamer, the film coalescence aid of 0.1-0.4% weight, the flow agent of 2-5% weight and coating can be adjusted to thickening material, the thickening leveling agent that viscosity is 96-100 and coating pH value be adjusted in the pH value conditioning agent of 8-9.5 one or more.
Described sterilant is different thiophene quinoline copper (U.S. ROHMHAAS product), wetting agent is alkane diethylstilbestrol Soxylat A 25-7 (a LG-DOW company product), dispersion agent is sodium polyacrylate salt brine solution (a Jin Yuan chemical reagents corporation product), defoamer is organosilicon Dormant oils mixture (extra large river chemical company produce), film coalescence aid is TEXANOR (U.S. Yi Shi Man product), flow agent is UH530 (the electrochemical Co., Ltd. of the Japanese rising sun produces), thickening material is TCP618 (a Jin Yuan chemical reagents corporation product), pH value conditioning agent is TCP95 (a Jin Yuan chemical reagents corporation product), the thickening leveling agent is UH420 (the electrochemical Co., Ltd. of the Japanese rising sun produces).
The present invention also provides the preparation technology of described infrared resistant coating, it is characterized in that, comprises the steps:
(1) water and color stuffing mix the back grinding in mixing tank;
(2) add described weight part base-material, drop into paint mixing unit and be in harmonious proportion, filter, get filtrate.
In step (1) and step (2), add in an amount of sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent, the thickening leveling agent one or more as required.
Preferred addition is sterilant, wetting agent, dispersion agent, defoamer, the film coalescence aid of 0.1-0.4% weight, the flow agent of 2-5% weight and coating can be adjusted to thickening material, the thickening leveling agent that viscosity is 96-100 and coating pH value be adjusted to the pH value conditioning agent of 8-9.5
The beneficial effect that the present invention realized is as follows:
Product provided by the present invention both had great reflection potential (the infrared reflection rate is more than 70%) to infrared rays, and certain heat preservation and insulation (cenosphere has heat-insulating property) is arranged again.It is coated on the white ceramic tile, and 8:30 is exposed to the sun in the sun from the morning,, is coated with the ceramic tile of " city's flooring " to 12 noon, and surface temperature is 42.5 degrees centigrade, and the surface temperature that is coated with the ceramic tile of our material is 38-39 degree centigrade.Coating provided by the present invention is coated on the sheet glass, and soaked test after the drying was not also bubbled in 60 days.
Be used in building surface, can effectively resist the solar infrared heat effect, effectively stop the influence of sun heat radiation, reduce the temperature of buildings, and certain insulation effect is arranged, reach effective purpose of energy saving buildings in summer.
The preparation technology of infrared resistant coating provided by the present invention is simple, and cost is low, and infrared reflection is effective.Be coated in building surface, can effectively reduce the temperature in the buildings.
Embodiment
Embodiment 1:
The prescription that present embodiment adopted is as follows:
With 300-500 weight part base-material and 300-500 weight part color stuffing is that main component is formulated.
Described base-material is: Acrylate copolymer or acid-organosilicon crylic acid multipolymer are preferably AD66 Acrylate copolymer (Dongfang Chemical Plant, Beijing, The East Chemical Plant,Beijing's production) or acid-organosilicon crylic acid multipolymer KD8 acid-organosilicon crylic acid multipolymer (Dongfang Chemical Plant, Beijing, The East Chemical Plant,Beijing's production).
Described color stuffing is: titanium dioxide (Du Pont's product), dicalcium powder (1250 order), wollastonite (800 order), sericite (800 order), process white (800 order), kaolins (1250 order), ceramic fine bead (2500 orders, the inferior nano material of Shanghai Ge Run company limited) or a kind of or its arbitrary combination in the cenosphere (2500 orders, the inferior nano material of Shanghai Ge Run company limited).
In the process for preparation of above-mentioned infrared resistant coating, add an amount of sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent, thickening leveling agent as required.Preferred addition is sterilant, wetting agent, dispersion agent, defoamer, the film coalescence aid of 0.1-0.4% weight, the flow agent of 2-5% weight and coating can be adjusted to thickening material, the thickening leveling agent that viscosity is 96-100 and coating pH value be adjusted to the pH value conditioning agent of 8-9.5.
Described sterilant is different thiophene quinoline copper (U.S. ROHMHAAS product), wetting agent is alkane diethylstilbestrol Soxylat A 25-7 (a LG-DOW company product), dispersion agent is sodium polyacrylate salt brine solution (a Jin Yuan chemical reagents corporation product), defoamer is organosilicon Dormant oils mixture (extra large river chemical company produce), film coalescence aid is TEXANOR (U.S. Yi Shi Man product), flow agent is UH530 (the electrochemical Co., Ltd. of the Japanese rising sun produces), thickening material is TCP618 (a Jin Yuan chemical reagents corporation product), pH value conditioning agent is TCP95 (a Jin Yuan chemical reagents corporation product), the thickening leveling agent is UH420 (the electrochemical Co., Ltd. of the Japanese rising sun produces).
The present invention also provides the preparation technology of described infrared resistant coating, it is characterized in that, comprises the steps:
(1) water and color stuffing mix the back grinding in mixing tank;
(2) add described weight part base-material, drop into paint mixing unit and be in harmonious proportion, filter, get filtrate.
In step (1) and step (2), add an amount of sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent, thickening leveling agent as required.
Preferred addition is sterilant, wetting agent, dispersion agent, defoamer, the film coalescence aid of 0.1-0.4% weight, the flow agent of 2-5% weight and coating can be adjusted to thickening material, the thickening leveling agent that viscosity is 96-100 and coating pH value be adjusted to the pH value conditioning agent of 8-9.5
Use the compliance test result of the prepared infrared resistant coating of present embodiment as follows:
The existing counter infrared ray heat effect of the infrared resistant coating effect that present embodiment is prepared has certain heat-insulating property again.Be coated in building surface, effectively reduce the temperature of buildings.Concrete process of the test and result data are described below: under summer strong sunshine condition, Portland cement roof temperature is 56 degrees centigrade, scribbles 34 degrees centigrade of the roof surface temperature of this coating, and the temperature difference reaches 22 degrees centigrade.
Embodiment 2
The prescription of present embodiment following (in weight part):
Distilled water 122
The different thiophene quinoline of LXE ketone 2
The own phenol polyethenoxy ether 2 of X405 alkane
The 8030N polycarboxylate sodium aqueous solution 30%
8045 sodium polyacrylate salt brine solutions 45%6
SN154 organosilicon Dormant oils mixture 1
Propylene-glycol ethyl ether amyl acetate 30
R902 titanium dioxide 150
Wollastonite 50
Kaolin 40
Cenosphere (2500M order) 200
KD8 acid-organosilicon crylic acid multipolymer 360
A10 Dormant oils mixture 1
TEXANOR12 lipidol 18
The high alkali organic amino 2 of TCP95 special chemical structure
UH450 non-ionic hydrophobic polyurethane 12
UH530 non-ionic hydrophobic polyurethane 6
The preparation method is as follows:
(1) water and color stuffing mix the back grinding in mixing tank;
(2) add described weight part base-material, drop into paint mixing unit and be in harmonious proportion, filter, get filtrate.
In step (1) and step (2), add sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent or the thickening leveling agent of described amount as required.
Use the compliance test result of the prepared infrared resistant coating of present embodiment as follows:
The infrared resistant coating that present embodiment is prepared is coated in building surface, effectively reduces the temperature of buildings.Concrete process of the test and result data are described below:
Under summer strong sunshine condition, Portland cement roof temperature is 52 degrees centigrade, scribbles 32 degrees centigrade of the roof surface temperature of this coating, and the temperature difference reaches 20 degrees centigrade.
Embodiment 3:
The prescription of present embodiment following (in weight part):
Distilled water 110
The different thiophene quinoline of LXE ketone 2
The own phenol polyethenoxy ether 1.5 of X405 alkane
8045 polyacrylic acid sodium salts, 45% aqueous solution 4
SN154 organosilicon Dormant oils mixture 1
Propylene-glycol ethyl ether amyl acetate 25
R902 titanium dioxide 180
Dicalcium powder 70
Process white 50
Cenosphere (2500 order) 60
AD66 modified polyacrylic acid fat 450
A10 Dormant oils mixture 2
TEXANOR12 lipidol 20
The high alkali organic amino 2 of TCP95 special chemical structure
UH450 non-ionic hydrophobic polyurethane 5
UH530 non-ionic hydrophobic polyurethane 15
TCP007 acrylic polymer 12
The preparation method is as follows:
(1) water and color stuffing mix the back grinding in mixing tank;
(2) add described weight part base-material, drop into paint mixing unit and be in harmonious proportion, filter, get filtrate.
In step (1) and step (2), add sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent or the thickening leveling agent of described amount as required.
Use the compliance test result of the prepared infrared resistant coating of present embodiment as follows:
The infrared resistant coating that present embodiment is prepared is coated in building surface, effectively reduces the temperature of buildings.Concrete process of the test and result data are described below:
Under summer strong sunshine condition, Portland cement roof temperature is 52 degrees centigrade, scribbles 32 degrees centigrade of the roof surface temperature of this coating, and the temperature difference reaches 20 degrees centigrade.
Embodiment 4:
The prescription of present embodiment following (in weight part):
Distilled water 115
The different thiophene quinoline of LXE ketone 2
The own phenol polyethenoxy ether 2 of X405 alkane
8045 polyacrylic acid sodium salts, 45% aqueous solution 5
SN154 organosilicon Dormant oils mixture 1
Propylene-glycol ethyl ether amyl acetate 25
R902 titanium dioxide 150
Sericite 20
Talcum powder 20
Ceramic fine bead (2500 order) 160
AD66 modified polyacrylic acid fat 450
A10 Dormant oils mixture 2
TEXANOR12 lipidol 22
UH530 non-ionic hydrophobic polyurethane 15
TCP6186
UH420 non-ionic hydrophobic polyurethane 3
The preparation method is as follows:
(1) water and color stuffing mix the back grinding in mixing tank;
(2) add described weight part base-material, drop into paint mixing unit and be in harmonious proportion, filter, get filtrate.
In step (1) and step (2), add sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent or the thickening leveling agent of described amount as required.
Use the compliance test result of the prepared infrared resistant coating of present embodiment as follows:
The infrared resistant coating that present embodiment is prepared is coated in building surface, effectively reduces the temperature of buildings.Concrete process of the test and result data are described below:
Under summer strong sunshine condition, Portland cement roof temperature is 52 degrees centigrade, scribbles 32 degrees centigrade of the roof surface temperature of this coating, and the temperature difference reaches 20 degrees centigrade.
Embodiment 5:
The prescription that present embodiment adopted is as follows:
With 3 weight part base-materials and 5 weight part color stuffings is that main component is formulated.
Described base-material is: Acrylate copolymer or acid-organosilicon crylic acid multipolymer are preferably AD66 Acrylate copolymer (Dongfang Chemical Plant, Beijing, The East Chemical Plant,Beijing's production) or acid-organosilicon crylic acid multipolymer KD8 acid-organosilicon crylic acid multipolymer (Dongfang Chemical Plant, Beijing, The East Chemical Plant,Beijing's production).
Described color stuffing is: a kind of or its arbitrary combination in titanium dioxide (Du Pont's product), dicalcium powder (1250 order), wollastonite (800 order), sericite (800 order), process white (800 order), kaolin (1250 order), the ceramic fine bead (2500 orders, the inferior nano material of Shanghai Ge Run company limited).
In the process for preparation of above-mentioned infrared resistant coating, add an amount of sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent, thickening leveling agent as required.Addition is sterilant, wetting agent, dispersion agent, defoamer, the film coalescence aid of 0.1-0.4% weight, the thickening leveling agent of 2-5% weight and coating pH value is adjusted to the pH value conditioning agent of 8-9.5.
Described sterilant is that different thiophene quinoline copper (U.S. ROHMHAAS product), wetting agent are that alkane diethylstilbestrol Soxylat A 25-7 (LG-DOW company product), dispersion agent are that sodium polyacrylate salt brine solution (Jin Yuan chemical reagents corporation product), defoamer are that organosilicon Dormant oils mixture (extra large river chemical company produce), film coalescence aid are that TEXANOR (U.S. Yi Shi Man products), pH value conditioning agent are that TCP95 (Jin Yuan chemical reagents corporation product), thickening leveling agent are UH420 (the electrochemical Co., Ltd. of Japanese rising sun product).
The present invention also provides the preparation technology of described infrared resistant coating, it is characterized in that, comprises the steps:
(1) water and color stuffing mix the back grinding in mixing tank;
(2) add described weight part base-material, drop into paint mixing unit and be in harmonious proportion, filter, get filtrate.
In step (1) and step (2), add an amount of sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent, thickening leveling agent as required.Addition is sterilant, wetting agent, dispersion agent, defoamer, the film coalescence aid of 0.1-0.4% weight, the thickening leveling agent of 2-5% weight and coating pH value is adjusted to the pH value conditioning agent of 8-9.5,
Use the compliance test result of the prepared infrared resistant coating of present embodiment as follows:
The existing counter infrared ray heat effect of the infrared resistant coating effect that present embodiment is prepared has certain heat-insulating property again.Be coated in building surface, effectively reduce the temperature of buildings.Concrete process of the test and result data are described below: under summer strong sunshine condition, Portland cement roof temperature is 56 degrees centigrade, scribbles 34 degrees centigrade of the roof surface temperature of this coating, and the temperature difference reaches 22 degrees centigrade.
Embodiment 6:
The prescription that present embodiment adopted is as follows:
With 5 heavy parts of base-materials and 3 weight part color stuffings is that main component is formulated.
Described base-material is: Acrylate copolymer or acid-organosilicon crylic acid multipolymer are preferably AD66 Acrylate copolymer (Dongfang Chemical Plant, Beijing, The East Chemical Plant,Beijing's production) or acid-organosilicon crylic acid multipolymer KD8 acid-organosilicon crylic acid multipolymer (Dongfang Chemical Plant, Beijing, The East Chemical Plant,Beijing's production).
Described color stuffing is: a kind of or its arbitrary combination in titanium dioxide (Du Pont's product), dicalcium powder (1250 order), wollastonite (800 order), sericite (800 order), process white (800 order), kaolin (1250 order), the cenosphere (2500 orders, the inferior nano material of Shanghai Ge Run company limited).
In the process for preparation of above-mentioned infrared resistant coating, add an amount of sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent as required.Addition is sterilant, wetting agent, dispersion agent, defoamer, the film coalescence aid of 0.1-0.4% weight, the flow agent of 2-5% weight and coating can be adjusted to the thickening material that viscosity is 96-100 and coating pH value be adjusted to the pH value conditioning agent of 8-9.5.
Described sterilant is different thiophene quinoline copper (U.S. ROHMHAAS product), wetting agent is alkane diethylstilbestrol Soxylat A 25-7 (a LG-DOW company product), dispersion agent is sodium polyacrylate salt brine solution (a Jin Yuan chemical reagents corporation product), defoamer is organosilicon Dormant oils mixture (extra large river chemical company produce), film coalescence aid is TEXANOR (U.S. Yi Shi Man product), flow agent is UH530 (the electrochemical Co., Ltd. of the Japanese rising sun produces), thickening material is TCP618 (a Jin Yuan chemical reagents corporation product), pH value conditioning agent is TCP95 (a Jin Yuan chemical reagents corporation product).
The present invention also provides the preparation technology of described infrared resistant coating, it is characterized in that, comprises the steps:
(1) water and color stuffing mix the back grinding in mixing tank;
(2) add described weight part base-material, drop into paint mixing unit and be in harmonious proportion, filter, get filtrate.
In step (1) and step (2), add an amount of sterilant, wetting agent, dispersion agent, defoamer, film coalescence aid, flow agent, thickening material, pH value conditioning agent as required.
Preferred addition is sterilant, wetting agent, dispersion agent, defoamer, the film coalescence aid of 0.1-0.4% weight, the flow agent of 2-5% weight and coating can be adjusted to the thickening material that viscosity is 96-100 and coating pH value be adjusted to the pH value conditioning agent of 8-9.5
Use the compliance test result of the prepared infrared resistant coating of present embodiment as follows:
The existing counter infrared ray heat effect of the infrared resistant coating effect that present embodiment is prepared has certain heat-insulating property again.Be coated in building surface, effectively reduce the temperature of buildings.Concrete process of the test and result data are described below: under summer strong sunshine condition, Portland cement roof temperature is 56 degrees centigrade, scribbles 34 degrees centigrade of the roof surface temperature of this coating, and the temperature difference reaches 22 degrees centigrade.
Claims (5)
1. an infrared resistant coating is characterized in that, the prescription of described coating is as follows:
3-5 parts by weight of acrylic resin copolymer, the color stuffing of 3-5 weight part, and an amount of coatings additive(s);
Described an amount of coatings additive(s) is meant: account in sterilant, wetting agent, dispersion agent, defoamer or the film coalescence aid of coating gross weight 0.1-0.4% one or more, or account for coating gross weight 2-5% flow agent, coating can be adjusted to thickening material that viscosity is 96-100, thickening leveling agent, coating pH value be adjusted in the pH value conditioning agent of 8-9.5 one or more.
2. infrared resistant coating according to claim 1 is characterized in that, described color stuffing is a kind of or its arbitrary combination in titanium dioxide, dicalcium powder, wollastonite, sericite, process white, kaolin or the cenosphere.
3. infrared resistant coating according to claim 2, it is characterized in that described sterilant is that different thiophene quinoline copper, wetting agent are that alkane diethylstilbestrol Soxylat A 25-7, dispersion agent are that sodium polyacrylate salt brine solution, defoamer are that organosilicon Dormant oils mixture, film coalescence aid are that TEXANOR, flow agent are that UH530, thickening material are that TCP618, pH value conditioning agent are that TCP95, thickening leveling agent are UH420.
4. the preparation technology of any described infrared resistant coating of claim 1-3 is characterized in that, comprises the steps:
(1) water and color stuffing mix the back grinding in mixing tank;
(2) add described weight part base-material, drop into paint mixing unit and be in harmonious proportion, filter, get filtrate;
In step (1) and step (2), add an amount of coatings additive(s) as required.
5. the preparation technology of preferred infrared resistant coating according to claim 4, it is characterized in that, in step (1) and step (2), addition is sterilant, wetting agent, dispersion agent, defoamer, the film coalescence aid of 0.1-0.4% weight as required, the flow agent of 2-5% weight and coating can be adjusted to thickening material, the thickening leveling agent that viscosity is 96-100 and coating pH value be adjusted in the pH value conditioning agent of 8-9.5 one or more.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2006101496902A CN100371402C (en) | 2006-10-16 | 2006-10-16 | Infrared resistant coating and preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101496902A CN100371402C (en) | 2006-10-16 | 2006-10-16 | Infrared resistant coating and preparation process |
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| CN1927964A CN1927964A (en) | 2007-03-14 |
| CN100371402C true CN100371402C (en) | 2008-02-27 |
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| CNB2006101496902A Expired - Fee Related CN100371402C (en) | 2006-10-16 | 2006-10-16 | Infrared resistant coating and preparation process |
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Cited By (1)
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| CN102350841A (en) * | 2011-06-22 | 2012-02-15 | 中纺新材料科技有限公司 | Making technology of sound-proof, thermal insulating and high shading efficiency curtain fabric |
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| CN101092533B (en) * | 2007-08-16 | 2011-06-08 | 陈庆洪 | Paint with spectral selectivity, preparation method, and application |
| CN104164003A (en) * | 2014-07-15 | 2014-11-26 | 滁州市富力克斯电线电缆有限公司 | Modified mica powder for chlorinated polyethylene cable materials and preparation method thereof |
| CN104212291A (en) * | 2014-09-25 | 2014-12-17 | 徐妍玲 | Water-based thermal insulation primer |
| CN104212283A (en) * | 2014-09-25 | 2014-12-17 | 徐妍玲 | Method for preparing water-based thermal insulation primer |
| CN107674462A (en) * | 2017-10-11 | 2018-02-09 | 大连理工大学 | A kind of preparation method and application of 3 D multi-colour CQDs@MeOOH anti-infrared nano-functional materials |
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| Publication number | Publication date |
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| CN1927964A (en) | 2007-03-14 |
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