CN100371384C - Reacting nano inorganic particle/polymer composite material - Google Patents
Reacting nano inorganic particle/polymer composite material Download PDFInfo
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- CN100371384C CN100371384C CNB2006100340117A CN200610034011A CN100371384C CN 100371384 C CN100371384 C CN 100371384C CN B2006100340117 A CNB2006100340117 A CN B2006100340117A CN 200610034011 A CN200610034011 A CN 200610034011A CN 100371384 C CN100371384 C CN 100371384C
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- 229920000642 polymer Polymers 0.000 title claims abstract description 28
- 239000002131 composite material Substances 0.000 title claims abstract description 13
- 239000010954 inorganic particle Substances 0.000 title claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 47
- 239000011159 matrix material Substances 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 27
- 239000000126 substance Substances 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 30
- -1 diamine compounds Chemical class 0.000 claims description 27
- 239000004743 Polypropylene Substances 0.000 claims description 20
- 229920001155 polypropylene Polymers 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000003999 initiator Substances 0.000 claims description 16
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 16
- 239000002105 nanoparticle Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 239000007822 coupling agent Substances 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 230000035484 reaction time Effects 0.000 claims description 10
- 239000005543 nano-size silicon particle Substances 0.000 claims description 9
- 238000002203 pretreatment Methods 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical group CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical group CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 6
- 238000010559 graft polymerization reaction Methods 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 238000011068 loading method Methods 0.000 claims description 4
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 238000005576 amination reaction Methods 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
- 238000007306 functionalization reaction Methods 0.000 claims description 3
- 230000004927 fusion Effects 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims 1
- 239000012716 precipitator Substances 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 7
- 238000012545 processing Methods 0.000 abstract description 6
- 239000006185 dispersion Substances 0.000 abstract description 3
- 230000009471 action Effects 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 25
- 239000000463 material Substances 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 17
- 229960001866 silicon dioxide Drugs 0.000 description 12
- 239000002114 nanocomposite Substances 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 11
- 229920002189 poly(glycerol 1-O-monomethacrylate) polymer Polymers 0.000 description 8
- 235000012239 silicon dioxide Nutrition 0.000 description 8
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 5
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000004781 supercooling Methods 0.000 description 2
- 238000002411 thermogravimetry Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Description
Modified manometer silicon dioxide weight (g) | Functional poly propylene (PP-g-NH 2) weight (g) | Polypropylene (g) | |
|
2 (SiO 2-g-PGMA) 3 (SiO 2-g-PGMA) | 10 10 | 88 87 |
Embodiment 3 embodiment 4 | 2 (SiO 2-g-P(BA-co-GMA)) 3 (SiO 2-g-P(BA-co-GMA)) | 10 10 | 88 87 |
Nano silicon weight (g) | Functional poly propylene (PP-g-NH 2) weight (g) | Polypropylene (g) | |
Comparative example 1 comparative example 2 comparative examples 3 comparative examples 4 comparative examples 5 | 0 2 (SiO 2) 3 (SiO 2) 3 (SiO 2-g-PGMA) 2 (SiO 2-g-P(BA-co-GMA)) | 0 0 0 0 0 | 100 98 97 97 98 |
Performance | Embodiment | Comparative example | |||||||
1 | 2 | 3 | 4 | 1 | 2 | 3 | 4 | 5 | |
Simply supported beam notched Izod impact strength (kJ/m 2) tensile strength (MPa) tensile modulus (GPa) fusing point Tm (℃) the fastest temperature T c of crystallization (℃) Δ T=Tm-Tc (℃) crystallinity Xc (%) | 3.29 42.2 1.28 165.6 125.7 39.9 59.7 | 3.22 42.3 1.33 165.8 125.5 40.3 58.1 | 3.44 42.3 1.34 165.4 125.7 39.7 54.7 | 3.35 42.2 1.40 165.5 125.9 39.6 55.7 | 1.85 37.8 1.06 164.8 115.9 48.9 54.3 | 2.09 38.0 1.27 164.5 116.5 48.0 54.6 | 1.93 38.5 1.33 164.2 116.9 47.3 54.8 | 1.95 40.9 1.22 165.3 118.6 46.7 52.2 | 1.98 41.5 1.18 164.0 118.9 45.1 54.3 |
Claims (3)
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CNB2006100340117A CN100371384C (en) | 2006-03-03 | 2006-03-03 | Reacting nano inorganic particle/polymer composite material |
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CNB2006100340117A CN100371384C (en) | 2006-03-03 | 2006-03-03 | Reacting nano inorganic particle/polymer composite material |
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CN1834147A CN1834147A (en) | 2006-09-20 |
CN100371384C true CN100371384C (en) | 2008-02-27 |
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Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2110388A1 (en) * | 2008-04-18 | 2009-10-21 | Nanoresins AG | Polymerisable substance with connected nanoparticles |
BR112012007064A2 (en) * | 2009-09-29 | 2016-04-19 | Interfacial Soluitons Ip Llc | compatibilizer mixture for polymeric compositions |
CN102504611A (en) * | 2011-10-17 | 2012-06-20 | 中科院广州化学有限公司 | Improved silicon dioxide, high-performance lithium ion battery separator membrane and application thereof |
CN102604204B (en) * | 2012-01-18 | 2013-10-23 | 大连工业大学 | Polypropylene composite material and preparation method thereof |
CN103275372A (en) * | 2013-05-21 | 2013-09-04 | 苏州旭光聚合物有限公司 | Wear-resistant PP (Propene Polymer)/PE (Poly Ethylene) composite |
CZ307301B6 (en) | 2013-12-17 | 2018-05-23 | Univerzita Tomáše Bati ve Zlíně | A compact formation of a composite character and a method of its preparation |
CN104962026B (en) * | 2015-07-09 | 2017-05-03 | 河北工业大学 | Preparing method of composite compatilizer |
CN105482228A (en) * | 2016-01-05 | 2016-04-13 | 广州枫叶管业有限公司 | Polyethylene nano-modified composite and preparing method and application thereof |
US10767018B2 (en) * | 2016-08-26 | 2020-09-08 | Csir | Isotactic polypropylene based composite |
CN108623749A (en) * | 2018-04-23 | 2018-10-09 | 郑州大学 | Polypropylene compatibilization and toughening agent and preparation method thereof |
CN108676344A (en) * | 2018-05-16 | 2018-10-19 | 江苏兆鋆新材料股份有限公司 | A kind of modified polycarbonate, its manufactured polycarbonate thermoplastic prepreg and preparation method |
CN109135551B (en) * | 2018-08-09 | 2020-11-20 | 深圳市前海奇迹新材料有限公司 | High-flexibility water-based UV coating |
CN112514685A (en) * | 2020-12-04 | 2021-03-19 | 安徽强茗塑业科技有限公司 | Reinforced grass planting grid and preparation method thereof |
CN113667220A (en) * | 2021-09-30 | 2021-11-19 | 遵义职业技术学院 | Preparation method of synergistic interface layer applied to polypropylene/nano silicon dioxide composite material |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1493607A (en) * | 2002-10-29 | 2004-05-05 | 中国科学院化学研究所 | Polypropylene/clay nano complex substance and its preparation method and application |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1493607A (en) * | 2002-10-29 | 2004-05-05 | 中国科学院化学研究所 | Polypropylene/clay nano complex substance and its preparation method and application |
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CN1834147A (en) | 2006-09-20 |
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Assignee: Zhejiang Wansheng Chemical Co., Ltd. Assignor: Sun Yat-sen University Contract fulfillment period: 2008.12.12 to 2014.12.11 contract change Contract record no.: 2008330002760 Denomination of invention: Reacting nano inorganic particle/polymer composite material Granted publication date: 20080227 License type: Exclusive license Record date: 20081223 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.12.12 TO 2014.12.11; CHANGE OF CONTRACT Name of requester: ZHEJIANG PROVINCE WANSHENG CHEMICAL CO., LTD. Effective date: 20081223 |
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