CN100367926C - Shampoo containing plant extracts - Google Patents
Shampoo containing plant extracts Download PDFInfo
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- CN100367926C CN100367926C CNB2006100783609A CN200610078360A CN100367926C CN 100367926 C CN100367926 C CN 100367926C CN B2006100783609 A CNB2006100783609 A CN B2006100783609A CN 200610078360 A CN200610078360 A CN 200610078360A CN 100367926 C CN100367926 C CN 100367926C
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Abstract
The present invention discloses a shampoo containing plant extracts, which comprises surface active agents, foam booster, adhesion promoter, pearling agents, conditioner, preservatives, pigments, essence and deionized water. The shampoo is characterized in that the shampoo also contains 0.05 to 15.0% of shaddock leaf and/or Chinese wampee leaf extract of the weight of the shampoo. The shampoo of the present invention is rich in flavonoid substances, such as naringin, hesperidin, flavonoid glycoside, etc. The shampoo can achieve the effects of sterilizing bacteria, relieving itch, stopping dandruff, resisting inflammation, resisting allergy, preventing skin cancer, enhancing immunity, etc. The product of the present invention has the advantages of convenient use, mildness, no stimulation, rich foam, fragrant flavor and refreshment. After the shampoo is used, hair is smooth and elegant, and skin can be clean and comfortable. The shampoo integrates various functions, such as cleaning hair, protecting hair and benefiting skin.
Description
Technical field
The present invention relates to a kind of shampoo that contains plant extract.
Background technology
Along with the raising of people's living standard, also more and more higher to the prescription of shampoo.Originally, as long as shampoo satisfies clean of people's requirement, but along with growth in the living standard, it is straight smooth that people require to wash the back hair at leisure, anti-dandruff or the like, nowadays, along with the trend of naturalization, nutrient laden and the curative effectization of international hair shampoo article, more and more be subjected to the favor of consumer with the composite shampoo of the natural Chinese medicinal herb, plant extraction liquid and the natural nutriment that have no side effect, have curative effect and Nutrition.
Summary of the invention
The object of the present invention is to provide a kind of shampoo that contains plant extract, its mature production technology, product is easy to use, gentle, non-stimulated, foam enriches, smooth elegant with the back hair, skin is totally comfortable, and have sterilization, antipruritic, end functions such as bits, antiinflammatory, antiallergic and prevention skin carcinoma, enhancing immunity, be the Mobyneb shampoo that integrates clean, hair care and skin and complexion improving.
For achieving the above object, the present invention adopts following technical scheme:
A kind of shampoo that contains plant extract of the present invention, it comprises surfactant, suds booster, viscosifier, pearling agent, conditioner, antiseptic, pigment, essence, deionized water, also contain leaf of Fructus Citri grandis and/or Folium clausenae lansii extract in the described shampoo, the percentage by weight that described plant extract accounts for shampoo is 0.05~15.0%.
The extracting method of leaf of Fructus Citri grandis of the present invention and Folium clausenae lansii extract is: get leaf of Fructus Citri grandis and Folium clausenae lansii defat with petroleum ether after-filtration, obtain defat leaf of Fructus Citri grandis and Folium clausenae lansii; To the alcoholic solution that wherein adds 70%, under 80 ℃ of constant temperature, refluxed 6 hours, cooled and filtered is concentrated to 1/7 volume with the filtrate decompression distillation, with isopyknic water-saturated n-butanol extraction, getting the distilling under reduced pressure of n-butyl alcohol phase is concentrated to and is the thick time cooling of brown, the dissolve with methanol solution of adding 80% adds acetone again and fully vibrates centrifugation, dry pale yellow powder shape extract, i.e. flavonoid material.
Surfactant of the present invention is selected from one or more combination of ammonium lauryl sulfate, Sodium Alcohol Ether Sulphate or fat alcohol polyethylene ether ammonium sulfate.
Suds booster of the present invention and viscosifier are selected from one or more combination of coconut monoethanolamide, cocoanut oil diethan olamide, Oleum Cocois acyl group CAB or sodium chloride.
Pearling agent of the present invention is a polyethylene glycol stearate diester.
Conditioner of the present invention is selected from one or more combination of cation guar gum, polyquaternary ammonium salt-39 or polyquaternium-7.
Antiseptic of the present invention is an isothiazolone magnesium sulfate.
Leaf of Fructus Citri grandis is rich in the plain material of multiple flavonoid such as naringin, hesperidin, they have unique armaticity and significant pharmacotoxicological effect, can prevent and treat the disease and the chronic bronchitis of cardiovascular system, also have cough-relieving, relieving asthma eliminate the phlegm, anti-capillary fragility, anti-inflammatory and effects such as irritated active, antibacterial, anticancer, antioxidation, blood circulation promoting and enhancing immunity.And be rich in flavonoid glycoside in the Folium clausenae lansii, treatment diabetes, anoxia, amnesia etc. are had significant curative effect.
The present invention extracts the active ingredient of leaf of Fructus Citri grandis and Folium clausenae lansii and is applied in the shampoo, reach the sterilization of high-efficient and lasting ground, antipruritic, end bits, antiinflammatory, the purpose of antiallergic and prevention skin carcinoma and enhancing immunity, again in conjunction with anion surfactant and other surfactants, make product easy to use, gentle, non-stimulated, foam is abundant, smooth elegant with the back hair, skin is totally comfortable, and has a sterilization, antipruritic, end bits, antiinflammatory, antiallergic, and prevention skin carcinoma, functions such as enhancing immunity are clean of collection, hair care and skin and complexion improving are in the Mobyneb shampoo of one.
The ammonium lauryl sulfate that the present invention selects to use is K12 ammonium salt (ALSA), belongs to mild acidulous anion surfactant.Foam is abundant, and zest is little, and viscosity is big, easily flushing.
Polyoxyethylenated alcohol sodium sulfate is soluble in water, has good decontamination, emulsifying, foam performance and anti-performance of hard water, and biological degradability is good.AESA has good washing detergency ability and biological degradability, and anti-hard water is strong, in hard water, promptly is when having a large amount of dirts to exist, also to have good foaming characteristic.Foam is abundant, fine and smooth, and gives hair soft with easy combing sense with skin is smooth and comfort.
Surfactant of the present invention aspect is selected ammonium lauryl sulfate (K12A), Sodium Alcohol Ether Sulphate (AES) or fat alcohol polyethylene ether ammonium sulfate (AESA) for use; With coconut monoethanolamide (CMEA), cocoanut oil diethan olamide (6501) and Oleum Cocois acyl group CAB (CAB) or sodium chloride is suds booster and viscosifier, play a part foam enhancing, surely the bubble and tackify.Selecting polyethylene glycol stearate diester for use is pearling agent, gives the product pearl effect.With cation pawl that glue (C-14-S), polyquaternary ammonium salt-7 (M550) and polyquaternary ammonium salt-39 is conditioner, further improves the sensation after washing.Antiseptic is selected isothiazolone magnesium sulfate for use.Good product performance after these compositions are composite, bubble soon, also have the ability of certain bacteria growing inhibiting, keep the soft and smooth of the normal function of skin and hair quality, do not damage hair quality.
The batch process production method is adopted in the production procedure that contains the shampoo of plant extract of the present invention.
In mixing kettle, heat up earlier surfactant ammonium lauryl sulfate (K12A), Sodium Alcohol Ether Sulphate (AES) or the dissolvings such as (AESA) of fat alcohol polyethylene ether ammonium sulfate, then add pearlescent flake, dissolving, be warmed up to 84~87 ℃, water with about 3% disperses your glue of cation pawl the back to add, then temperature is raised to 85~87 ℃, polyquaternary ammonium salt-7 (M550) and polyquaternary ammonium salt-39 after the water dilution of adding about 3%, because the system under the high temperature is very rare, and polyquaternary ammonium salt-7 (M550) and polyquaternary ammonium salt-39 are very thick, disperse polyquaternary ammonium salt-7 (M550) and polyquaternary ammonium salt-39 to disperse with enough big shearing force, and rare system can't provide enough big shearing force, disperses so polyquaternary ammonium salt-7 (M550) and polyquaternary ammonium salt-39 dilution add easily.Cool to about 70 ℃; add coconut monoethanolamide (CMEA), cocoanut oil diethan olamide (6501) and raw materials such as Oleum Cocois acyl group CAB (CAB) or sodium chloride then successively; add plant extract (flavonoid), essence and pigment when stirring is cooled to 40 ℃ of left and right sides, stir.
The shampoo sample that contains plant extract of the present invention meets national body lotion QB1994 standard through the light industrial goods supervision and inspection station check of Guangdong Bureau of Technical Supervision.Through the check of Guangdong health and epidemic prevention station, its every index meets the sanitary quality standard and the security requirement of national regulation fully.
The shampoo that contains plant extract of the present invention, walk the road of green plants comprehensive exploitation, from leaf of Fructus Citri grandis and Folium clausenae lansii, extract flavonoid materials such as naringin, hesperidin and Clausena lansium (Lour.) Skeels glycoside, have sterilization, antipruritic, only bits, antiinflammatory, antiallergic and effects such as prevention skin carcinoma and enhancing immunity.
Shampoo performance gentleness of the present invention, foam are abundant, and be clearly comfortable, integrates clean, hair care, skin and complexion improving, through many batches on probation, effect is fine, does not have any untoward reaction.
The specific embodiment
The extraction and the evaluation of embodiment 1 leaf of Fructus Citri grandis extract
Take by weighing fresh leaf of Fructus Citri grandis 50 gram, clean, dry and pulverizes afterwards standby; With filtering with buchner funnel behind the defat with petroleum ether, obtain the defat leaf of Fructus Citri grandis; The defat leaf of Fructus Citri grandis is placed the 500ml boiling flask, shake up to the alcoholic solution 350ml that wherein adds 70% then, under 80 ℃ of constant temperature, refluxed 6 hours with Rotary Evaporators, filter with buchner funnel the cooling back, the filtrate decompression distillation is concentrated to 50ml, with isopyknic water-saturated n-butanol extraction, getting the distilling under reduced pressure of n-butyl alcohol phase is concentrated to and is the thick time cooling of brown, add 80% methanol solution 3ml dissolving, adding acetone 40ml more fully vibrates, centrifugation, oven dry promptly gets pale yellow powder shape extract, and wherein flavonoids content is 50%.
Test experience: extract and dense ammonia, magnesium powder/hydrochloric acid reaction produce feature yellow fluorescence and dark pink respectively, and judging above-mentioned leaf of Fructus Citri grandis extract qualitatively is flavonoids.
Details are as follows for flavonoids qualitative experiment scheme:
1, dense ammonia react:
Extract is dissolved with small amount of ethanol, point is on silica gel H (5%CMC is a binding agent) plate, use petroleum ether respectively: ethyl acetate=2: 1, chloroform: methanol=10: 1, ethyl acetate: acetone=10: 1 chromatographies, smoked on the strong aqua ammonia layer, place immediately under the fluorescent lamp, produce 3~4 bright yellow fluorescence speckles.
2, hydrochloric acid, magnesium powder reaction:
The alcoholic solution 1ml that gets extract adds magnesium powder in test tube an amount of, and the concentrated hydrochloric acid number droplet of reinjecting (1 time add) is dark pink at the foam place.
3, there is characteristic absorption the ultra-violet (UV) band of extract about 250nm.
4, extract is the pale yellow powder shape, has hydrophilic to a certain degree.
The extraction and the evaluation of embodiment 2 Folium clausenae lansii extracts
1, gets fresh Folium clausenae lansii 1000 gram, clean, dry and pulverizes afterwards standby;
2, with filtering with buchner funnel behind the defat with petroleum ether, obtain the defat Folium clausenae lansii;
3, the defat Folium clausenae lansii is placed the boiling flask of 5L, shake up to the alcoholic solution 3.5L that wherein adds 70% then, under 80 ℃ of constant temperature, refluxed 6 hours, filter with buchner funnel the cooling back, the filtrate decompression distillation is concentrated to 500ml, with isopyknic water-saturated n-butanol extraction, getting the distilling under reduced pressure of n-butyl alcohol phase is concentrated to and is the thick time cooling of brown, the methanol solution 30ml dissolving of adding 80%, adding 400ml acetone more fully vibrates, centrifugation, oven dry promptly gets pale yellow powder shape extract, and wherein flavonoids content is 50%.
4, test experience: extract and dense ammonia, magnesium powder/hydrochloric acid reaction produce feature yellow fluorescence and dark pink respectively, judge that qualitatively the said extracted thing is the flavonoids in leaf of Fructus Citri grandis or the Folium clausenae lansii.
Flavonoids qualitative experiment scheme is with embodiment 1.
The extraction and the evaluation of embodiment 3 leaf of Fructus Citri grandis and Folium clausenae lansii extract
1, gets fresh leaf of Fructus Citri grandis and Folium clausenae lansii totally 1000 grams, clean, dry and pulverizes afterwards standby;
2, with filtering with buchner funnel behind the defat with petroleum ether, obtain defat leaf of Fructus Citri grandis and Folium clausenae lansii;
3, defat leaf of Fructus Citri grandis and Folium clausenae lansii are placed the boiling flask of 5L, shake up to the alcoholic solution 3.5L that wherein adds 70% then, under 80 ℃ of constant temperature, refluxed 6 hours, filter with buchner funnel the cooling back, the filtrate decompression distillation is concentrated to 500ml, with isopyknic water-saturated n-butanol extraction, getting the distilling under reduced pressure of n-butyl alcohol phase is concentrated to and is the thick time cooling of brown, the methanol solution 30ml dissolving of adding 80%, add 400ml acetone again and fully vibrate, centrifugation, oven dry promptly gets pale yellow powder shape extract, wherein, flavonoids content is 50%.
4, test experience: extract and dense ammonia, magnesium powder/hydrochloric acid reaction produce feature yellow fluorescence and dark pink respectively, judge that qualitatively the said extracted thing is the flavonoids in leaf of Fructus Citri grandis and the Folium clausenae lansii.
Flavonoids qualitative experiment scheme is with embodiment 1.
The preparation of embodiment 4-7 shampoo
The shampoo that contains plant extract of the present invention, comprise surfactant, suds booster, viscosifier, pearling agent, conditioner, antiseptic, pigment, essence, deionized water, also containing plant extract, is the flavonoid material that extracts from leaf of Fructus Citri grandis and/or Folium clausenae lansii; The percentage by weight of described plant extract is 0.05~15.0.
Concrete preparation method is as follows:
In mixing kettle, heat up earlier surfactant ammonium lauryl sulfate (K12A), Sodium Alcohol Ether Sulphate (AES) or the dissolvings such as (AESA) of fat alcohol polyethylene ether ammonium sulfate, then add the pearling agent polyethylene glycol stearate diester, dissolving, be warmed up to 84~87 ℃, water with about 3% disperses your glue of cation pawl the back to add, then temperature is raised to 85~87 ℃, add polyquaternary ammonium salt-7 (M550) and polyquaternary ammonium salt-39 after 3% left and right sides water dilutes, (because the system under the high temperature is very rare, and polyquaternary ammonium salt-7 (M550) and polyquaternary ammonium salt-39 are very thick, disperse polyquaternary ammonium salt-7 (M550) and polyquaternary ammonium salt-39 to disperse with enough big shearing force, and rare system can't provide enough big shearing force, disperses so polyquaternary ammonium salt-7 (M550) and polyquaternary ammonium salt-39 dilution add easily.) cool to about 70 ℃; add coconut monoethanolamide (CMEA), cocoanut oil diethan olamide (6501) and raw materials such as Oleum Cocois acyl group CAB (CAB) or sodium chloride then successively; add plant extract, essence and pigment when stirring is cooled to 40 ℃ of left and right sides, stir.
Concrete proportioning such as following table, the plant extract in its invading the exterior in the proportioning 1,2,3 and 4 be corresponding embodiment 1,2,3 and 4 plant extracts that prepare respectively.
Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | ||
Composition | Proportioning 1 (weight %) | Proportioning 2 (weight %) | Proportioning 3 (weight %) | Proportioning 4 (weight %) | |
Plant extract | 0.05 | 5.0 | 10.0 | 15.0 | |
Surfactant | Ammonium lauryl sulfate (25%) | 15.0 | 8.0 | 0 | 0 |
Sodium Alcohol Ether Sulphate (70%) | 5.0 | 7.0 | 0 | 9.0 | |
Fat alcohol polyethylene ether ammonium sulfate (70%) | 0 | 6.0 | 10.0 | 7.0 | |
Suds booster and viscosifier | Coconut monoethanolamide | 0 | 1.5 | 2.0 | 0 |
Cocoanut oil diethan olamide | 1.5 | 0 | 1.8 | 2.0 | |
Oleum Cocois acyl group CAB | 1.6 | 1.7 | 1.5 | 0 | |
Sodium chloride | In right amount | In right amount | In right amount | In right amount | |
Pearling agent | Polyethylene glycol stearate diester | 1.7 | 1.5 | 1.8 | 2.0 |
Conditioner | Cation guar gum | 0 | 0.5 | 0 | 0.5 |
Polyquaternary ammonium salt-39 | 3.0 | 0 | 3.5 | 3.3 | |
Polyquaternium-7 | 2.3 | 2.5 | 0 | 1.9 | |
Antiseptic | Isothiazolone magnesium sulfate | 0.1 | 0.1 | 0.1 | 0.1 |
Pigment | In right amount | In right amount | In right amount | In right amount | |
Essence | In right amount | In right amount | In right amount | In right amount | |
Deionized water | To 100.0 | To 100.0 | To 100.0 | To 100.0 |
Embodiment 8 trial effects that contain the shampoo of plant extract of the present invention
Object of study: scalp itch, dandruff is many, scalp is irritated, subinflammatory people, is divided into four experimental grouies, establishes a normal control group again, every group of each 50 people, wherein male 20 people, women 30 people.
Trial scheme:
Four experimental grouies every day 1-2 time, used 1 month continuously respectively with the shampoo hair washing of embodiment of the invention 4-7 preparation.
The normal control group every day 1-2 time, is used January continuously with the common shampoo hair washing on the market.
Experimental result:
Experimental group one | Experimental group two | Experimental group three | Experimental group four | The normal control group | |
Alleviate | 38 | 40 | 35 | 33 | 0 |
Obviously improve | 7 | 8 | 11 | 15 | 0 |
Invalid | 5 | 2 | 4 | 2 | 0 |
Worsen | 0 | 0 | 0 | 0 | 0 |
The result shows:
For scalp itch, dandruff is many, scalp is irritated, subinflammatory user, the life-time service shampoo that contains plant extract of the present invention has obvious effects.
The present invention is not limited to above-mentioned preferred forms, and other any identical with the present invention or akin products that anyone draws under enlightenment of the present invention all drop within protection scope of the present invention.
Claims (5)
1. shampoo that contains plant extract, it comprises surfactant, suds booster, viscosifier, pearling agent, conditioner, antiseptic, pigment, essence, deionized water, it is characterized in that: contain the percentage by weight that accounts for shampoo in the described shampoo and be 0.05~15.0% leaf of Fructus Citri grandis and/or Folium clausenae lansii extract;
The extracting method of described leaf of Fructus Citri grandis and/or Folium clausenae lansii extract is: get leaf of Fructus Citri grandis and/or Folium clausenae lansii defat with petroleum ether after-filtration, obtain defat leaf of Fructus Citri grandis and/or Folium clausenae lansii; To the alcoholic solution that wherein adds 70%, under 80 ℃ of constant temperature, refluxed 6 hours, cooled and filtered is concentrated to 1/7 volume with the filtrate decompression distillation, with isopyknic water-saturated n-butanol extraction, getting the distilling under reduced pressure of n-butyl alcohol phase is concentrated to and is the thick time cooling of brown, the dissolve with methanol solution of adding 80% adds acetone again and fully vibrates centrifugation, dry pale yellow powder shape extract, promptly contain the material of 50% flavonoid.
2. the shampoo that contains plant extract as claimed in claim 1 is characterized in that: described surfactant is selected from one or more combination of ammonium lauryl sulfate, Sodium Alcohol Ether Sulphate or fat alcohol polyethylene ether ammonium sulfate.
3. the shampoo that contains plant extract as claimed in claim 1 is characterized in that: described pearling agent is a polyethylene glycol stearate diester.
4. the shampoo that contains plant extract as claimed in claim 1 is characterized in that: described conditioner is selected from one or more combination of cation guar gum, polyquaternary ammonium salt-39 or polyquaternium-7.
5. the shampoo that contains plant extract as claimed in claim 1 is characterized in that: described antiseptic is an isothiazolone magnesium sulfate.
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CN101601637B (en) * | 2009-07-02 | 2011-10-05 | 李慧娟 | Pumelo leaf extract and skin cream using same |
CN104095780A (en) * | 2013-04-09 | 2014-10-15 | 廖少波 | Hair-blacking and hair loss-preventing plant shampoo and preparation method thereof |
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CN104382792A (en) * | 2014-11-27 | 2015-03-04 | 青岛厚科信息工程有限公司 | Liquid shampoo incapable of generating excessive hair degreasing and dryness phenomena |
CN104382797A (en) * | 2014-11-27 | 2015-03-04 | 青岛市市南区隆德中医药研究所 | Shampoo for inhibiting bacteria and removing dandruff |
CN105012164A (en) * | 2015-07-03 | 2015-11-04 | 黄庆生 | Shampoo and preparation method thereof |
CN105902449A (en) * | 2016-06-18 | 2016-08-31 | 广州聚注专利研发有限公司 | Chinese wampee leaf extract, preparing method thereof and application thereof in wash supplies |
CN106420406A (en) * | 2016-08-27 | 2017-02-22 | 惠州市博美化妆品有限公司 | Velvet smoothening liquid shampoo |
CN107897629A (en) * | 2017-11-23 | 2018-04-13 | 成都新柯力化工科技有限公司 | A kind of antiseptics for natural food extracted from shaddock leaf and extracting method |
CN110664703A (en) * | 2018-07-03 | 2020-01-10 | 南京伯朗生物科技有限公司 | Anti-hair loss traditional Chinese medicine lotion |
CN109363981A (en) * | 2018-09-30 | 2019-02-22 | 江门职业技术学院 | A kind of plant amino acid shampoo |
CN109718290A (en) * | 2019-03-20 | 2019-05-07 | 龚小妹 | It dispels miliaria compound pomelo peel frost and preparation method |
CN111297701A (en) * | 2020-03-13 | 2020-06-19 | 上海水分子婴童用品有限公司 | Foam skin cleaning towel and its making process |
CN113616578A (en) * | 2021-08-26 | 2021-11-09 | 漳州柚皮王生物技术有限公司 | Shampoo capable of preventing skin diseases and preparation method thereof |
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CN1229638A (en) * | 1999-03-06 | 1999-09-29 | 刘思强 | Refreshing shaddock shampoo |
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