CN100365058C - Architectural joint filling material made from waste polyurethane and waste fiber, and its preparation method - Google Patents

Architectural joint filling material made from waste polyurethane and waste fiber, and its preparation method Download PDF

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Publication number
CN100365058C
CN100365058C CNB200610029184XA CN200610029184A CN100365058C CN 100365058 C CN100365058 C CN 100365058C CN B200610029184X A CNB200610029184X A CN B200610029184XA CN 200610029184 A CN200610029184 A CN 200610029184A CN 100365058 C CN100365058 C CN 100365058C
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China
Prior art keywords
waste
component
waste polyurethane
fiber
polyurethane
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Expired - Fee Related
Application number
CNB200610029184XA
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Chinese (zh)
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CN1903932A (en
Inventor
曹民干
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Tongji University
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Tongji University
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Priority to CNB200610029184XA priority Critical patent/CN100365058C/en
Publication of CN1903932A publication Critical patent/CN1903932A/en
Application granted granted Critical
Publication of CN100365058C publication Critical patent/CN100365058C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The present invention belongs to the filed of building material technology, in particular, it relates to a building joint-filling material prepared by utilizing waste polyurethane and waste fibre and its preparation method. It is made up by using waste polyurethane and waste polypropylene fibre as aggregate, and mixing them with chemical raw materials of acrylic acid emulsion, sodium hexametaphosphate, sodium benzoate, ethylene glycol, propylene glycol, polydimethylsiloxane, methyl cellulose, calcium carbonate and colouring agent according to a certain mixing ratio.

Description

Utilize waste polyurethane and useless fiber production building pointing and preparation method thereof
Technical field
The invention belongs to building material technical field, be specifically related to a kind of waste polyurethane and useless fiber production building pointing and preparation method thereof of utilizing.
Background technology
Along with the fast development of urban construction and environmental protection, need to call various energy-conserving and environment-protective energy saving building materials.The urethane wall heat insulation material was because its outstanding comprehensive physicochemical property more and more widely was applied to energy-conservation lagging material in recent years.Yet a large amount of polyurethane waste materials have caused new environmental pollution again, also occur new utilized industrial waste resource simultaneously; In addition, various man-made fiber have also become the resource of urban construction; Because a lot of novel energy-conserving building materials are applied, and need more supplementary material common combination, become easy to use and the perfect performance application system.
Moreover some novel wall material of construction are often run into the defective of splicing seams, shrinkage joint, adopt energy-saving material to the outer insulation of metope and heat insulation etc., all need novel building pointing fit applications.
In sum, research a kind of have functional, can joint filling, to strengthen, can resist fissured environment protection multifunctional reinforced composite be those skilled in the art's goal in research.
Summary of the invention
The objective of the invention is to propose a kind ofly has well attached ability, intensity to utilize waste polyurethane and useless fiber production building pointing and preparation method thereof preferably.
The present invention proposes utilizes waste polyurethane and useless fiber production building pointing, is to be that main raw material adds batching and forms with waste polyurethane material and waste and old man-made fiber, and the weight percent of its component is:
Waste polyurethane powder 20-25%
Waste and old polypropylene fiber 5-8%
ACRYLIC EMULSION 40-45%
Sodium hexametaphosphate 99 4-5%
Sodium Benzoate 0.5-0.6%
Ethylene glycol 0.8-1.0%
Propylene glycol 3.5-4.5%
Polydimethylsiloxane 0.05-0.06%
Lime carbonate 15-20%
Methylcellulose gum 1.5-2%
All the other are water,
Its weight satisfies 100%.
Among the present invention, described waste polyurethane powder directly is the 60-80 order.
Among the present invention, described waste and old polypropylene fiber length is 3-5mm.Selecting for use also of fiber can be according to the color of body of wall, or is formed with special lathe work and variegated style.
Among the present invention, can also add tinting material in pointing, its consumption is the 0.07-0.1% of pointing gross weight, the color of tinting material should select for use can be as far as possible with the color of filling out building wall be same system.
The preparation method who utilizes waste polyurethane and useless fiber production building pointing that the present invention proposes, its concrete steps are as follows:
Part by weight by each component, measure each component, earlier waste polyurethane powder, polypropylene fiber and lime carbonate are mixed as component A, again ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, ethylene glycol, propylene glycol, methylcellulose gum, tinting material are mixed as B component, then component A and B component are mixed, add polydimethylsiloxane, water at last, stir, promptly get desired product.
Among the present invention, the waste polyurethane powder is that trade wastes such as the scrap stock pulverizing of waste polyurethane goods or polyurethane building lagging material obtains, or for obtaining after the treated pulverizing of spontaneous scrap stock in the polyurethane product course of processing, be uniform fine particulate object, the rubber powder particle diameter that this pointing adopts is about about 80 orders; The used fiber of the present invention is that the trade waste of chemical fibre source mill is cut into the following length specification of 5mm after treatment, perhaps can directly buy the product of this specification from market.
The matrix material that the present invention proposes has good physicochemical property.Press GB through appropriate authority and detect performance such as following table:
Title Conditioned disjunction unit Performance
Surface drying time H 2h-2.5h
Water tolerance 48h The no bubble in surface, slight crack, obscission
Alkali resistance 48h, saturated aqua calcis The no bubble in surface
Abrasion resistance 500 times Do not have and destroy
Adhesion strength MPa 0.5-0.58
Winter hardiness -40C,24h No change
Thermotolerance 80C,24h No change
Tensile strength MPa 1.5
Elongation at break /% 25
Shear bonding strength MPa 0.5
The present invention is main aggregate owing to having used the waste polyurethane products waste, has improved economic worth greatly, and product itself also has good physicochemical property.The available special spray gun spraying of constructing also can be scraped and be smeared, and need not that other adhesive can satisfy the joint filling requirement and cost is low.
Material of the present invention can be used for various metopes, also can be used for slits such as post, plate fills up.Owing to be water-based environment-friendly,, do not have newly and pollute at making, construction, nontoxic, the odorlessness of prolonged application process.
Embodiment
Embodiment 1: its set of dispense is such as following:
Waste polyurethane powder (80 order) 200g
Waste and old polypropylene fiber (5mm is long) 61g
ACRYLIC EMULSION 416g
Sodium hexametaphosphate 99 40g
Sodium Benzoate 6g
Ethylene glycol 9.5g
Propylene glycol 45g
Polydimethylsiloxane 0.5g
Lime carbonate 150g
Methylcellulose gum 20g
Water 52g
Tinting material 0.7g
In the above-mentioned raw materials ratio, earlier waste polyurethane powder, polypropylene fiber and lime carbonate are mixed as component A, again ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, ethylene glycol, propylene glycol, methylcellulose gum, tinting material are mixed as B component, then component A and B component are mixed, add polydimethylsiloxane, water at last, stir, promptly get desired product.Its performance index are:
Time of drying: 2h
Adhesion strength: 0.54MPa
Other every indexs are ditto described.
Embodiment 2: set of dispense is such as following:
Waste polyurethane powder (60 order) 200g
Waste and old polypropylene fiber (4m is long) 50g
ACRYLIC EMULSION 410g
Sodium hexametaphosphate 99 45g
Sodium Benzoate 5g
Ethylene glycol 8g
Propylene glycol 45g
Polydimethylsiloxane 0.5g
Lime carbonate 165g
Methylcellulose gum 18g
Water 53.5g
Tinting material 0.9g
In the above-mentioned raw materials ratio, earlier waste polyurethane powder, polypropylene fiber and lime carbonate are mixed as component A, again ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, ethylene glycol, propylene glycol, methylcellulose gum, tinting material are mixed as B component, then component A and B component are mixed, add polydimethylsiloxane, water at last, stir, promptly get desired product.Its performance index are:
Time of drying: 2h
Adhesion strength: 0.53MPa
Other every indexs are ditto described.
Embodiment 3: set of dispense is such as following:
Waste polyurethane powder (60 order) 205g
Waste and old polypropylene fiber (4mm is long) 60g
ACRYLIC EMULSION 400g
Sodium hexametaphosphate 99 50g
Sodium Benzoate 5g
Ethylene glycol 8g
Propylene glycol 45g
Polydimethylsiloxane 0.6g
Lime carbonate 170g
Methylcellulose gum 15g
Water 41.4g
Tinting material 1.0g
In the above-mentioned raw materials ratio, earlier waste polyurethane powder, polypropylene fiber and lime carbonate are mixed as component A, again ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, ethylene glycol, propylene glycol, methylcellulose gum, tinting material are mixed as B component, then component A and B component are mixed, add polydimethylsiloxane, water at last, stir, promptly get desired product.Its performance index are:
Time of drying: 2h
Adhesion strength: 0.54MPa
Other every indexs are ditto described.

Claims (3)

1. one kind is utilized waste polyurethane and useless fiber production building pointing, it is characterized in that being is that main raw material adds batching and forms with waste polyurethane material and waste and old man-made fiber, and the weight percent of its component is:
Waste polyurethane powder 20-25%
Waste and old polypropylene fiber 5-8%
ACRYLIC EMULSION 40-45%
Sodium hexametaphosphate 99 4-5%
Sodium Benzoate 0.5-0.6%
Ethylene glycol 0.8-1.0%
Propylene glycol 3.5-4.5%
Polydimethylsiloxane 0.05-0.06%
Lime carbonate 15-20%
Methylcellulose gum 1.5-2%
All the other are water,
Its weight satisfies 100%;
Wherein, described waste polyurethane powder directly is the 60-80 order, and described waste and old polypropylene fiber length is 3-5mm.
2. waste polyurethane and the useless fiber production building pointing of utilizing according to claim 1 is characterized in that also being added with tinting material, and the consumption of tinting material is the 0.07-0.1% of pointing gross weight.
3. preparation method who utilizes waste polyurethane and useless fiber production building pointing as claimed in claim 2, it is characterized in that concrete steps are as follows: by the part by weight of each component, measure each component, earlier waste polyurethane powder, polypropylene fiber and lime carbonate are mixed as component A, again ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, ethylene glycol, propylene glycol, methylcellulose gum, tinting material are mixed as B component, then component A and B component are mixed, add polydimethylsiloxane, water at last, stir, promptly get desired product.
CNB200610029184XA 2006-07-20 2006-07-20 Architectural joint filling material made from waste polyurethane and waste fiber, and its preparation method Expired - Fee Related CN100365058C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB200610029184XA CN100365058C (en) 2006-07-20 2006-07-20 Architectural joint filling material made from waste polyurethane and waste fiber, and its preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB200610029184XA CN100365058C (en) 2006-07-20 2006-07-20 Architectural joint filling material made from waste polyurethane and waste fiber, and its preparation method

Publications (2)

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CN1903932A CN1903932A (en) 2007-01-31
CN100365058C true CN100365058C (en) 2008-01-30

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101440171B (en) * 2008-10-22 2011-07-13 无锡吉兴汽车部件有限公司 Process for recovering polyurethane composite waste material for automobile roof liner
CN103881623A (en) * 2013-11-13 2014-06-25 东南大学 Acrylic water-based joint mixture and preparation method thereof
CN106009610A (en) * 2016-06-02 2016-10-12 陈昌 High-strength environmental-protection material and preparation method thereof
CN106318317A (en) * 2016-07-25 2017-01-11 启东市林海制衣厂 Flexible joint mixture
TR201717716A2 (en) * 2017-11-10 2019-05-21 Arcelik As ONE COMPOSITE MATERIAL

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1446868A (en) * 2003-03-20 2003-10-08 同济大学 Iron dross crylic acid surface decoration meterial
WO2004011044A1 (en) * 2002-07-26 2004-02-05 Kimberly-Clark Worldwide, Inc. Fluid storage material including particles secured with a crosslinkable binder composition
CN1651528A (en) * 2005-01-18 2005-08-10 巢启 Wall body paint having multi colour effect
CN1670096A (en) * 2005-03-16 2005-09-21 上海市建筑科学研究院有限公司 Monocomponent high elastic aqueous polyurethane/acrylate waterproof paint and process for preparing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004011044A1 (en) * 2002-07-26 2004-02-05 Kimberly-Clark Worldwide, Inc. Fluid storage material including particles secured with a crosslinkable binder composition
CN1446868A (en) * 2003-03-20 2003-10-08 同济大学 Iron dross crylic acid surface decoration meterial
CN1651528A (en) * 2005-01-18 2005-08-10 巢启 Wall body paint having multi colour effect
CN1670096A (en) * 2005-03-16 2005-09-21 上海市建筑科学研究院有限公司 Monocomponent high elastic aqueous polyurethane/acrylate waterproof paint and process for preparing same

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