CN100360033C - Re-compounded pesticide of chlorfluazuron and profenofos or DDVP - Google Patents
Re-compounded pesticide of chlorfluazuron and profenofos or DDVP Download PDFInfo
- Publication number
- CN100360033C CN100360033C CNB200510050230XA CN200510050230A CN100360033C CN 100360033 C CN100360033 C CN 100360033C CN B200510050230X A CNB200510050230X A CN B200510050230XA CN 200510050230 A CN200510050230 A CN 200510050230A CN 100360033 C CN100360033 C CN 100360033C
- Authority
- CN
- China
- Prior art keywords
- fluorine pyridine
- profenofos
- pyridine urea
- chlorfluazuron
- pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Pyridine Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a compounded pesticide of chlorfluazuron and profenofos or DDVP, which belongs to the technical field of compounded pesticides. The compounded pesticide of chlorfluazuron and profenofos comprises 0.5 to 10 percent of chlorfluazuron and 10 to 40 percent of profenofos. The compounded pesticide of chlorfluazuron and DDVP is characterized in that the compounded pesticide of chlorfluazuron and DDVP comprises 0.5 to 10 percent of chlorfluazuron and 20 to 60 percent of DDVP. The cotoxicity coefficient of the compounded pesticide of chlorfluazuron and profenofos or DDVP reaches 102 to 217, the disinsection range is wide, the effect on preventing and controlling pests of lepidoptera, coleoptera, hymenoptera, diptera, thysanoptera, etc. is good, the preventing and controlling rate reaches 95 to 100 percent, the quick effect and the durable effect are good, and the use cost is low and is about 58 to 60 percent lower than that of a chlorfluazuron pesticide.
Description
Technical field
The invention belongs to technical field of compounded pesticide.
Background technology
Fluorine pyridine urea has another name called UC 62644, presses down hooligan, IKI-7899, CGA112913, is a kind of phenyl formoxyl urea insecticide, insect based on stomach poison function, is had concurrently stronger action of contace poison, poor permeability, no systemic action.It is a little matter enzyme inhibitors of insect, suppresses chitinous formation, hinders insect and normally casts off a skin, and makes ovum hatching, larval molting, pupa development deformity, and the emergence of adult, lays eggs etc. to be obstructed and to bring into play insecticidal action.Very high to the insect activity, but speed of action is slower, can very fast death behind the larva contact medicine, but food ingestion obviously weakens.This medicine has very high activity to some insects such as multiple lepidoptera pest and orthoptera, coleoptera, Hymenoptera, dipteras, is the insecticide of comparison wide spectrum.The insect that insecticides such as organic phosphor, carbamate, pyrethroid are developed immunity to drugs has good control efficiency.Safer to natural enemy, honeybee, fish, but silkworm is had certain toxicity, be to be more satisfactory insecticide in the current integrated pest control, but quick-acting is poor, medicine valency cost is higher.
Summary of the invention
For overcoming the problems referred to above, the object of the invention is to provide the technical scheme of insects such as a kind of cost is low, insecticidal spectrum wide, control Lepidoptera, coleoptera, Hymenoptera, diptera, thrips effective and quick-acting, the lasting effect urea of fluorine pyridine preferably and Profenofos or atgard mixed pesticide.
Described fluorine pyridine urea and Profenofos Recompounded pesticide is characterized in that: contain fluorine pyridine urea 0.5-10%, Profenofos 10-40%.
Described fluorine pyridine urea and Profenofos Recompounded pesticide is characterized in that: the content of fluorine pyridine urea is 1-5%, and the content of Profenofos is 15-35%.
Described fluorine pyridine urea and Profenofos Recompounded pesticide is characterized in that: the content of fluorine pyridine urea is 1-3%, and the content of Profenofos is 20-30%.
Described fluorine pyridine urea and atgard mixed pesticide is characterized in that: contain fluorine pyridine urea 0.5-10%, dichlorvos 20-60%.
Described fluorine pyridine urea and atgard mixed pesticide is characterized in that: the content of fluorine pyridine urea is 1-5%, and the content of dichlorvos is 30-50%.
Described fluorine pyridine urea and atgard mixed pesticide is characterized in that: the content of fluorine pyridine urea is 1-3%, and the content of dichlorvos is 35-45%.
The chemical name of fluorine pyridine urea is: 1-[3,5-chloro-4-(3-chloro-5-trifluoromethyl-2-pyridine oxygen base) phenyl]-3-(2, the 6-difluoro benzoyl) urea, be known substance, can buy by Zhejiang water chestnutization Group Co.,Ltd.
The chemical name of Profenofos is O (4-bromo-2-chlorphenyl)-O-ethyl-S-propyl group-phosphoric sulfide acid esters, is known substance, can be buied by Shandong Yantai Keda Chemical Co., Ltd..
The chemical name of dichlorvos is O, O, and-dimethyl-O-(2.2.-dichloro) vinyl phosphate is known substance, can be buied by former Shanghai insecticide factory.
Described fluorine pyridine urea and Profenofos or atgard mixed pesticide can be made into missible oil, promptly former medicine solubilizer and emulsifier.Concrete composite production technology and usual auxiliaries all belong to existing known technology, do not repeat them here.
Described fluorine pyridine urea and Profenofos or atgard mixed pesticide, co-toxicity coefficient reaches 102-217, insecticidal spectrum is wide, insects such as control Lepidoptera, coleoptera, Hymenoptera, diptera, thrips are effective, control efficiency reaches 95～100%, quick-acting and lasting effect are better, and use cost is low, reduce about 58-65% than fluorine pyridine urea agricultural chemicals.
Proportioning in the present patent application is the weight percentage of the pure material of active ingredient.
Embodiment
The following stated embodiment describes the present invention in detail.In these embodiments, unless otherwise indicated, all percentages all are weight percentage.
Prescription one: Profenofos: 29.5%, fluorine pyridine urea: 0.5%.
Prescription two: Profenofos: 29.0%, fluorine pyridine urea: 1.0%.
Prescription three: Profenofos: 28.5%, fluorine pyridine urea: 1.5%.
Prescription four: dichlorvos: 39.5%, fluorine pyridine urea: 0.5%.
Prescription five: dichlorvos: 39.0%, fluorine pyridine urea: 1.0%.
Prescription six: dichlorvos: 38.5%, fluorine pyridine urea: 1.5%.
Prescription seven: dichlorvos: 38.0%, fluorine pyridine urea: 2.0%.
Prescription eight: dichlorvos: 37.5%, fluorine pyridine urea: 2.5%.
The Recompounded pesticide of above-mentioned prescription and 5% 5 percent of hexaflumuron emulsifiable concentrate, 40% Profenofos missible oil, 80% DDT EC compare test, and be as follows to co-toxicity coefficient and the field control effectiveness test data of prodenia litura:
Composite dose of fluorine pyridine urea and Profenofos are measured statistics to the prodenia litura co-toxicity coefficient
| Medicament | LC 50mg/ml | The toxicity regression line | 95% confidence interval | Co-toxicity coefficient |
| 5% 5 percent of hexaflumuron emulsifiable concentrate | 0.03382 | Y＝6.76908+ 1.20277X | 0.02076～ 1.40193 | |
| 40% Profenofos missible oil | 0.01669 | Y＝13.08924 +4.55084X | 0.01265～ 0.01949 | |
| 30% fluorine pyridine urea Profenofos (prescription one) | 0.01813 | Y＝11.52829 +3.74828X | 0.01538～ 0.02262 | 183.4302 |
| 30% fluorine pyridine urea Profenofos (prescription two) | 0.01505 | Y＝11.98133 +3.83101X | 0.01236～ 0.01775 | 217.2071 |
| 30% fluorine pyridine urea Profenofos (prescription three) | 0.01613 | Y＝11.95103 +3.87834X | 0.01324～ 0.01969 | 199.3881 |
Fluorine pyridine urea and atgard mixed dose are measured statistics to the prodenia litura co-toxicity coefficient
| Medicament | LC 50mg/ml | The toxicity regression line | 95% confidence interval | Co-toxicity coefficient |
| 5% 5 percent of hexaflumuron emulsifiable concentrate | 0.03382 | Y＝6.76908+ 1.20277X | 0.02076～ 1.40193 | |
| 80% DDT EC | 0.04320 | Y＝7.93062+ 2.14775X | 0.02416～ 0.05732 | |
| 40% fluorine pyridine urea DDT EC (prescription four) | 0.03299 | Y＝8.49282+ 2.35749X | 0.02477～ 0.04598 | 102.7832 |
| 40% fluorine pyridine urea DDT EC (prescription five) | 0.03008 | Y＝9.06809+ 2.67345X | 0.02292～ 0.03901 | 113.0289 |
| 40% fluorine pyridine urea DDT EC (prescription six) | 0.03397 | Y＝7.74544+ 1.86907X | 0.02355～ 0.05463 | 100.3674 |
| 40% fluorine pyridine urea DDT EC (prescription seven) | 0.03402 | Y＝8.3210+ 2.26190X | 0.02542～ 0.04891 | 100.4947 |
| 40% fluorine pyridine urea DDT EC (prescription eight) | 0.02764 | Y＝8.79891+ 2.43753X | 0.01936～ 0.03637 | 124.0523 |
5% 5 percent of hexaflumuron emulsifiable concentrate is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.050 | 20 | 11 | 55.0 | 43.9 |
| 0.025 | 20 | 10 | 50.0 | 38.9 |
| 0.017 | 20 | 7 | 35.0 | 23.9 |
| 0.013 | 20 | 6 | 30.0 | 18.9 |
| 0.010 | 20 | 5 | 25.0 | 13.9 |
40% Profenofos missible oil is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.04 | 21 | 20 | 95.2 | 95.2 |
| 0.027 | 18 | 16 | 88.9 | 88.9 |
| 0.02 | 19 | 11 | 57.9 | 57.9 |
| 0.016 | 17 | 7 | 41.25 | 41.2 |
| 0.013 | 16 | 6 | 37.5 | 37.5 |
80% DDT EC is to the test of pesticide effectiveness record of prodenia litura
| Dosage (mg/l) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.4 | 20 | 17 | 85 | 85 |
| 0.27 | 20 | 15 | 75 | 75 |
| 0.2 | 20 | 13 | 65 | 65 |
| 0.16 | 20 | 10 | 50 | 50 |
| 0.13 | 20 | 6 | 30 | 30 |
30% fluorine pyridine urea Profenofos missible oil (prescription one) is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.03 | 20 | 16 | 80.0 | 80.0 |
| 0.02 | 20 | 12 | 60.0 | 60.0 |
| 0.015 | 20 | 6 | 30.0 | 30.0 |
| 0.012 | 20 | 5 | 25.0 | 25.0 |
| 0.01 | 20 | 4 | 20.0 | 20.0 |
30% fluorine pyridine urea Profenofos missible oil (prescription two) is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.03 | 20 | 18 | 90.0 | 90.0 |
| 0.02 | 20 | 13 | 65.0 | 65.0 |
| 0.015 | 20 | 9 | 45.0 | 45.0 |
| 0.012 | 20 | 8 | 40.0 | 40.0 |
| 0.01 | 20 | 5 | 25.0 | 25.0 |
30% fluorine pyridine urea Profenofos missible oil (prescription three) is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.03 | 19 | 17 | 89.5 | 89.5 |
| 0.02 | 15 | 9 | 60.0 | 60.0 |
| 0.015 | 18 | 7 | 38.9 | 38.9 |
| 0.012 | 12 | 3 | 25.0 | 25.0 |
| 0.01 | 17 | 5 | 29.4 | 29.4 |
40% fluorine pyridine urea DDT EC (prescription four) is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.08 | 18 | 14 | 77.8 | 77.8 |
| 0.04 | 18 | 11 | 61.1 | 61.1 |
| 0.027 | 19 | 9 | 47.4 | 47.4 |
| 0.020 | 17 | 6 | 35.3 | 35.3 |
| 0.016 | 20 | 3 | 15.0 | 15.0 |
40% fluorine pyridine urea DDT EC (prescription five) is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.08 | 18 | 15 | 83.3 | 83.3 |
| 0.04 | 18 | 12 | 66.7 | 66.7 |
| 0.027 | 18 | 9 | 50.0 | 50.0 |
| 0.020 | 19 | 7 | 36.3 | 36.3 |
| 0.016 | 20 | 3 | 15.0 | 15.0 |
40% fluorine pyridine urea DDT EC (prescription six) is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.08 | 20 | 14 | 70.0 | 70.0 |
| 0.04 | 20 | 12 | 60.0 | 60.0 |
| 0.027 | 18 | 10 | 55.6 | 55.6 |
| 0.020 | 17 | 5 | 29.4 | 29.4 |
| 0.016 | 16 | 3 | 18.7 | 18.7 |
40% fluorine pyridine urea DDT EC (prescription seven) is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.08 | 17 | 13 | 76.5 | 76.5 |
| 0.04 | 19 | 11 | 57.9 | 57.9 |
| 0.027 | 17 | 8 | 47.1 | 47.1 |
| 0.020 | 20 | 7 | 35.0 | 35.0 |
| 0.016 | 20 | 3 | 15.0 | 15.0 |
40% fluorine pyridine urea DDT EC (prescription eight) is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.08 | 15 | 12 | 80.0 | 80.0 |
| 0.04 | 17 | 12 | 70.6 | 70.6 |
| 0.027 | 19 | 11 | 57.9 | 57.9 |
| 0.020 | 19 | 8 | 42.1 | 42.1 |
| 0.016 | 19 | 3 | 15.8 | 15.8 |
30% fluorine pyridine urea Profenofos missible oil (prescription two), 40% fluorine pyridine urea DDT EC (prescription five), 5% 5 percent of hexaflumuron emulsifiable concentrate, 40% Profenofos missible oil, 80% DDT EC are as follows to the field control effectiveness test data of prodenia litura:
The effect table of fluorine pyridine urea and Profenofos missible oil control prodenia litura
| Medicament | Working concentration (doubly) | Borer population (head) before the medicine | Behind the medicine 3 days | Behind the medicine 7 days | ||||
| Borer population (head) | Slip (%) | Anti-rate (%) is levied in the school | Borer population (head) | Slip (%) | Anti-rate (%) is levied in the school | |||
| 30% fluorine pyridine urea Profenofos missible oil (prescription two) | 1000 | 35 32 subtotals 67 | 0 0 0 | 100 | 100 | 0 0 0 | 100 | 100 |
| 2000 | 28 39 subtotals 67 | 2 3 5 | 92.5 | 91.2 | 0 2 4 | 97.0 | 93.3 | |
| 5% 5 percent of hexaflumuron emulsifiable concentrate | 1000 | 42 27 subtotals 69 | 9 6 15 | 81.0 | 77.8 | 0 0 0 | 100 | 100 |
| 40% Profenofos missible oil | 1000 | 34 26 subtotals 60 | 2 4 6 | 90.0 | 88.3 | 1 3 4 | 93.3 | 85.4 |
| The clear water contrast | 42 34 subtotals 76 | 38 27 65 | 14.5 | 20 14 34 | 55.3 |
The effect table of fluorine pyridine urea and atgard mixed dose of control prodenia litura
| Medicament | Working concentration (doubly) | Borer population (head) before the medicine | Behind the medicine 3 days | Behind the medicine 7 days | ||||
| Borer population (head) | Slip (%) | Proofread and correct control rate (%) | Borer population (head) | Slip (%) | Proofread and correct control rate (%) | |||
| 2000 | 28 39 subtotals 67 | 2 3 5 | 92.5 | 91.2 | 0 2 4 | 97.0 | 93.3 | |
| 40% fluorine pyridine urea DDT EC (prescription five) | 1000 | 13 15 subtotals 28 | 1 1 2 | 92.8 | 90.1 | 1 0 1 | 96.4 | 87.8 |
| 2000 | 25 18 subtotals 43 | 2 2 4 | 90.7 | 87.1 | 1 0 1 | 97.7 | 92.2 | |
| 5% 5 percent of hexaflumuron emulsifiable concentrate | 1000 | 36 33 subtotals 69 | 4 6 10 | 85.5 | 80.0 | 0 0 0 | 100 | 100 |
| 80% DDT EC | 500 | 32 21 subtotals 53 | 4 5 9 | 83.0 | 76.5 | 4 4 8 | 84.9 | 48.6 |
| The clear water contrast | 27 24 subtotals 51 | 21 19 40 | 27.5 | 9 6 15 | 70.6 |
Analyze above-mentioned data, measurement result shows that the co-toxicity coefficient of fluorine pyridine urea and Profenofos different proportion prescription all has obvious synergistic effect all greater than 100.With 30% fluorine pyridine urea Profenofos missible oil (prescription two) co-toxicity coefficient maximum, consider that wherein 30% fluorine pyridine urea Profenofos missible oil (prescription two) can be used as prioritization scheme and selects from pesticide cost and drug effect.
Measurement result shows, the co-toxicity coefficient of fluorine pyridine urea and dichlorvos different proportion prescription is all greater than 100, both composite summation actions that are essentially.Consider that from pesticide cost and drug effect 40% fluorine pyridine urea DDT EC (prescription five) can be used as prioritization scheme and selects.
Find out from the effect table of above-mentioned fluorine pyridine urea and Profenofos missible oil control prodenia litura: 30% fluorine pyridine urea Profenofos missible oil uses 1000,2000 times of liquid control prodenia lituras, the insect population slip is respectively that the insect population slip is respectively 100% and 97.0% after 100% and 92.5%, 7 day after 3 days.Behind the medicine 3 days composite dose all better than two contrast medicament fluorine pyridine ureas, Profenofos, behind the medicine 7 days, 1000 times of liquid were consistent with the drug effect that contrasts medicament, 2000 times of liquid preventive effects also reach 93.3%.
From reagent cost, 30% fluorine pyridine urea Profenofos missible oil is roughly equal to 50,000 yuan/ton, and 120,000 yuan/ton of 5% 5 percent of hexaflumuron emulsifiable concentrate, reagent cost can descend about 58%.
Find out from the effect table of above-mentioned fluorine pyridine urea and atgard mixed dose of control prodenia litura: 40% fluorine pyridine urea DDT EC is used 1000,2000 times of liquid control prodenia lituras, the insect population slip is respectively 92.8% and 90.7% after 3 days, proofread and correct preventive effect and be respectively 90.1% and 87.1%, the insect population slip is respectively 96.4% and 97.7% after 7 days, proofreaies and correct preventive effect and is respectively 87.7% and 92.2%.Behind the medicine 3 days composite dose all better than two contrast medicament fluorine pyridine ureas, dichlorvos, 7 days drug effects of composite dose are with single close with 5% 5 percent of hexaflumuron emulsifiable concentrate behind the medicine.
From reagent cost, 40% fluorine pyridine urea DDT EC is roughly equal to 4.2 ten thousand yuan/ton, 120,000 yuan/ton of 5% 5 percent of hexaflumuron emulsifiable concentrate, and every 100g that uses per mu, the cost of composite dose (1000 times of liquid) descends 65%.
Claims (6)
1, fluorine pyridine urea and Profenofos Recompounded pesticide is characterized in that containing fluorine pyridine urea weight content 0.5-3%, Profenofos weight content 20-30%.
2, fluorine pyridine urea as claimed in claim 1 and Profenofos Recompounded pesticide is characterized in that containing fluorine pyridine urea weight content 1-3%, Profenofos weight content 20-30%.
3, fluorine pyridine urea as claimed in claim 1 and Profenofos Recompounded pesticide is characterized in that containing fluorine pyridine urea weight content 0.5-1.5%, Profenofos weight content 28.5-29.5%.
4, fluorine pyridine urea and atgard mixed pesticide is characterized in that containing fluorine pyridine urea weight content 0.5-3%, dichlorvos weight content 35-45%.
5, fluorine pyridine urea as claimed in claim 4 and atgard mixed pesticide is characterized in that containing fluorine pyridine urea weight content 1-3%, dichlorvos weight content 35-45%.
6, fluorine pyridine urea as claimed in claim 4 and atgard mixed pesticide is characterized in that containing fluorine pyridine urea weight content 0.5-2.5%, dichlorvos weight content 37.5-39.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510050230XA CN100360033C (en) | 2005-04-12 | 2005-04-12 | Re-compounded pesticide of chlorfluazuron and profenofos or DDVP |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510050230XA CN100360033C (en) | 2005-04-12 | 2005-04-12 | Re-compounded pesticide of chlorfluazuron and profenofos or DDVP |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1846501A CN1846501A (en) | 2006-10-18 |
| CN100360033C true CN100360033C (en) | 2008-01-09 |
Family
ID=37076428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200510050230XA Expired - Fee Related CN100360033C (en) | 2005-04-12 | 2005-04-12 | Re-compounded pesticide of chlorfluazuron and profenofos or DDVP |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100360033C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101263819B (en) * | 2008-05-07 | 2010-12-08 | 国家农药创制工程技术研究中心 | Indoxacarb and chlorfluazuron insecticidal composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1478393A (en) * | 1998-07-08 | 2004-03-03 | 安万特杭州作物科学有限公司 | Fipronil complex pesticide |
| CN1561738A (en) * | 2004-03-12 | 2005-01-12 | 中国水稻研究所 | Chlorfluazuron mixed pesticide |
-
2005
- 2005-04-12 CN CNB200510050230XA patent/CN100360033C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1478393A (en) * | 1998-07-08 | 2004-03-03 | 安万特杭州作物科学有限公司 | Fipronil complex pesticide |
| CN1561738A (en) * | 2004-03-12 | 2005-01-12 | 中国水稻研究所 | Chlorfluazuron mixed pesticide |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1846501A (en) | 2006-10-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101243798A (en) | Insecticidal composition containing indoxacarb | |
| Khater et al. | Erratum to: The acaricidal efficacy of peracetic acid and deltamethrin against the fowl tick, Argas persicus, infesting laying hens | |
| CN101473840A (en) | Insecticidal composition containing avermectin and indoxacarb | |
| CN102657176A (en) | Tolfenpxrad-containing smoke agent | |
| CN101133738A (en) | Insecticidal composition containing fipronil for corps | |
| CN101406195B (en) | Composition containing ethiprole and avermectin with synergistic disinsection function | |
| CN100382698C (en) | Synergistic compound pesticide contg. flufenoxuron | |
| CN103300054B (en) | A kind of Pesticidal combination containing ring worm hydrazides and organic phosphates | |
| CN100360033C (en) | Re-compounded pesticide of chlorfluazuron and profenofos or DDVP | |
| CN103875703B (en) | A kind of agricultural chemicals paste preventing and treating longicorn | |
| CN113826633B (en) | Pesticide for preventing and treating sugarcane borers | |
| CN102726438A (en) | Dinotefuran-containing insecticidal composition and its application | |
| CN101305727B (en) | Efficient pesticides composition containing avermectin and profenofos | |
| CN101796958B (en) | Insecticidal composition containing clothianidin and carbosulfan | |
| CN101019546A (en) | Recompounded pesticide of emamectin benzoate and fipronil | |
| CN1322812C (en) | Composite pesticide | |
| CN1288979C (en) | Chlorfluazuron mixed pesticide | |
| CN1911030A (en) | Synergistic compound pesticide contg. trans-cypermethrin and fipronil | |
| CN100387130C (en) | Compound insecticide contg. fipronil | |
| CN101380007B (en) | Disinsection composition containing chlorfenapyr and chlorfluazuron with synergistic action | |
| CN102763668A (en) | Insecticidal composition containing dinotefuran and emamectin benzoate | |
| CN101385454B (en) | Insecticidal composition containing spinosad and chlorfluazuron | |
| CN101878778A (en) | Stable acephate abamectin missible oil | |
| CN101099471A (en) | Insecticide composition containing tebufenozide and cypermethrin | |
| CN1288980C (en) | Triflumuron mixed pesticide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080109 |