CN100345784C - Colour glass green colouring pigment and its preparing process - Google Patents
Colour glass green colouring pigment and its preparing process Download PDFInfo
- Publication number
- CN100345784C CN100345784C CNB2004100235376A CN200410023537A CN100345784C CN 100345784 C CN100345784 C CN 100345784C CN B2004100235376 A CNB2004100235376 A CN B2004100235376A CN 200410023537 A CN200410023537 A CN 200410023537A CN 100345784 C CN100345784 C CN 100345784C
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- China
- Prior art keywords
- coloring agent
- preparation
- pigment
- fusing assistant
- novel
- Prior art date
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Abstract
The present invention relates to a color glass coloring agent and a preparation technique thereof. The color glass coloring agent is prepared from plumbum, boron, zinc, chromium, lithium and copper; the preparation technique comprises technical processes of fluxing agent preparation, glaze fusing powder preparation, coloring matter preparation, coloring agent preparation and the like, so that a granular color glass green coloring agent is obtained. When the novel coloring agent is used, the quality of a product is stable; the novel coloring agent overcomes the defect of the easy generation of color channels and gas bubbles of the similar products and has the advantage of convenient operation; the effect of the novel coloring agent is superior to that of the similar coloring agent; the production cost of the novel coloring agent is greatly reduced; and the novel coloring agent can replace import products.
Description
Technical field
The present invention relates to a kind of glass coloring immunomodulator compounds and preparation method.
Background technology
Late 1960s, coloured glass begins to occur abroad, China began one's study the seventies, originally be in the road, to add Powdered pigment, dye melts is after stirring action, make itself and parent glass be mixed into the material of homogeneous, through the homogenizing postforming, yet this coloured glass is had to limited popularization.The first, when in glass metal, adding tinting material, can produce many difficulties, the second, glass metal is carried out second-heating detrimentally affect, and subject matter is reboil bubble to occur.U.S.'s import particulate state tinting material is used in the back, and this tinting material generally adopts the boracic prescription, though improvement is arranged, but still have unstable product quality, defectives such as look road, bubble, color lump very easily appear, and the product import, cost an arm and a leg, be badly in need of substitute products.
Summary of the invention
Cost an arm and a leg in order to overcome prior art, unstable product quality, effect is undesirable, defectives such as look road, bubble, color lump very easily occur, the invention provides a kind of new coloured glass tinting material and production technique.
New coloured glass green colourant provided by the present invention adopts plumbous boron prescription, and adds zinc, lithium composition in prescription, adopts chromium, copper coloring, and its chemical ingredients is as follows: SiO
220-25%; Al
2O
33-5%; PbO 30-35%; B
2O
34-8%; CuO 2-3%; Cr
2O
35-8%; R
2O 15-20%; ZnO 6-8%.
Above-mentioned compound can prepare by following method.
(a) preparation of fusing assistant: the fusing assistant proportioning raw materials is: SiO
230-35%; AI
2O
36-10%; CaO 0.5-2%; MgO 0.1-1%; PbO 45-50%; B
2O
34-8%; K
2O+Na
2O 10-15%.
(b) preparation of melted glaze powder: fusing assistant is heated in crucible 1100-1200 ℃ by above-mentioned chemical constitution batching back and is founded, soak 40-60min, and through shrend, ball milling, drying, sieving obtains melted glaze powder.
(c) preparation of pigment, it is toner that copper, chromium are adopted in green agent, its composition of raw materials: Cr
2O
320-30%; CuO 8-12%; ZnO 16-20%; Li
2CO
316-20%; B
2O
312-20%.Borax is earlier soluble in water, and powder adds behind all the other raw material blendings, mixes oven dry thoroughly, and ball milling sieves, and obtains pigment
(d) preparation of tinting material: fusing assistant and pigment by fusion in crucible after 2: 1 mixed, are injected the cold water hardening crack then, and dry back fragmentation is sieved, the green particles agent.
Embodiment
The invention will be further described below in conjunction with embodiment
The preparation of the coloured glass green colourant of indication of the present invention realizes by following processing method.
One, the preparation of fusing assistant
In order to adapt to the processing temperature of expecting the road and the chemical constitution and the chemical property of glass basestocks.Reduce PbO, B
2O
3Deng the volatile quantity of raw material, fusing assistant is selected following raw materials according proportioning: SiO for use
230-35%; Al
2O
36-10%; CaO 0.5-2%; MgO 0.1-1%; PbO 45-50%; B
2O
34-8%; K
2O+Na
2O10-15%.
Two, the preparation of melted glaze powder
Fusing assistant is formed the batching back by its said ratio and found into vitreum in crucible, and glass melting temperature is about 1180 ℃, and top temperature keeps 45min, pours into then and carries out shrend in the water, the molten glaze ball milling after the shrend 28 hours.80 mesh sieves are crossed in dry back, obtain powdered frit.
Three, the preparation of pigment
It is toner that green colourant adopts copper, chromium, its pigment raw material proportioning: Cr
2O
320-30%; CuO 8-12%; ZnO 16-20%; Li
2CO
316-20%; B
2O
36-10%.The raw materials used chemical pure raw material that all adopts of pigment requires steady quality, and borax is earlier soluble in water, and powder behind all the other raw material blendings is added, mixes thoroughly oven dry, and ball milling was crossed 280 mesh sieves about 25 hours, obtained pigment.
Four, the preparation of tinting material
By after 2: 1 mixed, the cold water hardening crack is injected in fusion in crucible then with fusing assistant and pigment, broken 4 orders of crossing in dry back, and 10 mesh sieves, intermediate particle is the particulate state green colourant, its main chemical compositions: SiO
220-25%; Al
2O
33-5%; PbO 30-35%; B
2O
34-8%; CuO 2-3%; Cr
2O
35-8%; R
2O 15-20%; ZnO 6-8%.
Claims (1)
1, a kind of coloured glass green colourant is characterized in that this tinting material is to adopt the method for following step to prepare:
(a) the fusing assistant proportioning raw materials is counted SiO with percent by weight
230-35%, Al
2O
36-10%, CaO0.5-2%, MgO 0.1-1%, PbO 45-50%, B
2O
34-8%, K
2O+Na
2O 10-15%;
(b) preparation of fusing assistant: above-mentioned fusing assistant raw material is placed crucible, 1100-1200 ℃ of down heating 40-60 minute, again through shrend, ball milling, drying, sieving obtains described fusing assistant;
(c) pigment preparation, the pigment raw material proportioning is counted Cr with percent by weight
2O
320-30%, CuO8-12%, ZnO 16-20%, Li
2CO
316-20%, B
2O
36-10%; Earlier that borax is soluble in water, add all the other raw materials behind the mixing again, mix oven dry thoroughly, ball milling, sieving obtains described pigment;
(d) above-mentioned fusing assistant is mixed according to weight ratio with above-mentioned pigment at 2: 1, the cold water hardening crack is injected in fusion in crucible more then, and dry back fragmentation is sieved and obtained described coloured glass green colourant.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100235376A CN100345784C (en) | 2004-01-17 | 2004-01-17 | Colour glass green colouring pigment and its preparing process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100235376A CN100345784C (en) | 2004-01-17 | 2004-01-17 | Colour glass green colouring pigment and its preparing process |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1640833A CN1640833A (en) | 2005-07-20 |
CN100345784C true CN100345784C (en) | 2007-10-31 |
Family
ID=34868441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004100235376A Expired - Fee Related CN100345784C (en) | 2004-01-17 | 2004-01-17 | Colour glass green colouring pigment and its preparing process |
Country Status (1)
Country | Link |
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CN (1) | CN100345784C (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102190914A (en) * | 2011-03-09 | 2011-09-21 | 都匀开发区福田化工有限责任公司 | Formula of thermal-spraying colorants for toughened glass |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1055163A (en) * | 1990-03-27 | 1991-10-09 | 石家庄市第一玻璃厂 | Glass containing high lead low soda ash |
US5403664A (en) * | 1992-05-11 | 1995-04-04 | Nippon Electric Glass Co., Ltd. | Marble-like glass ceramic |
CN1121491A (en) * | 1994-10-27 | 1996-05-01 | 开原市玻璃厂 | Blue heat-absorbing float glass |
US6313053B1 (en) * | 1997-10-20 | 2001-11-06 | Ppg Industries Ohio, Inc. | Infrared and ultraviolet radiation absorbing blue glass composition |
-
2004
- 2004-01-17 CN CNB2004100235376A patent/CN100345784C/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1055163A (en) * | 1990-03-27 | 1991-10-09 | 石家庄市第一玻璃厂 | Glass containing high lead low soda ash |
US5403664A (en) * | 1992-05-11 | 1995-04-04 | Nippon Electric Glass Co., Ltd. | Marble-like glass ceramic |
CN1121491A (en) * | 1994-10-27 | 1996-05-01 | 开原市玻璃厂 | Blue heat-absorbing float glass |
US6313053B1 (en) * | 1997-10-20 | 2001-11-06 | Ppg Industries Ohio, Inc. | Infrared and ultraviolet radiation absorbing blue glass composition |
Also Published As
Publication number | Publication date |
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CN1640833A (en) | 2005-07-20 |
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C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20071031 Termination date: 20110117 |