CN100333644C - Fire retardant, anticorrosive insecticide, and preparation method - Google Patents
Fire retardant, anticorrosive insecticide, and preparation method Download PDFInfo
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- CN100333644C CN100333644C CNB2005101158899A CN200510115889A CN100333644C CN 100333644 C CN100333644 C CN 100333644C CN B2005101158899 A CNB2005101158899 A CN B2005101158899A CN 200510115889 A CN200510115889 A CN 200510115889A CN 100333644 C CN100333644 C CN 100333644C
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Abstract
The present invention discloses a fire-retardant antiseptic pesticide which is characterized in that the pesticide is a solution mixed with components A, B, C, wherein the component A is composed of 80 to 240 parts by weight of ammonium phosphate, 40 to 120 parts bye weight of ammonium sulfate, 25 to 50 parts by weight of borax and 8 to 25 parts by weight of boracic acid; the component B is composed of 1 to 12 parts by weight of sodium fluoride and 1 to 7 parts by weight of sodium octaborate; the component C is 1000 parts by weight of water. The present invention also discloses a process for preparing the fire-retardant antiseptic pesticide, which is characterized in that the process comprises the following steps: adding the component A to the component C, and heating the mixture in a reaction vessel to 50 DEG C while stirring until the solution becomes transparent; adding the component B to the solution, and continuously stirring and heating until the solution becomes transparent; cooling the solution to the normal temperature.
Description
Technical field
The present invention relates to a kind of fire retardant, anticorrosive insecticide, is a kind of multipurpose fire retardant, anticorrosive insecticide that can be applied to timber, textile and paper.
Background technology
Occurring in nature overwhelming majority natural organic has inflammability and perishability, these two kinds of defectives cause this class material or its derived material for example yarn fabric and paper all have characteristics inflammable, perishable, that easily damage by worms, make the historical material that much has historical value or historical relic, building fail to preserve.
In order to make full use of these materials, be necessary these materials are carried out study on the modification, make its performance obtain extending and development, more help being used by the mankind.In all age, the mankind are exploring this always untiringly, for these materials are protected, have created various methods, have the method for physics chemical method also to be arranged, the method that also has physico chemistry to combine.
Fire-retardant and anticorrosion two aspects handling as modification are always considered separately and are handled by separated at present, or handle step by step, have produced the problem on many performances, use and the cost thus.For example adopt fire retardant and preservative step by step material to be handled separately, operating expenses is higher, and material is to the absorption problem of inorganic agent of construction at twice, and the acidity of using in the inorganic agent or alkali electroless composition are to the strength of materials and other original Effect on Performance, also have environmentally harmful material pollution on the environment, all make this inorganic agent have such or such deficiency.
Summary of the invention
The object of the present invention is to provide the fire retardant, anticorrosive insecticide of a kind of tool, make and to carry out fire-retardant and can carry out simultaneously during preservative treatment, and the application of the material after handling is wider with fire-retardant, anticorrosion and insecticidal function.
Fire-retardant, anticorrosive insecticide provided by the invention, form the solution that part is mixed and made into by following A, B, C three: the A component is made up of diammonium hydrogen phosphate 80-240 weight portion, ammonium sulfate 40-120 weight portion, borax 25-50 weight portion, boric acid 8-25 weight portion, the B component is made up of sodium fluoride 1-12 weight portion, eight Boratex 1-7 weight portions, and the C component is water 1000 weight portions.
Most preferred mode is, described A component is made up of diammonium hydrogen phosphate 100 weight portions, ammonium sulfate 50 weight portions, borax 20 weight portions, boric acid 10 weight portions, correspondingly the B component is made up of sodium fluoride 10 weight portions, eight Boratexes, 5 weight portions, and the C component is water 1000 weight portions.The fire retardant, anticorrosive insecticide that adopts this prescription to make is based on the characteristics exploitation of timber, be specially adapted to all kinds of fire retardant anticorrosion desinsections with infiltrative natural timber each several part artificial board, the for example fire prevention of solid wood board, wood-based plate, furniture, anticorrosion, mildew-resistant processing do not have broken ring to the native texture and the outward appearance of timber.
Characteristics according to the dry goods material, described A component is made up of diammonium hydrogen phosphate 160 weight portions, ammonium sulfate 80 weight portions, borax 20 weight portions, boric acid 10 weight portions, correspondingly the B component is made up of sodium fluoride 3 weight portions, eight Boratexes, 1.64 weight portions, and the C component is water 1000 weight portions.The fire retardant, anticorrosive insecticide of being made by this prescription is particularly suitable for the dry goods material and uses, and handles as the fire prevention of linen-cotton kind fabric, synthetic class organic fabric, anticorrosion, insect protected, mildew-resistant.
Characteristics according to paper-like materials, described A component is made up of diammonium hydrogen phosphate 200 weight portions, ammonium sulfate 100 weight portions, borax 40 weight portions, boric acid 20 weight portions, correspondingly the B component is made up of sodium fluoride 2 weight portions, eight Boratexes, 1.64 weight portions, and the C component is water 1000 weight portions.The fire retardant, anticorrosive insecticide of being made by this prescription is particularly suitable for paper-like materials and uses, as be used for the fire prevention of important literature, artistic products, bank note, anticorrosion, insect protected, antirust, mildew-resistant is handled.
The present invention also provides the production method of above-mentioned fire retardant, anticorrosive insecticide, comprises the steps: that (1) joins described A component in the C component, in reactor temperature is raised to 50 ℃, heats while stirring, and is the fusion pellucidity to solution; (2) add B component in above-mentioned solution, lasting agitating heating makes solution reach the fusion pellucidity; (3) above-mentioned solution is cooled to normal temperature.
This fire retardant, anticorrosive insecticide outward appearance provided by the invention is transparent settled solution, and proportion is 1.10-1.28, and pH value is 4.0-7.0.This fire retardant, anticorrosive insecticide, adopt plurality of raw materials to utilize its synergy, it is fire-retardant that it is had simultaneously, anticorrosion, mildew-resistant, antirust, insecticidal action, can be used for timber, paper, fabric fire-retardant, anticorrosion, mildew-resistant, desinsection is handled, can directly soak or spary, test by national building engineering quality supervision inspection center, its fire-retardant index can reach " GB50222-1995 code for fire prevention design of interior decoration of buildings " B1 level (difficult combustion level) requirement, anticorrosion index reaches " GB50206-2002 timber structure construction quality acceptance specification " HJI level-HJIII level requirement, and environmental protection index reaches total volatile organism TVOC and content of formaldehyde requirement that " GB50325-2001 civil building engineering indoor environmental pollution control standard " requires.So can disposable material requested be handled, make it reach the fire retardant, anticorrosive double effects, and this preparation is minimum to the strength of materials and other original Effect on Performance for being neutrality or faintly acid.In addition, this preparation also has certain mildew-resistant, insect protected performance.So the material after handling had both had safety, has durability again, and environment is had no adverse effects, make the material range of application after the processing wider, the characteristics advantage that self has can obtain performance to a greater extent, and economic and social benefit is met jointly.This fire retardant, anticorrosive insecticide is tried out in a plurality of key state projects, has obtained resultant effect preferably.
Embodiment
Below in conjunction with specific embodiment fire retardant, anticorrosive insecticide of the present invention and preparation method thereof is described further.
Embodiment 1
Fire retardant, anticorrosive insecticide in the present embodiment is applicable to the wood type material: handle as the fire prevention of solid wood board, wood-based plate, furniture, anticorrosion, insect protected, mildew-resistant.
Component A is diammonium hydrogen phosphate 100 grams, ammonium sulfate 50 grams, borax 20 grams, boric acid 10 grams;
B component is sodium fluoride 10 grams, eight Boratexes, 5 grams;
Component C is water 1000 grams.
The A component is joined in the C component, in reactor temperature is risen to 50 ℃, heat while stirring, the time is 40 minutes, to solution fusion pellucidity; B component is joined in the solution of first step reaction, continue agitating heating 30 minutes, make solution reach the fusion pellucidity, be cooled to normal temperature then, obtaining product density is that 1.10-1.28, pH value are the transparent clear liquid state product of 4.0-7.0.
Embodiment 2
Fire retardant, anticorrosive insecticide in the present embodiment is applicable to the dry goods material: handle as the fire prevention of linen-cotton kind fabric, synthetic class organic fabric, anticorrosion, insect protected, antirust, mildew-resistant.
Component A is diammonium hydrogen phosphate 160 grams, ammonium sulfate 80 grams, borax 20 grams, boric acid 10 grams;
B component is sodium fluoride 3 grams, eight Boratexes, 1.64 grams;
Component C is water 1000 grams.
The A component is joined in the C component, in reactor temperature is risen to 50 ℃, heat while stirring, the time is 40 minutes, to solution fusion pellucidity; B component is joined in the solution of first step reaction, continue agitating heating 30 minutes, make solution reach the fusion pellucidity, be cooled to normal temperature then, obtaining product density is that 1.10-1.28, pH value are the transparent clear liquid state product of 4.0-7.0.
Embodiment 3
Fire retardant, anticorrosive insecticide in the present embodiment is applicable to paper-like materials: as be used for the fire prevention of important literature, artistic products, bank note, anticorrosion, insect protected, mildew-resistant and handle.
Component A is diammonium hydrogen phosphate 200 grams, ammonium sulfate 100 grams, borax 40 grams, boric acid 20 grams;
B component is sodium fluoride 2 grams, eight Boratexes, 1.64 grams;
Component C is water 1000 grams.
The A component is joined in the C component, in reactor temperature is risen to 50 ℃, heat while stirring, the time is 40 minutes, to solution fusion pellucidity; B component is joined in the solution of first step reaction, continue agitating heating 30 minutes, make solution reach the fusion pellucidity, be cooled to normal temperature then, obtaining product density is that 1.10-1.28, pH value are the transparent clear liquid state product of 4.0-7.0.
Claims (5)
1, a kind of fire retardant, anticorrosive insecticide, it is characterized in that: form the solution that part is mixed and made into by following A, B, C three: the A component is made up of diammonium hydrogen phosphate 80-240 weight portion, ammonium sulfate 40-120 weight portion, borax 25-50 weight portion, boric acid 8-25 weight portion, the B component is made up of sodium fluoride 1-12 weight portion, eight Boratex 1-7 weight portions, and the C component is water 1000 weight portions.
2, fire retardant, anticorrosive insecticide as claimed in claim 1, it is characterized in that: form the solution that part is mixed and made into by following A, B, C three: described A component is made up of diammonium hydrogen phosphate 100 weight portions, ammonium sulfate 50 weight portions, borax 20 weight portions, boric acid 10 weight portions, correspondingly the B component is made up of sodium fluoride 10 weight portions, eight Boratexes, 5 weight portions, and the C component is water 1000 weight portions.
3, fire retardant, anticorrosive insecticide as claimed in claim 1, it is characterized in that: form the solution that part is mixed and made into by following A, B, C three: described A component is made up of diammonium hydrogen phosphate 160 weight portions, ammonium sulfate 80 weight portions, borax 20 weight portions, boric acid 10 weight portions, correspondingly the B component is made up of sodium fluoride 3 weight portions, eight Boratexes, 1.64 weight portions, and the C component is water 1000 weight portions.
4, fire retardant, anticorrosive insecticide as claimed in claim 1, it is characterized in that: form the solution that part is mixed and made into by following A, B, C three: described A component is made up of diammonium hydrogen phosphate 200 weight portions, ammonium sulfate 100 weight portions, borax 40 weight portions, boric acid 20 weight portions, correspondingly the B component is made up of sodium fluoride 2 weight portions, eight Boratexes, 1.64 weight portions, and the C component is water 1000 weight portions.
5, the preparation method of described fire retardant, anticorrosive insecticide one of in a kind of claim 1 to 4, it is characterized in that this method comprises the steps: that (1) joins described A component in the C component, in reactor, temperature is raised to 50 ℃, heats while stirring, to solution fusion pellucidity; (2) add B component in above-mentioned solution, lasting agitating heating makes solution reach the fusion pellucidity; (3) above-mentioned solution is cooled to normal temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101158899A CN100333644C (en) | 2005-11-10 | 2005-11-10 | Fire retardant, anticorrosive insecticide, and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101158899A CN100333644C (en) | 2005-11-10 | 2005-11-10 | Fire retardant, anticorrosive insecticide, and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1760329A CN1760329A (en) | 2006-04-19 |
| CN100333644C true CN100333644C (en) | 2007-08-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2005101158899A Expired - Fee Related CN100333644C (en) | 2005-11-10 | 2005-11-10 | Fire retardant, anticorrosive insecticide, and preparation method |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103612305B (en) * | 2013-11-07 | 2014-12-10 | 陕西师范大学 | Fireproofing and insect-proofing modifying liquid for collection tools of files and cultural relics and application of modifying liquid |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100592A (en) * | 1994-01-08 | 1995-03-29 | 谭永良 | Flame retarding anticorrosive agent for wood (bamboo) or plywood |
| CN1124272A (en) * | 1994-12-04 | 1996-06-12 | 卢力华 | Fire-proof flame-retarded agent and its producing method and use |
| CN1439766A (en) * | 2002-02-23 | 2003-09-03 | 孙晓平 | Fire-proofing agent |
| JP2003246985A (en) * | 2002-02-25 | 2003-09-05 | Itoki Crebio Corp | Antibacterial and flameproofing agent |
-
2005
- 2005-11-10 CN CNB2005101158899A patent/CN100333644C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100592A (en) * | 1994-01-08 | 1995-03-29 | 谭永良 | Flame retarding anticorrosive agent for wood (bamboo) or plywood |
| CN1124272A (en) * | 1994-12-04 | 1996-06-12 | 卢力华 | Fire-proof flame-retarded agent and its producing method and use |
| CN1439766A (en) * | 2002-02-23 | 2003-09-03 | 孙晓平 | Fire-proofing agent |
| JP2003246985A (en) * | 2002-02-25 | 2003-09-05 | Itoki Crebio Corp | Antibacterial and flameproofing agent |
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| CN1760329A (en) | 2006-04-19 |
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