CH623728A5 - - Google Patents

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Info

Publication number: CH623728A5
Authority: CH; Switzerland
Prior art keywords: metal; complex; antimicrobial; activity; salts
Prior art date: 1977-08-11

Application number

CH993477A

Other languages

English (en)

French (fr)

Inventor

Gerald L Maurer

Sudhir K Shringarpurey

Original Assignee

Nat Res Lab

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-08-11

Filing date

1977-08-12

Publication date

1981-06-30

1977-08-11 Priority to FR7724775A priority Critical patent/FR2399847A1/fr

1977-08-12 Application filed by Nat Res Lab filed Critical Nat Res Lab

1977-08-12 Priority to BE180154A priority patent/BE857769A/fr

1977-08-12 Priority to CH993477A priority patent/CH623728A5/fr

1977-08-15 Priority to GB3420877A priority patent/GB1587671A/en

1977-08-19 Priority to DE19772738041 priority patent/DE2738041A1/de

1981-06-30 Publication of CH623728A5 publication Critical patent/CH623728A5/fr

Links

229910052751 metal Inorganic materials 0.000 claims description 36
239000002184 metal Substances 0.000 claims description 36
238000010494 dissociation reaction Methods 0.000 claims description 27
230000005593 dissociations Effects 0.000 claims description 27
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 26
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 23
239000004599 antimicrobial Substances 0.000 claims description 22
229910021645 metal ion Inorganic materials 0.000 claims description 22
150000003839 salts Chemical class 0.000 claims description 22
230000000845 anti-microbial effect Effects 0.000 claims description 21
231100000331 toxic Toxicity 0.000 claims description 18
230000002588 toxic effect Effects 0.000 claims description 18
239000007787 solid Substances 0.000 claims description 16
239000000126 substance Substances 0.000 claims description 15
230000000694 effects Effects 0.000 claims description 13
241000894006 Bacteria Species 0.000 claims description 12
150000004696 coordination complex Chemical class 0.000 claims description 12
239000000463 material Substances 0.000 claims description 11
239000013110 organic ligand Substances 0.000 claims description 10
230000035899 viability Effects 0.000 claims description 10
230000015572 biosynthetic process Effects 0.000 claims description 9
238000010586 diagram Methods 0.000 claims description 9
238000000034 method Methods 0.000 claims description 9
150000001875 compounds Chemical class 0.000 claims description 8
229910001431 copper ion Inorganic materials 0.000 claims description 8
239000002609 medium Substances 0.000 claims description 8
244000005700 microbiome Species 0.000 claims description 8
230000000844 anti-bacterial effect Effects 0.000 claims description 7
230000001580 bacterial effect Effects 0.000 claims description 7
230000003115 biocidal effect Effects 0.000 claims description 7
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 7
150000001768 cations Chemical class 0.000 claims description 6
239000003795 chemical substances by application Substances 0.000 claims description 6
229910001385 heavy metal Inorganic materials 0.000 claims description 6
239000000047 product Substances 0.000 claims description 6
239000012736 aqueous medium Substances 0.000 claims description 5
230000000813 microbial effect Effects 0.000 claims description 5
239000000203 mixture Substances 0.000 claims description 5
241000894007 species Species 0.000 claims description 5
241000700605 Viruses Species 0.000 claims description 4
239000002253 acid Substances 0.000 claims description 4
239000012634 fragment Substances 0.000 claims description 4
150000002500 ions Chemical class 0.000 claims description 4
239000003446 ligand Substances 0.000 claims description 4
150000002739 metals Chemical class 0.000 claims description 4
239000003899 bactericide agent Substances 0.000 claims description 3
230000002070 germicidal effect Effects 0.000 claims description 3
-1 hydrogen ions Chemical class 0.000 claims description 3
230000002401 inhibitory effect Effects 0.000 claims description 3
150000002736 metal compounds Chemical class 0.000 claims description 3
230000002421 anti-septic effect Effects 0.000 claims description 2
230000001413 cellular effect Effects 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
230000008569 process Effects 0.000 claims description 2
108090000623 proteins and genes Proteins 0.000 claims description 2
102000004169 proteins and genes Human genes 0.000 claims description 2
239000000725 suspension Substances 0.000 claims description 2
229910052500 inorganic mineral Inorganic materials 0.000 claims 6
239000011707 mineral Substances 0.000 claims 6
239000013522 chelant Substances 0.000 claims 4
239000003139 biocide Substances 0.000 claims 3
230000006378 damage Effects 0.000 claims 3
230000001066 destructive effect Effects 0.000 claims 3
239000005416 organic matter Substances 0.000 claims 3
230000001105 regulatory effect Effects 0.000 claims 3
230000005764 inhibitory process Effects 0.000 claims 2
150000001450 anions Chemical class 0.000 claims 1
229940064004 antiseptic throat preparations Drugs 0.000 claims 1
230000003385 bacteriostatic effect Effects 0.000 claims 1
239000000645 desinfectant Substances 0.000 claims 1
230000009931 harmful effect Effects 0.000 claims 1
239000002855 microbicide agent Substances 0.000 claims 1
150000007524 organic acids Chemical class 0.000 claims 1
235000005985 organic acids Nutrition 0.000 claims 1
150000002894 organic compounds Chemical class 0.000 claims 1
239000007800 oxidant agent Substances 0.000 claims 1
230000003647 oxidation Effects 0.000 claims 1
238000007254 oxidation reaction Methods 0.000 claims 1
230000002035 prolonged effect Effects 0.000 claims 1
239000002422 sporicide Substances 0.000 claims 1
231100000167 toxic agent Toxicity 0.000 claims 1
231100000721 toxic potential Toxicity 0.000 claims 1
239000003440 toxic substance Substances 0.000 claims 1
231100000419 toxicity Toxicity 0.000 claims 1
230000001988 toxicity Effects 0.000 claims 1
239000010949 copper Substances 0.000 description 34
239000000243 solution Substances 0.000 description 27
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 22
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 20
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 18
229910052802 copper Inorganic materials 0.000 description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
238000012360 testing method Methods 0.000 description 17
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 7
238000013270 controlled release Methods 0.000 description 7
229960001484 edetic acid Drugs 0.000 description 7
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
210000004027 cell Anatomy 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
229960004106 citric acid Drugs 0.000 description 6
239000007788 liquid Substances 0.000 description 6
239000003381 stabilizer Substances 0.000 description 6
230000000087 stabilizing effect Effects 0.000 description 6
239000006228 supernatant Substances 0.000 description 6
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 5
150000001860 citric acid derivatives Chemical class 0.000 description 5
239000012141 concentrate Substances 0.000 description 5
239000002826 coolant Substances 0.000 description 5
235000019262 disodium citrate Nutrition 0.000 description 5
239000002526 disodium citrate Substances 0.000 description 5
CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 5
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 5
239000013078 crystal Substances 0.000 description 4
238000001704 evaporation Methods 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
238000000605 extraction Methods 0.000 description 4
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
230000003287 optical effect Effects 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
239000001509 sodium citrate Substances 0.000 description 4
235000011083 sodium citrates Nutrition 0.000 description 4
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
239000002585 base Substances 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
150000004699 copper complex Chemical class 0.000 description 3
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
238000005555 metalworking Methods 0.000 description 3
239000011780 sodium chloride Substances 0.000 description 3
229910052725 zinc Inorganic materials 0.000 description 3
239000011701 zinc Substances 0.000 description 3
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 3
241000588915 Klebsiella aerogenes Species 0.000 description 2
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
241000191967 Staphylococcus aureus Species 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000004480 active ingredient Substances 0.000 description 2
229960004543 anhydrous citric acid Drugs 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
239000000470 constituent Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
239000002178 crystalline material Substances 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
239000012535 impurity Substances 0.000 description 2
230000003834 intracellular effect Effects 0.000 description 2
230000000670 limiting effect Effects 0.000 description 2
238000003754 machining Methods 0.000 description 2
239000012528 membrane Substances 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
239000008188 pellet Substances 0.000 description 2
239000012071 phase Substances 0.000 description 2
229920000768 polyamine Polymers 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
230000006641 stabilisation Effects 0.000 description 2
238000011105 stabilization Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000003860 storage Methods 0.000 description 2
238000001429 visible spectrum Methods 0.000 description 2
239000011592 zinc chloride Substances 0.000 description 2
235000005074 zinc chloride Nutrition 0.000 description 2
241000228245 Aspergillus niger Species 0.000 description 1
244000063299 Bacillus subtilis Species 0.000 description 1
235000014469 Bacillus subtilis Nutrition 0.000 description 1
241000222122 Candida albicans Species 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
241000588923 Citrobacter Species 0.000 description 1
VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
241000588914 Enterobacter Species 0.000 description 1
241000588697 Enterobacter cloacae Species 0.000 description 1
241000588724 Escherichia coli Species 0.000 description 1
241000233866 Fungi Species 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
241000588748 Klebsiella Species 0.000 description 1
241000588772 Morganella morganii Species 0.000 description 1
241000588653 Neisseria Species 0.000 description 1
229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
238000013494 PH determination Methods 0.000 description 1
241000588769 Proteus <enterobacteria> Species 0.000 description 1
241000588770 Proteus mirabilis Species 0.000 description 1
241000588767 Proteus vulgaris Species 0.000 description 1
241000588777 Providencia rettgeri Species 0.000 description 1
241000589517 Pseudomonas aeruginosa Species 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001413 amino acids Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000003637 basic solution Substances 0.000 description 1
238000004166 bioassay Methods 0.000 description 1
238000005842 biochemical reaction Methods 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
230000003139 buffering effect Effects 0.000 description 1
229940095731 candida albicans Drugs 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
230000030833 cell death Effects 0.000 description 1
210000000170 cell membrane Anatomy 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
238000010668 complexation reaction Methods 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
XYNZKHQSHVOGHB-UHFFFAOYSA-N copper(3+) Chemical compound [Cu+3] XYNZKHQSHVOGHB-UHFFFAOYSA-N 0.000 description 1
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
229960003280 cupric chloride Drugs 0.000 description 1
238000004925 denaturation Methods 0.000 description 1
230000036425 denaturation Effects 0.000 description 1
SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical compound [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 1
KPHBXCOBSIAOGG-UHFFFAOYSA-L dilithium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Li+].[Li+].OC(=O)CC(O)(C([O-])=O)CC([O-])=O KPHBXCOBSIAOGG-UHFFFAOYSA-L 0.000 description 1
KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical compound [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000001962 electrophoresis Methods 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
229960004756 ethanol Drugs 0.000 description 1
235000019441 ethanol Nutrition 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000001963 growth medium Substances 0.000 description 1
230000020169 heat generation Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000011534 incubation Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229940071264 lithium citrate Drugs 0.000 description 1
WJSIUCDMWSDDCE-UHFFFAOYSA-K lithium citrate (anhydrous) Chemical compound [Li+].[Li+].[Li+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WJSIUCDMWSDDCE-UHFFFAOYSA-K 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000002503 metabolic effect Effects 0.000 description 1
230000004060 metabolic process Effects 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000001457 metallic cations Chemical class 0.000 description 1
230000003641 microbiacidal effect Effects 0.000 description 1
229940124561 microbicide Drugs 0.000 description 1
238000013508 migration Methods 0.000 description 1
230000005012 migration Effects 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000004570 mortar (masonry) Substances 0.000 description 1
APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
150000002815 nickel Chemical class 0.000 description 1
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000035699 permeability Effects 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
230000035755 proliferation Effects 0.000 description 1
229940007042 proteus vulgaris Drugs 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
238000002798 spectrophotometry method Methods 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
230000003330 sporicidal effect Effects 0.000 description 1
238000004659 sterilization and disinfection Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
239000000758 substrate Substances 0.000 description 1
238000012549 training Methods 0.000 description 1
239000001974 tryptic soy broth Substances 0.000 description 1
108010050327 trypticase-soy broth Proteins 0.000 description 1
238000002211 ultraviolet spectrum Methods 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/235—Saturated compounds containing more than one carboxyl group
- C07C59/245—Saturated compounds containing more than one carboxyl group containing hydroxy or O-metal groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/235—Saturated compounds containing more than one carboxyl group
- C07C59/245—Saturated compounds containing more than one carboxyl group containing hydroxy or O-metal groups
- C07C59/265—Citric acid
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages

Landscapes

Life Sciences & Earth Sciences (AREA)
Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Agronomy & Crop Science (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
General Health & Medical Sciences (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

CH993477A 1975-07-21 1977-08-12 CH623728A5 (de)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
FR7724775A FR2399847A1 (fr)	1977-08-11	1977-08-11	Agents antimicrobiens et leur application
BE180154A BE857769A (fr)	1975-07-21	1977-08-12	Agents antimicrobiens et leur application
CH993477A CH623728A5 (de)	1977-08-11	1977-08-12
GB3420877A GB1587671A (en)	1977-08-11	1977-08-15	Metal complexes for use as antimicrobial agents
DE19772738041 DE2738041A1 (de)	1977-08-11	1977-08-19	Antimikrobale wirkstoffe und verfahren zu ihrer herstellung

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
FR7724775A FR2399847A1 (fr)	1977-08-11	1977-08-11	Agents antimicrobiens et leur application
CH993477A CH623728A5 (de)	1977-08-11	1977-08-12
GB3420877A GB1587671A (en)	1977-08-11	1977-08-15	Metal complexes for use as antimicrobial agents
DE19772738041 DE2738041A1 (de)	1977-08-11	1977-08-19	Antimikrobale wirkstoffe und verfahren zu ihrer herstellung

Publications (1)

Publication Number	Publication Date
CH623728A5 true CH623728A5 (de)	1981-06-30

Family

ID=27429259

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH993477A CH623728A5 (de)	1975-07-21	1977-08-12

Country Status (4)

Country	Link
CH (1)	CH623728A5 (de)
DE (1)	DE2738041A1 (de)
FR (1)	FR2399847A1 (de)
GB (1)	GB1587671A (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1218600A (en) *	1982-12-06	1987-03-03	Gerald L. Maurer	Methods and compositions for treating inflammation or arthritis
JP2002529411A (ja) *	1998-11-09	2002-09-10	ジェイニューマン，アイラ	イオン性銀錯体
US20060089407A1 (en) *	2004-10-25	2006-04-27	National Research Laboratories, Ltd.	Methods for Making and Using Synergistic Multifunctional Compositions

1977
- 1977-08-11 FR FR7724775A patent/FR2399847A1/fr active Granted
- 1977-08-12 CH CH993477A patent/CH623728A5/fr not_active IP Right Cessation
- 1977-08-15 GB GB3420877A patent/GB1587671A/en not_active Expired
- 1977-08-19 DE DE19772738041 patent/DE2738041A1/de not_active Ceased

Also Published As

Publication number	Publication date
DE2738041A1 (de)	1979-03-01
FR2399847B1 (de)	1982-03-05
GB1587671A (en)	1981-04-08
FR2399847A1 (fr)	1979-03-09

Legal Events

Date	Code	Title	Description
1990-04-30	PL	Patent ceased

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