CH616702A5 - Handwashing paste. - Google Patents

Handwashing paste. Download PDF

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Publication number
CH616702A5
CH616702A5 CH1313675A CH1313675A CH616702A5 CH 616702 A5 CH616702 A5 CH 616702A5 CH 1313675 A CH1313675 A CH 1313675A CH 1313675 A CH1313675 A CH 1313675A CH 616702 A5 CH616702 A5 CH 616702A5
Authority
CH
Switzerland
Prior art keywords
mixture
paste
oil
sodium perborate
agent
Prior art date
Application number
CH1313675A
Other languages
German (de)
Inventor
Heinz Wallrath
Original Assignee
Thomae Gmbh Dr K
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19742448716 external-priority patent/DE2448716C3/en
Application filed by Thomae Gmbh Dr K filed Critical Thomae Gmbh Dr K
Publication of CH616702A5 publication Critical patent/CH616702A5/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0042—Reducing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Devices For Medical Bathing And Washing (AREA)

Description

616702 616702

Claims (1)

PATENTANSPRÜCHE PATENT CLAIMS 1. Handwaschpaste mit einem Gehalt an einem reduzierend und an einem oxidierend wirkenden Mittel, dadurch gekennzeichnet, dass sie ein wasserfreies Reduktionsmittel sowie ein mit Silikonöl überzogenes Natriumperborat-Granulat neben wasserfreien Netzmitteln und Bimsmehl enthält.1. Hand washing paste containing a reducing agent and an oxidizing agent, characterized in that it contains an anhydrous reducing agent and a silicone oil-coated sodium perborate granulate in addition to anhydrous wetting agents and pumice powder. 2. Handwaschpaste nach Anspruch 1, dadurch gekennzeichnet, dass diese Natriumdithionit als Reduktionsmittel enthält.2. Hand washing paste according to claim 1, characterized in that it contains sodium dithionite as a reducing agent. 3. Handwaschpaste nach Anspruch 1, dadurch gekennzeichnet, dass das Gewichtsverhältnis Natriumperborat zu Silikonöl 2:1 bis 4:1 beträgt.3. Hand washing paste according to claim 1, characterized in that the weight ratio of sodium perborate to silicone oil is 2:1 to 4:1. 4. Handwaschpaste nach Anspruch 1, dadurch gekennzeichnet, dass diese wasserfreie, hautschonende Netzmittel enthält.4. Hand washing paste according to claim 1, characterized in that it contains water-free, skin-friendly wetting agents. Die vorliegende Erfindung betrifft eine neue Handwaschpaste, die vorzugsweise zum Entfernen von Farbverschmutzungen geeignet ist.The present invention relates to a new hand washing paste which is preferably suitable for removing color soiling. In der deutschen Patentschrift 1 031 460 wird erstmals eine Handwaschpaste beschrieben, bei welcher das Netzmittel erst im Augenblick der Anwendung gebildet wird. Bei dieser wird die der waschaktiven Substanz zugrunde liegende Säure in einfacher Weise auf Grund ihrer Öllöslichkeit in eine Ölphase eingearbeitet. Z.B. lässt sich die auf Grund einer Kondensation von Fettsäure mit Sarkosin erhaltene Säure in ein natürliches Pflanzenöl wie Rizinusöl einarbeiten, wobei zur Konsistenzverbesserung noch Metallseifen zugefügt werden können. In diese Grundlage lässt sich nun ein Gemisch aus Soda, Natriumdithionit und Bimssteinpulver einarbeiten. Diese anorganischen Grundstoffe werden von der Ölphase derart umgeben, dass eine Reaktion mit der Säure unter Salzbildung nicht möglich ist. Selbst geringe Wasseranteile werden in einer derartigen Weise emulgiert, dass auch sie keinen vorzeitigen Ablauf der Reaktion bewirken. Beim Aufbringen dieser Paste auf die Hände und Zugabe von Wasser setzt dann erst der Neutralisationsvorgang unter Bildung des wirksamen Netzmittels wie auch der Entwicklung von Schwefeldioxid ein.In German Patent Specification 1 031 460, a hand washing paste is described for the first time in which the wetting agent is only formed at the moment of use. In this case, the acid on which the washing-active substance is based is incorporated into an oil phase in a simple manner because of its oil solubility. For example, the acid obtained as a result of a condensation of fatty acid with sarcosine can be incorporated into a natural vegetable oil such as castor oil, with metal soaps being added to improve the consistency. A mixture of soda, sodium dithionite and pumice powder can now be worked into this base. These inorganic base materials are surrounded by the oil phase in such a way that a reaction with the acid to form salts is not possible. Even small amounts of water are emulsified in such a way that they do not cause the reaction to proceed prematurely. When this paste is applied to the hands and water is added, the neutralization process begins with the formation of the effective wetting agent and the development of sulfur dioxide. Es wurde nun überraschenderweise gefunden, dass die bleichende und somit die reinigende Wirkung bei einer Waschpaste ähnlicher Zusammensetzung, wie in der Deutschen Patentschrift 1 031 460 beschrieben, die beispielsweise Butyl-glykol, Lauridit, Emulan, Hexylenglykol, Pine-Öl, Lanolin, Triäthanolamin, Talkum, Ärosil, Bimsmehl und ein wasserfreies Reduktionsmittel wie Natriumdithionit enthält, dadurch wesentlich gesteigert wird, dass ihr gleichzeitig als Oxidations-mittel granuliertes, mit Silikonöl überzogenes Natriumperborat beigemischt wird.Surprisingly, it has now been found that the bleaching and thus the cleaning effect of a washing paste with a composition similar to that described in German Patent Specification 1 031 460, which contains, for example, butyl glycol, lauridite, emulan, hexylene glycol, pine oil, lanolin, triethanolamine, talc, Aerosil, pumice powder and an anhydrous reducing agent such as sodium dithionite, is significantly enhanced by the fact that granulated sodium perborate coated with silicone oil is also added to it as an oxidizing agent. Das Natriumperborat-Granulat hat vorzugsweise eine Teil-chengrösse, die der des verwendeten Bimsmehls entspricht und in der Grössenordnung von 30 bis 60 fi liegt (DIN-Normgrösse ca. GV2). Es ist erforderlich, dieses Natriumperborat-Granulat zuerst mit Silikonöl zu vermischen, wobei die Gewichtsverhältnisse Natriumperborat zu Silikonöl zwischen 2 :1 und 4 :1 schwanken können. Diese Mischung wird dann mit der zweiten Mischung, bestehend aus einem wasserfreien Netzmittel, einem Reduktionsmittel, Bimsmehl und gegebenenfalls den übrigen, oben angegebenen Bestandteilen, innig vermengt. Als Reduktionsmittel eignen sich beispielsweise Brenzkate-chin, Natriumsulfit- oder bisulfit, insbesondere aber Natriumdithionit.The sodium perborate granules preferably have a particle size that corresponds to that of the pumice powder used and is in the order of 30 to 60 microns (DIN standard size approx. GV2). It is necessary to first mix this sodium perborate granulate with silicone oil, whereby the weight ratios of sodium perborate to silicone oil can vary between 2:1 and 4:1. This mixture is then intimately mixed with the second mixture, consisting of an anhydrous wetting agent, a reducing agent, pumice powder and optionally the other ingredients specified above. Examples of suitable reducing agents are pyrocatechol, sodium sulfite or bisulfite, but especially sodium dithionite. In dieser so hergestellten Paste kann das Reduktionsmittel nicht mit dem Oxidationsmittel Natriumperborat reagieren, diese Paste ist unbeschränkt lagerfähig, sie verliert auch nach langer Lagerzeit nicht ihre reduzierenden und oxidierenden Eigenschaften. Wird diese Paste zum Waschen benutzt, so tritt zuerst die reduzierende und, hiervon zeitlich verzögert, die oxidierende Wirkung in den Vordergrund.In the paste produced in this way, the reducing agent cannot react with the oxidizing agent sodium perborate. This paste can be stored indefinitely, and it does not lose its reducing and oxidizing properties even after a long period of storage. If this paste is used for washing, the reducing and then the oxidizing effect comes to the fore first. Es war zu erwarten, dass beim Waschprozess durch die lösende Wirkung des Wassers, verstärkt durch die Wirkung des Netzmittels, das Reduktionsmittel in erster Linie mit dem Oxidationsmittel reagiert, wobei sich dann beide Stoffe gegenseitig neutralisieren und damit für die reinigende bzw. bleichende Wirkung auf die Haut oder das Gewebe ausfallen. Es hat sich tatsächlich aber gezeigt, dass beim Waschprozess zuerst das Reduktionsmittel auf die Haut einwirkt und erst später, etwa nach 2 bis 5 Minuten, auch das Oxidationsmittel voll wirksam wird.It was to be expected that during the washing process, due to the dissolving effect of the water, reinforced by the effect of the wetting agent, the reducing agent would primarily react with the oxidizing agent, with the two substances then neutralizing each other and thus contributing to the cleaning or bleaching effect on the skin skin or tissue fall out. However, it has actually been shown that during the washing process the reducing agent acts on the skin first and only later, after about 2 to 5 minutes, does the oxidizing agent also become fully effective. Dieser doppelte Reinigungseffekt der erfindungsgemässen Waschpaste ist von grosser Bedeutung, z.B. bei der Entfernung von Schmutzflecken, die gleichzeitig Farbstoffe enthalten, die nur reduktiv oder oxidativ gebleicht werden können.This double cleaning effect of the washing paste according to the invention is of great importance, e.g. when removing dirt stains which at the same time contain dyes which can only be bleached by reduction or oxidation. Beispiel 1example 1 72,0 kg granuliertes Natrium-perborat werden in 25,0 kg Silikonöl 2000 eingerührt (Mischung I). 28,48 kg Butylglykol, 128,55 kg Lauridit VD, 31,0 kg Emulan, 8,02 kg Pine-Öl, 40,41 kg Hexylenglykol, 196,84 kg Talkum, 5,0 kg Ärosil,72.0 kg of granulated sodium perborate are stirred into 25.0 kg of silicone oil 2000 (mixture I). 28.48 kg butyl glycol, 128.55 kg Lauridit VD, 31.0 kg Emulan, 8.02 kg pine oil, 40.41 kg hexylene glycol, 196.84 kg talc, 5.0 kg Aerosil, 15.04 kg Lanolin, 27,5 kg Triäthanolamin, 94,0 kg Natriumdithionit und 158,07 kg Bimsmehl G V2 werden zusammen gegeben und intensiv miteinander vermischt (Mischung II).15.04 kg of lanolin, 27.5 kg of triethanolamine, 94.0 kg of sodium dithionite and 158.07 kg of pumice powder G V2 are added and mixed intensively with one another (mixture II). Mischung I wird in Mischung II eingetragen und gut vermengt.Mixture I is added to Mixture II and mixed well. Beispiel 2example 2 Es werden 6,1 kg Natrium-perborat mit 2,9 kg Silikonöl 2000 kalt granuliert (Mischung I). 21,0 kg Rizinusöl, 8,5 kg Kondensationsprodukt Fettsäure-Sarkosin, 4,0 kg Aluminium-palmitat und 2,0 kg Hexylenglykol werden miteinander vermischt (Mischung II). Gleichzeitig wird eine Mischung von 6,9 kg kalzinierter Soda, 15,0 kg Natriumdithionit und6.1 kg of sodium perborate are cold-granulated with 2.9 kg of silicone oil 2000 (mixture I). 21.0 kg of castor oil, 8.5 kg of the condensation product of fatty acid sarcosine, 4.0 kg of aluminum palmitate and 2.0 kg of hexylene glycol are mixed together (mixture II). Simultaneously, a mixture of 6.9 kg of soda ash, 15.0 kg of sodium dithionite and 33.5 kg Bimssteinmehl hergestellt (Mischung III).33.5 kg of pumice powder produced (mixture III). Die Mischung III wird mit der Mischung II kalt vermengt, danach wird Mischung I in die Mischung 11+III eingetragen.Mixture III is mixed cold with mixture II, then mixture I is added to mixture II+III. 22 ss 1010 1515 2020 2525 3030 3535 4040 4545 5050 BB
CH1313675A 1974-10-12 1975-10-09 Handwashing paste. CH616702A5 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19742448716 DE2448716C3 (en) 1974-10-12 Hand washing paste

Publications (1)

Publication Number Publication Date
CH616702A5 true CH616702A5 (en) 1980-04-15

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ID=5928167

Family Applications (1)

Application Number Title Priority Date Filing Date
CH1313675A CH616702A5 (en) 1974-10-12 1975-10-09 Handwashing paste.

Country Status (14)

Country Link
AT (1) AT342173B (en)
BE (1) BE834410A (en)
CH (1) CH616702A5 (en)
DK (1) DK152377C (en)
ES (1) ES441719A1 (en)
FI (1) FI58512C (en)
FR (1) FR2287506A1 (en)
GB (1) GB1501942A (en)
IE (1) IE43304B1 (en)
IT (1) IT1047535B (en)
LU (1) LU73570A1 (en)
NL (1) NL180851B (en)
NO (1) NO142531C (en)
SE (1) SE417980B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6087310A (en) * 1998-09-23 2000-07-11 Castrol Limited Skin cleaning compositions and uses comprising a polymer latex emulsion
DE19918265A1 (en) * 1999-04-22 2000-10-26 Henkel Kgaa Abrasive-containing aqueous liquid cleaning or scouring agent for hard surfaces contains microcapsules containing an ingredient to be protected e.g. a perfume
FR2843540A1 (en) * 2002-11-06 2004-02-20 Oreal Transparent composition for external application comprising a volatile hydrocarbon, non-ionic surfactant and hexylene glycol, useful for skin cleansing or make-up removal
WO2006094309A2 (en) 2005-03-04 2006-09-08 The Procter & Gamble Company Rinse-off or wipe-off skin cleansing compositions
DE102018221598A1 (en) * 2018-12-13 2020-06-18 Henkel Ag & Co. Kgaa Means for the reductive color proofing of colored keratin fibers

Also Published As

Publication number Publication date
NO142531B (en) 1980-05-27
SE7511412L (en) 1976-04-13
IE43304B1 (en) 1981-01-28
ATA736275A (en) 1977-07-15
IE43304L (en) 1976-04-12
DE2448716B2 (en) 1977-01-13
DK152377C (en) 1988-07-25
LU73570A1 (en) 1977-02-09
IT1047535B (en) 1980-10-20
FR2287506A1 (en) 1976-05-07
DK451775A (en) 1976-04-13
FR2287506B1 (en) 1979-01-05
NL180851B (en) 1986-12-01
ES441719A1 (en) 1977-11-01
GB1501942A (en) 1978-02-22
FI58512C (en) 1981-02-10
FI752827A (en) 1976-04-13
DE2448716A1 (en) 1976-04-22
AT342173B (en) 1978-03-28
FI58512B (en) 1980-10-31
DK152377B (en) 1988-02-22
NO753437L (en) 1976-04-13
NL7511930A (en) 1976-04-14
NO142531C (en) 1980-09-03
BE834410A (en) 1976-04-12
SE417980B (en) 1981-04-27

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