CA3138889A1

CA3138889A1 - Methods of producing continuously cast hot rolled high strength steel sheet products

Info

Publication number: CA3138889A1
Application number: CA3138889A
Authority: CA
Inventors: David Paul Hoydick; Eduardo Augusto SILVA; Matthew Michael MCCOSBY
Original assignee: United States Steel Corp
Current assignee: United States Steel Corp
Priority date: 2019-05-07
Filing date: 2020-05-06
Publication date: 2020-11-12
Also published as: MX2021013567A; KR20220004213A; WO2020227438A1; EP3966355A1; JP2022531669A; CN113825846A; AU2020268370A1; BR112021021467A2

Abstract

Methods of producing high strength continuously cast hot rolled steel sheet products are disclosed. The methods include continuously casting a steel slab and then hot rolling with finish rolling on a hot strip mill, quenching on the hot strip mill to form a predominantly matrensitic microstructure, and performing a thermal cycling step including soaking at an intercritical temperature followed by holding at a lower temperature. The resultant hot rolled steel sheet products have a microstructure comprising ferrite and retained austenite. Steels processed in accordance with the present invention exhibit favorable combined ultimate tensile strength and total elongation (UTSTE) properties, and may fall into the category of Generation 3 advanced high strength steels, desirable in various industries including automobile manufacturers.

Description

METHODS OF PRODUCING CONTINUOUSLY CAST HOT ROLLED
HIGH STRENGTH STEEL SHEET PRODUCTS
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application is a continuation-in-part of U.S. Patent Application No.
16/544,127 filed August 19, 2019, which is a continuation-in-part of U.S.
Patent Application No. 15/591,344 filed May 10, 2017, now U.S. Patent No. 10,385,419, which claims priority to U.S. Provisional Application No. 62/334,189 filed May 10, 2016, and U.S.
Provisional Application No. 62/396,602 filed September 19, 2016. This application also claims priority to U.S. Provisional Application No. 62/844,301 filed May 7, 2019. All of the foregoing applications are incorporated herein by reference.
FIELD OF THE INVENTION

[0002] The present invention relates to methods of providing continuously cast hot rolled high strength steel sheet products, including quenching finish rolled steel sheets on a hot strip mill to produce a predominantly martensitic microstructure, followed by soaking at a temperature in an intercritical regime and holding at a lower temperature to produce a microstructure that is predominantly ferrite and retained austenite.
BACKGROUND INFORMATION

[0003] Over past several years, the worldwide steel industry has focused on development of a third generation of advanced high strength steel (AHSS) for the automotive market. These Generation 3 steels have a favorable balance of tensile strength and elongation, typically in a UTS=TE range of about 20,000 MPa% or greater.
However, the steel industry has had a difficult time commercializing Generation 3 AHSS as the majority of approaches require high alloy content, e.g., typically greater than 4 weight percent manganese, which results in difficulties when manufacturing such steels with conventional steel production equipment. Additionally, currently available AHSS has been difficult to weld by techniques such as spot welding, have been difficult to coat with zinc-based galvanic coatings, and have been difficult to manufacture into the thin gauge sheet needed for wide scale application.

[0004] U. S . Patent No. 10,385,419 and U.S. Application Publication No.
US 2020/0040422, which are incorporated herein by reference, disclose annealing processes for making high strength steel products.
SUMMARY OF THE INVENTION

[0005] The present invention provides methods of producing continuously cast hot rolled steel sheet products, including continuously casting a steel slab and then hot rolling with finish rolling on a hot strip mill, quenching on the hot strip mill to form a predominantly martensitic microstructure, and performing a thermal cycling step including soaking at an intercritical temperature followed by holding at a lower temperature. The thermal cycling step can take place on a continuous galvanize line or continuous annealing line. The resultant hot rolled steel sheet products have a microstructure comprising ferrite and retained austenite.
Steels processed in accordance with the present invention exhibit favorable combined ultimate tensile strength and total elongation (UTS=TE) properties, e.g., of greater than 25,000 MPa-%. Steels with these properties may fall into the category of Generation 3 advanced high strength steels, and are highly desired by various industries including automobile manufacturers.

[0006] An aspect of the present invention is to provide a method of producing a high strength continuously cast hot rolled steel sheet product, the method comprising:
continuously casting a steel slab comprising from 0.15 to 0.5 weight percent C, from 1 to 3 weight percent Mn, and from 0.8 to 3 weight percent of a combination of Si and Al; hot rolling the continuously cast steel slab including a finish rolling step on a hot strip mill with a finish rolling temperature of at least 820 C to form a hot rolled steel sheet product on the hot strip mill; quenching the hot rolled steel sheet product on the hot strip mill to form a predominantly martensitic microstructure; subjecting the quenched hot rolled steel sheet product to a thermal cycling step comprising soaking the sheet product in an intercritical regime at a temperature of from 720 to 850 C followed by holding the sheet product at a temperature of from 360 to 445 C; and quenching the thermally cycled sheet product to room temperature, wherein the steel sheet product comprises ferrite and retained austenite grains, and has a combination of ultimate tensile strength and total elongation UTS=TE
of greater than 25,000 MPa%.

[0007] Another aspect of the present invention is to provide a high strength continuously cast hot rolled steel sheet product produced by the method described above.

8 [0008] These and other aspects of the present invention will be more apparent from the following description.
BRIEF DESCRIPTION OF THE DRAWINGS

[0009] Fig. 1 includes plots of temperature versus time illustrating a two-step annealing process.

[0010] Fig. 2 includes plots of temperature versus time illustrating a two-step annealing process.

[0011] Fig. 3 is a plot of temperature versus time illustrating a two-step annealing process that combines the two-step thermal process with an optional zinc-based hot-dipped coating operation in a single production facility.

[0012] Fig. 4 is a plot of temperature versus time for a second step of an annealing process defining soaking and holding zones in the thermal cycle.

[0013] Figs. 5 and 6 are electron backscatter diffraction (EBSD) photomicrographs illustrating the microstructure of a high strength steel sheet product.

[0014] Fig. 7 is an optical photomicrograph of a steel sheet product subjected to the thermal process shown in Fig. 1, showing darker ferrite grains and lighter austenite grains.

[0015] Fig. 8 is a bar graph illustrating aspect ratios of the austenite grains shown in Fig. 7.

[0016] Figs. 9 and 10 are graphs for a high strength steel sheet product showing austenite and ferrite grain size distributions.

[0017] Figs. 11 is EBSD photomicrograph illustrating the microstructure of a high strength steel sheet product processed as shown in Fig. 1.

[0018] Figs. 12 and 13 are EBSD photomicrographs showing steel sheet products processed as shown in Fig. 2.

[0019] Fig. 14 is an EBSD photomicrograph of a steel sheet product processed as shown in Fig. 3.

[0020] Fig. 15 is a graph of total elongation vs. ultimate tensile strength for high strength steel sheet products in comparison with other steel sheet products processed outside the scope of the present invention.

[0021] Fig. 16 is a graph of total elongation vs. ultimate tensile strength for high strength steel products produced in mill trials.

[0022] Fig. 17 is a plot of temperature versus time for cold rolled and hot rolled substrates processed with a thermal cycle.

[0023] Fig. 18 is an EBSD photomicrograph of a cold rolled steel sheet substrate subjected to the thermal process shown in Fig. 17 showing darker ferrite grains and lighter retained austenite grains.

[0024] Fig. 19 is an EBSD photomicrograph of a hot rolled steel sheet substrate subjected to the thermal process shown in Fig. 17 showing darker ferrite grains and lighter retained austenite grains.

[0025] Fig. 20 is a plot of temperature versus time illustrating the first step of a two-step thermal treatment process in which a hot rolled sheet is quenched on the runout table to form martensite in accordance with an embodiment of the present invention.

[0026] Fig. 21 is a plot of temperature versus time illustrating the second step of a two- step thermal treatment process in accordance with an embodiment of the present invention in which the quench annealed sheet of Fig. 17 is subjected to a thermal cycling step.
DETAILED DESCRIPTION

[0027] The high strength steel sheet products of the present invention have controlled compositions that, in combination with controlled annealing processes, produce desirable microstructures and favorable mechanical properties including high strengths and ultra-high formabilities. In certain embodiments, the steel composition may include carbon, manganese and silicon, along with any other suitable alloying additions known to those skilled in the art.
Examples of steel compositions including ranges of C, Mn, Si, Al, Ti, and Nb are listed in Table 1 below.
Table 1 Steel Compositions (wt. %) Example C Mn Si Al Si + Al Ti Nb A 0.15-1 0.5-4 0-2 0-2 0.8-3 0-0.05 0-0.05 0.2-0.4 1.3-2.5 0.2-1.8 0-1.5 0.9-2.5 0-0.03 0-0.03 0.17-0.35 1.5-2.3 0.4-1.6 0-1 1-2 0-0.02 0-0.02

[0028] In addition to the amounts of C, Mn, Si, Al, Ti and Nb listed in Table 1, the steel compositions may include minor or impurity amounts of other elements, such as 0.015 max S, 0.03 max P, 0.2 max Cu, 0.02 max Ni, 0.2 max Cr, 0.2 max Mo, 0.1 max Sn, 0.015 max N, 0.1 max V, and 0.004 max B. As used herein the term "substantially free", when referring to the composition of the steel sheet product, means that a particular element or material is not purposefully added to the composition, and is only present as an impurity or in trace amounts.

[0029] In the steel sheet products of the present invention, C provides increased strength and promotes the formation of retained austenite. Mn provides hardening and acts as a solid solution strengthener. Si inhibits iron carbide precipitation during heat treatment, and increases austenite retention. Al inhibits iron carbide precipitation during heat treatment, and increases austenite retention. Ti and Nb may act as a strength-enhancing grain refiners.

[0030] In certain embodiments, Al may be present in an amount of at least 0.1 weight percent or at least 0.2 weight percent. For example, Al may be present in an amount of from 0.5 to 1.2 weight percent, or from 0.7 to 1.1 weight percent, in certain embodiments.
Alternatively, the steel sheet product may be substantially free of Al.

[0031] Steel sheet products having compositions as described above are subjected to a two-stage annealing process, as more fully described below. The resultant sheet products have been found to possess favorable mechanical properties including desirable ultimate tensile strengths, high elongations, high lambda values, high bendability and high yield ratios (YS/UTS).

[0032] In certain embodiments, the ultimate tensile strength (UTS) of the steel sheet products range from 700 to 1,100 MPa or more. In certain embodiments, the steel sheet product has an ultimate tensile strength of greater than 700 MPa, for example, from 720 to 1,100 MPa, or from 750 to 1,050 MPa.

[0033] In certain embodiments, the steel sheet products have a total elongation (TE) typically greater than 22 percent, for example, greater than 27 percent, or greater than 33 percent. For example, the steel sheet product may have a total elongation of at least 20% or at least 25% or at least 27%, e.g., from 22 to 45%, or from 25 to 40%.

[0034] The steel sheet products may possess lambda (2) values as measured by a standard hole expansion test typically greater than 20 percent, for example, greater than 25 percent, or greater than 30 percent, or greater than 35 percent. The whole expansion ratio or lambda may be greater than 20%, for example, from 22 to 80%, or from 25 to 60%.

[0035] In certain embodiments, increased values of both total elongation (TE) and hole expansion (2\,) result in steel sheet products exhibiting good global formability and local formability.

[0036] Strength elongation balances (UTS=TE) of greater than 25,000 are observed for the present steel sheet products, making them fall into the category of Generation 3 steels highly desired by industries such as the auto industry. In certain embodiments UTS=TE
values may be greater than 26,000, or greater than 27,000, or greater than 30,000.

[0037] In accordance with certain embodiments of the invention, the final microstructure of the steel sheet products may primarily comprise ferrite, e.g., at least 50% up to 80% or higher, with lesser amounts of retained austenite, e.g., from 5 to 25%, and minor amounts of fresh martensite, e.g., from 0 to 10% or 15%. The amounts of ferrite, austenite and martensite may be determined by standard EBSD techniques. Alternatively, retained austenite content may be determined by magnetic saturation methods. Unless otherwise specified herein, the volume percent of retained austenite is determined by the EBSD
technique.

[0038] In certain embodiments, the retained austenite comprises from 1 to 25 volume percent, for example, from 5 to 20 volume percent. The amount of fresh martensite may comprise less than 15 volume percent, or less than 10 volume percent, or less than 5 volume percent. In certain embodiments, the steel sheet product is substantially free of fresh martensite. It has been found that when fresh martensite amounts are greater than 15%, hole expansion values decrease significantly, e.g., local formability is significantly decreased.

[0039] At least a portion of the ferrite may be formed during the soaking or heating section, as described below, by recrystallization and/or tempering of martensite, or during the cooling and holding section of the thermal cycling process by austenite decomposition. Some of the ferrite may be considered bainitic ferrite. The ferrite, austenite and martensite phases are fine grained, e.g., having average grain sizes of less than 10 microns, for example, less than 5 microns, or less than 3 microns. For example, ferrite grain size may range from less than 10 microns, for example, less than 8 microns, or less than 6 microns.
Average austenite grain size may range from less than 2 microns, for example, less than 1 micron, or less than 0.5 micron. Martensite grain size, when present, may range from less than 10 microns, for example, less than 8 microns, or less than 6 microns.

[0040] The austenite grains may be substantially equiaxed, e.g., having average aspect ratios less than 3:1 or less than 2:1, for example, about 1:1. It has been found that amounts of retained austenite below about 5% results in significantly decreased total elongations (TE). It has further been found that amounts of retained austenite above 25% can only be obtained at very high carbon levels, which results in poor weldability.

[0041] In certain embodiments of the invention, a two-step thermal treatment process is used to produce advanced high strength steel products with favorable mechanical properties, such as those described above. The first step is performed on a hot strip mill after a steel slab has been continuously cast and hot rolled including a finish rolling step on the hot strip mill. The finish rolled steel sheet is quenched on the hot strip mill to form a predominantly martensitic microstructure, and the second step includes soaking the steel sheet in an intercritical regime followed by holding at a lower temperature.
The second step can be performed on a continuous annealing line or continuous galvanizing line. The final steel sheet product comprises ferrite and retained austenite, i.e., having a microstructure that is predominantly ferrite and retained austenite.

[0042] In certain embodiments, the steel sheet products may be produced on a combined continuous casting and hot rolling line in which molten steel is continuously cast to form a slab of steel that may be subjected to initial rough hot rolling to reduce thickness, followed by final hot rolling to further reduce thickness. The continuous casting/hot rolling line may comprise an endless strip production (ESP) process or the like. After final hot rolling, the sheet may be fed to a runout cooling table where it may be subjected to a quenching process to a temperature below MF, e.g., using a thermomechanical schedule as shown in Fig. 20. The resultant quenched hot rolled sheet may then be subjected to the second step of the process, e.g., by adopting a two-stage thermal cycle as shown in Fig. 21.

[0043] In certain embodiments, Step 1 of the two-step process may be performed using continuous casting and hot rolling equipment and processes as disclosed in Arvedi U.S.
Patent Nos. 5,329,688; 5,497,821; 6,125,916; 7,343,961; 7,832,460; 7,967,056;
8,025,092;
8,162,032; 8,257,647; and 9,186,721, which are incorporated herein by reference.

[0044] Within each of the first and second annealing or thermal cycling steps, multiple methodologies for undertaking the heat treatment may be used.
Examples of two-step annealing processes as described in U.S. Patent No. 10,385,419 and U.S.
Application Publication No. US 2020/0040422 are shown in Figs. 1-3 and described below.
Fig. 1 represents a continuous annealing line (CAL) followed by a continuous annealing line (CAL) production route. Fig. 2 represents a CAL plus continuous galvanizing line (CGL) production route. Fig. 3 represents a specially designed line allowing for both CAL + CAL

or CAL + CGL steps to take place in a single facility. While a direct-fired furnace (DFF) followed by a radiant tube (RT) furnace embodiment is shown in Fig. 3, other embodiments such as all radiant tube, electric radiant heating, and the like may be used to achieve the desired thermal cycles.
Step 1

[0045] The goal of the first step of the process is to achieve a predominantly martensitic microstructure in the continuously cast and hot rolled steel sheet product. In the first step, the hot rolled steel sheet has a finish rolling temperature above the A3, for example, a finish rolling temperature of at least 820 C may be provided on the hot strip mill prior to quenching. In certain embodiments, the quench annealing temperature may typically range from 830 to 980 C, for example, from 830 to 940 C, or from 840 to 930 C, or from 860 to 925 C.

[0046] The continuously cast and finish rolled steel sheet is quenched to room temperature, or to a controlled temperature above room temperature, as more fully described below. The quench temperature may not necessarily be room temperature but should be below the martensite start temperature (Ms), and preferably below the martensite finish temperature (MF), to form a microstructure of predominantly martensite.

[0047] Quenching to below MF (typically below 250 C) may be accomplished by conventional techniques such as water quenching, submerged knife/nozzle water quenching, gas cooling, rapid cooling using a combination of cold, warm or hot water and gas, water solution cooling, other liquid or gas fluid cooling, chilled roll quench, water mist spray, wet flash cooling, non-oxidizing wet flash cooling, and the like. For example, water quenching may be used in Step 1 as is typically used to cool the strip after finish rolling on the runout table of a conventional hot strip mill, CSP mill, or ESP mill. A quench rate of from 30 to 1,000 C/sec may typically be used.

[0048] Various types of cooling and quenching systems and processes known to those skilled in the art may be adapted for use in the processes of the present invention. Suitable cooling/quenching systems and processes conventionally used on a commercial basis may include water quench, water mist cooling, dry flash and wet flash, oxidizing and non-oxidizing cooling, alkane fluid to gas phase change cooling, hot water quenching, including two-step water quenching, roll quenching, high percentage hydrogen or helium gas jet cooling, and the like. For example, dry flash and/or wet flash oxidizing and non-oxidizing cooling/quenching such as disclosed in published PCT Application No.
W02015/083047 to Fives Stein may be used. Other Fives Stein patent documents describing cooling/quenching systems and processes that may be adapted for use in the processes of the present invention include U.S. Patent Nos. 6,464,808B2; 6,547,898B2; and 8,918,199B2, and U.S.
Patent Application Publication Nos. U52009/0158975A1; US2009/0315228A1; and U52011/0266725A1. Other examples of cooling/quenching systems and processes that may be adapted for use in the processes of the present invention include those disclosed in U.S.
Patent Nos. 8,359,894B2; 8,844,462B2; and 7,384,489B2, and U.S. Patent Application Publication Nos. 2002/0017747A1 and 2014/0083572A1.

[0049] In certain embodiments, after the steel is quenched to form martensite, the martensite can be optionally tempered to soften the steel somewhat to make further processing more feasible. Tempering may take place in a continuous annealing process by raising the temperature of the steel in the range of room temperature to about 500 C, e.g., from 30 to 500 C, and holding for up to 600 seconds, e.g., from 1 to 600 seconds.
Tempering may also take place using a batch annealing process, where the same temperature could be reached over a period of several days. For example, the intermediate batch tempering may be performed at a temperature of from 125 to 500 C for up to seven days. If tempering is utilized, the tempering temperature may be held constant, or may be varied within this preferred range.

[0050] After tempering, the temperature may be ramped down to room temperature.
The rate of such ramp-down may typically range up to 40 C/sec, for example, from 0.1 to 20 C/sec.
Step 2

[0051] The second step of the thermal treatment process may include a first soak stage that is conducted at relatively high soaking temperature, and a second hold stage that is conducted at relatively low temperature. These stages may be defined as the "soaking" and "holding" zones, as described in Figs. 4 and 21. The temperatures are controlled in order to promote the formation of the desired microstructure in the final product.

[0052] In the first soaking stage of the second step, a soaking zone temperature in an intercritical regime between At and A3 may be used, for example, a soak temperature of at least 720 C may be used. In certain embodiments, the soak temperature may typically range from 720 to 850 C, for example, from 760 to 825 C. In certain embodiments, the peak annealing temperature may be typically held for at least 15 seconds, for example, from 20 to 300 seconds, or from 30 to 150 seconds.

[0053] During the first stage of the second step, the soaking zone temperature may be achieved by heating the steel from a relatively low temperature below Ms, e.g., room temperature, at an average rate of from 0.5 to 50 C/sec, for example, from about 2 to 20 C/sec. In certain embodiments, the ramp-up may take from 25 to 800 seconds, for example, from 100 to 500 seconds. The first stage heating of the second step may be accomplished by any suitable heating system or process, such as using radiant heating, induction heating, direct fired furnace heating and the like.

[0054] After the soak temperature is reached and held for the desired period of time, the steel may be cooled to a controlled temperature above room temperature to the holding zone. In certain embodiments, the steel sheet product is maintained at a temperature above 300 C between the second step soaking process and the second step holding process.
Cooling from the soaking to holding zone may be accomplished by conventional techniques such as water cooling, gas cooling and the like. An average cooling rate of from 5 to 400 C/sec may typically be used. Any suitable types of cooling and quenching systems may be adapted for use in cooling from the soaking temperature to the holding temperature, including those described above.

[0055] In accordance with embodiments of the invention, the holding zone step is carried out at a typical temperature of from 360 to 445 C, for example, from 370 to 440 C.
The holding zone may be held for up to 800 seconds, for example, from 30 to 600 seconds.

[0056] The holding zone temperature may be held constant, or may be varied somewhat within the preferred temperature range. After holding, the steel may be reheated, such as by induction or other heating method, to enter a hot-dip coating pot at the proper temperature for good coating results, if the steel is to be hot-dip coated.

[0057] In certain embodiments, after the holding zone temperature has been maintained for a desired period of time, the temperature may be ramped down to room temperature. Such a ramp-down may typically take from 10 to 1,000 seconds, for example, from about 20 to 500 seconds. The rate of such ramp-down may typically range from 1 to 1,000 C/sec, for example, from 2 to 20 C/sec.

[0058] Examples of heating systems that may be adapted for use in the soak and hold thermal cycling step of the present invention are disclosed in U.S. Patent Nos. 5,798,007;
7,368,689; 8,425,225; and 8,845,324, U.S. Patent Application No. 2009/0158975, and Published PCT Application No. WO/2015083047, assigned to Fives Stein.
Additional examples of heating systems that may be adapted for use in the soak and hold thermal cycling step of the present invention include U.S. Patent No. 7,384,489 assigned to Dreyer International, and U.S. Patent No. 9,096,918 assigned to Nippon Steel and Sumitomo Metal Corporation. Any other suitable known types of heating systems and processes may be adapted for use in Step 1 and Step 2.

[0059] In accordance with certain embodiments, the second-step thermal cycling processes may be performed on a continuous annealing line (CAL). After going through a CAL process, the steel may be electrogalvanized to produce a zinc based coated product.

[0060] In certain embodiments, the annealed steel sheet is hot-dip galvanized at the end of the holding zone. Galvanizing temperatures may typically range from 440 to 480 C, for example, from 450 to 470 C. In certain embodiments, the galvanizing step may be performed as part of the second-step holding zone process on a continuous galvanizing line (CGL), e.g., as shown in Fig. 2. This CGL process can be used to produce both a zinc-based or zinc alloy-based hot-dip galvanized product or reheated after coating to produce an iron-zinc galvanneal type coated product. An optional nickel-based coating step can take place prior to the CGL step in the process to improve zinc coating properties. The use of a continuous galvanizing line in the second step may increase the efficiency of producing coated GEN3 products.

[0061] The following examples are not intended to limit the scope of the invention.
Example 1

[0062] A cold rolled steel sheet having a composition as listed in Table 2, Sample No.
1, was subjected to a two-step annealing process as illustrated in Fig. 1. The microstructure of the resultant product is shown in Figs. 5 and 6. EBSD techniques using commercial EDAX orientation imaging microscopy software show the dark ferrite grains and light austenite grains in Fig. 5.
Example 2

[0063] A cold rolled steel sheet having a composition as listed in Table 2, Sample No.
2, was subjected to a two-step annealing process as illustrated in Fig. 1. The microstructure of the resultant product is shown in Fig. 11. Mechanical properties of Sample No. 2 are listed in Table 2. Grain size distributions of austenite and ferrite are shown in Figs. 9 and 10, respectively. The average austenite grain size is less than 1 micron and the average ferrite grain size is less than 10 microns.

[0064] The microstructure includes about 80 volume percent ferrite with an average grain size of about 5 microns, about 10 volume percent retained austenite having substantially equiaxed grains and an average grain size of about 0.5 micron, and about 10 volume percent fresh martensite with an average grain size of about 5 microns. Mechanical properties of Sample No. 1 are listed in Table 2 below.
Example 3

[0065] A cold rolled steel sheet having a composition as listed in Table 2, Sample No.
3, was subjected to a two-step annealing process as illustrated in Fig. 2. The microstructure of the resultant product is shown in Figs. 12 and 13. In Fig. 13, austenite is light in color and ferrite is dark in color. Mechanical properties of Sample No. 3 are listed in Table 2.
Example 4

[0066] A cold rolled steel sheet having a composition as listed in Table 2, Sample No.
4, was subjected to a two-step annealing process as illustrated in Fig. 3. The microstructure of the resultant product is shown in Figure 14. In Fig. 14, austenite is light in color and ferrite is dark in color. Mechanical properties of Sample No. 4 are listed in Table 2.
Example 5

[0067] A cold rolled steel sheet having a composition as listed in Table 2, Sample No.
5, was subjected to a two-step annealing process as illustrated in Fig. 1.
Mechanical properties of Sample No. 5 are listed in Table 2.
Example 6

[0068] A cold rolled steel sheet having a composition as listed in Table 2, Sample No.
6, was subjected to a two-step annealing process as illustrated in Fig. 1.
Mechanical properties of Sample No. 6 are listed in Table 2. Fig. 7 is an optical image showing the microstructure of the steel shown in Fig. 2, Sample No. 6, which was subjected to the two-step annealing process shown in Fig. 1. In Fig. 7, the dark regions of the photomicrograph are ferrite grains, while the light regions are austenite grains. Fig. 8 is a graph illustrating the aspect ratios of the austenite grains shown in Fig. 7. The optical image of Fig. 7 was used to determine the aspect ratios of the austenite grains using image analysis with commercially available software. Fig. 7 shows that the average aspect ratio is less than 3:1 for the austenite grains.
Example 7

[0069] A cold rolled steel sheet having a composition as listed in Table 2, Sample No.
7, was subjected to a two-step annealing process as illustrated in Fig. 2.
Mechanical properties of Sample No. 7 are listed in Table 2.
Example 8

[0070] A cold rolled steel sheet having a composition as listed in Table 2, Sample No.
8, was subjected to a two-step annealing process as illustrated in Fig. 3.
Mechanical properties of Sample No. 8 are listed in Table 2.

[0071] The steels in Examples 1-8 exhibited UTS levels in the range of 700 to 1,100 MPa.
Comparative Examples 1-4

[0072] Cold rolled steel sheets having compositions as listed in Table 2, Sample Nos. Cl-C4, were subjected to a two-step annealing process as illustrated in Fig. 1.
Mechanical properties of Sample Nos. C1-C4 are listed in Table 2. The steels in Comparative Examples 1-4 exhibited UTS levels less than 700 MPa.
Comparative Examples 5-8

[0073] Cold rolled steel sheets having compositions as listed in Table 2, Sample Nos. C5-C8, were subjected to a two-step annealing process as illustrated in Fig. 1.
Mechanical properties of Sample Nos. C5-C8 are listed in Table 2. The steels in Comparative Examples 5-8 exhibited UTS levels greater than 1,100 MPa.
Comparative Examples 9-11

[0074] Cold rolled steel sheets having compositions as listed in Table 2, Sample Nos. C9-C11, were subjected to a two-step annealing process similar to that illustrated in Fig.
1, except the soaking or holding temperature in the second anneal were outside the preferred ranges of the invention. Mechanical properties of Sample Nos. C9-C11 are listed in Table 2.

Comparative Example 12

[0075] A cold rolled sheet having a composition listed in Table 2, Sample No.
C12, was subjected to a two-step annealing process similar to that illustrated in Fig. 2, except the holding zone temperature in the second anneal was outside the preferred range of the invention. Mechanical properties of Sample No. C12 are listed in Table 2.

Table 2 Sample YS UTS TE
Product Type Process C Mn Si Other UTS=TE Lambda 0 No. (MPa) (MPa) (%) CR 780 GEN3 CAL +
1 0.22 1.5 1.5 657 831 39.2 super elongation CAL
CAL +
2 CR 980 GEN3 0.185 2.2 1.4 630 1030 25 CAL

0.8 Al, Hot-dipped 980 CAL +
3 0.22 2.25 0.45 0.02 Ti, 576 988 30.2 29838 20 0.02Nb Single process in Hot-dipped 980 4 GEN3 newly 0.185 2.2 1.4 580 998 29.1 29042 designed CGL
CR 980 GEN3 CAL +
0.35 1.5 1.5 685 999 38.2 38161 25 Super elongation CAL
CAL +
6 CR 780 GEN3 0.175 1.8 1.5 630 840 33 CAL
Hot-dipped 780 CAL +
7 0.2 2.3 0.4 1.0 Al 533 915 32.8 30012 30 Single process in Hot-dipped 780 8 GEN3 newly 0.2 2.3 0.4 1.0 Al 589 865 34.4 29756 designed CGL
1-d Table 2 (continued) Sample Product YS UTS TE
t.) Process C Mn Si Other UTS=TE Lambda o No. Type (MPa) (MPa) (%) t.) o CAL +
Cl Alloy 1 0.105 1.55 1.2 512 666 32.6 21712 67 t.) CAL

.6.
CAL +
oe C2 Alloy 2 0.14 1.5 1.3 556 690 30.2 20838 59 CAL
CAL +
C3 Alloy 3 0.17 1.1 1.1 560 686 26.9 18453 53 CAL
CAL +
C4 Alloy 4 0.13 0.9 0.9 533 618 26.0 16068 81 CAL
CAL +
C5 Alloy 1 0.21 2.15 1.5 0.003 B 597 1125 17.2 19350 25 CAL
CAL +
P
C6 Alloy 2 0.2 2.2 1.5 0.2 Mo 585 1148 16.3 18712 13 o CAL
, 1-, CAL +
.
c: C7 Alloy 3 0.23 2.4 1.5 0.003 B 683 1231 16.2 19942 6.7 CAL
r., CAL +

, C8 Alloy 4 0.19 2.64 2.0 635 1359 14.8 20113 3.4 ' , CAL
, , Alloy 1 -, CAL +
C9 High Soak 0.18 2.2 1.34 693 1058 18.2 19256 25 CAL
(849 C) Alloy 2 -CAL +
C10 Low Hold 0.18 2.2 1.34 602 1035 21.2 21942 30 CAL
(350 C) Alloy 3 -CAL +
Iv C11 High Hold 0.18 2.2 1.34 477 1059 19.7 20862 19 n CAL
(450 C) Alloy 4 -cp CAL +
t.) C12 High Hold 0.22 2.4 0.4 0.8 Al 465 1012 23.0 23276 16.5 CGL
o (471 C) 'a 1-, 1-, v:,

[0076] Fig. 15 plots the total elongation (TE) and ultimate tensile strength (UTS) of Samples 1-8 of Examples 1-8, as well as Samples C1-C12 of Comparative Examples C1-C12. A
line corresponding to UTS=TE of 25,000 is roughly drawn in Fig. 15. As can be seen, the high strength steel sheet samples produced in accordance with the present invention possess superior combinations of strength and elongation versus the comparative samples, i.e., high total elongation properties at high UTS levels are observed for the inventive examples. The Sample 1 through Sample 8 steels fall into the category of Generation 3 advanced high strength steels, which are highly desirable for automotive and other industries.
Example 9

[0077] Mill trials were conducted for samples labeled Ml-M5 in Table 3 below using either the CAL+CAL or CAL+CGL process. For Samples Ml, M2 and M5, the CAL+CAL
processing times and temperatures shown in Fig. 1 were used. For Samples M3 and M4, the CAL+CGL processing times and temperatures shown in Fig. 2 were used.
Table 3 Mill Trial Results Mill Coat YS UTS lE
Trial Process C Mn Si Other UTS=TE Lambda (MP) (MPa) (%) No.
CAL + None M1 0.22 1.4 1.4 627 810 38.6 31266 CAL
CAL + None M2 0.185 2.2 1.4 624 1009 25 25255 CAL
0.8 Al, HDGI
+
M3 CALCGL 0.23 2.4 0.4 0.02 Ti, 567 989 26.4 0.02Nb 0.8 Al, HDGI
+
M4 CALCGL 0.22 2.3 0.4 0.02 Ti, 655 941 30.9 0.02Nb CAL + None M5 0.19 2.25 1.5 635 1048 25.3 26514 29 CAL

[0078] Fig. 16 shows the strength-elongation balance of the mill trial materials, all meeting a minimum UTS=TE of 25,000. The trial materials exhibited lambda values greater than 20%.
Example 10

[0079] Cold rolled and hot rolled steel sheets having a composition of 0.23 weight percent C, 2.3 weight percent Mn, 0.6 weight percent Si and 0.8 weight percent Al corresponding to Sample Nos. 9A-12B in Table 4 were subjected to a two-stage annealing process as shown in Fig. 17. In Table 4, cold rolled samples are listed as "CR" substrate types, and hot rolled samples are listed as "HR" substrate types. Mechanical properties of Sample Nos. 9A-12B are listed in Table 4. The hot rolled substrate samples showed comparable exceptional YS, UTS, TE
and hole expansion properties as the cold rolled samples, showing that a hot rolled substrate processed directly into the two stage annealing process can produce Generation properties. Furthermore, as indicated in the EB SD phase maps shown in Figs.
18 and 19 in which the retained austenite grains are lighter than the ferrite grains, similar austenite contents, distributions and morphologies are observed for the hot rolled material when compared to the cold rolled material. Fig. 18 shows the austenite content of cold rolled sample 11A and Fig. 19 shows the austenite content of hot rolled sample 12A. A fine, predominantly equiaxed distribution of austenite is observed in both microstructures.
Table 4 Specimen Substrate Cycle Type YS (MPa) UTS TE (%) UTS=TE Hole ID Type (MPa) Expansion Ratio (%) 9A CR 427 C 706.32 973.1 31.39 30545.61 35 (800 F) 9B 712.02 959.2 34.41 33006.07 Hold - GI
10A HR 427 C 696.37 963.8 30.26 29164.59 10B (800 F) 695.40 954.4 35.18 33575.79 Hold - GI
11A CR 443 C 618.23 1032.9 - - 31 11B (830 F) 614.00 1030.4 28.04 28892.42 Hold - GI
12A HR 443 C 650.39 1002.2 27.21 27269.86 (830 F) 12B 622.82 1007.6 27.75 27960.90 Hold - GI

Example 11

[0080] In accordance with an embodiment of the present invention, a hot rolled steel sheet having a composition of C = 0.29%, Mn = 1.85%, Si = 1.55%, Al = 0.04, the balance typical steel residuals, was subjected to a two-step process as illustrated in Figs. 20 and 21. In Step 1, martensite is formed on a hot strip mill by water quenching after finish rolling using the thermomechanical schedule shown in Fig. 20. An overageing step (not shown) could optionally be added at the end of this thermal cycle to soften and toughen the hot band for subsequent processing. In Step 2, a thermal cycle as shown in Fig. 21 is then performed.
The resultant mechanical properties are: YS = 864 MPa; UTS = 864 MPa; Total Elongation =
31.2%; and UTS x TE = 26957 MPa %.

[0081] As used herein, "including," "containing" and like terms are understood in the context of this application to be synonymous with "comprising" and are therefore open-ended and do not exclude the presence of additional undescribed or unrecited elements, materials, phases or method steps. As used herein, "consisting of' is understood in the context of this application to exclude the presence of any unspecified element, material, phase or method step.
As used herein, "consisting essentially of' is understood in the context of this application to include the specified elements, materials, phases, or method steps, where applicable, and to also include any unspecified elements, materials, phases, or method steps that do not materially affect the basic or novel characteristics of the invention.

[0082] Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard variation found in their respective testing measurements.

[0083] Also, it should be understood that any numerical range recited herein is intended to include all sub-ranges subsumed therein. For example, a range of "1 to 10"
is intended to include all sub-ranges between (and including) the recited minimum value of 1 and the recited maximum value of 10, that is, having a minimum value equal to or greater than 1 and a maximum value of equal to or less than 10.

[0084] In this application, the use of the singular includes the plural and plural encompasses singular, unless specifically stated otherwise. In addition, in this application, the use of "or" means "and/or" unless specifically stated otherwise, even though "and/or" may be explicitly used in certain instances. In this application and the appended claims, the articles "a,"
"an," and "the" include plural referents unless expressly and unequivocally limited to one referent.

[0085] Whereas particular embodiments of this invention have been described above for purposes of illustration, it will be evident to those skilled in the art that numerous variations of the details of the present invention may be made without departing from the invention.

Claims

WHAT IS CLAIMED IS:

1. A method of producing a high strength continuously cast hot rolled steel sheet product, the method comprising:
continuously casting a steel slab comprising from 0.15 to 0.5 weight percent C, from 1 to 3 weight percent Mn, and from 0.8 to 3 weight percent of a combination of Si and Al;
hot rolling the continuously cast steel slab including a finish rolling step on a hot strip mill with a finish rolling temperature of at least 820 C to form a hot rolled steel sheet product on the hot strip mill;
quenching the hot rolled steel sheet product on the hot strip mill to form a predominantly martensitic microstructure;
subjecting the quenched hot rolled steel sheet product to a thermal cycling step comprising soaking the sheet product in an intercritical regime at a temperature of from 720 to 850 C followed by holding the sheet product at a temperature of from 360 to 445 C; and quenching the thermally cycled sheet product to room temperature, wherein the steel sheet product comprises ferrite and retained austenite grains, and has a combination of ultimate tensile strength and total elongation UT S= TE of greater than 25,000 MPa%.

2. The method of claim 1, wherein the hot rolling step is performed immediately after the continuously casting step.

3. The method of claim 1, wherein the step of quenching the hot rolled sheet product on the hot strip mill is performed on a run out table of the hot strip mill.

4. The method of claim 1, wherein the step of quenching the hot rolled sheet product on the hot strip mill comprises water quenching.

5. The method of claim 1, wherein the step of quenching the hot rolled steel sheet product on the hot strip mill may be performed at a quench rate of from 30 to 1,000 C/second.

6. The method of claim 1, further comprising rough rolling the continuously cast steel slab during the hot rolling step prior to the finish rolling step.

7. The method of claim 1, wherein the finish rolling temperature of the finish rolling step is from 830 to 940 C.

8. The method of claim 1, further comprising subjecting the quenched hot rolled steel sheet product to an intermediate tempering step prior to the thermal cycling step.

9. The method of claim 8, wherein the intermediate tempering step is performed at a temperature of from 30 to 500 C for up to 7 days.

10. The method of claim 8, wherein the intermediate tempering step is performed at a temperature of from 125 to 500 C.

11. The method of claim 1, wherein the C comprises greater than 0.2 weight percent.

12. The method of claim 1, wherein the C comprises from 0.2 to 0.4 weight percent, the Mn comprises from 1.3 to 2.5 weight percent, the Si comprises from 0.2 to 1.8 weight percent, and the Al comprises up to 1.5 weight percent.

13. The method of claim 1, wherein the ferrite comprises at least 50 volume percent, and the retained austenite comprises from 5 to 25 volume percent of the steel sheet product.

14. The method of claim 1, wherein the rolled steel sheet product comprises less than 15 volume percent of fresh martensite.

15. The method of claim 1, wherein the rolled steel sheet product has an ultimate tensile strength of from 720 to 1,100 MPa and has a total elongation of at least 20 percent.

16. The method of claim 1, wherein the hot rolled steel sheet product has a hole expansion ratio of greater than 20 percent.

17. The method of claim 1, further comprising applying a zinc-based coating on the hot rolled steel sheet product.

18. A high strength continuously cast rolled steel sheet product produced by the method of claim 1.