CA2909974C - Procede et systeme pour produire un gaz de synthese au moyen d'un systeme de reformage a base de membrane de transport d'oxygene - Google Patents
Procede et systeme pour produire un gaz de synthese au moyen d'un systeme de reformage a base de membrane de transport d'oxygene Download PDFInfo
- Publication number
- CA2909974C CA2909974C CA2909974A CA2909974A CA2909974C CA 2909974 C CA2909974 C CA 2909974C CA 2909974 A CA2909974 A CA 2909974A CA 2909974 A CA2909974 A CA 2909974A CA 2909974 C CA2909974 C CA 2909974C
- Authority
- CA
- Canada
- Prior art keywords
- stream
- oxygen
- synthesis gas
- transport membrane
- oxygen transport
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 245
- 239000001301 oxygen Substances 0.000 title claims abstract description 245
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 243
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 167
- 239000007789 gas Substances 0.000 title claims abstract description 160
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 152
- 239000012528 membrane Substances 0.000 title claims abstract description 148
- 238000002407 reforming Methods 0.000 title claims abstract description 117
- 238000000034 method Methods 0.000 title claims abstract description 60
- 239000001257 hydrogen Substances 0.000 claims abstract description 55
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 55
- 239000012466 permeate Substances 0.000 claims abstract description 55
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 53
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 53
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 51
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 46
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 46
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 39
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 31
- 229910052751 metal Inorganic materials 0.000 claims abstract description 27
- 239000002184 metal Substances 0.000 claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- 238000010410 dusting Methods 0.000 claims abstract description 17
- 238000005260 corrosion Methods 0.000 claims abstract description 16
- 230000007797 corrosion Effects 0.000 claims abstract description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 66
- 239000003054 catalyst Substances 0.000 claims description 54
- 239000012465 retentate Substances 0.000 claims description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 15
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 7
- 238000004064 recycling Methods 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 230000005855 radiation Effects 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 4
- 230000000153 supplemental effect Effects 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 3
- 239000000446 fuel Substances 0.000 claims description 3
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 230000008569 process Effects 0.000 description 32
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 16
- 239000003345 natural gas Substances 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000001991 steam methane reforming Methods 0.000 description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 238000007792 addition Methods 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- -1 oxygen ions Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000010744 Boudouard reaction Methods 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000001833 catalytic reforming Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 238000005276 aerator Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/061—Methanol production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0822—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel the fuel containing hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
- C01B2203/1264—Catalytic pre-treatment of the feed
- C01B2203/127—Catalytic desulfurisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
L'invention concerne un procédé et un système permettant de produire un gaz de synthèse dans un système de reformage à base de membrane de transport d'oxygène, qui utilise un flux d'alimentation combiné (200) ayant un rapport vapeur/carbone compris entre environ 1,6 et 3,0 et une température située entre environ 500 et 750 °C, ledit système de reformage à base de membrane de transport d'oxygène et l'équipement du processus de production de synthèse associé étant sensiblement exempts de formation de carbone et de corrosion due aux poussières métalliques. Le flux d'alimentation combiné se compose d'une charge hydrocarbure pré-reformée (195), de vapeur surchauffée (180) et d'un flux de produit de réaction (198) généré par la réaction d'un flux contenant de l'hydrogène (163) mis à réagir avec l'oxygène soumis à perméation côté perméat des éléments de la membrane de transport d'oxygène (120) .
Applications Claiming Priority (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361816293P | 2013-04-26 | 2013-04-26 | |
| US201361816297P | 2013-04-26 | 2013-04-26 | |
| US201361816310P | 2013-04-26 | 2013-04-26 | |
| US61/816293 | 2013-04-26 | ||
| US61/816310 | 2013-04-26 | ||
| US61/816297 | 2013-04-26 | ||
| US14/090,289 US9611144B2 (en) | 2013-04-26 | 2013-11-26 | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion |
| US14/090194 | 2013-11-26 | ||
| US14/090,194 US20140319425A1 (en) | 2013-04-26 | 2013-11-26 | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system using a combined feed stream |
| US14/090289 | 2013-11-26 | ||
| US14/098,731 US9365422B2 (en) | 2013-04-26 | 2013-12-06 | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system with recycling of the produced synthesis gas |
| US14/098731 | 2013-12-06 | ||
| PCT/US2014/033160 WO2014176020A1 (fr) | 2013-04-26 | 2014-04-07 | Procédé et système pour produire un gaz de synthèse au moyen d'un système de reformage à base de membrane de transport d'oxygène |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2909974A1 CA2909974A1 (fr) | 2014-10-30 |
| CA2909974C true CA2909974C (fr) | 2019-03-05 |
Family
ID=51792298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2909974A Active CA2909974C (fr) | 2013-04-26 | 2014-04-07 | Procede et systeme pour produire un gaz de synthese au moyen d'un systeme de reformage a base de membrane de transport d'oxygene |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN105377750A (fr) |
| CA (1) | CA2909974C (fr) |
| WO (1) | WO2014176020A1 (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3115336B2 (fr) * | 2015-07-10 | 2022-01-05 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Installation et procede de refroidissement de gaz de synthese |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6048472A (en) | 1997-12-23 | 2000-04-11 | Air Products And Chemicals, Inc. | Production of synthesis gas by mixed conducting membranes |
| US6296686B1 (en) | 1998-06-03 | 2001-10-02 | Praxair Technology, Inc. | Ceramic membrane for endothermic reactions |
| US6114400A (en) | 1998-09-21 | 2000-09-05 | Air Products And Chemicals, Inc. | Synthesis gas production by mixed conducting membranes with integrated conversion into liquid products |
| US7261751B2 (en) | 2004-08-06 | 2007-08-28 | Conocophillips Company | Synthesis gas process comprising partial oxidation using controlled and optimized temperature profile |
| US7686856B2 (en) * | 2006-06-19 | 2010-03-30 | Praxair Technology, Inc. | Method and apparatus for producing synthesis gas |
| US8262755B2 (en) | 2007-06-05 | 2012-09-11 | Air Products And Chemicals, Inc. | Staged membrane oxidation reactor system |
| US20120148485A1 (en) * | 2010-12-09 | 2012-06-14 | Morrow Jeffrey M | Steam methane reforming process |
| US8349214B1 (en) * | 2011-07-08 | 2013-01-08 | Praxair Technology, Inc. | Synthesis gas method and apparatus |
| CN102826508B (zh) * | 2012-08-29 | 2015-02-18 | 中国科学院过程工程研究所 | 一种利用冶金熔渣余热重整富含甲烷的可再生资源制氢方法 |
-
2014
- 2014-04-07 CN CN201480035848.6A patent/CN105377750A/zh active Pending
- 2014-04-07 WO PCT/US2014/033160 patent/WO2014176020A1/fr active Application Filing
- 2014-04-07 CA CA2909974A patent/CA2909974C/fr active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014176020A1 (fr) | 2014-10-30 |
| CA2909974A1 (fr) | 2014-10-30 |
| CN105377750A (zh) | 2016-03-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20170127 |