CA2595686A1 - Soluble diverting agents - Google Patents

Soluble diverting agents Download PDF

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Publication number
CA2595686A1
CA2595686A1 CA002595686A CA2595686A CA2595686A1 CA 2595686 A1 CA2595686 A1 CA 2595686A1 CA 002595686 A CA002595686 A CA 002595686A CA 2595686 A CA2595686 A CA 2595686A CA 2595686 A1 CA2595686 A1 CA 2595686A1
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CA
Canada
Prior art keywords
diverting
poly
oxide
water
fluid
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Granted
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CA002595686A
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French (fr)
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CA2595686C (en
Inventor
A. Richard Sinclair
Syed Akbar
Patrick R. Okell
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Covia Solutions Inc
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Individual
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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/80Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
    • C09K8/805Coated proppants
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/42Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
    • C09K8/46Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
    • C09K8/467Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement containing additives for specific purposes
    • C09K8/487Fluid loss control additives; Additives for reducing or preventing circulation loss
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/80Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/14Obtaining from a multiple-zone well
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/25Methods for stimulating production
    • E21B43/26Methods for stimulating production by forming crevices or fractures
    • E21B43/261Separate steps of (1) cementing, plugging or consolidating and (2) fracturing or attacking the formation

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Medicinal Preparation (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Materials For Medical Uses (AREA)
  • Peptides Or Proteins (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

Methods and compositions for stimulating single and multiple intervals in subterranean wells by diverting well treatment fluids into a particular direction or into multiple intervals using water soluble coated diverting agents are described. The water soluble coating of the diverting material is preferably a collagen, poly(alkylene) oxide, poly(lactic acid), polyvinylacetate, polyvinylalcohol, polyvinylacetate/polyvinylalcohol polymer or a mixture thereof applied as a coating on any number of proppants. The method allows for the diverting of the flow of fluids in a downhole formation during a well treatment, such as during a fracturing process. Following completion of a treatment such as a hydraulic stimulation, the soluble diverting agent can be dissolved and removed by the water component of the well production.

Claims (27)

1. A diverting material comprising:
a particulate substrate; and a water-soluble polymer coating, wherein the water-soluble polymer coating forms a substantial outer coating on the particulate substrate.
2. The diverting material of claim 1, wherein the particulate substrate is selected from the group consisting of natural materials, silica proppants, ceramic proppants, metallic proppants, synthetic organic proppants, and mixtures thereof.
3. The diverting material of claim 1, wherein the particulate substrate is a resin coated proppant.
4. The diverting material of claim 1, wherein the water-soluble polymer is collagen, poly(alkylene) oxide, poly(lactic acid), polyvinylacetate, polyvinylalcohol, polylactone, polyacrylate, latex, polyester, periodic chart elements of group I or II
(alkali metal or alkaline earth metal) silicate polymers or admixtures thereof.
5. The diverting material of claim 1, wherein the particulate substrate has a particle size of from about 3 mesh to about 200 mesh.
6. The diverting material of claim 4, wherein the collagen is Type I collagen, Type II
collagen, Type III collagen, Type IV collagen, or Type V collagen.
7. The diverting material of claim 4, wherein the water-soluble collagen is crosslinked with a cross-linking agent selected from the group consisting of aldehydes, carbodiimides, isocyanates, and acyl azides.
8. The diverting material of claim 1, further comprising a non-water-soluble polymer in combination with the water-soluble polymer coating.
9. The diverting material of claim 8, wherein the non water-soluble polymer is phenol-aldehyde novolac polymers and phenol-aldehyde resole polymers.
10. The diverting material of claim 1, wherein the water-soluble polymer is poly(alkylene) oxide, poly(lactic acid), polyvinylacetate, polyvinylalcohol, polyvinylacetate/polyvinylalcohol graft polymers or admixtures thereof.
11. The diverting material of claim 10, wherein the poly(alkylene) oxide is poly(ethylene) oxide, poly(propylene) oxide, poly (ethylene oxide)-poly (propylene oxide) block copolymers, or mixtures thereof.
12. A diverting fluid for diverting oil well treating liquids to progressively less permeable portions of a subterranean formation, said fluid comprising:
an aqueous carrier liquid having dispersed therein particulate diverting material of any one of claims 1-11.
13. The diverting fluid of claim 12, wlierein the particulate diverting material comprises varying densities greater or less than the density of the carrier fluid.
14. The diverting fluid of claim 12, wherein the diverting material is present in the carrier liquid in an amount from about 0.001 pounds per gallon to about 10 pounds per gallon of the carrier liquid.
15. The diverting fluid of claim 12, wherein the carrier liquid is water, brine, aqueous acid solutions, or gelled acid solutions.
16. A method of treating a subterranean formation during fracturing treatment so as to increase the stimulation of the subterranean formation, the method comprising:
pumping into the subterranean formation a diverting fluid of any one of claims 12-15 ;
allowing the carrier liquid to permeate into the formation so as to carry the diverting material into the subterranean formation; and allowing the diverting material to plug porous portions of the formations thereby diverting flow of treating fluid to less permeable portions of the formation.
17. The method of claim 16, wherein the formation has a temperature from about 75 °F to about 400 °F.
18. The method of claim 16, wherein the treating of the subterranean formation is a fracturing treatment, and wherein the stimulation increased is the length of the fractures.
19. A method treating a cased wellbore to divert flow of fluids from one zone to another, the method comprising:
pumping into said wellbore a diverting fluid comprising an aqueous carrier liquid having dispersed therein a particulate form of a water soluble polymer, wherein the particulate polymer has a density greater than or less than the density of the carrier liquid;
allowing the particulate polymer to divert flow of a treating fluid from one zone to another.
20. The method of claim 19, wherein the treating fluid is diverted to flow into a zone of higher pore pressure or lower permeability.
21. The method of claim 19, wherein the wellbore has a temperature from about 75 °F to about 400 °F.
22. The method of claim 19, wherein the water-soluble polymer is collagen, poly(alkylene) oxide, poly(lactic acid), polyvinylacetate, polyvinylalcohol, polylactone, polyacrylate, latex, polyester, polyvinylacetate/polyvinylalcohol graft polymer, periodic chart elements of group I or II (alkali metal or alkaline earth metal) silicate polymer, or mixtures thereof.
23. The method of claim 19, wherein the particulate polymer has a particle size of from about 3 mesh to about 70 mesh.
24. The method of claim 22, wherein the poly(alkylene) oxide is poly(ethylene) oxide, poly(propylene) oxide, poly (ethylene oxide)-poly (propylene oxide) block copolymers, or mixtures thereof.
25. The method of claim 19, wherein the particulate polymer is comprised of varying densities greater or less than the density of the carrier fluid.
26. The method of claim 19, wherein the particulate polymer is present in the carrier liquid in an amount from about 0.001 pounds per gallon to about 10 pounds per gallon of the carrier liquid.
27. The method of claim 19, wherein the carrier liquid is water, brine, aqueous acid solutions, or gelled acid solutions.
CA2595686A 2005-01-21 2006-01-20 Soluble diverting agents Active CA2595686C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US64623105P 2005-01-21 2005-01-21
US60/646,231 2005-01-21
PCT/US2006/001916 WO2006088603A1 (en) 2005-01-21 2006-01-20 Soluble diverting agents

Publications (2)

Publication Number Publication Date
CA2595686A1 true CA2595686A1 (en) 2006-08-24
CA2595686C CA2595686C (en) 2012-09-18

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Family Applications (1)

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CA2595686A Active CA2595686C (en) 2005-01-21 2006-01-20 Soluble diverting agents

Country Status (8)

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US (1) US20060175059A1 (en)
CN (1) CN101146888B (en)
CA (1) CA2595686C (en)
GB (1) GB2437869B (en)
MX (1) MX2007008850A (en)
NO (1) NO20074239L (en)
RU (1) RU2433157C2 (en)
WO (1) WO2006088603A1 (en)

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