CA2544382A1 - Dual phase steel strip suitable for galvanizing - Google Patents

Dual phase steel strip suitable for galvanizing Download PDF

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Publication number
CA2544382A1
CA2544382A1 CA002544382A CA2544382A CA2544382A1 CA 2544382 A1 CA2544382 A1 CA 2544382A1 CA 002544382 A CA002544382 A CA 002544382A CA 2544382 A CA2544382 A CA 2544382A CA 2544382 A1 CA2544382 A1 CA 2544382A1
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Canada
Prior art keywords
strip
temperature
max
cooling
steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002544382A
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French (fr)
Other versions
CA2544382C (en
Inventor
David P. Hoydick
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UEC Technologies LLC
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Individual
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Filing date
Publication date
Priority claimed from PCT/US2003/035095 external-priority patent/WO2004048634A1/en
Application filed by Individual filed Critical Individual
Publication of CA2544382A1 publication Critical patent/CA2544382A1/en
Application granted granted Critical
Publication of CA2544382C publication Critical patent/CA2544382C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/185Hardening; Quenching with or without subsequent tempering from an intercritical temperature
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C23C2/0224Two or more thermal pretreatments
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26After-treatment
    • C23C2/28Thermal after-treatment, e.g. treatment in oil bath
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26After-treatment
    • C23C2/28Thermal after-treatment, e.g. treatment in oil bath
    • C23C2/29Cooling or quenching
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0278Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Coating With Molten Metal (AREA)

Abstract

Dual phase steel sheet is made using a time/temperature cycle including a soak at about AC1+45~F to AC1+135~F and a hold at 850-940F, where the steel has the composition in weight percent, carbon: 0.02-0.20; aluminum: 0.010-0.150;
titanium: 0.01 max; silicon: 0.5 max; phosphorous: 0.060 max; sulfur: 0.030 max; manganese: 0.8-2.40; chromium: 0.03-1.50; molybdenum: 0. 03 -1.50; with the provisos that the amounts of manganese, chromium and molybdenum have the relationship: (Mn + 6Cr + 10 Mo) = at least 3.5%. The sheet is preferably in the form of a strip suitable for coating in a continuous galvanizing or galvannealing line, and the product is predominantly ferrite and martensite.
The strip may be galvanized or galvannealed at a temperature within thirty degrees F of the temperature of the bath.

Claims (20)

1. Method of making an incipient dual phase steel sheet, wherein said steel sheet has the composition, in weight percent, carbon: 0.02-0.20; aluminum: 0.010-0.150; titanium: 0.01 max; silicon: 0.5 max; phosphorous: 0.060 max; sulfur:
0.030 max; manganese: 0.8-2.40; chromium: 0.03-1.50; molybdenum:0.03-1.50; with the provisos that the amounts of manganese, chromium and molybdenum have the relationship: (Mn + 6Cr + 10 Mo) = at least 3.5%, comprising soaking said steel sheet for 20 to 90 seconds at a temperature within the range of A c1+45°F, to A c1+135°F, cooling said steel sheet at a rate of at least 1°C per second to a temperature in the range 850-940°F, and holding said steel sheet in the range 850-940°F for 20 to 100 seconds.
2. Method of claim 1 wherein said steel sheet is a steel strip and said method is conducted continuously on a steel strip of at least 1000 feet.
3. Method of claim 1 including coating said steel sheet in a vessel of molten galvanizing metal at a temperature in the range 850-940°F before, during, or immediately after said holding.
4. Method of claim 3 wherein the temperature of said steel sheet during said coating is maintained within ~ 20°F of the molten metal temperature to minimize heat transfer between said steel strip and said molten metal.
5. Method of claim 1 followed by cooling said steel sheet to ambient temperature at a rate of at least 5°C per second, and wherein said dual phase is manifested thereafter in a microstructure predominantly of ferrite and martensite.
6. Method of claim 1 including galvannealing said steel sheet and cooling the steel sheet coated thereby at a rate of at least 5°C per second, and wherein said dual phase is manifested thereafter in a microstructure predominantly of ferrite and martensite.
7. Method of claim 1 wherein the carbon content of said steel is 0.03-0.12%.
8. Method of substantially continuously galvanizing steel strip in a galvanizing line including a galvanizing bath, comprising feeding a coil of steel strip having the composition, in weight percent, carbon: 0.02-0.20; aluminum:
0.010-0.150; titanium: 0.01 max; silicon: 0.5 max; phosphorous: 0.060 max;
sulfur: 0.030 max; manganese: 0.8-2.40; chromium: 0.03-1.50;
molybdenum:0.03-1.50; With the provisos that the amounts of manganese, chromium and molybdenum have the relationship (M.n + 6Cr + 10 Mo) at least 3.5%, to a heating zone in said galvanizing line, passing said strip through a heating zone continuously to heat said strip to 1340-1425°F, passing said strip through a soaking zone to maintain said strip within the range of 1340-1425°F
for a period of 20 to 90 seconds, passing said strip through a cooling zone to cool said strip at a rate greater than 1°C per second, discontinuing cooling said strip when the temperature of said strip has been reduced to a temperature ~
30 degrees F of the temperature of said galvanizing bath, holding said strip at a temperature between 850-940°F and within 30 degrees F of the temperature of said galvanizing bath for a period of 20 to 100 seconds, passing said strip through said galvanizing bath, and cooling said strip to ambient temperature.
9. Method of claim 8 wherein the residence time of said strip in said galvanizing bath is 3-6 seconds.
10. Method of claim 8 wherein said cooling in said cooling zone is conducted at 5 to 40 degrees F per second.
11. Method of claim 8 wherein said strip enters said galvanizing bath at a temperature within 20 degrees F of the temperature of said galvanizing bath.
12. Method of claim 8 wherein said strip is passed into said galvanizing bath immediately on discontinuing said cooling.
13. Method of claim 8 wherein said strip is passed into said galvanizing bath near the end of said period of 20 to 100 seconds.
14. Method of claim 8 whereby the galvanized steel strip so made has a predominantly ferrite-martensite microstructure containing less than 5% other morphological constituents.
15. Method of claim 8 wherein the carbon content of said steel strip is 0.03-0.12 weight percent.
16. Method of claim 8 wherein said steel strip is galvannealed prior to cooling to ambient temperature.
17. Method of making a galvanized steel strip having a predominantly martensite and ferrite microstructure, wherein said steel has the ingredients, in weight percent, carbon: 0.02-0.20; aluminum: 0.010-0.150; titanium: 0.01 max;
silicon: 0.5 max; phosphorous: 0.060 max; sulfur: 0.030 max; manganese: 0.8-2.40; chromium: 0.03-1.50; molybdenum:0.03-1.50, comprising soaking said steel strip at A cl+45°F, to A cl+135°F, for at least 20 seconds, cooling said strip at a rate of at least 1°C per second, passing said strip through a galvanizing vessel for a residence time therein of 2-9 seconds to coat said strip at any time while holding said strip at 895°F ~45°F for 20 to 100 seconds, and cooling the strip so coated to ambient temperature.
18. Method of claim 17 including galvannealing said strip prior to cooling to ambient temperature.
19. Method of claim 17 wherein said strip is within 30°F of the temperature of the galvanizing vessel during said residence time therein.
20. Method of claim 17 wherein said strip is within 20°F of the temperature of the galvanizing vessel during said residence time therein.
CA2544382A 2003-11-04 2004-05-17 Dual phase steel strip suitable for galvanizing Expired - Fee Related CA2544382C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
USPCT/US2003/035095 2003-11-04
PCT/US2003/035095 WO2004048634A1 (en) 2002-11-26 2003-11-04 Method for the production of dual phase sheet steel
PCT/US2004/015675 WO2005047550A1 (en) 2003-11-04 2004-05-17 Dual phase steel strip suitable for galvanizing

Publications (2)

Publication Number Publication Date
CA2544382A1 true CA2544382A1 (en) 2005-05-26
CA2544382C CA2544382C (en) 2010-04-06

Family

ID=34589294

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2544382A Expired - Fee Related CA2544382C (en) 2003-11-04 2004-05-17 Dual phase steel strip suitable for galvanizing

Country Status (6)

Country Link
EP (1) EP1682686B1 (en)
AU (1) AU2004289949B2 (en)
CA (1) CA2544382C (en)
ES (1) ES2530066T3 (en)
PL (2) PL210446B3 (en)
WO (1) WO2005047550A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5223360B2 (en) * 2007-03-22 2013-06-26 Jfeスチール株式会社 High-strength hot-dip galvanized steel sheet with excellent formability and method for producing the same

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4473414A (en) * 1980-03-31 1984-09-25 Kawasaki Steel Corporation High tensile strength cold rolled steel sheets and high tensile strength hot-dip galvanized steel sheets
KR100441413B1 (en) * 1999-02-22 2004-07-27 신닛뽄세이테쯔 카부시키카이샤 High strength galvanized steel plate excellent in adhesion of plated metal and formability in press working and high strength alloy galvanized steel plate and method for production thereof
US6312536B1 (en) * 1999-05-28 2001-11-06 Kabushiki Kaisha Kobe Seiko Sho Hot-dip galvanized steel sheet and production thereof
DE60116765T2 (en) * 2000-01-24 2006-11-02 Jfe Steel Corp. FIREPLATED STEEL PLATE AND METHOD OF MANUFACTURING THEREOF
WO2002044434A1 (en) * 2000-11-28 2002-06-06 Kawasaki Steel Corporation Composite structure type high tensile strength steel plate, plated plate of composite structure type high tensile strength steel and method for their production
CN1169991C (en) * 2001-10-19 2004-10-06 住友金属工业株式会社 Thin steel plate with good machining performance and formed precision and its mfg. method
US6811624B2 (en) * 2002-11-26 2004-11-02 United States Steel Corporation Method for production of dual phase sheet steel

Also Published As

Publication number Publication date
PL1682686T3 (en) 2015-04-30
EP1682686A1 (en) 2006-07-26
AU2004289949A1 (en) 2005-05-26
CA2544382C (en) 2010-04-06
PL379761A1 (en) 2006-11-13
EP1682686A4 (en) 2007-06-27
AU2004289949B2 (en) 2011-04-28
PL210446B3 (en) 2012-01-31
EP1682686B1 (en) 2014-11-12
ES2530066T3 (en) 2015-02-26
WO2005047550A1 (en) 2005-05-26

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