CA2347456C - Desalination process/equipment ii - Google Patents

Desalination process/equipment ii Download PDF

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Publication number
CA2347456C
CA2347456C CA2347456A CA2347456A CA2347456C CA 2347456 C CA2347456 C CA 2347456C CA 2347456 A CA2347456 A CA 2347456A CA 2347456 A CA2347456 A CA 2347456A CA 2347456 C CA2347456 C CA 2347456C
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water
hydrophilic
heat
cotton
container
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CA2347456A
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French (fr)
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CA2347456A1 (en
Inventor
Asha Suppiah
Kamalamma Suppiah
Sellathurai Suppiah
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0078Condensation of vapours; Recovering volatile solvents by condensation characterised by auxiliary systems or arrangements
    • B01D5/0084Feeding or collecting the cooling medium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/10Vacuum distillation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/14Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/138Water desalination using renewable energy
    • Y02A20/142Solar thermal; Photovoltaics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

A desalination container is enclosed to contain water vapour. Salt water is provided to a hydrophilic, evaporating support surface, preferably of woven cotton or fine wire mesh, placed to receive heat from the heat source, preferably solar energy, and release water vapour. Water vapour condenses on a cooled condensation surface located within the container. Fresh water is collected from the condensing surface as it condenses. The hydrophilic support surface may be in the form of a planar, stationary sheet, the face of a rotating disc, or the surface of a rotating cylinder.

Description

TITLE: DESALINATION PROCESS/EQUIPMENT II
FIELD OF THE INVENTION
This invention relates to the desalination of salt water. More particularly it provides an apparatus and method for producing fresh water from salt water using solar radiation.
BACKGROUND TO THE INVENTION
In many parts of the world there is an extreme shortage of drinking water. Fresh water which can be used by man is only a minute fraction of the total amount of water present as sea water. It is becoming important to find inexpensive ways to provide fresh water for drinking and agriculture for the increasing population of the world.
Nearly 65% of the population of the world live within 60 km radius from an ocean. Many countries that experience a shortage of drinking water have an abundant amount of sunshine which could be converted to heat.
Currently about two-thirds of the world's sea water desalination is done by distillation. Reverse osmosis technology ("RO") is becoming more popular because it is currently more economical than distillation. Worldwide, there are 10,000 sea water desalination plants, producing about 20 Mm3/d of fresh water. Recently, more efficient and cheaper membranes have become available to allow treatment of sea water which has high salt content (3.5 to 4.6 wt%). Mechanical vapour compression (MVC) is another method becoming popular.
In these processes one of the major costs is in the use of high pressure pumps to achieve the high pressure (-6 MPa) necessary to overcome the osmotic pressure of sea water. This drives about 50% of the water through the membrane as permeate, leaving a waste brine stream that is sent back to the sea. Better economies are achieved by recovering some of the pressure energy from the waste brine.
The total dissolved solid (TDS) content of water from RO is around 300 mg/L.
Though this meets drinking water standards, it often does not suffice for industrial use. Further treatment may be necessary. The osmotic pressure is dependent on temperature and the salt content and this will affect the RO
operation.
In some situations, multistage flash (NSF) evaporation method may be better suited. In this method the pressure of the water is suddenly reduced below its equilibrium vapor pressure causing "explosive" boiling. This pressure reduction is achieved by introducing the sea water into a chamber through an orifice.
An external heat source is used.
In yet another method of multi-effect distillation (MED), preheated sea water is sprayed onto the heat transfer area of a single-effect evaporator and the resulting vapour is transferred to the second and further stages by operating at progressively lower temperatures. Generally, power requirements are higher for distillation methods than for RO.
RO, MVC, thermocompression, MET) and NSF require about 22, 38, 8, 8 and 16 kWh/1000 US gal, respectively. NSF, MED and thermocompression also require steam 11b/7-12 lb of water. Improvements are made to lower steam usage through serrated-profile tubes in the evaporator.
Use of solar energy for water distillation is well known, particularly in arid, coastal regions. In simple terms, sea water is evaporated by solar energy and then condensed to provide the fresh water. Since solar energy is free, the cost of the desalination process mainly depends on the cost of the materials used for construction of the desalinator. Since salt water is extremely corrosive, the right choice of materials is very important.
Techniques of increasing the rate of evaporation by increasing the surface area of evaporation are well known and many inventions, such as U. S . Patents 6,001,222; 2,213,894 and 3,801,474 exploit this idea.
The current invention provides a simple method that is extremely low energy consuming and that does not require specialized materials or high capital investments. When properly designed, it would produce very little waste and it would require little maintenance.
The invention in its general form will first be described, and then its implementation in terms of specific embodiments will be detailed with reference to the drawings following hereafter. These embodiments are intended to demonstrate the principle of the invention, and the manner of its implementation. The invention in its broadest and more specific forms will then be further described, and defined, in each of the individual claims which conclude this Specification.
SUMMARY OF THE INVENTION
In one aspect of the present invention, there is provided a desalination system comprising: (1) a vapour-containing desalinator container with a heat receiving surface for receiving heat from an exterior source and delivering heat into the interior of the container; (2) a saltwater source for the supply of saltwater; (3) an evaporator surface comprising a displaceable hydrophilic water support, positioned to convey a thin film of salt water from the supply of salt water to the interior of the container whereby the salt water will receive heat from the heat receiving surface within the desalination container and to thereupon emit water vapour; (4) a condensing surface positioned within the container, proximate the evaporator surface, to receive the water vapour .and upon which the water vapour may condense and produce fresh water; and (5) fresh water collection means to collect fresh water condensing on the condensing surface, wherein water vapour emitted from the hydrophilic water support by exposure to the heat within the container passes to the condensing surface to be condensed into freshwater.
According to the present invention, in one aspect an evaporator surface is provided for the water portion of salt water to evaporate when heated with solar energy or any other form of heat. A
cooler, condensing surface is provided proximately to the evaporator surface for the vapour to condense and produce fresh water. Preferably, the vapour passes to the condensing surface primarily by diffusion. In order for the water to be evaporated more readily it is spread thinly over the evaporator surface and simultaneously heated. This encourages the water component to evaporate readily, provided that the vapour pressure in the 3a cp, 02347456 2001-05-11 evaporating environment can be maintained below the equilibrium value at the temperature of the water present therein.
According to one variant of the invention the salt water is preferably carried by a hydrophilic fibrous support, such as cotton, in order for it to evaporate more readily. Woven cotton spreads water very well due to the wicking effect caused by the surface tension of water.
Though cotton can soak-up a large amount of water, it can also release it very easily when heated to relatively low temperatures in air whose relative humidity is less than 100% at these temperatures. In our daily lives we do this when we dry our clothes in an electric drier or in the sun.
When drying in the sun, it takes a short time when the humidity of the air is low and a longer time when the humidity is high.
Although cotton is a preferred support for evaporating water, any hydrophilic fiber or surface may be employed, such a sisal, hemp, fine wire mesh and other similar materials.
According to a further variant of the invention, a layer of cotton, preferably woven, is positioned inside a flat plate-type solar heat collector presented at a suitable angle to capture solar energy. The vapour produced by the heat absorbed is then condensed on an adjacent cooler surface and collected as fresh water.
Salt water may be dripped into a woven cotton evaporator layer while the cotton is held taut within the interior of a desalinator container and heat is applied through the collector surface to the cotton layer. It is preferable to hold the cotton taut to minimize local accumulation of water and avoid dripping.
Water vapour is produced due to heat that is provided. At the same time water is condensed on a cooler condensing surface located adjacent to the hydrophilic cotton evaporator surface, across a gap within the desalinator container. The evaporator support, eg. cotton, may or may not touch the heat collection surface, so long as it is exposed to heat.
, ak 02347456 2001-05-11 The solar collector side of the desalinator may be made according to the current knowledge on solar energy collectors including the use of a simple glass plate. A stainless steel sheet may be alternately employed as the heat collection surface, with the evaporator layer preferably placed in intimate contact with such surface.
An advantage of using a hydrophilic fiber such as cotton for the evaporator is that the temperature rise in the desalinator container will be limited by the absorption of heat through vaporization of water. This will reduce the cooling load that must be accommodated by the collection surface.
There are various methods available to increase the capture of energy through the use of black bodies, including cotton dyed black and the use of a glass painted black. The angle of the energy capture surface and with it the cotton layer can be easily adjusted from vertical to almost horizontal to maximize the capture of the heat energy.
At controlled flow rates of water through the evaporator layer, cotton of a density suitable for desalination, will hold the salt water sufficiently well so that no dripping from the cotton onto the condensing side of the desalinator occurs even when the heat capture side is almost horizontal.
The vapour condensing surface can be cooled by one of many means available. Cold salt water may be made to flow over external portion of the condensing surface via a cotton layer placed on the outside of the desalinator container. In this case the cotton is used advantageously to do even more for the desalinator. The layer of cotton placed on the external side of the condensing surface of the desalinator can carry a significant amount of water to effectively cool the surface for vapour condensation to occur on the inside surface.
Alternately, a jacket may be provided on the external side for cooling water to flow directly against the cooled wall of the desalinator on the ak 02347456 2001-05-11 opposite side to the condensing surface. As a further alternative a water pump may used to spray cooling water on the cooled wall surface.
Hence, a large number of choices is available for cooling the condensing side of the desalinator.
The condensing surface may be made of a number of materials that can be cooled easily including glass or stainless steel. Since the condensed water that comes in contact with the cooling surface is fresh water free of salt, problems related to corrosion are reduced on this side of the desalinator. If the external cooling is not carried out with salt water then a large choice of materials such as aluminum and plain steel is available for construction of this surface.
Even without external cooling, the condensing surface will be cooler since heat is applied to the evaporator cotton even if some of that heat is absorbed by the water evaporating from it.
Therefore, in some cases active external cooling may not have to be provided at all for the vapour to condense.
The escape of vapour from the desalinator container's interior should be minimized by at least closing its upper end, and preferably by closing the lower end as well. The objective is to contain convective air flow. Thus the narrow ends of the desalinator are preferably covered to avoid water vapour escaping the desalinator. These covers may be made of a suitable material such as wood, plastic or metal.
The fresh water produced from the condensing vapour can be removed by a number of methods that make sure that a minimum amount of vapour within the desalinator is allowed to escape.
Condensing water may be allowed to drip from the desalinator container through a narrow slot. The condensing water may also be removed from the desalinator using a short length of cotton fabric wedged between the condensing surface and the cover plate to serve as a wick. The bottom edge of this cotton layer may then be cut to form one or more V-notches so that the condensed water ¨ ¨

cp, 02347456 2001-05-11 rolling down the cotton will drip from the V-notches in an uniform, directed fashion into collection containers. Within the desalinator, this wicking layer of cotton need only extend a few millimetres into the interior of the desalinator container so that the area of the available cooling surface is not reduced.
The flow of sea water through the desalinator may be controlled depending on the type of operation desired.
For example, the flow may be sufficiently small such that no brine exits the bottom of the desalinator. In this case, the water is completely evaporated leaving salt to accumulate on the evaporator surface. On the other hand, a very small flow of water may be allowed to exit the evaporator in which case all the cotton inside the evaporator remains wet at the temperature of evaporation. In any case, the flow of water through the evaporator is preferably kept low so that the water is evaporated efficiently without wasting the injected heat through the exiting of heated water from the desalinator.
Periodically the cotton will have to be removed from the desalinator and the accumulated salt removed by washing the cotton with sea water, or by simply shaking it to let the salt fall off the cotton.
In this invention the fresh water production rate depends on the rate of flow of water through the evaporator cotton and the rate of heat capture through the heat collector surface.
As mentioned above, wastage of heat can be avoided if excess water is not flowed through the evaporator cotton. Excess water flowing this way will carry the heat out of the desalinator rendering the efficiency lower than achievable.
As a further variant of the invention, the woven evaporator cotton may be in the form of a circulating band that passes adjacent to the heat collecting surface. Similarly the condensing surface may be cooled by a circulating band of moist ak 02347456 2001-05-11 cotton fabric. Preferably the rotations of these two bands are in opposite directions.
As another variant, the evaporating cotton may be fixed to a rotating wheel that carries moisture up from a reservoir and passes it closely to the heat collecting surface.
A similar cooling wheel of cotton may optionally be used to carry cooling water up to the external side of the condensing surface.
A further variant of the desalinator consists of a chamber with a sloping side to receive the sun energy, a horizontal surface to hold the salt water, and a cooler, nearly vertical side to condense the water vapour. In its simplest form, the salt water carried on the bottom floor of the desalinator in a shallow pond inside the desalinator is heated by the sun rays.
A glass or any other suitable plastic material that would allow the sun's rays to pass through with minimal absorption and reflection is used on the sloping, solar energy capture side.
The condensation surface may be vertical or sloped and cooled by water or air either internally or on its exterior surface. The salt water (e.g. sea water) being fed to the pond may also be used to cool the condensation side by first passing it through a cooling tank formed on the outside of the condensation surface.
In this way the heat of condensation can also be recovered, rendering the process more efficient.
A continuous stream of sea water may flow through the desalinator instead of a batch type operation.
The condensed water rolling down the cooler surfaces may be collected by a number of methods known in the art.
For example, troughs may be positioned to run along the base of the condensing walls to collect the condensing water and then carry water outside into fresh water collection containers.
Alternately, wicks may be placed with one end inside, at the base of the condensing surface, and the other end placed outside the desalinator to deliver the condensing water to a receiving container To promote the evaporation of water from the salt water pond suitable hydrophilic, wettable materials such as black cotton or a fine wire mesh may be placed on a form in the shape of a rotating cylinder positioned within the desalinator chamber.
This cylinder may be rotated by a simple low speed motor, optionally powered by solar energy. The rotating cylinder should be placed in such a way that the lower part of it is immersed in the sea water pond. As the cylinder is rotated, the cotton picks up the water from the pond and the sun rays, streaming through the glass, heats the water carried on the cylinder and evaporates it.
The water vapour then condenses on cooler surfaces within the desalinator and water droplets that roll down these surfaces are collected. The diameter and length of the cylinder should be as large as possible to occupy the volume of the desalinator so that the evaporation surface is maximized. The direction of rotation should be such that the water picked up from the pond is heated the best way possible.
This may mean that the direction of rotation will be clockwise.
The cylinder may be made by any convenient way. Thin strips of wood or a suitable metal (e.g. stainless steel) attached to circular end plates to form a frame may be used. The cotton can then be wrapped around this frame to complete the cylinder.
Another method is to form a cylinder using a metal screen with suitable end plates and use this as the frame around which the cotton is wrapped. Of course the end plates should be amenable to passing the shaft of the motor through.
The evaporation surface need not be limited to cotton.
Any suitable material on which water would form a film on may be used. For example, fine mesh screens (woven, expanded) or thin sheets of metal punched with holes are suitable. The materials should be selected so that they are compatible with salt water.
Examples of suitable screening are 10 to 400 mesh stainless screen, woven or expanded. The small openings present in these screens are ideal for water to be picked up as a thin film because of surface tension properties. Also, the screen may be corrugated so that the available surface area can be further increased quite significantly. The depth and pitch of the corrugations can be adjusted to alter the available area for evaporation.
The foregoing summarizes the principal features of the invention and some of its optional aspects. The invention maybe further understood by the description of the preferred embodiments, in conjunction with the drawings, which now follow.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 is a side view of the desalinator showing the stationery cotton layer used for evaporation and the condensing surface;
Figure 2 is a side view showing the desalinator with circulating wetted cotton used for both evaporation and for cooling; and Figure 3 is a side view showing desalination using a wheel of cotton for evaporation.
Figure 4 is a face view of Figure 3.
Figure 5 is a pictorial depiction of an alternate embodiment wherein condensation occurs outside of the desalinator container.
Figure 6 is a schematic pictorial depiction of a desalinator using a rotating cylinder as the evaporator.
DESCRIPTIONOFTHEPREFERREDEMBODIMENT
In the installation of Figure 1 a heat collector surface 1 is made of a glass plate or metal is provided to serve as a heat receiving surface. A cotton layer 2 is positioned adjacent the inner side of this heat collector surface 1 to serve as a hydrophilic salt water support The inside surface of the glass may be coated with black paint to increase absorption of the heat energy. Alternately, the cotton layer 2 may be dyed black. The cotton 2 is preferably in intimate contact with this heat collecting surface 1 so that the heat is transferred efficiently to the salt water 3 being introduced therein from a salt water source.
The evaporating water 4 (released by the sun's rays 42) in vapour state is condensed on the condensing surface 6 located on the other internal side of the desalinator container 5 to provide condensed fresh water 7. This condensing surface 6 can be maintained at a cooler temperature simply by circulating cool salt water 8 through a cotton-drenched cooling layer 9 placed against its exterior surface. If sea water is used for this cooling process, it may be necessary to use glass or stainless steel on this side so that rusting-related problems are avoided.
As a schematic demonstration, a receiving container 11 with three compartments 11 a, 1 1 b, and 11c is positioned to respectively catch the escaping brine 10, the condensed water 7, and the cooling water 8.
A significant amount of the heat is recovered from the condensing water vapour 4 developed within the desalinator. This recovered heat is present within the cooling water 8 present on the cooling layer 9 placed on the exterior side of the condensing surface 6. This partially heated water 8 can be diverted as feed water for the evaporator side of the desalinator, taking advantage of the heat of condensation that it has absorbed.
The invention outlined above using cotton overcomes number of deficiencies of the solar distillation apparatus markets as the Rosendahl system. In the Rosendahl system, sea water is evaporated by flowing it over a surface made of a special material ("soakage filler") and then condensed on the inside surface of the same glass plate-covering that lets the heat waves in. Since heat is received through this glass covering, the condensation process is made inefficient.
In the present invention the vapour 4 is condensed on a significantly cooler surface condensating surface 6 since it is on the other side of the desalination container from cotton-evaporator layer 2.
Allowing the vapour 4 to condense on the "non-heated"
side of the desalinator container 5 in the current invention is more efficient since the condensed water 7 is not heated unnecessarily by the heat entering through the heat collector surface 1.
According to the invention, the ability of the cotton 2 to spread the water 3 on its surface and hold a significant amount avoids the need for specialized materials for evaporation.
The fact that the water 3 can be held by cotton 2 without dripping enables the provision of a condensing surface 6 that is located below the evaporating surface.
Another method of desalination using the above idea is shown in Figure 2. In this apparatus an endless evaporator cotton band 20 is circulated through the desalinator container 5 and a salt water reservoir 21 so that the salt water 22 picked up in the reservoir 21 by the cotton band 20 is evaporated fully or substantially within the desalinator container 5. The use of cotton to transport the water 22 into the desalinator in this fashion renders it possible for the water 22 to be heated conveniently by solar energy compared to other known arrangements.
Here again, the current knowledge available to capture the sun energy can be used to its fullest capacity.
If the cotton is mostly dry as it exits the desalinator, provisions can be made to remove the salt residue on it by means of continuous vibration or scraping applied to the moving belt.
In this case, salt can be a by-product of the process.
A similar endless cotton band 23 may be used to cool the condensing surface.
Preferably this band 23 rotates in the opposite direction to band 20.
In case the heat collector is made of a material that is prone to corrosion, then the circulating cotton band 20 may be made to pass adjacent to the interior side of the heating surface 1 without coming into contact with the actual heat collector surface 1.
If it is required to squeeze excess water out of cotton band 20 to avoid dripping within the desalinator, wiper blades 24 made of rubber materials that are resistant to salt water may be positioned at the entrance to the desalinator container 5.
If a need arises to place a separating layer between the circulating, heated, evaporator cotton band 20 and the condensation side, Teflon coated screens (not shown) may be used.
Aluminum or stainless mesh screens may be coated with Teflon so that salt water 22 will not come in contact with the condensing surface 6. These screens placed between the evaporator cotton band 20 and the condensing surface 6 can be perforated so that the vapour 4 can flow freely through the screen without any resistance.
Since the only power requirement for this variant of the desalinator is that required to circulate the cotton belts 20,23, use of a low hp motor 25 with a minimal overall power requirement is possible.
For a given heat collector with a specific area and heat absorption characteristics, the rate of fresh water 7 production in this apparatus can be controlled by adjusting the evaporator cotton belt 20 recirculation rate. The rate of circulation of cotton belt 20 may be programmed within a controller 26 to be a function of the heat available for absorption which would depend on the time of the day (when solar energy is used for evaporation). In this manner, the temperature rise within the belt 20 can be adjusted to the maximum level possible.
The use of recirculating cotton 20 allows flexibility to produce very little waste brine 10 from the process since the rate of circulation can be adjusted to evaporate all most all the salt water 22 entering the desalinator container 5. The salt residue on the cotton belt 20 can be removed by a simple scraping or by vibration, or it can be redissolved in the sea water 22 in the pond or reservoir 21.
Another configuration for the desalinator is shown in Figure 3. This is similar to dehumidification wheels used for building humidity control. An evaporator wheel 30 carrying a layer of cotton, is almost half immersed in a sea water pond 31 rotates slowly, thereby picking up the water 32 from the pond and losing it in the top section where solar energy is used to evaporate the water 32. As the side view shows, the top half or so of the wheel 30 is contained within the desalinator chamber 5, adjacent a heat collecting surface 1 and adjacent a condensing surface 6. The condensing surface 6 can be cooled by one of many methods including another rotating cotton-covered cooling wheel 33 located in intimate contact with the external side of the condensation surface 6.
A pump (not shown) may alternately be used instead to simply spray the pond water over the external side of the condensing surface 6 to maintain a lower temperature.
The structure supporting the evaporator and cooling wheels 30, 33 may be made of plastic materials. Seals 34 between the rotating wheels 30,33 and the desalinator chamber 5 may be maintained with rubber wiper blade-type seals to provide maximum containment of water vapour 4.
In another configuration of the desalinator shown in Figure 5, multiple layers of cotton 40 may be used to evaporate the water in a common chamber 41 heated by solar energy 42 or other forms of heat. Sea water 43 can be gently sprayed on the layers of cotton 40 placed in the chamber 41 at suitable angles to capture the heat. The vapour 44 produced may be transferred continuously by applying a slight vacuum provided by a vacuum pump 45 into a separate cooling chamber 46 where it is condensed to form fresh water 47.
Example 1 A test was carried out using the set-up shown in Figure 1 with the evaporator cotton vertical and in contact with the heat collector surface.
A 250 w infra red heat lamp was used to simulate solar power. It was placed 50 mm away from the heat collection surface of the desalinator. Approximately 144 mL/h of water were dripped onto the top end of the evaporator cotton and allowed to flow down the cotton. Sufficient water was made to flow over the condensation side cooling cotton to maintain it in a moist state.
Salt-free condensed water soaked the small piece of cotton at the bottom on the fresh water condensation surface of the desalinator and dripped from it into a container within 15 min of starting the experiment.
In a 90 min long test, approximately 45 mL of fresh water was collected. The density of this fresh water was found to be 0.999 g/mL showing that there was no salt in the water. The material of the heat collection surface was stainless steel foil and the cotton layer was 100 mm wide by 300 mm long with a thickness of 0.3 mm. The gap between the cotton layer and the ak 02347456 2001-05-11 condensing surface was around 20mm. The salt water used for the test had a density of 1.033 g/mL which translates into 4.1% salt in water and the brine collected had a density of 1.083 g/mL which represents about 11.5% salt in water. The temperature of vapour within the desalinator was within the range of 40 to 50'C and this temperature was reached within 5 min of starting the experiment.
The exterior ambient temperature was 200C.
Based on theoretical assessments, it is believed that a heat collector surface of 150 mm by 300 mm dimensions exposed to a solar flux of 256 cal/s/m2 can produce 50 grams of water per hour as a maximum. The gap between the evaporator cotton layer and the condensing surface should be as short as possible. A gap of lOmm is believed to be practical if provision is made to minimize sagging of the cotton layer. In larger units a 20mm or even a 30-40mm gap may be suitable.
Figure 6 shows another form of the desalinator. In this arrangement a chamber 48, shown with panels cut out for a clear view of the inner components, includes a glass panel 49 through which solar energy will pass. This energy is absorbed by water present on the rotating hydrophilic screen 50 which is partially immersed in a salt water pond 51. As the warm screen 50 rotates by mean of the drive motor 52 evaporation takes place. The vapour condenses on the surface 6 of a tank of cool water 53 and is collected as fresh water 7 in the fresh water tank 54.
The attached Table presents some of the results obtained from an experimental rotating cylinder-type desalinator. A desalinator chamber, approximately 24 cm wide (glass side) by 30 cm long (side walls) by 30 cm high (condensation side), was assembled using wood pieces, thin aluminum sheets, Silicone sealant, 28-mesh stainless screen, a glass plate, a 12 V dc motor and photovoltaic cells.
A 250 W infrared heat lamp was used to simulate the sun. A wooden frame was first built and sheets of aluminum cut and folded in appropriate dimensions were placed inside the wooden frame to form the vessel shape as shown in Figure 6. The seams were sealed with Silicone sealant.
An 11-cm diameter cylinder was fabricated out of the 28-mesh stainless steel screen with aluminum end plates. A threaded rod was passed through the end plates and the screen was secured in place with bolts and nuts. The threaded rod was also passed through two holes on the opposite sidewalls of the desalinator chamber with one end connected to the motor to mount the shaft for rotation. The height of the shaft above the pond water was such that the lower part of the screen cylinder was immersed in the saltwater in the pond.
After placing a known volume of a salt solution (prepared from tap water and cooking salt) in the pond, the sheet of glass was secured on the desalinator making sure that a good vapour seal was formed between the glass plate and the desalinator vessel. The motor was switched on to rotate the screen cylinder, and the number of batteries employed was adjusted to control the speed of rotation.
Since this work was done inside the home during winter/spring months, batteries were used instead of the solar cells to power The motor.
The cooling water tank in the backside of the desalinator was filled with tap water. An infrared heat lamp was turned on after setting a timer for 5 hours. Temperatures at various locations within the desalinator were measured and recorded periodically. An immersed copper coil carrying cooling water was used to maintain the temperature of the water in the cooling water tank (at the back of the desalinator condensation surface) below 27 C.
The water from the saltwater pond evaporated and condensed on the inside walls of the desalinator. Condensation was heavy on the surface of the back wall, which was cooled by the cooling water in the tank. The condensing water rolled down the ak 02347456 2001-05-11 condensing surface walls and soaked cotton wicking strips that had been placed at the base of the condensing surface to drain the water out into a collection container.
After a period of 5 hours, the heat lamp and the motor were turned off and the amount of water collected was measured.
When the desalinator had cooled down to ambient temperature, any water present on the inside walls and the floor of the desalinator was syringed out and its volume measured. The total volumes and densities of the fresh 'water collected and the remaining saltwater inside the desalinator were measured and recorded.
The attached Table shows the performance, using various combinations of parameters, of a rotating cylinder desalinator.
This Table indicates that the presence of a rotating cylinder of black cotton or plain 28 mesh screen or corrugated 28 mesh screen increased the amount of water evaporated and recovered as fresh water quite significantly.
Based on the foregoing, an efficient, low cost system may be provided to produce fresh water from salt water.
CONCLUSION
The foregoing has constituted a description of specific embodiments showing how the invention may be applied and put into use. These embodiments are only exemplary. The invention in its broadest, and more specific aspects, is further described and defined in the claims which now follow.
These claims, and the language used therein, are to be understood in terms of the variants of the invention which have been described. They are not to be restricted to such variants, but are to be read as covering the full scope of the invention as is implicit within the invention and the disclosure that has been provided herein.

:
i i ITable : Results from desalinator experiments with and without screen rotators.
I Exp#18 Exp# 3 Exp#17 Exp#20 Exp#22 __________________________________________________ _A.
Screen (stainless screen) None 28 mesh 28 mesh corrugated 28 mesh corrugated Black Cotton , Speed of motor ______________ rpm 0 1.4 2.9 5 5 i --, Distance of lamp from glass cm 12.7 12.7 12.7 12.7 12.7 i , Test duration h 5 5 i IVolume of salt water started with mL 800 800 Volume of brine at the end of experiment -mL 648 616.8 556.8 = 502.2 573.4 _ Volume of fresh water collected mL 124.2 140.6 214.4 242.4 170.9 Density of salt water started with g/mL t034 1.00 1.033- 1.03 1.032 0 Density of fresh water collected Ig/mL 0.9991 0.9981 0.999 0.999.: 0 999 I
. Temperature of vapour within desalinator 1 88 ' 821 81 0iwv 0.
i Temperature of salt water in pond C 55 5-5.
52 53 co .4 0.
Temperature of screen surface C - -0, µ Temperature of water in the cooling tank C
25 to 29 18-20 _____ 25 to 29 25 24, _ i , 1-.
i , !

i I

I

Claims (19)

1. A desalination system comprising:
(1) a vapour-containing desalinator container with a heat receiving surface for receiving heat from an exterior source and delivering heat into the interior of the container, (2) a saltwater source for the supply of saltwater (3) an evaporator surface comprising a displaceable hydrophilic water support, positioned to convey a thin film of salt water from the supply of salt water to the interior of the container whereby the salt water will receive heat from the heat receiving surface within the desalination container and to thereupon emit water vapour;
(4) a condensing surface positioned within the container, proximate the evaporator surface, to receive the water vapour and upon which the water vapour may condense and produce fresh water; and (5) fresh water collection means to collect fresh water condensing on the condensing surface.
wherein water vapour emitted from the hydrophilic water support by exposure to the heat within the container passes to the condensing surface to be condensed into freshwater.
2. A system as in claim I wherein the hydrophilic water support is carried on a rotating cylinder which is partially immersed in the salt water source and carries saltwater to be exposed to receive heat from the heat receiving surface within the desalination container.
3. A system as claimed in claim 2 wherein the evaporator surface comprises a corrugated wire mesh to provide an increased surface area for evaporation.
4. A system as in claim 1 wherein the hydrophilic water support is carried by a circulating band that is partially immersed in the salt water source and carries saltwater to be exposed to receive heat from the heat receiving surface within the desalination container.
5. A system as in claim 1 wherein the hydrophilic water support is carried by a rotating wheel that is partially immersed in the salt water source and carries saltwater to be exposed to receive heat from the heat receiving surface within the desalination container.
6. A system as in any one of claims 1 to 5, wherein the hydrophilic water support comprises cotton.
7. A system as in any one of claims 1 to 6, wherein the hydrophilic water support comprises woven cotton.
8. A system as in any one of claims 1 to 7, wherein the heat receiving surface is coated to absorb solar energy.
9. A system as in any one of claims 1 to 8, comprising cooling means to cool the condensing surface.
10. A system as claimed in claim 9 wherein the cooling means comprises: a jacket provided on the side of the condensing surface opposite to the hydrophilic water support;
and a source of cooling water whereby the vapour condensing surface may be cooled by water directed to flow over external portions of the condensing surface.
11. A system as in any one of claims 9 or 10 wherein the cooling means comprises a hydrophilic cooling layer placed on the side of the condensing surface opposite to the hydrophilic water support to contain cooling water.
12. A system as claimed in any one of claims 9, 10 or 11, wherein the cooling means comprises a water pump positioned to spray cooling water on the side of the condensing surface opposite to the hydrophilic water support.
13. A system as in any one of claims 9, 10 or 11 wherein the cooling means comprises a circulating band of hydrophilic cooling water support material that carries cooling water to the side of the condensing surface opposite to the hydrophilic water support.
14. A system as in any one of claims 11 or 12 wherein the hydrophilic cooling layer comprises cotton.
15. The system as in claim 13 wherein the circulating band of hydrophilic cooling water support material comprises cotton.
16. A system as in any one of claims 9, 10 or 11 wherein the cooling means comprises a rotating wheel for carrying cooling water that is partially immersed in a water source and carries water to the side of the condensing surface opposite to the hydrophilic water support.
17. A desalination system as in any one of claims 1 to 16, wherein the heat receiving surface is positioned and exposed to receive solar radiation.
18. A system as in any one of claims 1 to 7 wherein the heat receiving surface is transparent to pass solar energy to the hydrophilic water support.
19. A system as in claim 18 wherein the hydrophilic water support is darkened to absorb solar energy.
CA2347456A 2000-05-12 2001-05-11 Desalination process/equipment ii Expired - Lifetime CA2347456C (en)

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FR3037254A1 (en) * 2015-06-15 2016-12-16 Cyril Marc Michel Grandpierre SOLAR DISTILLATOR WITH ENDLESS CARPET
CN105600854B (en) * 2016-03-08 2016-12-14 山东大学(威海) A kind of seawater desalination system that loop circuit heat pipe is set
CN111278524B (en) * 2017-10-24 2022-08-02 阿卜杜拉国王科技大学 Method and device for water evaporation
CN108285186A (en) * 2018-01-24 2018-07-17 中山大学 A kind of solar energy sea water desalination apparatus
US20210047203A1 (en) * 2018-03-06 2021-02-18 King Abdullah University Of Science And Technology Method and device for continuous salt extraction from brine
CN114644377A (en) * 2022-02-24 2022-06-21 上海交大平湖智能光电研究院 Photovoltaic power generation sea water desalination combined system

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