CA2220660C - Procede de preparation d'huiles lubrifiantes - Google Patents
Procede de preparation d'huiles lubrifiantes Download PDFInfo
- Publication number
- CA2220660C CA2220660C CA002220660A CA2220660A CA2220660C CA 2220660 C CA2220660 C CA 2220660C CA 002220660 A CA002220660 A CA 002220660A CA 2220660 A CA2220660 A CA 2220660A CA 2220660 C CA2220660 C CA 2220660C
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- CA
- Canada
- Prior art keywords
- chemical
- sample
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- data
- properties
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 61
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 28
- 239000000126 substance Substances 0.000 claims abstract description 40
- 239000011159 matrix material Substances 0.000 claims abstract description 29
- 238000012549 training Methods 0.000 claims abstract description 26
- 238000004821 distillation Methods 0.000 claims abstract description 17
- 238000001311 chemical methods and process Methods 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 230000000704 physical effect Effects 0.000 claims abstract description 11
- 238000009835 boiling Methods 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims description 44
- 239000000523 sample Substances 0.000 claims description 38
- 230000014759 maintenance of location Effects 0.000 claims description 34
- 150000002500 ions Chemical class 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 25
- 239000013074 reference sample Substances 0.000 claims description 17
- 238000004458 analytical method Methods 0.000 claims description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- 229930195733 hydrocarbon Natural products 0.000 claims description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 13
- 239000012634 fragment Substances 0.000 claims description 12
- 238000000605 extraction Methods 0.000 claims description 10
- 239000000470 constituent Substances 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 6
- 238000012544 monitoring process Methods 0.000 claims description 3
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 abstract description 26
- 238000007670 refining Methods 0.000 abstract 1
- 238000005070 sampling Methods 0.000 description 18
- 230000003595 spectral effect Effects 0.000 description 17
- 239000003921 oil Substances 0.000 description 14
- 238000012628 principal component regression Methods 0.000 description 14
- 238000011282 treatment Methods 0.000 description 10
- 238000012937 correction Methods 0.000 description 9
- 238000010238 partial least squares regression Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000001819 mass spectrum Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 5
- 238000004817 gas chromatography Methods 0.000 description 5
- 238000012417 linear regression Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- 238000002098 selective ion monitoring Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 150000001555 benzenes Chemical class 0.000 description 3
- 238000002790 cross-validation Methods 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000012925 reference material Substances 0.000 description 3
- 238000000611 regression analysis Methods 0.000 description 3
- 239000013598 vector Substances 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 125000004062 acenaphthenyl group Chemical class C1(CC2=CC=CC3=CC=CC1=C23)* 0.000 description 2
- 150000001454 anthracenes Chemical class 0.000 description 2
- 210000001217 buttock Anatomy 0.000 description 2
- 150000001793 charged compounds Chemical class 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 150000002468 indanes Chemical class 0.000 description 2
- 150000002469 indenes Chemical class 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 150000002790 naphthalenes Chemical class 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 150000002987 phenanthrenes Chemical class 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 230000008521 reorganization Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- 101150011616 Ctcf gene Proteins 0.000 description 1
- 241000406799 Deto Species 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 101000941356 Nostoc ellipsosporum Cyanovirin-N Proteins 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- IOYNQIMAUDJVEI-BMVIKAAMSA-N Tepraloxydim Chemical compound C1C(=O)C(C(=N/OC\C=C\Cl)/CC)=C(O)CC1C1CCOCC1 IOYNQIMAUDJVEI-BMVIKAAMSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 238000003965 capillary gas chromatography Methods 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000000451 chemical ionisation Methods 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000001955 cumulated effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005264 electron capture Effects 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000013178 mathematical model Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 108700023468 protein-bound SN-C polysaccharide Proteins 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000004808 supercritical fluid chromatography Methods 0.000 description 1
- 238000004885 tandem mass spectrometry Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000017105 transposition Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2888—Lubricating oil characteristics, e.g. deterioration
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2829—Mixtures of fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
- G01N1/16—Devices for withdrawing samples in the liquid or fluent state with provision for intake at several levels
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
- G01N1/20—Devices for withdrawing samples in the liquid or fluent state for flowing or falling materials
- G01N1/2035—Devices for withdrawing samples in the liquid or fluent state for flowing or falling materials by deviating part of a fluid stream, e.g. by drawing-off or tapping
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Lubricants (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
Abstract
Cette invention concerne un procédé qui permet de gérer la fabrication d'huiles lubrifiantes, lequel comprend des étapes de distillation, d'extraction, de déparaffinage et éventuellement d'hydrofinissage, ou encore de gérer des unités opérationnelles associées au raffinage ou à des traitements chimiques de matières premières et de produits entrant en ébullition au-dessus de 350 DEG C. Ce procédé consiste à choisir une ou plusieurs propriétés chimiques, perceptuelles, physiques ou de performance d'une huile lubrifiante ou encore de matières premières, d'un distillat ou d'un raffinat qui sont utilisés durant le processus de fabrication, ou des matières premières ou produits du raffinage ou d'un traitement chimique. Un ensemble d'entraînement est ensuite créé à partir d'échantillons de référence qui contiennent des espèces moléculaires caractéristiques présentes dans l'huile lubrifiante, les matières premières, le distillat ou le raffinat utilisés durant le processus de fabrication ou issus d'opérations de raffinage ou de traitement chimique. Les échantillons de référence sont soumis à une analyse par chromatographie gazeuse/spectrométrie de masse (CG/SM), et les données souvent colinéaires ainsi obtenues sont traitées par des procédés de corrélation à variables multiples. L'ensemble d'entraînement fournit des coefficients qui sont multipliés par la matrice issue d'une analyse CG/SM d'un échantillon inconnu, afin de produire une valeur prévue de la propriété ou du groupe de propriétés chimiques, de performance, perceptuelles ou physiques choisies.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/494,643 | 1995-06-23 | ||
| US08/494,643 US5699270A (en) | 1995-06-23 | 1995-06-23 | Method for preparing lubrication oils (LAW232) |
| PCT/US1996/007174 WO1997000926A1 (fr) | 1995-06-23 | 1996-05-17 | Procede de preparation d'huiles lubrifiantes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2220660A1 CA2220660A1 (fr) | 1997-01-09 |
| CA2220660C true CA2220660C (fr) | 2007-04-03 |
Family
ID=37951719
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002220660A Expired - Lifetime CA2220660C (fr) | 1995-06-23 | 1996-05-17 | Procede de preparation d'huiles lubrifiantes |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA2220660C (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20240076563A1 (en) * | 2020-12-30 | 2024-03-07 | Chevron U.S.A. Inc. | Improved Process to Make Finished Base Oils and White Oils from Dewaxed Bulk Base Oils |
-
1996
- 1996-05-17 CA CA002220660A patent/CA2220660C/fr not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20240076563A1 (en) * | 2020-12-30 | 2024-03-07 | Chevron U.S.A. Inc. | Improved Process to Make Finished Base Oils and White Oils from Dewaxed Bulk Base Oils |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2220660A1 (fr) | 1997-01-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20160517 |