CA2210285C - Adhesif au polyurethanne a deux composants durcissant a l'humidite - Google Patents

Adhesif au polyurethanne a deux composants durcissant a l'humidite Download PDF

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Publication number
CA2210285C
CA2210285C CA002210285A CA2210285A CA2210285C CA 2210285 C CA2210285 C CA 2210285C CA 002210285 A CA002210285 A CA 002210285A CA 2210285 A CA2210285 A CA 2210285A CA 2210285 C CA2210285 C CA 2210285C
Authority
CA
Canada
Prior art keywords
weight
parts
isocyanate
adhesive
moieties
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002210285A
Other languages
English (en)
Other versions
CA2210285A1 (fr
Inventor
Shailesh S. Bhat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Essex Specialty Products LLC
Original Assignee
Essex Specialty Products LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Essex Specialty Products LLC filed Critical Essex Specialty Products LLC
Priority claimed from PCT/US1996/000371 external-priority patent/WO1996021688A1/fr
Publication of CA2210285A1 publication Critical patent/CA2210285A1/fr
Application granted granted Critical
Publication of CA2210285C publication Critical patent/CA2210285C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/3844—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing one nitrogen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/409—Dispersions of polymers of C08G in organic compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

L'invention porte sur un adhésif à deux composants comportant (A) une première partie d'un prépolymère de polyuréthane présentant un fragment réactif d'isocyanate, et (B) une deuxième partie d'un durcisseur formée de i) une polyurée comprenant le produit de réaction d'une polyamine et d'un polyisocyanate, dispersé dans un prépolymère de polyuréthanne à base polyétherpolyol présentant un fragment réactif hydroxyle et facultativement un plastifiant, ii) un composé présentant au moins un fragment d'oxazolidine susceptible de réagir avec un isocyanate dans des conditions de durcissement, et (iii) un catalyseur capable de catalyser la réaction des fragments isocyanate et hydroxyles en présence d'humidité. L'adhésif objet de cette invention donne un temps raisonnable de sortie de chaîne pour les verres qui viennent d'être posés dans une automobile. Ce temps est de préférence de 60 minutes ou mieux de 30 minutes après l'application de l'adhésif. Ledit adhésif offre également un temps d'ouvrabilité raisonnable de 10 à 12 minutes. De plus la contrainte de cisaillement de recouvrement après écoulement du temps de sortie de chaîne est de préférence de 1033 kPa, ou mieux encore, de 1723 kPa selon la norme ASTM D-3163.
CA002210285A 1995-01-13 1996-01-03 Adhesif au polyurethanne a deux composants durcissant a l'humidite Expired - Fee Related CA2210285C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US37314695A 1995-01-13 1995-01-13
US08/373,146 1995-01-13
PCT/US1996/000371 WO1996021688A1 (fr) 1995-01-13 1996-01-03 Adhesif au polyurethanne a deux composants durcissant a l'humidite

Publications (2)

Publication Number Publication Date
CA2210285A1 CA2210285A1 (fr) 1996-07-18
CA2210285C true CA2210285C (fr) 2006-10-24

Family

ID=37309469

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002210285A Expired - Fee Related CA2210285C (fr) 1995-01-13 1996-01-03 Adhesif au polyurethanne a deux composants durcissant a l'humidite

Country Status (1)

Country Link
CA (1) CA2210285C (fr)

Also Published As

Publication number Publication date
CA2210285A1 (fr) 1996-07-18

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Legal Events

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EEER Examination request
MKLA Lapsed

Effective date: 20150105