CA2203876A1 - Propylene-ethylene copolymer composition and process for producing the same - Google Patents
Propylene-ethylene copolymer composition and process for producing the sameInfo
- Publication number
- CA2203876A1 CA2203876A1 CA002203876A CA2203876A CA2203876A1 CA 2203876 A1 CA2203876 A1 CA 2203876A1 CA 002203876 A CA002203876 A CA 002203876A CA 2203876 A CA2203876 A CA 2203876A CA 2203876 A1 CA2203876 A1 CA 2203876A1
- Authority
- CA
- Canada
- Prior art keywords
- propylene
- weight
- ethylene
- copolymer composition
- ethylene copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005653 propylene-ethylene copolymer Polymers 0.000 title abstract 4
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- 229920001155 polypropylene Polymers 0.000 abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 239000013078 crystal Substances 0.000 abstract 2
- 239000000155 melt Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A propylene-ethylene copolymer composition is obtained which has a good moldability and is excellent in the balance of rigidity, toughness, and impact-strength.
A propylene-ethylene copolymer composition having a melt flow rate of 10 to 300 g/10 minutes and obtained by producing 60 to 95 % by weight, based on the weight of whole polymer, of a propylene polymer having a melt flow rate (ASTM
D-1238) in the range of 100 to 1,000 g/10 minutes and having a ratio (Cf) of integrated values of the propylene polymer dissolved in o-dichlorobenzene at a temperature of lower than 112°C, and a temperature of 112°C or higher, respectively, which is an index of the stereoregurality in molecules and molecular weight distribution, when the amounts of the propylene polymer dissolved therein at each of the temperatures were determined by raising the temperature of the o-dichlorobenzene continuously or stepwise, of 0.5 or less, by carrying out polymerization of propylene in the presence of a highly stereoregular catalyst and hydrogen in a polymerization step (I), and then producing 5 to 40 % by weight, based on the weight of whole polymer, of an ethylene-propylene copolymer by feeding ethylene and propylene to the propylene polymer produced in the polymerization step (I) to react so that the content of ethylene becomes 30 to 80 % by weight, in a polymerization step (II); and a propylene-ethylene copolymer composition comprising the composition mentioned above and .alpha.-crystal and/or .beta.-crystal nucleator added therewith.
A propylene-ethylene copolymer composition having a melt flow rate of 10 to 300 g/10 minutes and obtained by producing 60 to 95 % by weight, based on the weight of whole polymer, of a propylene polymer having a melt flow rate (ASTM
D-1238) in the range of 100 to 1,000 g/10 minutes and having a ratio (Cf) of integrated values of the propylene polymer dissolved in o-dichlorobenzene at a temperature of lower than 112°C, and a temperature of 112°C or higher, respectively, which is an index of the stereoregurality in molecules and molecular weight distribution, when the amounts of the propylene polymer dissolved therein at each of the temperatures were determined by raising the temperature of the o-dichlorobenzene continuously or stepwise, of 0.5 or less, by carrying out polymerization of propylene in the presence of a highly stereoregular catalyst and hydrogen in a polymerization step (I), and then producing 5 to 40 % by weight, based on the weight of whole polymer, of an ethylene-propylene copolymer by feeding ethylene and propylene to the propylene polymer produced in the polymerization step (I) to react so that the content of ethylene becomes 30 to 80 % by weight, in a polymerization step (II); and a propylene-ethylene copolymer composition comprising the composition mentioned above and .alpha.-crystal and/or .beta.-crystal nucleator added therewith.
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7/248775 | 1995-08-31 | ||
JP24877595 | 1995-08-31 | ||
JP11929896 | 1996-05-14 | ||
JP8/119298 | 1996-05-14 | ||
JP8/120011 | 1996-05-15 | ||
JP12001296 | 1996-05-15 | ||
JP8/120012 | 1996-05-15 | ||
JP12001196 | 1996-05-15 | ||
PCT/JP1996/002449 WO1997008218A1 (en) | 1995-08-31 | 1996-08-30 | Propylene-ethylene copolymer compositions and process for the production thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2203876A1 true CA2203876A1 (en) | 1997-03-06 |
CA2203876C CA2203876C (en) | 2007-04-10 |
Family
ID=38007187
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002203876A Expired - Fee Related CA2203876C (en) | 1995-08-31 | 1996-08-30 | Propylene-ethylene copolymer composition and process for producing the same |
Country Status (1)
Country | Link |
---|---|
CA (1) | CA2203876C (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3037466A1 (en) * | 2014-12-23 | 2016-06-29 | Dow Global Technologies LLC | Polyethylene compositions with improved optical properties |
WO2016135107A1 (en) * | 2015-02-25 | 2016-09-01 | Borealis Ag | Propylene copolymer composition with improved long-term mechanical properties |
CN113563717A (en) * | 2021-07-27 | 2021-10-29 | 金旸(厦门)新材料科技有限公司 | Antibacterial low-precipitation flame-retardant polyamide material and preparation method thereof |
-
1996
- 1996-08-30 CA CA002203876A patent/CA2203876C/en not_active Expired - Fee Related
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3037466A1 (en) * | 2014-12-23 | 2016-06-29 | Dow Global Technologies LLC | Polyethylene compositions with improved optical properties |
WO2016105610A1 (en) * | 2014-12-23 | 2016-06-30 | Dow Global Technologies Llc | Polyethylene compositions with improved optical properties |
US10316168B2 (en) | 2014-12-23 | 2019-06-11 | Dow Global Technologies Llc | Polyethylene compositions with improved optical properties |
WO2016135107A1 (en) * | 2015-02-25 | 2016-09-01 | Borealis Ag | Propylene copolymer composition with improved long-term mechanical properties |
CN113563717A (en) * | 2021-07-27 | 2021-10-29 | 金旸(厦门)新材料科技有限公司 | Antibacterial low-precipitation flame-retardant polyamide material and preparation method thereof |
CN113563717B (en) * | 2021-07-27 | 2022-10-25 | 金旸(厦门)新材料科技有限公司 | Antibacterial low-precipitation flame-retardant polyamide material and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CA2203876C (en) | 2007-04-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0790262A4 (en) | Propylene-ethylene copolymer compositions and process for the production thereof | |
US6723829B1 (en) | Heterophasic copolymers | |
EP2176340B1 (en) | Sterilisable and tough impact polypropylene composition | |
NO934729L (en) | Process for Preparing a Mixture Containing Ethylene Polymers, Mixture Containing Ethylene Polymers, and Using the Mixture | |
GB0008690D0 (en) | Process | |
AU582175B2 (en) | Impact-resistant polypropylene compositions having an improved whitening resistance | |
KR20080086439A (en) | Polypropylene composition comprising a propylene homopolymer component | |
US5115027A (en) | Polypropylene stretched film | |
CA2198177A1 (en) | High-molecular-weight polypropylene having a broad molecular-weight distribution | |
KR950024924A (en) | Ethylene polymer and preparation method thereof, solid titanium catalyst component for ethylene polymerization and catalyst for ethylene polymerization | |
CA2205887A1 (en) | High-molecular-weight ethylene-propylene reactor blend with broad molecular weight distribution | |
MY113195A (en) | Elastic substantially linear ethylene polymers | |
AU710486B2 (en) | Polypropylene resin composition | |
TR200000180T2 (en) | Wide MWD, composition-equivalent ethylene interpolymer compositions, method for producing them, and articles thereof. | |
EP1106647A3 (en) | Propylene-based copolymer composition | |
CA2203876A1 (en) | Propylene-ethylene copolymer composition and process for producing the same | |
US5534595A (en) | Syndiotactic propylene copolymer, preparation of the same, and resin composition containing the same | |
JP4389307B2 (en) | Propylene-based block copolymer composition | |
AU2002227923A1 (en) | Tubes obtained from a propylene polymer composition | |
JPH0141178B2 (en) | ||
JPS61243842A (en) | Polypropylene composition | |
EP1041114A1 (en) | Polyolefin resin modifier, polyolefin resin composition and oriented polyolefin film | |
JP3416880B2 (en) | Resin composition | |
JPH07171869A (en) | Injection molding method for polypropylene resin composition and molded form obtained thereby | |
JP2646104B2 (en) | Propylene copolymer composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |