CA2193951A1 - Catalytic system for the reduction of nitrogen oxides - Google Patents
Catalytic system for the reduction of nitrogen oxidesInfo
- Publication number
- CA2193951A1 CA2193951A1 CA002193951A CA2193951A CA2193951A1 CA 2193951 A1 CA2193951 A1 CA 2193951A1 CA 002193951 A CA002193951 A CA 002193951A CA 2193951 A CA2193951 A CA 2193951A CA 2193951 A1 CA2193951 A1 CA 2193951A1
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- Prior art keywords
- catalyst
- iron
- zeolite
- prepared
- hours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
- B01D53/8646—Simultaneous elimination of the components
- B01D53/865—Simultaneous elimination of the components characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9436—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/208—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/912—HC-storage component incorporated in the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
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- Catalysts (AREA)
Abstract
A catalytic process for the treatment of exhaust containing NOx along with other undesirable compounds is described. One embodiment of the process comprises a catalytic stage to selectively catalytically reduce NOx over an intermediate pore size zeolite catalyst that has been treated or modified to contain iron and then has been hydrothermally treated at least one time.
Description
~WO g~/Ol~i89 . ~ ,.S.
CATALYTIC SYSTEN FOR THE
REDUCTION OF NITROGEN OXIDES
.
This invention is concerned with the abatement of nitrogen oxides and, optionally, other undesirable compounds, in industrial and engine exhaust gases. In particular, it is concerned with a catalytic method for efficiently eliminating these undesirable " before discharge to the a, ,h~re. It is more particularly c~n~PrnPd with the use of a specially prepared catalyst comprising an intermediate pore size zeolite that has been treated or modified to contain iron or an iron ~- onnd for the selective catalytic reduction of the NOX present in the exhaust gas.
The present invention concerns a catalyst that is useful for treating an exhaust gas comprising NOX and ammonia, the catalyst comprising an int~ te pore size zeolite and iron or an iron , _ ' that has been hydrothermally treated, the hydrothermal treatment and the iron concentration being effective to produce a catalyst that is capable of converting at least 75 percent of the NOy and ammonia present in the exhaust gas after the catalyst has been treated in 100 percent steam at a temperature of 700~C for 10 hours.
The present invention also concerns a process for treating exhaust gas comprising NOX and ammonia comprising contacting the exhaust gas with the catalyst described above under conditions effective for the conversion of at least a portion of the NOX and ammonia to innocuous ~ --An embodiment of the invention is a method for treating a gas mixture comprising NOX, ammonia, and, optionally, at least one of CO and a hydrocarbon and mixtures thereof, said method comprising directing the gas mixture along with a source of oxygen, such as air, over a catalyst under conditions effective for the selective catalytic reduction of NOX, said catalyst comprising an WO96/016~9 2 1 9 3 9 5 1 .~
int~ te pore size zeolite which has been treated to contain iron or an iron _ulld, has been hydroth~rr~lly treated at least once, and optionally further comprises a binder.
As mentioned above, catalysts useful in this invention comprise int~ te pore size zeolites that have been treated or modified with iron or an iron ~- ~. The iron may be added by ferrocene impregnation, ion-exchange under specified conditions, contacting the zeolite with a water soluble i~Uli containing salt or salt precursor, contacting the zeolite with another type of inorganic iron-containing ~ ', e.g., iron oxide, or the iron may be incoL~ ted into the zeolite during the in-situ production of the zeolite from zeolite seeds, silica, and ~lay. Each of these methods will be further described below.
The term "exhaust gas" as used herein means any waste gas which is formed in an industrial process or operation and which is normally dicpo5~d of by discharge to the ~1 ~h~re, with or without additional treatment. "Exhaust gas" also includes the gas produced by internal combustion engines. The composition of such a gas varies and depends on the particular process or operation which leads to its formation.
The conversion of N0x to Nz is believed to proceed Z5 generally according to equations (1) and (2).
CATALYTIC SYSTEN FOR THE
REDUCTION OF NITROGEN OXIDES
.
This invention is concerned with the abatement of nitrogen oxides and, optionally, other undesirable compounds, in industrial and engine exhaust gases. In particular, it is concerned with a catalytic method for efficiently eliminating these undesirable " before discharge to the a, ,h~re. It is more particularly c~n~PrnPd with the use of a specially prepared catalyst comprising an intermediate pore size zeolite that has been treated or modified to contain iron or an iron ~- onnd for the selective catalytic reduction of the NOX present in the exhaust gas.
The present invention concerns a catalyst that is useful for treating an exhaust gas comprising NOX and ammonia, the catalyst comprising an int~ te pore size zeolite and iron or an iron , _ ' that has been hydrothermally treated, the hydrothermal treatment and the iron concentration being effective to produce a catalyst that is capable of converting at least 75 percent of the NOy and ammonia present in the exhaust gas after the catalyst has been treated in 100 percent steam at a temperature of 700~C for 10 hours.
The present invention also concerns a process for treating exhaust gas comprising NOX and ammonia comprising contacting the exhaust gas with the catalyst described above under conditions effective for the conversion of at least a portion of the NOX and ammonia to innocuous ~ --An embodiment of the invention is a method for treating a gas mixture comprising NOX, ammonia, and, optionally, at least one of CO and a hydrocarbon and mixtures thereof, said method comprising directing the gas mixture along with a source of oxygen, such as air, over a catalyst under conditions effective for the selective catalytic reduction of NOX, said catalyst comprising an WO96/016~9 2 1 9 3 9 5 1 .~
int~ te pore size zeolite which has been treated to contain iron or an iron _ulld, has been hydroth~rr~lly treated at least once, and optionally further comprises a binder.
As mentioned above, catalysts useful in this invention comprise int~ te pore size zeolites that have been treated or modified with iron or an iron ~- ~. The iron may be added by ferrocene impregnation, ion-exchange under specified conditions, contacting the zeolite with a water soluble i~Uli containing salt or salt precursor, contacting the zeolite with another type of inorganic iron-containing ~ ', e.g., iron oxide, or the iron may be incoL~ ted into the zeolite during the in-situ production of the zeolite from zeolite seeds, silica, and ~lay. Each of these methods will be further described below.
The term "exhaust gas" as used herein means any waste gas which is formed in an industrial process or operation and which is normally dicpo5~d of by discharge to the ~1 ~h~re, with or without additional treatment. "Exhaust gas" also includes the gas produced by internal combustion engines. The composition of such a gas varies and depends on the particular process or operation which leads to its formation.
The conversion of N0x to Nz is believed to proceed Z5 generally according to equations (1) and (2).
2 N02+ 4 NH3 +~2 - > 3 N2+ 6 H20 (1) 4 N0 + 4 NH, +0z- > 4 N2~ 6 H20 (2) This invention is effective for treating exhaust gas containing the approximate stoichiometric amount of ammonia. The ammonia may be present in the gas, may be added to the gas, or may be produced by an upstream process. As used herein, the expression "approximate stoichiometric amount of ammonia" is intended to mean 0.75 to 1.25 times the molar amount of ammonia indicated in equations tl) and (2) when excess oxygen is present.
Carbon monoxide and hydrocarbons present in the exhaust gas may be oxidized to carbon dioxide and water 2 1 ~395 t ~ WO96~1~9 PCT~S9S/08253 over the catalyst. Additionally, hydrocarbons may be selectively absorbed/~q~rhed on the catalyst.
Feeds This invention is effective to treat industrial and engine exhaust gases to remove N0x, and optionally other undesirable c ~ ds~ such as C0 and hydrocarbons, if present. These exhaust gases are typically produced in internal combustion engines, and coal or gas-fired or oil-fired furnaces, boilers and incinerators, and by the manufacture of nitric acid, by the nitration of organic ~h~;C.~15, and by other chemical operations such as the ~e~,uc--~inq of spent nuclear fuel rods by dissolution in nitric acid to recover uranyl nitrate followed by calcination to convert the nitrate to uranium oxide.
Process Conditions The exhaust gas may be treated in the catalytic system of this invention at a temperature of 200 C to l,OOO-C or more, e.g., within the range of 225~C to 900-C, e.g., of 225~C to 750~C, e.g., of 250-C to 600~C and at a gas hourly space velocity, GHS~, (vols. of gas at STP per volume of catalyst per hour) adjusted to provide the desired conversion. The GHSV can be from 1,000 to 500,000 hr~l, e.g., within the range of 2,500 to 250,000 hr~~, e.g., from 5,000 to 150,000 hr~l, e.g., from 10,000 to 100,000 hr~l.
The process of this invention may be operated at subd ~-ric to superatmospheric pressure, e.g. at 34.5 to 3,450 kPaa (5 to 500 psia), e.g., at 68.9 to 345 kPaa (10 to 50 psia), i.e. near or slightly abo~e ai ~ ric pressure.
The gas mixture directed over the catalyst m~y contain at least a stoichiometric amount of oxygen as indicated by eguations (1) and (2) above. Excess levels of oxygen above the stoichiometric amount may be desirable. In the method of this invention, a source of oxygen, such as air, is co-fed over the catalyst along with the exhaust gas. If 2 1 93q5 1 WO'~6/01689 sufficient oxygen is not present in the exhaust gas, a source of oxygen, e.g. air, may be added to the exhaust gas, and if sufficient oxygen i5 present in the exhaust gas, no air need be added to the exhaust gas.
Adequate conversion may be readily achieved with a simple stationary fixed-bed of catalyst. However, other contacting means are also contemplated, such as contacting with a fluid bed, a transport bed, and a monolithic catalyst structure such as a honeycomb. Suitable mixing may be used in the exhaust gas before the treatment according to the present invention to produce a homogeneous gas mixture for treatment.
Catalvst r~nn~itiOn Catalysts useful in this invention may comprise an active material and a support or binder. The support for the catalysts of this invention may be the samc as the active material and further can be a synthetic or naturally occurring substance as well as an inorganic material such as clay, silica, zirconia, titania and~or one or more other metal oxides. One binder that is suitable is d low acidity titania prepared from a mixture comprising a low acidity titanium oxide binder material and an aqueous slurry of titanium oxide hydrate. The preferred support is one that is a high surface area material that also possesses a high temperature stability and further possesses a high oxidation stability.
The binder may be prepared according to methods disclosed in U.S. Patent Nos. 5,430,000; 4,631,267;
4,631,268; 4,637,995; and 4,657,880. Also, the catalysts described herein may be combined with any of the binder precursors described in the above application and patents, and then may be formed, such as by extrusion, into the shape desired, and then hydrothermally treated and/or calcined as hereinafter described. The preferred binder may include less than 50 weight percent alumina, e.g., less than 2 weight percent alumina, e.g., is substantially free = =
~ WO ~IG89 -~ P~
of alumina. By the term "substantially free of alumina" is meant that no alumina is intentionally added to the binder, however, it is recognized that trace amounts of alumina may be present.
When low acidity titania is used as a binder, it may be desirable that the formable, e.g., extrudable, mass prepared by combininy the zeolite, the iron salt, and the titania binder precursors contain at least 0.5 wt.%, e.g., 1 wt.% to 20 wt.%, e.g., 2 to 8 wt.~ of the aqueous slurry of titanium oxide hydrate.
The low acidity titania may be added in dry particulate form, e.g., titanium oxide hydrate, so as to control the moisture content of the binder/dispersant mixture at a level to promote satisfactory forming, e.g., lS extrusion.
The catalysts may also contain stabilizers such as ~lk~l in~ earth oxides, phosphates and combinations thereof.
Catalysts useful in invention are frequently used with a substrate. A material can be both substrate and part of the catalyst. The catalyst may be combined with the substrate in any method that ensures that the catalyst will remain intact during the catalytic reaction, e,g., the c~talyst may be present as a coating on the substrate, or it can be present as an integral part of the substrate.
The catalyst useful in this invention will now be described in detail. It comprises an intermediate pore size zeolite (e.g., less than 7 Angstroms pore size, such as from 5 to less than 7 Angstroms) having a silica to alumina molar ratio of at least 5, e.g., at least 20, e.g., between 40 and 1000, e.g., 50 to 500, a Constraint Index of 1 to 12, said zeolite having been treated or modified to contain iron or a iron compound. The Constraint Index qualifies it as having an intermediate pore size. The method by which Constraint Index is det~min~d is described fully in U.S. Pat. No. 4,016,218.
Examples of such zeolites include ZSM-5 (U.S. Patent No. 3,702,886 and Re. 29,948); ZSM-ll (U.S. Patent No.
WO96~16~ ~ 2 1 q 3 ~ 5 ~ r~
Carbon monoxide and hydrocarbons present in the exhaust gas may be oxidized to carbon dioxide and water 2 1 ~395 t ~ WO96~1~9 PCT~S9S/08253 over the catalyst. Additionally, hydrocarbons may be selectively absorbed/~q~rhed on the catalyst.
Feeds This invention is effective to treat industrial and engine exhaust gases to remove N0x, and optionally other undesirable c ~ ds~ such as C0 and hydrocarbons, if present. These exhaust gases are typically produced in internal combustion engines, and coal or gas-fired or oil-fired furnaces, boilers and incinerators, and by the manufacture of nitric acid, by the nitration of organic ~h~;C.~15, and by other chemical operations such as the ~e~,uc--~inq of spent nuclear fuel rods by dissolution in nitric acid to recover uranyl nitrate followed by calcination to convert the nitrate to uranium oxide.
Process Conditions The exhaust gas may be treated in the catalytic system of this invention at a temperature of 200 C to l,OOO-C or more, e.g., within the range of 225~C to 900-C, e.g., of 225~C to 750~C, e.g., of 250-C to 600~C and at a gas hourly space velocity, GHS~, (vols. of gas at STP per volume of catalyst per hour) adjusted to provide the desired conversion. The GHSV can be from 1,000 to 500,000 hr~l, e.g., within the range of 2,500 to 250,000 hr~~, e.g., from 5,000 to 150,000 hr~l, e.g., from 10,000 to 100,000 hr~l.
The process of this invention may be operated at subd ~-ric to superatmospheric pressure, e.g. at 34.5 to 3,450 kPaa (5 to 500 psia), e.g., at 68.9 to 345 kPaa (10 to 50 psia), i.e. near or slightly abo~e ai ~ ric pressure.
The gas mixture directed over the catalyst m~y contain at least a stoichiometric amount of oxygen as indicated by eguations (1) and (2) above. Excess levels of oxygen above the stoichiometric amount may be desirable. In the method of this invention, a source of oxygen, such as air, is co-fed over the catalyst along with the exhaust gas. If 2 1 93q5 1 WO'~6/01689 sufficient oxygen is not present in the exhaust gas, a source of oxygen, e.g. air, may be added to the exhaust gas, and if sufficient oxygen i5 present in the exhaust gas, no air need be added to the exhaust gas.
Adequate conversion may be readily achieved with a simple stationary fixed-bed of catalyst. However, other contacting means are also contemplated, such as contacting with a fluid bed, a transport bed, and a monolithic catalyst structure such as a honeycomb. Suitable mixing may be used in the exhaust gas before the treatment according to the present invention to produce a homogeneous gas mixture for treatment.
Catalvst r~nn~itiOn Catalysts useful in this invention may comprise an active material and a support or binder. The support for the catalysts of this invention may be the samc as the active material and further can be a synthetic or naturally occurring substance as well as an inorganic material such as clay, silica, zirconia, titania and~or one or more other metal oxides. One binder that is suitable is d low acidity titania prepared from a mixture comprising a low acidity titanium oxide binder material and an aqueous slurry of titanium oxide hydrate. The preferred support is one that is a high surface area material that also possesses a high temperature stability and further possesses a high oxidation stability.
The binder may be prepared according to methods disclosed in U.S. Patent Nos. 5,430,000; 4,631,267;
4,631,268; 4,637,995; and 4,657,880. Also, the catalysts described herein may be combined with any of the binder precursors described in the above application and patents, and then may be formed, such as by extrusion, into the shape desired, and then hydrothermally treated and/or calcined as hereinafter described. The preferred binder may include less than 50 weight percent alumina, e.g., less than 2 weight percent alumina, e.g., is substantially free = =
~ WO ~IG89 -~ P~
of alumina. By the term "substantially free of alumina" is meant that no alumina is intentionally added to the binder, however, it is recognized that trace amounts of alumina may be present.
When low acidity titania is used as a binder, it may be desirable that the formable, e.g., extrudable, mass prepared by combininy the zeolite, the iron salt, and the titania binder precursors contain at least 0.5 wt.%, e.g., 1 wt.% to 20 wt.%, e.g., 2 to 8 wt.~ of the aqueous slurry of titanium oxide hydrate.
The low acidity titania may be added in dry particulate form, e.g., titanium oxide hydrate, so as to control the moisture content of the binder/dispersant mixture at a level to promote satisfactory forming, e.g., lS extrusion.
The catalysts may also contain stabilizers such as ~lk~l in~ earth oxides, phosphates and combinations thereof.
Catalysts useful in invention are frequently used with a substrate. A material can be both substrate and part of the catalyst. The catalyst may be combined with the substrate in any method that ensures that the catalyst will remain intact during the catalytic reaction, e,g., the c~talyst may be present as a coating on the substrate, or it can be present as an integral part of the substrate.
The catalyst useful in this invention will now be described in detail. It comprises an intermediate pore size zeolite (e.g., less than 7 Angstroms pore size, such as from 5 to less than 7 Angstroms) having a silica to alumina molar ratio of at least 5, e.g., at least 20, e.g., between 40 and 1000, e.g., 50 to 500, a Constraint Index of 1 to 12, said zeolite having been treated or modified to contain iron or a iron compound. The Constraint Index qualifies it as having an intermediate pore size. The method by which Constraint Index is det~min~d is described fully in U.S. Pat. No. 4,016,218.
Examples of such zeolites include ZSM-5 (U.S. Patent No. 3,702,886 and Re. 29,948); ZSM-ll (U.S. Patent No.
WO96~16~ ~ 2 1 q 3 ~ 5 ~ r~
3,709,979); 28M-12 (U.S. Patent No. 3,8~2,449~; ZSM-21 ~U.S. Patent No. 4,046,859); ZSM-22 (U.S. Patent No.
4,556,477); Z~3N-23 (U.S. Patent No. 4,076,842~; ZSM-35 (U.S. Patent No. 4,016,245); ZSM-38 (U.S. Patent No.
4,406,859~; gSM-48 (U.S. Patent No. 4,397,827); ZSM-57 (U.S. Patent No. 4,046,685); and ZSM-58 (U.S. Patent No.
4,417,780).
A catalyst useful in the method of this invention may be prepared by combining a zeolite, such as ~ZSM-5, an iron salt or other iron containing _ ~, a high molecular weight, hydroxy functional silicone, such as Dow Corning ~6-2230 silicone resin, a suitable extrusion aid, such as methyl cellulose, and a suitable polar, water soluble carrier, such as methanol, ethanol, isopropyl alcohol, N-methyl pyrrolidone or a dibasic ester along with water asneeded, then forming the mixture into the desired shape, such as by extrusion, then simultaneously calcining and hydrothermally treating the formed material. One particular methyl cellulose that is effective as an extrusion aid in the method of this invention i8 a hydroxypropyl methyl cellulose, such as K75M Methocel~, available from Dow Ch~mic~l CO. Dibasic esters that are useful in this invention include dimethyl glutarate, dimethyl succinate, dimethyl adipate, and mixtures thereof, one example of which is DuPont Chemical Co. DBE, which typically comprises 50 to 75 percent dimethyl glutarate, 10 to 25 percent dimethyl adipate, 19 to 26 percent dimethyl succinate and less than 0.2 wt.% methanol. Other silicone resins that may be used in the method of this invention include those described in U.S. Patent No. 3,090,691.
The relative proportions of zeolite component and the support material on an anhydrous basis may vary widely with the zeolite content ranging from between 5 to 99 percent by weight and more usually in the range of 10 to 95 percent by weight, specifically from 20 to 9o percent by weight of the dry composite.
2 1 9395 ~
~ WO96~1689 r~
Original ions, e.g., alkali or alkaline earth metal, of the as-synthesized intermediate pore size material and any found in the zeolite/support material can be replaced in accordance with terhniq~C well known in the art, at least in part, by ion-exchanye with other ions. For the present catalyst composition, preferred replacing ions include hydL~g~n ions and hydL~gell precursor, e.g., ; ;nn ions. ZSM-5 in the hydrogen exchanged form is referred to herein as HZSM-5. Representative ion-exchange techniques are disclosed in a wide variety of patents including U.S. Patents 3,140,249: 3,140,251; and 3,140,253.
The desired iron loadiny on the zeolite -nent of the catalyst is O.Ol to 5 wt.%, e.g., at least 0.4 wt.~, e.g., at least 0.6 wt.%, e.g., at least 1 wt.%, e.g., at least 1.5 wt.~, preferably 2 wt.%, iron into the zeolite.
The catalyst may also optionally include another metal, such as a transition metal, preferably a noble metal, the combination of the metals being able to oxidize other undesirable -c present in the exhaust gas along with allowing the SCR of NOX. The metal may be at least one of copper, zinc, vanadium, chroïnium, r-nq~n~ce, cobalt, nickel, palladium, platinum, molybdenum, tungsten, sodium, potassium, magnesium, calcium, barium, cerium and mixtures thereof, with the noble metals, platinum, palladium and combinations of these, along with cerium, particularly preferred. The terms "metal" and "iron" as used herein are intended to include the elemental metal as well as metal oxides, metal sulfides, and other metal containing compounds.
After the int~ te pore size zeolites have been treated or modified to contain iron or an iron compound, they may be washed with water and dried at a temperature ranging from 65 C to 315~C. They may also be calcined or thermally treated in air, or in an inert gas, at temperatures ranging from 260~C to 925 C for periods of time ranging from 1 to 48 hours or more, typically at 538~C
2 ~ 939~ 1 WO 96/lll6X9 rc for 4 to 6 hours. ~hile suba ---phlric or superatmospheric can be employed for the thermal treatment, ~ Aric p~es~uL~ is preferred simply for reasons of convenience.
Catalysts of i L~ved selectivity and other beneficial properties, such as improved resistance to ageing in an atmosphere containing steam, can be obtained by subjecting the iron containing zeolite to at least one treatment with strea~s containing steam (hydrothermally treating the catalysts) at elevated temperatures ranging from 260-C to goo-C, e.g., 400~C to 850-C, e.g., 500~C to 750 c. The hydrothermal treatment may be accomplished in an atmosphere containing at least 20 ppm, 0.5%, 5, 10~, 20%, even up to 99% steam in air or some other suitable gas stream or in an ai - ~'~re consisting of steam or nitrogen and some other gas which is essentially inert to the zeolite. Optionally, more than one hydrothermal treatment may be used, specifically two, three, or more hydrothermal treatments at different temperatures, e.g., increasing temperatures, may be used. Examples of steaming conditions include 600 C
with 10 percent steam in air for 10 hours, 700 to 750-C
with 5 to 10 percent steam in air for 6 to 10 hours, and 850-C with 20 percent steam in air for 6 hours. Typical steaming conditions are described in U.S. Patent Nos.
4,429,176; 4,522,929; 4,594,146; and 4,6~3,492. The calcination and hydroth~r-l treatments of the catalysts are preferably combined into one treatment step and -conducted simultaneously.
As mentioned above, the iron may be added to the catalyst by ferrocene impregnation, ion-exchange under specified conditions, contacting the zeolite with an inorganic iron-containing salt or salt precursor, contacting the zeolite with another type of inorganic iron-containing compound, e.g., iron powder or iron oxide, or the iron may be incorporated into the zeolite during the in-situ production of the zeolite from zeolite seeds, silica, and clay.
2 1 9395 1~ WO9~0lC89 r~
_9_ Ferrocene impregnated catalysts may be prepared by contacting the zeolite with ferrocene which has been dissolved in a suitable solvent. Suitable solvents are those which dissolve the ferrocene and may then be removed from the impregnated zeolite under conditions sufficiently mild as to avoid causing the ferrocene to sublimate off the zeolite. Examples of suitable organic solvents include benzene, toluene, xylenes, and hexane among others. The impregnation is typically conducted for more than 4 hours, specifically from 4 hours to several days, more specifically from 6 hours to 100 hours. The impregnation is generally conducted at conditions cffective to achieve the desired iron loading or iron concentration on the zeolite.
The impregnation may occur either before or after the zeolite is combined with the support. For example, if the zeolite is first combined with the support and then impregnated, ferrocene that is deposited on the surface of the zeolite and on the support may be washed off using a solvent having an effective atomic diameter that is larger than the zeolite pore size, e.g., an organic solvent such as Tetralin~.
The impregnation may be conducted after first drying or dehydrating the zeolite. Also, the ferrocene solution may be preparcd using a water-free or dry solvent.
The impregnated zeolite is recovered by removing the solvent from the zeolite. It is desired to remove the solvent without causing the rerrocene to sublimate off the zeolite. One possible way i5 to evaporate the solvent at a temperature less than the ferrocene sublimation temperature, 100-C. This solvent removal may be done at superai _~h~ric pressure, if desired, or pressures ranging from sub~ ric to atmospheric. The recovered ferrocene impregnated zeolite then may be calcined at 450-C
to 550~C to oxidize the ferrocene and to convert the iron to its oxide.
21 ~3951 WO g6,0~68~ . ~ I .
Another catalyst comprises an inti ~';~te pore size zeolite which has been exposed to at leas~ one ion-exchange sequence under specific conditions, wherein the ion-exchange sequence comprises the steps of contacting the in~r~ te pore size zeolite with an aqueous solution of a ferrous, Fe(II), salt under suitable conditions, recovering the zeolite, and calcining the zeolite. The conditions include those effective to ~uba~dl,Lially prevent oxidation of the ferrous ion to the ferric form, such as using nitrogen, argon and the like inert gases to blanket the solution. The conditions also include stirring or mixing at a temperature of above 55-C, specifically above 65-C, or those temperatures effective to reduce the hydration sphere of the ferrous cation to a size small enough to enter the pores of the zeolite. The ferrous cation is reported to have an ionic radius in an aqueous solution of about 0.0000000006 meters (6 A) at 25'C, which is too large to enter ~SM-5 pores, which are slightly smaller than this. Increasing temperature is believed to reduce the size of the hydration sphere associated with the ferrous cation. For example, with increasing temperature, a ferrous ~ _ ', ferrous sulfate, changes from the heptahydrate form to the tetrahydrate form (at 56.6 C) and then to the monohydrate form (at 65-C~.
The ion-exchange may be conducted for more than 4 hours, e.g., from 4 hours to several days, e.g., from 6 hours to 100 hours. During the ion-exchange, the pH of the aqueous solution may be maintained between 1 and 4.~ or at a pH level effective to prevent precipitation of the ferrous salt.
It has been found that ferrous, Fe(II~, ions are more readily exchanged into the zeolite than ferric, Fe(III), ions.
Ferrous, ~e(II), salts useful in this invention include the water soluble salts, such as, ferrous ~mm~n;um sulfate, ferrous chloride, ferrous fluosilicate, ferrous hyposulfite, ferrous iodide, ferrous lactate, ferrous ~WO96101689 -ll- r~
nitrate, ferrous perchlorate, ferrous sulfate, and ferrous thiocyanate.
After the iron has been ion-oYrh~nqed into the zeolite, the zeolite may be recovered by cooling the aqueous solution below 55~C to 65-C, filtering the zeolite from the aqueous solution and washing the filtered zeolite with a neutral or slightly basic solvent, for example, an aqueous solvent with a pH of from 6 to 9, such as distilled or deionized water. The solvent washing may be conducted at conditions effective to avoid leaching the iron from the zeolite. The aqueous solution and the ion-exchanged zeolite need not be maintained under inert conditions after the solution has been cooled. The I~cuv~ed zeolite may be dried, calcined and hydrothermally treated as more fully described herein.
The ion-exchange sequence described above may be conducted at least once, e.g., at least twice, e.g., at least three times, e.g., four or more times.
Another method to incorporate iron onto the zeolite is to contact an into ~ te pore size zeolite with an iron salt or salt precursor. In this method, the iron salt may first be dissolved in water or another suitable solvent and then the zeolite may be contacted with the solution.
Alternatively, the iron salt and the zeolite, and any binder material desired, may be physically combined and then water or another suitable solvent added and the mixture recovered and formed, as desired. The formed material may be dried, calcined, or hydrothermally treated as is more fully described herein. A~ will be apparent to one skilled in the art, any method that is effective to contact the zeolite with the iron salt and to achieve a high degree of iron distribution on and inside the zeolite may be used, including, but not limited to an incipient wetness torhnique~
Suitable iron salts include all of the ferrous salts mentioned above, as well as ferric acetate, iron(III) benzoate, iron(III) cacodylate, iron(III) dichromate, WOs6~ 2 1 9 3 9 5 1 ~
iron(III) citrate, iron~III) fluoride, iron(III) fluosilicate, iron(III) formate, iron(III) glycelvL,~ h~te, iron(III) llydsogel, cyanide, iron(IlI) hydrosulfate, iron(III~ lactate, iron(III) malate, iron(III) oxalate, iron(III) orth~ te~ iron(III) hypophosphite~ iron(III) sulfide, iron(III) thiocyanate, ferric acetylacetonate, ferric ammoniumchloride, ferric chloride, iron(III) nitrate nanohydrate, iron~III) sulfate pentahydrate, i inm ferric sulfate, ferric bromide, ferric iodide, and any other ferrous, ferric, or other iron salts that are water soluble. Also included are precursors of all of the salts mentioned above.
The incorporation of iron onto the zeolite may be accomplished by contacting an intermediate pore size zeolite with an iron salt or salt precursor, such as those mentioned above. In this method, the iron salt may first be dissolved in water or another suitable carrier or solvent and then the zeolite may be contacted with the solution, recovered from the solution, dried and then bound 20 if desired. Alternatively, the iron salt and the zeolite, and any binder material desired, may be physically combined with water or another suitable carrier or solvent to produce a mixture and the mixture recovered and formed, such as by extrusion. The formed material may be dried, calcined, or hydrothermally treated as is more fully described herein. As will be apparent to one skilled in the art, any method that is effective to contact the zeolite with the iron salt may be used, including, but not limited to mulling or an incipient wetness techni~ue.
Yet another method that is suitable to add iron to the zeolite is to physically contact an intermediate pore size zeolite with an inorganic iron-containing compound, e.g., iron oxide. In this method, it is preferred to use a finely divided iron-containing compound, such as a fine pigment grade red iron oxide. It is also preferred to add a binder pLe~UL~VS to the physical mixture of the iron-containing compound and the zeolite and to form the ~ W096/016~ -13- P~~
physical mixture. After the desired shape has been formed, the i~on contacted zeolite may be calcined and hydrothermally treated as is more fully described herein.
Another catalyst may be prepared by in-situ crystallization of an ay~L~te~ e.g., a preformed clay E~.~Ley~te. The ay~L~te comprises four ~ A~ts: seeds of an int~ te pore size zeolite, e.g., ZSM-5 seeds, silica, e.g., a colloidal silica such as Ludox~ available from E. I. DuPont de Nemours & Co., clay, and iron oxide.
optionally, the aggregate can also include alumina.
Various terhni~lAc for preparing an in-situ crystallized zeolite are described in U.S. Patent Nos. 4,522,705;
4,091,007; and 4,800,187.
The zeolite may be prepared from a clay aggregate which comprises a non-clay added source of silica. The sources of silica in the reaction mixture may include both a clay and a non-clay source of silica, or a clay alone.
Non-clay sources of silica that can be employed in the synthesis are Ludox~, an aqueous dispersion of colloidal silica, water glass, sand, silica gel, fused silica, and finely-divided precipitated silicas, such as Hi-Sil, Quso, and Zeosil 100.
The clay cn~pon-Ant which is treated to form the zeolite-containing catalyst can be selected from the group consisting of kaolin, halloysite, montmorillonite, illite, and dickite, with kaolin preferred.
The preformed aggregate may be treated for one or more hours at a temperature sufficient to convert the clay into the me~k~nl in phase, e.g., greater than 927~C to 1000~C.
After the thermal treatment of the aggregate, the zeolite may be crystallized by treatment at a temperature of greater than 135'C, e.g., 149~C, in the presence of water, alkali metal cations, and optionally, a directing agent such as tetraalkylammonium ions, e.g., a tetraalkylammonium halide, such as tetrapropylammonium bromide, or a n-alkylamine, such as n-propylamine, with no additional nutrients for zeolite formation.
WO~0168~ 2 l 9 3 9 5 1 r~
The in-situ formed zeolite may be prepared from a aggregate comprising about 3-5% zeolite seeds, e.g., ZSM-5 seeds; 23-25~ silica, e.g. colloidal silica; 68-70% clay, e.g., kaolin clay; and 0.01-5$ metal oxide, e.g., iron oxide.
As noted above, the catalytic reduction of nitrogen oxides is substantially effected by the use of the present process. By substantially effected is meant a conversion of greater than 40, 75, 80, 85, 90, 95, or even 99% or more of the nitrogen oxides and the ammonia in the exhaust gas to innocuous ~ _ -c, such as nitrogen, through the use of this process. This is also referred to herein as conversion of a substantial portion of the N0x and ammonia in the exhaust gas to innocuouq compounds.
Exam~le 1 Base ZSM-5 A HZS~-5 sample, prepared according to U.S. Patent No.
3,702,886, was used as the reference sample and was used as the basis for all of the other examples.
Exam~le 2 Preparation of an iron containing ZSM-5 An iron containing ZSM-5 sample was prepared by the following method: lO0 g of distilled water was heated to about 85-C with constant stirring under a blanket of dry nitrogen. Approximately 0.11 g of ferrous sulfate and 5.1 g o~ the same HZSM-5 as Example l were added to the heated water. A solution p~ of about 2 was maintained by dropwise addition of nitric acid or ammonium hydroxide, as needed.
The exchange solution was maintained at about 85-C under a nitrogen blanket with continued stirring for approximately 17 hours. The solution was subsequently cooled to room temperature, filtered and washed with distilled water. The filtered solid was calcined in air for 8 hours at 538 C to produce the iron containing catalyst, Catalyst A. The iron loading of this catalyst as prepared is about 0.5 wt.~.
~ WO96~1689 2 1 9 3 9 5 ~
Example 3 Comparative testing against the base ZSM-5 In this example, the SCR activity of Catalyst A is compared with the base HZSM-5 catalyst from Example l. The catalyst samples were evaluated using a fixed bed quartz reactor operating between 250-550-C. The reactor inlet contained 500 ppm N0, 500 ppm NH" and 5 vol.% ~2 in a He carrier flowing at a constant gas hourly space velocity (GHSV) of 12,000 hr~1. The effluent from the reactor was cont;nuouCly monitored by non-dispersive infrared spectroscopy (NDIR) detectors. Catalyst activity results are reported below in Table l.
Table l Percent N in Feed Converted to N~
Tem~erature. ~C Base ZS~-5 Catalvst Catalvst A
550 89% 93%
455 100% 98%
400 lO0~ 98~
345 71~ 97%
250 26~ 92 Exam~le 4 Preparation of an Iron Containing ZSM-5 An iron containing ZSM-5 sample was prepared by the following method: a solution containing 25 g of the same HZSM-5 as Example l and 500 g of distilled water was heated to about 77 C with constant stirring under a blanket of dry argon. Approximately 0.3 g of ammonium ferrous sulfate was added to the heated solution. A solution pH of 3 was maintained by dropwise addition of nitric acid or ammonium hydroxide, as needed. The exchange solution was maintained at about 77 C under an argon blanket with continuous stirring for approximately 9 hours. The solution was subsequently cooled to room tcmperature, filtered and 21 93q51 washed with distilled water. The filtered solid was calcined in air $or 8 hours at 538 C to produce the iron c~nt~ining catalyst, Catalyst B. Ihe iron loading of this catalyst as prepared is about 0.5 wt.%.
ExamPle 5 Comparative testing against a base ZSM-5 In this example, the SCR activity of Catalyst B is compared with the base HZSM-5 catalyst from Example l. The catalyst samples were evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 2.
Table 2 Percent N in Feed Converted to N2 I~ _L~uLe. 'Ç Base ZSM-5 Çatalvst Çatalvst B
15 550 8g% 100%
455 100% 100%
400 '100% 100%
345 71% 100%
250 26% 90%
Exam~le 6 Preparation of an Iron Containing ZSM-5 An iron containing ZSM-5 sample was prepared by the following method: a solution containing 0.2354 g of ferrous acetate in 30 g distilled water was added to a flask containing 15 g of the same HZSM-5 as Example l at room te1.y~L~LuL~. The catalyst slurry was mixed for approxi~ately 2 hours and was air dried at room temperature for about 16 hours. The dried catalyst was calcined in air ~or 8 hours at 538-C to produce the iron containing catalyst, Catalyst C. The iron loading of this catalyst as prepared is about 0.5 wt.%.
2 1 ~3~5 1 ~ WO96/01689 ~ .iA
ExamPle 7 Comparative testing against a base ZSM-5 and Catalyst A
In this example, the SCR activity of Catalyst C is compared with the base HZSM-5 catalyst from Example 1 and Catalyst A as prepared in Example 2. The catalyst samples were evaluated using similar equipment and the same pLOCedu~e as Example 3. Catalyst activity results are reported below in Table 3.
Table 3 Percent N in Feed Converted to N2 TemPerature,~C Base Catalvst CatalYst A Catalvst C
550 89% 93% 89%
455 100% 98% 91%
400 100% 98% 91%
345 71% 97% 90%
250 26% 92% 85%
ExamPle 8 Preparation of an iron containing HZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: 7.6 g of the same HZSM-5 as that of Example 1 was heated in a stream of dry nitrogen to 375 C.
After this temperature was maintained for 4 hours, the catalyst was cooled, in a stream of dry nitrogen, to room temperature. A solution of 0.5 g of ferrocene (dicyclopentadienyliron) in 30 g dry benzene was then added to the calcined zeolite and the slurry allowed to mix on a roller for about 16 hours. The benzene was allowed to evaporate at room temperature to give a benzene/ferrocene wetted zeolite. This wet solid was then heated to a temperature that did not exceed lOO-C in a vacuum oven so as to remove the residual benzene. This dry catalyst was then calcined in a stream of air at about 450-C for about 6 Wo96~16~ 2 1 9 3 q 5 1 . ~
hours to produce the desired iron containing catalyst, Catalyst D. The iron loading of this catalyst is about 1.8 wt.~.
Exam~le 9 Catalytic evaluation of Catalyst D
In this example, the SCR activity of Catalyst D from Example 8 was evaluated. The catalyst sample was evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 4.
Tab~e 4 Percent N in Feed Converted to N~
T~nerature. ~C Catalvst D
550 9o~
400 98~
345 98%
250 95%
Exam~le lo Preparation of an iron containing HZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about lO g of the same H2SM-5 as that of Example 1 was heated in a stream o~ dry air to 375~C for 4 hours and then was cooled to room temperature. A solution of 0.1667 g of ferrocene (dicyclopentadienyliron) in 30 g dry toluene was then added to the dried zeolite and the slurry was mixed at room temperature overnight. Excess toluene was allowed to evaporate at room temperature to give a toluene/ferrocene wetted zeolite. The recovered solid was then calcined in a stream of dry air at about 538-C for about 6 hours to produce the desired iron containing catalyst, Catalyst E. The iron loading of this catalyst is about 0.45 wt.~.
~wo s6ml6ss -19- r~
ExamPle 11 Catalytic evaluation of Catalyst E
In this example, the SCR activity of Catalyst E from Example 10 was evaluated using similar ~li --L and the same procedure as Example 3. Catalyst activity results are reported below in Table 5.
Tab~e 5 Percent N in Feed Converted to N2 Tem~erature. ~C CatalYst E
455 99%
400 99%
345 98%
250 81%
Exam~le 12 Preparation of an iron containing HZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about 10 g of the same HZSM-5 as that of Example 1 was heated in a stream of dry air to 375~C for 4 hours and then was cooled to room temperature. A solution of 0.3331 g of ferrocene tdicyclopentadienyliron) in 30 g dry toluene was then added to the dried zeolite and the slurry was mixed at room temperature overnight. The slurry was filtered and washed once with 100 ml of Tetralin~ to remove excess ferrocene from the external surface of the zeolite. Excess Tetralin~ was, allowed to evaporate at room temperature to give a TetralinX/ferrocene wetted zeolite.
The recovered solid was then calcined in a stream of dry air at about 538'C for about 6 hours to produce the desired iron containing catalyst, Catalyst F. The iron loading of this catalyst is about 0.66 wt.%.
wo g6,0l689 2 1 9 3 9 5 1 P ~u~
Exam~le 13 Catalytic evaluation of Catalyst F
In this example, the SCR activity of Catalyst F from Example 12 was evaluated using similar e~ and the same ploceduLe as Example 3. Catalyst activity results are reported below in Table 6.
Table 6 Percent N in Feed Converted to N2 Tem~erature. ~C CatalYst F
455 98~
400 98%
345 96%
250 88%
Exam~le 14 Preparation of an iron containing HZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about 10 g of the same HZSN-5 as that of Example 1 was heated in a stream of dry air to 3~5-C for 4 hours and then was cooled to room temperature. A solution of 0.3331 g of ferrocene (dicyclopentadienyliron) in 30 g dry toluene was then added to the dried zeolite and the slurry was mixed at room temperature overnight. Excess toluene was allowed to evaporate at room temperature to give a toluene~ferrocene wetted zeolite. The recovered solid was then calcined in a stream of dry air at about 538-C for about 6 hours to produce the desired iron containing catalyst, Catalyst G. The iron loading of this catalyst is about 1.05 wt.%.
~ WO96~1689 Example 15 Catalytic evaluation of Catalyst G
In this example, the SCR activity of Catalyst G from Example 14 was evaluated using similar e~uipment and the same pLuCed~L- as Example 3. Catalyst activity results are reported below in Table 7.
Table 7 Percent N in Feed Converted to N2 Temperature. ~C CatalYst G
550 95%
455 98%
400 98%
345 97%
250 91%
Exam~le 16 Aging of the HZSM-5 catalysts The base HZSM-5 of Example 1 and Catalysts D through G
as prepared above in Examples 8, 10, 12, and 14 were hydrothcrmally aged. Approximately 5 g of each catalyst was placed in individual identical crucibles and put in a controlled al ~ re furnace. The furnace was continuously purged with air containing 20 wt.% water vapor. The samples were treated in this moist atmosphere at 850~C for 6 hours. The treated samples will be referred to as aged base HZSM-5, and aged Catalysts D through G.
Exam~le 17 Catalytic evaluation of aged base HZSM-5 In this example, the SCR activity of the aged base HZSM-5 from Example 16 was evaluated using similar ~cll; nt and the same procedure as Example 3. Catalyst activity results are reported below in Table 8.
W0~6~1689 r~u~
Table 8 Percent N in Feed Converted to N2 I~ ~Lur~. ~C A~ed base HZSM-5 Exam~le 18 Catalytic evaluation of aged Catalyst D
In this example, the SCR activity o~ the aged Catalyst D from Example 16 was evaluated using similar equipment and the same ~ ed~e as Example 3. Catalyst activity results are reported below in Table 9.
Table 9 Percent N in Feed Converted to ~2 Te~era~e. ~C Aqed Catalvst D
550 g8%
455 100%
400 100%
Exam~le 19 Catalytic evaluation of aged Catalyst E
In this example, the SCR activity o~ the aged Catalyst E from Example 16 was evaluated using si~ilar ~ and the same procedure as Example 3. Catalyst activity results are reported below in Table 10.
_ _ _ _ _ _ _ _ .. . . . _ . . _ ...
~ W096l0l68~ -23- I~
Tahle 10 Percent N in Feed Converted to N2 Tem~erature, ~C Aaed Catalvst E
550 98%
455 100~
400 99%
345 88~
250 37%
ExamPle 20 Catalytic evaluation of aqed Catalyst F
In this example, the SCR activity of the aged Catalyst F from Example 16 was evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 11.
Table 11 Percent N in Feed Converted to N2 TP~n~rature. ~C A~ed CatalYst F
550 9g%
455 99%
400 92%
345 57%
250 27%
Exam~le 21 Catalytic evaluation of aged Catalyst G
In this example, the SC~ activity of the aged Catalyst G from Example 16 was evaluated using similar equipment and the same procedure as Examplc 3. Catalyst activity results are reported below in Table 12.
WO 9~11689 2 1 9 3 9 5 1 "~ J, ~
Table 12 Percent N in Feed Converted to N2 Te~nerature. 'C A~ed Catalvst G
550 97%
455 100~
400 99%
ExamPle 22 Preparation of an iron containing ZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about 20 g of illm iron(III~ sulfate was dissolved in 74 g distilled water. This solution was added to about 120 g of the base HZSM-5 and the slurry was 15 mixed at about room temperature and was then dried at about lOO-C overnight. Approximately 10 g of the dri.ed, impregnated solid was then calcined in air at about 600 C
with about 10% steam for about 10 hours to produce the desired iron containing catalyst, Catalyst ~. The iron loading of this catalyst is about 2 wt.~.
ExamPle 23 Catalytic evaluation of Catalyst H
In this example, the SCR activity of Catalyst H from Example 22 was evaluated using similar equipment and the 25 same procedure as Example 3. Catalyst activity results are reported below in Table 13.
~ WOg610168g IR,~ el Table 13 Percent N in Feed Converted to N, T~nerat~re. ~C Catalvst H
550 76%
400 99%
Exam~le 24 Preparation of an iron containing ZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about 1.5 g of iron~III) nitrate was dissolved in 6.5 g distilled water. This solution was added to about 10 g of the base HZSM-.S and the slurry was mixed at about room temperature and was then dried at about lOO-C overnight. The dried, impregnated solid was then calcined in air at about 600~C with about 10~ steam for about 10 hours to produce the desired iron containing catalyst, Catalyst I. The i3'0n loading of this catalyst is about 2 wt.~.
ExamPle 25 Catalytic evaluation of Catalyst I
In this example, the SCR activity of Catalyst I from Example 24 was evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 14.
WO96/01~89 l~1 Table l~
Percent N in Feed Converted to N
TeDDerature. 'C Catalvst I
550 86%
455 97%
400 99%
250 92%
Exam~le 26 Preparation of a silica bound-iron containing ~SM-5 A silica bound iron containing ~SM-5 catalyst was prepared by the following method: about lO0 g of the dried, iron impregnated HZSM-5 catalyst prepared in Example 22 was dry blended with about 22 g of Dow Corning siliconc resin (Q6-2230~ and about 6.8 g of X75M Methocel~
(available from Dow Ch~mic~l Co.~. Approximately 89 ml of a l:l by volume mixture of water:isopropyl alcohol was then added to the dry blended powder. The slurry was mulled for a minimum of 5 minutes until the mixture reached the proper consistency for extrusion. The mixture was then extruded into l/16 inch diameter cylindrical strands ir a screw extruder and was allowed to dry. Approximately lO g of the dried extrudate was calcined in air at 600-C with lO~ steam for lO hours to produce the desired iron containing catalyst, Catalyst J. The iron loading of this catalyst is about 2 wt.~.
Exam~le 27 Catalytic evaluation of Catalyst J
In this example, the SCR activity of Catalyst J from ExaDple 26 was evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 15.
2 t 93~51 ~ WO961~1689 r~l,u~
Table 15 Percent N in Feed Converted to N2 ~em~erature. ~C Catalyst J
550 74%
455 97%
400 100%
345 99%
250 88%
Examl~le 28 Comparative testing after steaming In this example, the SCR activity of the base HZSM-5 and Catalysts H, I, and J are compared after each of the catalyst were treated with 100% steam at 700~C for 7 hours.
The catalyst samples were evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 16.
Table 16 Percent N in Feed Converted to N2 Steamed Catalvsts Tem~.. ~C Base Catalvst Catalvst H CatalYst I CatalYst J
550 56% 92% 98% 92%
455 46~100% 98% 100%
400 36%100% 97% 100%
345 zo%1~0% 99% 100%
250 6% 96% 77% 95%
Exam~le 29 An iron containing ZSM-5 catalyst was prepared by the following method: Approximately 1.5g of iron (III) nitrate was dissolved in 6.5g distilled water. This solution was _ _ _ _ _ _ _ _ _ _ _ _ _ , .. . . .. . . . . . . . . .
W0~6~l6 added to about lOg of the base HZSM-5 and the resulting slurry was mixed and dried at room temperature overnight.
The dried inpregnated solid was then calcined in air at 600-C with 10% steam for 10 hours to produce the desired catalyst, Catalyst R. The nominal iron loading of this sample is about 2 wt%.
Exam~le 30 In this example, the SCR activity of Catalyst R from Example 29 was evaluated using similar equipment and the same reaction conditions as Example 3. See Table 17 below.
Table 17 Percent N in Feed Converted to N2 Temperature, 'C Catalyst K
550 86~
455 97%
400 99%
345 99%
250 92%
Exam~le 31 In this example Catalyst K was hydrothermally treated at 850-C in air containing 20% steam for 6 hours.
This catalyst is re~erred to as Catalyst L.
~Y~le 32 In this example, the SCR activity of the hydroth~rr=lly treated cdtalyst~ Cataly5t L, from Ex~mple 31 was evaluated using similar equipment the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 18.
21 93q51 ~ W096l0l689 l~ll. .
TAhle 18 Percent N in Feed Converted to N2 Temperature, ~C Hydroth~rr-lly treated Catalyst L
550 ~ g6%
455 g9%
400 9g%
EYAmnle 33 In this example the hydrothermally treated catalyst, Catalyst L, from Example 31 was aged at 700-C in 100% steam for 7 hours. This catalyst is referred to as Catalyst M.
Exa~le 34 In this example, the SCR activity of the aged, hydro~h~r~lly treated catalyst, Catalyst M, from Example 33 was evaluated using similar equipment and the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 19.
Table 19 Percent N in Feed Converted to N2 Temperature, ~C Aged Catalyst o~ Example 33 550 99~
455 96%
400 95%
345 93%
250 82~
WO9610168g 21~3~51 p ,,~ ~
Exam~le 35 In this example the aged, hydrothermally treated catalyst, Catalyst ~, from Example 33 was further aged at 900-C in lO0~ steam for 7 hours. This catalyst is referred to as Catalyst N.
ExamPle 36 In this example, the SCR activity of the aged, hydrothermally treated catalyst, Catalyst N, from Example 35 was evaluatad using similar equipment and the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 20.
Table 20 Percent N in Feed Converted to N2 Temperature, ~C Aged Catalyst of Example 35 550 86~
455 71%
ioo 53%
345 28%
250 ll~
ExamPle 37 In this example Catalyst K was aged at 700 C in 100%
steam for 7 hours without the intermediate hydrothermal treatment. This catalyst will be referred to as Catalyst 0.
Exa~le 38 In this example, the SCR activity of the aged catalyst, Catalyst 0 from Example 37 was evaluated using similar equipment and the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 21.
.. ..... .. _ _ _ _ _ . _ ~ W096l0~689 ~1/ L ~!,.l Table 21 Percent N in Feed Converted to N2 T~ tUL~, ~C Aged Catalyst of Example 37 550 98%
455 98%
400 97%
345 99%
250 77%
Exam~le 39 In this example the aged catalyst, Catalyst 0, from Example 37 was further aged at 900-C in 100% steam for 7 hours. This catalyst will be referred to as Catalyst P.
Exam~le 40 In this example, the SCR activity of the twice-aged catalyst, Catalyst P, from Example 39 was evaluated using similar equipment and the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 22.
Table 22 Percent N in Feed Converted to N2 Temperature, ~C Aged Catalyst of Example 39 550 56%
455 32%
400 21%
345 14%
250 8%
21 g~q51 WO961~1689 r~a,~
Exam~le 41 A ZSN-5 catalyst was prepared by the i'ollowing ~ethod:
99 grams of calcined ZSM-5 were mixed in a muller with 20 grams of Dow Corning Q6-2230 silicone resin, and 6.5 grams of Dow ~ht~ic~l Co. K75M Methocel~. To this dry blend, 52.9 grams of distilled water znd 23.l grams of E. I.
DuPont de Nemours & Co. DBE (dibasic ester) were added while mulling. The mixture was then extruded to form l/16 inch cylindrical extrudates. The extrudates were dried overnight at lZO-C and then calcined at 600-C in 10% steam for lO hours to produce a ZSM-5 containing catalyst. This catalyst is referred to herein as Catalyst Q.
F~nle 42 An iron containing ZSM-5 sample was prepared by the following method: 99 grams of calcined ZSM-5 were mixed in a muller with 20 grams of Dow Corning Q6-2Z30 silicone resin, 6.5 grams of Dow K75M Methocel~, and 3.2 grams of iron oxide, Fe20~. To this dry blend, 52.9 grams of distilled water and 23.l grams of DuPont DBE (dibasic ester) were added while mulling. The mixture was then formed into 1~16 inch cylindrical extrudates. The extrudates were dried overnight at 120-C and then calcined at 600 C in 10% steam for lO hours to produce an iron containing catalyst, Catalyst R.
Exam~le 43 In this example, the SCR activity of Catalyst Q is compared with the SCR activity of Catalyst R. The catalyst samples were evaluated using a fixed-bed quartz reactor operating between 250 and 550~C. The reactor was loaded with 2.75 grams of catalyst with inlet qases consisting of 500 ppm N0, 500 ppm NH3, and 5% 0~ in a N2 carrier flowing at a constant flow rate of l,ooo cc/min. The effluent from ~ W096l01689 2 1 9395 I p the reactor was contin~n~ly monitored by FTIR (Fourier Transform Infrared) analysis. Catalyst activity results are summarized below in Table 23.
T~hle 23 Net N0 Conversion, %
Tem~erature. ~CCatalvst 0 CatalYst R
550 71% 92 454 74% 96%
398 72~ 96%
343 60% 96~
250 25% 65%
Exammle 44 An iron containing ZSM-5 sample was prepared by the following method: 99 grams of calcined ZSM-5 were mixed in a muller with 20 grams of Dow Corning Q6-2230 silicone resin, 6.5 grams of Dow ~75M Methocel~, and 0.32 grams of iron oxide, Fe203. To this dry blend, 52.9 grams of distilled water and 23.1 grams of DuPont DBE (dibasic ester) were added while mulling. The mixture was then formed into 1/16 inch cylindrical extrudates. The extrudates were dried overnight at 120-C and then calcined at 600-C in 10~ steam for 10 hours to produce an iron containing catalyst, Catalyst S.
Exam~le 45 In this example, the SCR activity of Catalyst Q is compared with the SCR activity of Catalyst S. The catalyst samples were evaluated using a fixed-bed quartz reactor operating between 250 and 550-C. The reactor was loaded with 2.75 grams of catalyst with inlet gases consisting of WOg6l~l689 2 1 9 3 9 5 ~
500 ppm N0, 500 ppm NH3, and 5% ~2 in a N2 carrier flowing at a constant flow rate of 1,000 cc~min. The effluent from the reactor was continuously monitored by FTIR ~Fourier Transform Infrared) analysis. Catalyst activity results are summarized below in Table 24.
T~hle 24 Net N0 Conversion, %
Tem~erature. 'C CatalYst Q CatalYst S
550 71% ~4%
454 74% S6%
398 72% 87 343 60% 82 250 25% 40 ~xam~le 46 A component of the in-situ grown ZSM-5 clay aggregate catalyst precursor was prepared by mixing 140 grams of calcined ZSM-5 seeds with 1~60 grams of kaolin clay (Kaopaque lOS, a Georgia kaolin clay, Dry Branch Chemical Co., Dry Branch, GA). The mixed cu~ olle.lLs will be referred to herein as Component A.
Exam~le 47 An in-situ grown ZSM-5 clay aggregate catalyst precursor was prepared by mixing 75.9 grams of Component A
from Example 46 with 7.6 grams of Dow Chemical Co. K75M
Methocel~ in a muller. To this dry blend, 60.3 grams of E.
I. DuPont de Nemours & Co. Ludox~ AS-40 colloidal silica were added while mulling. The mixture was then extruded into 1/16 inch cylindrical extrudates. The extrudates were dried overnight at 120-C and then calcined at lOlO-C for 3 hours to produce an in-situ grown ZSM-5 catalyst precursor, Precursor A.
... .. . , . . , _ _ _ _ _ . _ ~ WO96tO1689 Exam~le 48 An iron containing in-situ grown ZSM-5 clay aggregate catalyst ~e~ul~oI was prepared by mixing 75.9 grams of C~ J~L A from Example 46 with 7.6 grams of Dow ~75M
Methocel~ and 3.6 grams of Fe203 in a muller. To this dry blend, 60.3 grams of DuPont Ludox~ AS-40 colloidal silica were added while mulling. The mixture was then extruded into 1/16 inch cylindrical extrudates. The extrudates were dried overnight at 120-C and then calcined at 1010-C for 3 hours to produce an in-situ grown ZSM-5 catalyst precursor, Precursor B.
Exammle 49 An in-situ grown ZSM-5 catalyst was prepared by the following method: 100 grams of Precursor A from Example 47 were placed in the bottom of a 1 liter autoclave with 384 grams of water, 16.1 grams of a 50% NaOH solution, and 5.9 grams of n-propylamine. Crystallization was completed under autog~nollq pressure at 149-C for 6 hours with no additional nutrients. After synthesis, the extrudates were cooled to room temperature, washed and dried at 120-C. The extrudates were NH~t exchanged three times. A hybrid calcination followed which consisted of three hours in nitrogen at 482-C, with air slowly bled in to minimize the exotherm, then the temperature was raised to 537 C and held for six hours to produce an in-situ grown ZSM-5 catalyst, Catalyst T (greater than about 30% crystallinity).
Exam~le 50 An in-situ grown iron-containing ZSM-5 catalyst that should be effective in the mcthod of this invention may be - prepared by the following method: about 100 grams of Precursor B from Example 48 may be placed in the bottom of a 1 liter autoclave with about 384 grams of water, about 16.1 grams of a 50% NaOH solution, and about 5.9 grams of n-propylamine. Crystallization should be possible by treating the mixture under autogenous pressure at about 2 1 ~3~5 1 WO96/01689 I~
149-C for about 6 hours with no additional nutrients.
After cynthesis, the extrudates may be cooled to room t , ~LULe~ and then may be washed and may be dried at 120-C. The extrudates should be NH~ ~Yrh~ngr~ three times.
The illm exchanged extrudates may be hybrid ralcinr~d~
by treating them for about three hours in nitrogen at about 482-C, and then by slowly bleeding air in to m;nimize the exotherm that may be developed, then raising the temperature to 537"C and holding the extrudates at that temperature for about six hours.
-
4,406,859~; gSM-48 (U.S. Patent No. 4,397,827); ZSM-57 (U.S. Patent No. 4,046,685); and ZSM-58 (U.S. Patent No.
4,417,780).
A catalyst useful in the method of this invention may be prepared by combining a zeolite, such as ~ZSM-5, an iron salt or other iron containing _ ~, a high molecular weight, hydroxy functional silicone, such as Dow Corning ~6-2230 silicone resin, a suitable extrusion aid, such as methyl cellulose, and a suitable polar, water soluble carrier, such as methanol, ethanol, isopropyl alcohol, N-methyl pyrrolidone or a dibasic ester along with water asneeded, then forming the mixture into the desired shape, such as by extrusion, then simultaneously calcining and hydrothermally treating the formed material. One particular methyl cellulose that is effective as an extrusion aid in the method of this invention i8 a hydroxypropyl methyl cellulose, such as K75M Methocel~, available from Dow Ch~mic~l CO. Dibasic esters that are useful in this invention include dimethyl glutarate, dimethyl succinate, dimethyl adipate, and mixtures thereof, one example of which is DuPont Chemical Co. DBE, which typically comprises 50 to 75 percent dimethyl glutarate, 10 to 25 percent dimethyl adipate, 19 to 26 percent dimethyl succinate and less than 0.2 wt.% methanol. Other silicone resins that may be used in the method of this invention include those described in U.S. Patent No. 3,090,691.
The relative proportions of zeolite component and the support material on an anhydrous basis may vary widely with the zeolite content ranging from between 5 to 99 percent by weight and more usually in the range of 10 to 95 percent by weight, specifically from 20 to 9o percent by weight of the dry composite.
2 1 9395 ~
~ WO96~1689 r~
Original ions, e.g., alkali or alkaline earth metal, of the as-synthesized intermediate pore size material and any found in the zeolite/support material can be replaced in accordance with terhniq~C well known in the art, at least in part, by ion-exchanye with other ions. For the present catalyst composition, preferred replacing ions include hydL~g~n ions and hydL~gell precursor, e.g., ; ;nn ions. ZSM-5 in the hydrogen exchanged form is referred to herein as HZSM-5. Representative ion-exchange techniques are disclosed in a wide variety of patents including U.S. Patents 3,140,249: 3,140,251; and 3,140,253.
The desired iron loadiny on the zeolite -nent of the catalyst is O.Ol to 5 wt.%, e.g., at least 0.4 wt.~, e.g., at least 0.6 wt.%, e.g., at least 1 wt.%, e.g., at least 1.5 wt.~, preferably 2 wt.%, iron into the zeolite.
The catalyst may also optionally include another metal, such as a transition metal, preferably a noble metal, the combination of the metals being able to oxidize other undesirable -c present in the exhaust gas along with allowing the SCR of NOX. The metal may be at least one of copper, zinc, vanadium, chroïnium, r-nq~n~ce, cobalt, nickel, palladium, platinum, molybdenum, tungsten, sodium, potassium, magnesium, calcium, barium, cerium and mixtures thereof, with the noble metals, platinum, palladium and combinations of these, along with cerium, particularly preferred. The terms "metal" and "iron" as used herein are intended to include the elemental metal as well as metal oxides, metal sulfides, and other metal containing compounds.
After the int~ te pore size zeolites have been treated or modified to contain iron or an iron compound, they may be washed with water and dried at a temperature ranging from 65 C to 315~C. They may also be calcined or thermally treated in air, or in an inert gas, at temperatures ranging from 260~C to 925 C for periods of time ranging from 1 to 48 hours or more, typically at 538~C
2 ~ 939~ 1 WO 96/lll6X9 rc for 4 to 6 hours. ~hile suba ---phlric or superatmospheric can be employed for the thermal treatment, ~ Aric p~es~uL~ is preferred simply for reasons of convenience.
Catalysts of i L~ved selectivity and other beneficial properties, such as improved resistance to ageing in an atmosphere containing steam, can be obtained by subjecting the iron containing zeolite to at least one treatment with strea~s containing steam (hydrothermally treating the catalysts) at elevated temperatures ranging from 260-C to goo-C, e.g., 400~C to 850-C, e.g., 500~C to 750 c. The hydrothermal treatment may be accomplished in an atmosphere containing at least 20 ppm, 0.5%, 5, 10~, 20%, even up to 99% steam in air or some other suitable gas stream or in an ai - ~'~re consisting of steam or nitrogen and some other gas which is essentially inert to the zeolite. Optionally, more than one hydrothermal treatment may be used, specifically two, three, or more hydrothermal treatments at different temperatures, e.g., increasing temperatures, may be used. Examples of steaming conditions include 600 C
with 10 percent steam in air for 10 hours, 700 to 750-C
with 5 to 10 percent steam in air for 6 to 10 hours, and 850-C with 20 percent steam in air for 6 hours. Typical steaming conditions are described in U.S. Patent Nos.
4,429,176; 4,522,929; 4,594,146; and 4,6~3,492. The calcination and hydroth~r-l treatments of the catalysts are preferably combined into one treatment step and -conducted simultaneously.
As mentioned above, the iron may be added to the catalyst by ferrocene impregnation, ion-exchange under specified conditions, contacting the zeolite with an inorganic iron-containing salt or salt precursor, contacting the zeolite with another type of inorganic iron-containing compound, e.g., iron powder or iron oxide, or the iron may be incorporated into the zeolite during the in-situ production of the zeolite from zeolite seeds, silica, and clay.
2 1 9395 1~ WO9~0lC89 r~
_9_ Ferrocene impregnated catalysts may be prepared by contacting the zeolite with ferrocene which has been dissolved in a suitable solvent. Suitable solvents are those which dissolve the ferrocene and may then be removed from the impregnated zeolite under conditions sufficiently mild as to avoid causing the ferrocene to sublimate off the zeolite. Examples of suitable organic solvents include benzene, toluene, xylenes, and hexane among others. The impregnation is typically conducted for more than 4 hours, specifically from 4 hours to several days, more specifically from 6 hours to 100 hours. The impregnation is generally conducted at conditions cffective to achieve the desired iron loading or iron concentration on the zeolite.
The impregnation may occur either before or after the zeolite is combined with the support. For example, if the zeolite is first combined with the support and then impregnated, ferrocene that is deposited on the surface of the zeolite and on the support may be washed off using a solvent having an effective atomic diameter that is larger than the zeolite pore size, e.g., an organic solvent such as Tetralin~.
The impregnation may be conducted after first drying or dehydrating the zeolite. Also, the ferrocene solution may be preparcd using a water-free or dry solvent.
The impregnated zeolite is recovered by removing the solvent from the zeolite. It is desired to remove the solvent without causing the rerrocene to sublimate off the zeolite. One possible way i5 to evaporate the solvent at a temperature less than the ferrocene sublimation temperature, 100-C. This solvent removal may be done at superai _~h~ric pressure, if desired, or pressures ranging from sub~ ric to atmospheric. The recovered ferrocene impregnated zeolite then may be calcined at 450-C
to 550~C to oxidize the ferrocene and to convert the iron to its oxide.
21 ~3951 WO g6,0~68~ . ~ I .
Another catalyst comprises an inti ~';~te pore size zeolite which has been exposed to at leas~ one ion-exchange sequence under specific conditions, wherein the ion-exchange sequence comprises the steps of contacting the in~r~ te pore size zeolite with an aqueous solution of a ferrous, Fe(II), salt under suitable conditions, recovering the zeolite, and calcining the zeolite. The conditions include those effective to ~uba~dl,Lially prevent oxidation of the ferrous ion to the ferric form, such as using nitrogen, argon and the like inert gases to blanket the solution. The conditions also include stirring or mixing at a temperature of above 55-C, specifically above 65-C, or those temperatures effective to reduce the hydration sphere of the ferrous cation to a size small enough to enter the pores of the zeolite. The ferrous cation is reported to have an ionic radius in an aqueous solution of about 0.0000000006 meters (6 A) at 25'C, which is too large to enter ~SM-5 pores, which are slightly smaller than this. Increasing temperature is believed to reduce the size of the hydration sphere associated with the ferrous cation. For example, with increasing temperature, a ferrous ~ _ ', ferrous sulfate, changes from the heptahydrate form to the tetrahydrate form (at 56.6 C) and then to the monohydrate form (at 65-C~.
The ion-exchange may be conducted for more than 4 hours, e.g., from 4 hours to several days, e.g., from 6 hours to 100 hours. During the ion-exchange, the pH of the aqueous solution may be maintained between 1 and 4.~ or at a pH level effective to prevent precipitation of the ferrous salt.
It has been found that ferrous, Fe(II~, ions are more readily exchanged into the zeolite than ferric, Fe(III), ions.
Ferrous, ~e(II), salts useful in this invention include the water soluble salts, such as, ferrous ~mm~n;um sulfate, ferrous chloride, ferrous fluosilicate, ferrous hyposulfite, ferrous iodide, ferrous lactate, ferrous ~WO96101689 -ll- r~
nitrate, ferrous perchlorate, ferrous sulfate, and ferrous thiocyanate.
After the iron has been ion-oYrh~nqed into the zeolite, the zeolite may be recovered by cooling the aqueous solution below 55~C to 65-C, filtering the zeolite from the aqueous solution and washing the filtered zeolite with a neutral or slightly basic solvent, for example, an aqueous solvent with a pH of from 6 to 9, such as distilled or deionized water. The solvent washing may be conducted at conditions effective to avoid leaching the iron from the zeolite. The aqueous solution and the ion-exchanged zeolite need not be maintained under inert conditions after the solution has been cooled. The I~cuv~ed zeolite may be dried, calcined and hydrothermally treated as more fully described herein.
The ion-exchange sequence described above may be conducted at least once, e.g., at least twice, e.g., at least three times, e.g., four or more times.
Another method to incorporate iron onto the zeolite is to contact an into ~ te pore size zeolite with an iron salt or salt precursor. In this method, the iron salt may first be dissolved in water or another suitable solvent and then the zeolite may be contacted with the solution.
Alternatively, the iron salt and the zeolite, and any binder material desired, may be physically combined and then water or another suitable solvent added and the mixture recovered and formed, as desired. The formed material may be dried, calcined, or hydrothermally treated as is more fully described herein. A~ will be apparent to one skilled in the art, any method that is effective to contact the zeolite with the iron salt and to achieve a high degree of iron distribution on and inside the zeolite may be used, including, but not limited to an incipient wetness torhnique~
Suitable iron salts include all of the ferrous salts mentioned above, as well as ferric acetate, iron(III) benzoate, iron(III) cacodylate, iron(III) dichromate, WOs6~ 2 1 9 3 9 5 1 ~
iron(III) citrate, iron~III) fluoride, iron(III) fluosilicate, iron(III) formate, iron(III) glycelvL,~ h~te, iron(III) llydsogel, cyanide, iron(IlI) hydrosulfate, iron(III~ lactate, iron(III) malate, iron(III) oxalate, iron(III) orth~ te~ iron(III) hypophosphite~ iron(III) sulfide, iron(III) thiocyanate, ferric acetylacetonate, ferric ammoniumchloride, ferric chloride, iron(III) nitrate nanohydrate, iron~III) sulfate pentahydrate, i inm ferric sulfate, ferric bromide, ferric iodide, and any other ferrous, ferric, or other iron salts that are water soluble. Also included are precursors of all of the salts mentioned above.
The incorporation of iron onto the zeolite may be accomplished by contacting an intermediate pore size zeolite with an iron salt or salt precursor, such as those mentioned above. In this method, the iron salt may first be dissolved in water or another suitable carrier or solvent and then the zeolite may be contacted with the solution, recovered from the solution, dried and then bound 20 if desired. Alternatively, the iron salt and the zeolite, and any binder material desired, may be physically combined with water or another suitable carrier or solvent to produce a mixture and the mixture recovered and formed, such as by extrusion. The formed material may be dried, calcined, or hydrothermally treated as is more fully described herein. As will be apparent to one skilled in the art, any method that is effective to contact the zeolite with the iron salt may be used, including, but not limited to mulling or an incipient wetness techni~ue.
Yet another method that is suitable to add iron to the zeolite is to physically contact an intermediate pore size zeolite with an inorganic iron-containing compound, e.g., iron oxide. In this method, it is preferred to use a finely divided iron-containing compound, such as a fine pigment grade red iron oxide. It is also preferred to add a binder pLe~UL~VS to the physical mixture of the iron-containing compound and the zeolite and to form the ~ W096/016~ -13- P~~
physical mixture. After the desired shape has been formed, the i~on contacted zeolite may be calcined and hydrothermally treated as is more fully described herein.
Another catalyst may be prepared by in-situ crystallization of an ay~L~te~ e.g., a preformed clay E~.~Ley~te. The ay~L~te comprises four ~ A~ts: seeds of an int~ te pore size zeolite, e.g., ZSM-5 seeds, silica, e.g., a colloidal silica such as Ludox~ available from E. I. DuPont de Nemours & Co., clay, and iron oxide.
optionally, the aggregate can also include alumina.
Various terhni~lAc for preparing an in-situ crystallized zeolite are described in U.S. Patent Nos. 4,522,705;
4,091,007; and 4,800,187.
The zeolite may be prepared from a clay aggregate which comprises a non-clay added source of silica. The sources of silica in the reaction mixture may include both a clay and a non-clay source of silica, or a clay alone.
Non-clay sources of silica that can be employed in the synthesis are Ludox~, an aqueous dispersion of colloidal silica, water glass, sand, silica gel, fused silica, and finely-divided precipitated silicas, such as Hi-Sil, Quso, and Zeosil 100.
The clay cn~pon-Ant which is treated to form the zeolite-containing catalyst can be selected from the group consisting of kaolin, halloysite, montmorillonite, illite, and dickite, with kaolin preferred.
The preformed aggregate may be treated for one or more hours at a temperature sufficient to convert the clay into the me~k~nl in phase, e.g., greater than 927~C to 1000~C.
After the thermal treatment of the aggregate, the zeolite may be crystallized by treatment at a temperature of greater than 135'C, e.g., 149~C, in the presence of water, alkali metal cations, and optionally, a directing agent such as tetraalkylammonium ions, e.g., a tetraalkylammonium halide, such as tetrapropylammonium bromide, or a n-alkylamine, such as n-propylamine, with no additional nutrients for zeolite formation.
WO~0168~ 2 l 9 3 9 5 1 r~
The in-situ formed zeolite may be prepared from a aggregate comprising about 3-5% zeolite seeds, e.g., ZSM-5 seeds; 23-25~ silica, e.g. colloidal silica; 68-70% clay, e.g., kaolin clay; and 0.01-5$ metal oxide, e.g., iron oxide.
As noted above, the catalytic reduction of nitrogen oxides is substantially effected by the use of the present process. By substantially effected is meant a conversion of greater than 40, 75, 80, 85, 90, 95, or even 99% or more of the nitrogen oxides and the ammonia in the exhaust gas to innocuous ~ _ -c, such as nitrogen, through the use of this process. This is also referred to herein as conversion of a substantial portion of the N0x and ammonia in the exhaust gas to innocuouq compounds.
Exam~le 1 Base ZSM-5 A HZS~-5 sample, prepared according to U.S. Patent No.
3,702,886, was used as the reference sample and was used as the basis for all of the other examples.
Exam~le 2 Preparation of an iron containing ZSM-5 An iron containing ZSM-5 sample was prepared by the following method: lO0 g of distilled water was heated to about 85-C with constant stirring under a blanket of dry nitrogen. Approximately 0.11 g of ferrous sulfate and 5.1 g o~ the same HZSM-5 as Example l were added to the heated water. A solution p~ of about 2 was maintained by dropwise addition of nitric acid or ammonium hydroxide, as needed.
The exchange solution was maintained at about 85-C under a nitrogen blanket with continued stirring for approximately 17 hours. The solution was subsequently cooled to room temperature, filtered and washed with distilled water. The filtered solid was calcined in air for 8 hours at 538 C to produce the iron containing catalyst, Catalyst A. The iron loading of this catalyst as prepared is about 0.5 wt.~.
~ WO96~1689 2 1 9 3 9 5 ~
Example 3 Comparative testing against the base ZSM-5 In this example, the SCR activity of Catalyst A is compared with the base HZSM-5 catalyst from Example l. The catalyst samples were evaluated using a fixed bed quartz reactor operating between 250-550-C. The reactor inlet contained 500 ppm N0, 500 ppm NH" and 5 vol.% ~2 in a He carrier flowing at a constant gas hourly space velocity (GHSV) of 12,000 hr~1. The effluent from the reactor was cont;nuouCly monitored by non-dispersive infrared spectroscopy (NDIR) detectors. Catalyst activity results are reported below in Table l.
Table l Percent N in Feed Converted to N~
Tem~erature. ~C Base ZS~-5 Catalvst Catalvst A
550 89% 93%
455 100% 98%
400 lO0~ 98~
345 71~ 97%
250 26~ 92 Exam~le 4 Preparation of an Iron Containing ZSM-5 An iron containing ZSM-5 sample was prepared by the following method: a solution containing 25 g of the same HZSM-5 as Example l and 500 g of distilled water was heated to about 77 C with constant stirring under a blanket of dry argon. Approximately 0.3 g of ammonium ferrous sulfate was added to the heated solution. A solution pH of 3 was maintained by dropwise addition of nitric acid or ammonium hydroxide, as needed. The exchange solution was maintained at about 77 C under an argon blanket with continuous stirring for approximately 9 hours. The solution was subsequently cooled to room tcmperature, filtered and 21 93q51 washed with distilled water. The filtered solid was calcined in air $or 8 hours at 538 C to produce the iron c~nt~ining catalyst, Catalyst B. Ihe iron loading of this catalyst as prepared is about 0.5 wt.%.
ExamPle 5 Comparative testing against a base ZSM-5 In this example, the SCR activity of Catalyst B is compared with the base HZSM-5 catalyst from Example l. The catalyst samples were evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 2.
Table 2 Percent N in Feed Converted to N2 I~ _L~uLe. 'Ç Base ZSM-5 Çatalvst Çatalvst B
15 550 8g% 100%
455 100% 100%
400 '100% 100%
345 71% 100%
250 26% 90%
Exam~le 6 Preparation of an Iron Containing ZSM-5 An iron containing ZSM-5 sample was prepared by the following method: a solution containing 0.2354 g of ferrous acetate in 30 g distilled water was added to a flask containing 15 g of the same HZSM-5 as Example l at room te1.y~L~LuL~. The catalyst slurry was mixed for approxi~ately 2 hours and was air dried at room temperature for about 16 hours. The dried catalyst was calcined in air ~or 8 hours at 538-C to produce the iron containing catalyst, Catalyst C. The iron loading of this catalyst as prepared is about 0.5 wt.%.
2 1 ~3~5 1 ~ WO96/01689 ~ .iA
ExamPle 7 Comparative testing against a base ZSM-5 and Catalyst A
In this example, the SCR activity of Catalyst C is compared with the base HZSM-5 catalyst from Example 1 and Catalyst A as prepared in Example 2. The catalyst samples were evaluated using similar equipment and the same pLOCedu~e as Example 3. Catalyst activity results are reported below in Table 3.
Table 3 Percent N in Feed Converted to N2 TemPerature,~C Base Catalvst CatalYst A Catalvst C
550 89% 93% 89%
455 100% 98% 91%
400 100% 98% 91%
345 71% 97% 90%
250 26% 92% 85%
ExamPle 8 Preparation of an iron containing HZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: 7.6 g of the same HZSM-5 as that of Example 1 was heated in a stream of dry nitrogen to 375 C.
After this temperature was maintained for 4 hours, the catalyst was cooled, in a stream of dry nitrogen, to room temperature. A solution of 0.5 g of ferrocene (dicyclopentadienyliron) in 30 g dry benzene was then added to the calcined zeolite and the slurry allowed to mix on a roller for about 16 hours. The benzene was allowed to evaporate at room temperature to give a benzene/ferrocene wetted zeolite. This wet solid was then heated to a temperature that did not exceed lOO-C in a vacuum oven so as to remove the residual benzene. This dry catalyst was then calcined in a stream of air at about 450-C for about 6 Wo96~16~ 2 1 9 3 q 5 1 . ~
hours to produce the desired iron containing catalyst, Catalyst D. The iron loading of this catalyst is about 1.8 wt.~.
Exam~le 9 Catalytic evaluation of Catalyst D
In this example, the SCR activity of Catalyst D from Example 8 was evaluated. The catalyst sample was evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 4.
Tab~e 4 Percent N in Feed Converted to N~
T~nerature. ~C Catalvst D
550 9o~
400 98~
345 98%
250 95%
Exam~le lo Preparation of an iron containing HZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about lO g of the same H2SM-5 as that of Example 1 was heated in a stream o~ dry air to 375~C for 4 hours and then was cooled to room temperature. A solution of 0.1667 g of ferrocene (dicyclopentadienyliron) in 30 g dry toluene was then added to the dried zeolite and the slurry was mixed at room temperature overnight. Excess toluene was allowed to evaporate at room temperature to give a toluene/ferrocene wetted zeolite. The recovered solid was then calcined in a stream of dry air at about 538-C for about 6 hours to produce the desired iron containing catalyst, Catalyst E. The iron loading of this catalyst is about 0.45 wt.~.
~wo s6ml6ss -19- r~
ExamPle 11 Catalytic evaluation of Catalyst E
In this example, the SCR activity of Catalyst E from Example 10 was evaluated using similar ~li --L and the same procedure as Example 3. Catalyst activity results are reported below in Table 5.
Tab~e 5 Percent N in Feed Converted to N2 Tem~erature. ~C CatalYst E
455 99%
400 99%
345 98%
250 81%
Exam~le 12 Preparation of an iron containing HZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about 10 g of the same HZSM-5 as that of Example 1 was heated in a stream of dry air to 375~C for 4 hours and then was cooled to room temperature. A solution of 0.3331 g of ferrocene tdicyclopentadienyliron) in 30 g dry toluene was then added to the dried zeolite and the slurry was mixed at room temperature overnight. The slurry was filtered and washed once with 100 ml of Tetralin~ to remove excess ferrocene from the external surface of the zeolite. Excess Tetralin~ was, allowed to evaporate at room temperature to give a TetralinX/ferrocene wetted zeolite.
The recovered solid was then calcined in a stream of dry air at about 538'C for about 6 hours to produce the desired iron containing catalyst, Catalyst F. The iron loading of this catalyst is about 0.66 wt.%.
wo g6,0l689 2 1 9 3 9 5 1 P ~u~
Exam~le 13 Catalytic evaluation of Catalyst F
In this example, the SCR activity of Catalyst F from Example 12 was evaluated using similar e~ and the same ploceduLe as Example 3. Catalyst activity results are reported below in Table 6.
Table 6 Percent N in Feed Converted to N2 Tem~erature. ~C CatalYst F
455 98~
400 98%
345 96%
250 88%
Exam~le 14 Preparation of an iron containing HZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about 10 g of the same HZSN-5 as that of Example 1 was heated in a stream of dry air to 3~5-C for 4 hours and then was cooled to room temperature. A solution of 0.3331 g of ferrocene (dicyclopentadienyliron) in 30 g dry toluene was then added to the dried zeolite and the slurry was mixed at room temperature overnight. Excess toluene was allowed to evaporate at room temperature to give a toluene~ferrocene wetted zeolite. The recovered solid was then calcined in a stream of dry air at about 538-C for about 6 hours to produce the desired iron containing catalyst, Catalyst G. The iron loading of this catalyst is about 1.05 wt.%.
~ WO96~1689 Example 15 Catalytic evaluation of Catalyst G
In this example, the SCR activity of Catalyst G from Example 14 was evaluated using similar e~uipment and the same pLuCed~L- as Example 3. Catalyst activity results are reported below in Table 7.
Table 7 Percent N in Feed Converted to N2 Temperature. ~C CatalYst G
550 95%
455 98%
400 98%
345 97%
250 91%
Exam~le 16 Aging of the HZSM-5 catalysts The base HZSM-5 of Example 1 and Catalysts D through G
as prepared above in Examples 8, 10, 12, and 14 were hydrothcrmally aged. Approximately 5 g of each catalyst was placed in individual identical crucibles and put in a controlled al ~ re furnace. The furnace was continuously purged with air containing 20 wt.% water vapor. The samples were treated in this moist atmosphere at 850~C for 6 hours. The treated samples will be referred to as aged base HZSM-5, and aged Catalysts D through G.
Exam~le 17 Catalytic evaluation of aged base HZSM-5 In this example, the SCR activity of the aged base HZSM-5 from Example 16 was evaluated using similar ~cll; nt and the same procedure as Example 3. Catalyst activity results are reported below in Table 8.
W0~6~1689 r~u~
Table 8 Percent N in Feed Converted to N2 I~ ~Lur~. ~C A~ed base HZSM-5 Exam~le 18 Catalytic evaluation of aged Catalyst D
In this example, the SCR activity o~ the aged Catalyst D from Example 16 was evaluated using similar equipment and the same ~ ed~e as Example 3. Catalyst activity results are reported below in Table 9.
Table 9 Percent N in Feed Converted to ~2 Te~era~e. ~C Aqed Catalvst D
550 g8%
455 100%
400 100%
Exam~le 19 Catalytic evaluation of aged Catalyst E
In this example, the SCR activity o~ the aged Catalyst E from Example 16 was evaluated using si~ilar ~ and the same procedure as Example 3. Catalyst activity results are reported below in Table 10.
_ _ _ _ _ _ _ _ .. . . . _ . . _ ...
~ W096l0l68~ -23- I~
Tahle 10 Percent N in Feed Converted to N2 Tem~erature, ~C Aaed Catalvst E
550 98%
455 100~
400 99%
345 88~
250 37%
ExamPle 20 Catalytic evaluation of aqed Catalyst F
In this example, the SCR activity of the aged Catalyst F from Example 16 was evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 11.
Table 11 Percent N in Feed Converted to N2 TP~n~rature. ~C A~ed CatalYst F
550 9g%
455 99%
400 92%
345 57%
250 27%
Exam~le 21 Catalytic evaluation of aged Catalyst G
In this example, the SC~ activity of the aged Catalyst G from Example 16 was evaluated using similar equipment and the same procedure as Examplc 3. Catalyst activity results are reported below in Table 12.
WO 9~11689 2 1 9 3 9 5 1 "~ J, ~
Table 12 Percent N in Feed Converted to N2 Te~nerature. 'C A~ed Catalvst G
550 97%
455 100~
400 99%
ExamPle 22 Preparation of an iron containing ZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about 20 g of illm iron(III~ sulfate was dissolved in 74 g distilled water. This solution was added to about 120 g of the base HZSM-5 and the slurry was 15 mixed at about room temperature and was then dried at about lOO-C overnight. Approximately 10 g of the dri.ed, impregnated solid was then calcined in air at about 600 C
with about 10% steam for about 10 hours to produce the desired iron containing catalyst, Catalyst ~. The iron loading of this catalyst is about 2 wt.~.
ExamPle 23 Catalytic evaluation of Catalyst H
In this example, the SCR activity of Catalyst H from Example 22 was evaluated using similar equipment and the 25 same procedure as Example 3. Catalyst activity results are reported below in Table 13.
~ WOg610168g IR,~ el Table 13 Percent N in Feed Converted to N, T~nerat~re. ~C Catalvst H
550 76%
400 99%
Exam~le 24 Preparation of an iron containing ZSM-5 An iron containing ZSM-5 catalyst was prepared by the following method: about 1.5 g of iron~III) nitrate was dissolved in 6.5 g distilled water. This solution was added to about 10 g of the base HZSM-.S and the slurry was mixed at about room temperature and was then dried at about lOO-C overnight. The dried, impregnated solid was then calcined in air at about 600~C with about 10~ steam for about 10 hours to produce the desired iron containing catalyst, Catalyst I. The i3'0n loading of this catalyst is about 2 wt.~.
ExamPle 25 Catalytic evaluation of Catalyst I
In this example, the SCR activity of Catalyst I from Example 24 was evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 14.
WO96/01~89 l~1 Table l~
Percent N in Feed Converted to N
TeDDerature. 'C Catalvst I
550 86%
455 97%
400 99%
250 92%
Exam~le 26 Preparation of a silica bound-iron containing ~SM-5 A silica bound iron containing ~SM-5 catalyst was prepared by the following method: about lO0 g of the dried, iron impregnated HZSM-5 catalyst prepared in Example 22 was dry blended with about 22 g of Dow Corning siliconc resin (Q6-2230~ and about 6.8 g of X75M Methocel~
(available from Dow Ch~mic~l Co.~. Approximately 89 ml of a l:l by volume mixture of water:isopropyl alcohol was then added to the dry blended powder. The slurry was mulled for a minimum of 5 minutes until the mixture reached the proper consistency for extrusion. The mixture was then extruded into l/16 inch diameter cylindrical strands ir a screw extruder and was allowed to dry. Approximately lO g of the dried extrudate was calcined in air at 600-C with lO~ steam for lO hours to produce the desired iron containing catalyst, Catalyst J. The iron loading of this catalyst is about 2 wt.~.
Exam~le 27 Catalytic evaluation of Catalyst J
In this example, the SCR activity of Catalyst J from ExaDple 26 was evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 15.
2 t 93~51 ~ WO961~1689 r~l,u~
Table 15 Percent N in Feed Converted to N2 ~em~erature. ~C Catalyst J
550 74%
455 97%
400 100%
345 99%
250 88%
Examl~le 28 Comparative testing after steaming In this example, the SCR activity of the base HZSM-5 and Catalysts H, I, and J are compared after each of the catalyst were treated with 100% steam at 700~C for 7 hours.
The catalyst samples were evaluated using similar equipment and the same procedure as Example 3. Catalyst activity results are reported below in Table 16.
Table 16 Percent N in Feed Converted to N2 Steamed Catalvsts Tem~.. ~C Base Catalvst Catalvst H CatalYst I CatalYst J
550 56% 92% 98% 92%
455 46~100% 98% 100%
400 36%100% 97% 100%
345 zo%1~0% 99% 100%
250 6% 96% 77% 95%
Exam~le 29 An iron containing ZSM-5 catalyst was prepared by the following method: Approximately 1.5g of iron (III) nitrate was dissolved in 6.5g distilled water. This solution was _ _ _ _ _ _ _ _ _ _ _ _ _ , .. . . .. . . . . . . . . .
W0~6~l6 added to about lOg of the base HZSM-5 and the resulting slurry was mixed and dried at room temperature overnight.
The dried inpregnated solid was then calcined in air at 600-C with 10% steam for 10 hours to produce the desired catalyst, Catalyst R. The nominal iron loading of this sample is about 2 wt%.
Exam~le 30 In this example, the SCR activity of Catalyst R from Example 29 was evaluated using similar equipment and the same reaction conditions as Example 3. See Table 17 below.
Table 17 Percent N in Feed Converted to N2 Temperature, 'C Catalyst K
550 86~
455 97%
400 99%
345 99%
250 92%
Exam~le 31 In this example Catalyst K was hydrothermally treated at 850-C in air containing 20% steam for 6 hours.
This catalyst is re~erred to as Catalyst L.
~Y~le 32 In this example, the SCR activity of the hydroth~rr=lly treated cdtalyst~ Cataly5t L, from Ex~mple 31 was evaluated using similar equipment the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 18.
21 93q51 ~ W096l0l689 l~ll. .
TAhle 18 Percent N in Feed Converted to N2 Temperature, ~C Hydroth~rr-lly treated Catalyst L
550 ~ g6%
455 g9%
400 9g%
EYAmnle 33 In this example the hydrothermally treated catalyst, Catalyst L, from Example 31 was aged at 700-C in 100% steam for 7 hours. This catalyst is referred to as Catalyst M.
Exa~le 34 In this example, the SCR activity of the aged, hydro~h~r~lly treated catalyst, Catalyst M, from Example 33 was evaluated using similar equipment and the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 19.
Table 19 Percent N in Feed Converted to N2 Temperature, ~C Aged Catalyst o~ Example 33 550 99~
455 96%
400 95%
345 93%
250 82~
WO9610168g 21~3~51 p ,,~ ~
Exam~le 35 In this example the aged, hydrothermally treated catalyst, Catalyst ~, from Example 33 was further aged at 900-C in lO0~ steam for 7 hours. This catalyst is referred to as Catalyst N.
ExamPle 36 In this example, the SCR activity of the aged, hydrothermally treated catalyst, Catalyst N, from Example 35 was evaluatad using similar equipment and the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 20.
Table 20 Percent N in Feed Converted to N2 Temperature, ~C Aged Catalyst of Example 35 550 86~
455 71%
ioo 53%
345 28%
250 ll~
ExamPle 37 In this example Catalyst K was aged at 700 C in 100%
steam for 7 hours without the intermediate hydrothermal treatment. This catalyst will be referred to as Catalyst 0.
Exa~le 38 In this example, the SCR activity of the aged catalyst, Catalyst 0 from Example 37 was evaluated using similar equipment and the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 21.
.. ..... .. _ _ _ _ _ . _ ~ W096l0~689 ~1/ L ~!,.l Table 21 Percent N in Feed Converted to N2 T~ tUL~, ~C Aged Catalyst of Example 37 550 98%
455 98%
400 97%
345 99%
250 77%
Exam~le 39 In this example the aged catalyst, Catalyst 0, from Example 37 was further aged at 900-C in 100% steam for 7 hours. This catalyst will be referred to as Catalyst P.
Exam~le 40 In this example, the SCR activity of the twice-aged catalyst, Catalyst P, from Example 39 was evaluated using similar equipment and the same reaction conditions as Example 3. Catalyst activity results are reported below in Table 22.
Table 22 Percent N in Feed Converted to N2 Temperature, ~C Aged Catalyst of Example 39 550 56%
455 32%
400 21%
345 14%
250 8%
21 g~q51 WO961~1689 r~a,~
Exam~le 41 A ZSN-5 catalyst was prepared by the i'ollowing ~ethod:
99 grams of calcined ZSM-5 were mixed in a muller with 20 grams of Dow Corning Q6-2230 silicone resin, and 6.5 grams of Dow ~ht~ic~l Co. K75M Methocel~. To this dry blend, 52.9 grams of distilled water znd 23.l grams of E. I.
DuPont de Nemours & Co. DBE (dibasic ester) were added while mulling. The mixture was then extruded to form l/16 inch cylindrical extrudates. The extrudates were dried overnight at lZO-C and then calcined at 600-C in 10% steam for lO hours to produce a ZSM-5 containing catalyst. This catalyst is referred to herein as Catalyst Q.
F~nle 42 An iron containing ZSM-5 sample was prepared by the following method: 99 grams of calcined ZSM-5 were mixed in a muller with 20 grams of Dow Corning Q6-2Z30 silicone resin, 6.5 grams of Dow K75M Methocel~, and 3.2 grams of iron oxide, Fe20~. To this dry blend, 52.9 grams of distilled water and 23.l grams of DuPont DBE (dibasic ester) were added while mulling. The mixture was then formed into 1~16 inch cylindrical extrudates. The extrudates were dried overnight at 120-C and then calcined at 600 C in 10% steam for lO hours to produce an iron containing catalyst, Catalyst R.
Exam~le 43 In this example, the SCR activity of Catalyst Q is compared with the SCR activity of Catalyst R. The catalyst samples were evaluated using a fixed-bed quartz reactor operating between 250 and 550~C. The reactor was loaded with 2.75 grams of catalyst with inlet qases consisting of 500 ppm N0, 500 ppm NH3, and 5% 0~ in a N2 carrier flowing at a constant flow rate of l,ooo cc/min. The effluent from ~ W096l01689 2 1 9395 I p the reactor was contin~n~ly monitored by FTIR (Fourier Transform Infrared) analysis. Catalyst activity results are summarized below in Table 23.
T~hle 23 Net N0 Conversion, %
Tem~erature. ~CCatalvst 0 CatalYst R
550 71% 92 454 74% 96%
398 72~ 96%
343 60% 96~
250 25% 65%
Exammle 44 An iron containing ZSM-5 sample was prepared by the following method: 99 grams of calcined ZSM-5 were mixed in a muller with 20 grams of Dow Corning Q6-2230 silicone resin, 6.5 grams of Dow ~75M Methocel~, and 0.32 grams of iron oxide, Fe203. To this dry blend, 52.9 grams of distilled water and 23.1 grams of DuPont DBE (dibasic ester) were added while mulling. The mixture was then formed into 1/16 inch cylindrical extrudates. The extrudates were dried overnight at 120-C and then calcined at 600-C in 10~ steam for 10 hours to produce an iron containing catalyst, Catalyst S.
Exam~le 45 In this example, the SCR activity of Catalyst Q is compared with the SCR activity of Catalyst S. The catalyst samples were evaluated using a fixed-bed quartz reactor operating between 250 and 550-C. The reactor was loaded with 2.75 grams of catalyst with inlet gases consisting of WOg6l~l689 2 1 9 3 9 5 ~
500 ppm N0, 500 ppm NH3, and 5% ~2 in a N2 carrier flowing at a constant flow rate of 1,000 cc~min. The effluent from the reactor was continuously monitored by FTIR ~Fourier Transform Infrared) analysis. Catalyst activity results are summarized below in Table 24.
T~hle 24 Net N0 Conversion, %
Tem~erature. 'C CatalYst Q CatalYst S
550 71% ~4%
454 74% S6%
398 72% 87 343 60% 82 250 25% 40 ~xam~le 46 A component of the in-situ grown ZSM-5 clay aggregate catalyst precursor was prepared by mixing 140 grams of calcined ZSM-5 seeds with 1~60 grams of kaolin clay (Kaopaque lOS, a Georgia kaolin clay, Dry Branch Chemical Co., Dry Branch, GA). The mixed cu~ olle.lLs will be referred to herein as Component A.
Exam~le 47 An in-situ grown ZSM-5 clay aggregate catalyst precursor was prepared by mixing 75.9 grams of Component A
from Example 46 with 7.6 grams of Dow Chemical Co. K75M
Methocel~ in a muller. To this dry blend, 60.3 grams of E.
I. DuPont de Nemours & Co. Ludox~ AS-40 colloidal silica were added while mulling. The mixture was then extruded into 1/16 inch cylindrical extrudates. The extrudates were dried overnight at 120-C and then calcined at lOlO-C for 3 hours to produce an in-situ grown ZSM-5 catalyst precursor, Precursor A.
... .. . , . . , _ _ _ _ _ . _ ~ WO96tO1689 Exam~le 48 An iron containing in-situ grown ZSM-5 clay aggregate catalyst ~e~ul~oI was prepared by mixing 75.9 grams of C~ J~L A from Example 46 with 7.6 grams of Dow ~75M
Methocel~ and 3.6 grams of Fe203 in a muller. To this dry blend, 60.3 grams of DuPont Ludox~ AS-40 colloidal silica were added while mulling. The mixture was then extruded into 1/16 inch cylindrical extrudates. The extrudates were dried overnight at 120-C and then calcined at 1010-C for 3 hours to produce an in-situ grown ZSM-5 catalyst precursor, Precursor B.
Exammle 49 An in-situ grown ZSM-5 catalyst was prepared by the following method: 100 grams of Precursor A from Example 47 were placed in the bottom of a 1 liter autoclave with 384 grams of water, 16.1 grams of a 50% NaOH solution, and 5.9 grams of n-propylamine. Crystallization was completed under autog~nollq pressure at 149-C for 6 hours with no additional nutrients. After synthesis, the extrudates were cooled to room temperature, washed and dried at 120-C. The extrudates were NH~t exchanged three times. A hybrid calcination followed which consisted of three hours in nitrogen at 482-C, with air slowly bled in to minimize the exotherm, then the temperature was raised to 537 C and held for six hours to produce an in-situ grown ZSM-5 catalyst, Catalyst T (greater than about 30% crystallinity).
Exam~le 50 An in-situ grown iron-containing ZSM-5 catalyst that should be effective in the mcthod of this invention may be - prepared by the following method: about 100 grams of Precursor B from Example 48 may be placed in the bottom of a 1 liter autoclave with about 384 grams of water, about 16.1 grams of a 50% NaOH solution, and about 5.9 grams of n-propylamine. Crystallization should be possible by treating the mixture under autogenous pressure at about 2 1 ~3~5 1 WO96/01689 I~
149-C for about 6 hours with no additional nutrients.
After cynthesis, the extrudates may be cooled to room t , ~LULe~ and then may be washed and may be dried at 120-C. The extrudates should be NH~ ~Yrh~ngr~ three times.
The illm exchanged extrudates may be hybrid ralcinr~d~
by treating them for about three hours in nitrogen at about 482-C, and then by slowly bleeding air in to m;nimize the exotherm that may be developed, then raising the temperature to 537"C and holding the extrudates at that temperature for about six hours.
-
Claims (10)
1. A catalyst that is useful for treating an exhaust gas comprising NOx and ammonia, the catalyst comprising an intermediate pore size zeolite and iron or an iron compound that has been hydrothermally treated, the hydrothermal treatment and the iron concentration being effective to produce a catalyst that is capable of converting at least 75 percent of the NOx and ammonia present in the exhaust gas after the catalyst has been treated in 100 percent steam at a temperature of 700°C for 10 hours.
2. The catalyst of claim 1, wherein the catalyst is bound with silica, zirconia, titania, and combinations thereof.
3. The catalyst of claims 1 and 2, wherein the catalyst has been prepared by the impregnation of the intermediate pore size zeolite with ferrocene in a solvent.
4. The catalyst of claims 1 and 2, wherein the catalyst has been prepared by ion-exchanging iron in an aqueous solution onto the intermediate pore size zeolite under conditions effective to allow the iron to enter the pores of the zeolite. the ion-exchange conditions being further effective to maintain the iron in solution during the ion-exchange treatment, the conditions still further being effective to mantain the iron at a valence of 2 during the ion-exchange treatment.
5. The catalyst of claims 1 and 2, wherein the catalyst has been prepared by contacting the intermediate pore size zeolite with an iron salt or salt precursor in a suitable solvent for the salt or salt precursor.
6. The catalyst of claim 2, wherein the catalyst has been prepared by preparing a physical mixture of dry intermediate pore size zeolite, binder, and iron oxide and then forming the physical mixture into the desired shape.
7. The catalyst of claim 2, wherein the catalyst has been prepared by combining ZSM-5 seeds, silica, clay, and iron oxide into an aggregate; calcining the aggregate at a temperature of at least 1000°C; and crystallizing zeolite in the aggregate by heating the calcined aggregate to a temperature greater than 135°C (275°F) in the presence of caustic, and optionally, at least one organic directing agent.
8. The catalyst of claims 1 through 7, wherein the catalyst has been hydrothermally treated in an atmosphere of up to 100 percent steam at a temperature of from 400°C
to 850°C.
to 850°C.
9. A process for treating exhaust gas comprising NOx and ammonia comprising contacting the exhaust gas with the catalyst of claims 1 through 8 under conditions effective for the conversion of at least a portion of the NOx and ammonia to innocuous compounds.
10. The process of claim 9, wherein the contacting conditions comprise a temperature of from 200°C to 600°C, a pressure of from 34.5 to 3450 kPaa, and at a gas hourly space velocity (GHSV) of 1,000 to 100,000 hr-1.
Applications Claiming Priority (12)
Application Number | Priority Date | Filing Date | Title |
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US271,686 | 1988-11-16 | ||
US271,685 | 1988-11-16 | ||
US271,693 | 1994-07-07 | ||
US08/271,692 US5451387A (en) | 1994-07-07 | 1994-07-07 | Selective catalytic reduction of nitrogen oxides using an iron impregnated zeolite catalyst |
US271,692 | 1994-07-07 | ||
US271,694 | 1994-07-07 | ||
US08/271,685 US5589147A (en) | 1994-07-07 | 1994-07-07 | Catalytic system for the reducton of nitrogen oxides |
US08/271,693 US5520895A (en) | 1994-07-07 | 1994-07-07 | Method for the reduction of nitrogen oxides using iron impregnated zeolites |
US08/271,694 US5482692A (en) | 1994-07-07 | 1994-07-07 | Selective catalytic reduction of nitrogen oxides using a ferrocene impregnated zeolite catalyst |
US08/271,686 US5552129A (en) | 1994-07-07 | 1994-07-07 | Catalytic system for the reduction of nitrogen oxides |
US33561794A | 1994-11-08 | 1994-11-08 | |
US335,617 | 1994-11-08 |
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CA002193951A Abandoned CA2193951A1 (en) | 1994-07-07 | 1995-07-05 | Catalytic system for the reduction of nitrogen oxides |
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EP (1) | EP0935498A1 (en) |
AU (1) | AU687582B2 (en) |
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CN103140275A (en) * | 2011-08-08 | 2013-06-05 | 雅盖隆大学 | Catalyst for direct decomposition of nitric oxide and method of manufacturing the catalyst |
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GB9802504D0 (en) | 1998-02-06 | 1998-04-01 | Johnson Matthey Plc | Improvements in emission control |
US8833062B1 (en) | 2013-03-15 | 2014-09-16 | Daimier Ag | Catalytic reduction of NOx |
DE10020100A1 (en) * | 2000-04-22 | 2001-10-31 | Dmc2 Degussa Metals Catalysts | Process and catalyst for the reduction of nitrogen oxides |
US6914026B2 (en) † | 2001-09-07 | 2005-07-05 | Engelhard Corporation | Hydrothermally stable metal promoted zeolite beta for NOx reduction |
DE10226461A1 (en) † | 2002-06-13 | 2004-01-22 | Uhde Gmbh | Method and apparatus for reducing the content of NOx and N2O in gases |
EP1810751A1 (en) | 2006-01-20 | 2007-07-25 | Universität Karlsruhe (TH) | Method for preparing an iron-containing SCR-catalyst |
DK2517778T4 (en) * | 2007-04-26 | 2021-03-08 | Johnson Matthey Plc | TRANSITION METAL / AEI-ZEOLITE SCR CATALYST |
US7695703B2 (en) | 2008-02-01 | 2010-04-13 | Siemens Energy, Inc. | High temperature catalyst and process for selective catalytic reduction of NOx in exhaust gases of fossil fuel combustion |
CN103657742B (en) * | 2012-09-07 | 2016-01-13 | 中国石油化工股份有限公司 | A kind of iron ion exchanges the preparation method of modified molecular screen |
US8850802B1 (en) | 2013-03-15 | 2014-10-07 | Daimler Ag | Catalytic reduction of NOx |
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US4952385A (en) * | 1987-03-02 | 1990-08-28 | Georgia Tech Research Corp. | Ferrisilicate molecular sieve and use as a catalyst |
US5223236A (en) * | 1988-12-16 | 1993-06-29 | Tosoh Corporation | Method for exhaust gas cleaning |
US5271913A (en) * | 1989-12-28 | 1993-12-21 | Mitsubishi Jukogyo Kabushiki Kaisha | Denitration catalyst for high-temperature exhaust gas |
US5248643A (en) * | 1992-11-23 | 1993-09-28 | Corning Incorporated | Mixed zeolites and method for producing same |
-
1995
- 1995-07-05 EP EP95924763A patent/EP0935498A1/en not_active Withdrawn
- 1995-07-05 CA CA002193951A patent/CA2193951A1/en not_active Abandoned
- 1995-07-05 AU AU29149/95A patent/AU687582B2/en not_active Ceased
- 1995-07-05 WO PCT/US1995/008253 patent/WO1996001689A1/en not_active Application Discontinuation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103140275A (en) * | 2011-08-08 | 2013-06-05 | 雅盖隆大学 | Catalyst for direct decomposition of nitric oxide and method of manufacturing the catalyst |
CN103140275B (en) * | 2011-08-08 | 2015-09-23 | 雅盖隆大学 | For nitrogen oxide Direct Resolution catalyst and produce the method for this catalyst |
Also Published As
Publication number | Publication date |
---|---|
WO1996001689A1 (en) | 1996-01-25 |
EP0935498A1 (en) | 1999-08-18 |
AU687582B2 (en) | 1998-02-26 |
EP0935498A4 (en) | 1999-09-15 |
AU2914995A (en) | 1996-02-09 |
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