CA2069851A1 - Linear viscoelastic aqueous liquid automatic dishwasher detergent composition - Google Patents

Linear viscoelastic aqueous liquid automatic dishwasher detergent composition

Info

Publication number: CA2069851A1
Authority: CA; Canada
Prior art keywords: composition; alkali metal; salt; fatty acid; sodium
Prior art date: 1991-11-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2069851

Other languages

English (en)

French (fr)

Inventor

Makarand Shevade

Nagaraj S. Dixit

Divaker Kenkare

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Colgate Palmolive Co

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-11-08

Filing date

1992-05-28

Publication date

1993-05-09

1992-05-28 Application filed by Individual filed Critical Individual

1993-05-09 Publication of CA2069851A1 publication Critical patent/CA2069851A1/en

Status Abandoned legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 166
239000003599 detergent Substances 0.000 title claims abstract description 46
239000007788 liquid Substances 0.000 title claims abstract description 16
150000003839 salts Chemical class 0.000 claims abstract description 43
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 39
239000000194 fatty acid Substances 0.000 claims abstract description 39
229930195729 fatty acid Natural products 0.000 claims abstract description 39
239000011734 sodium Substances 0.000 claims abstract description 32
239000002562 thickening agent Substances 0.000 claims abstract description 29
150000004665 fatty acids Chemical class 0.000 claims abstract description 27
229920002125 Sokalan® Polymers 0.000 claims abstract description 23
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 19
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 12
239000011591 potassium Substances 0.000 claims abstract description 12
229910052700 potassium Inorganic materials 0.000 claims abstract description 12
239000007787 solid Substances 0.000 claims abstract description 11
239000004584 polyacrylic acid Substances 0.000 claims abstract description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
-1 alkali metal tripolyphosphate Chemical class 0.000 claims description 36
239000007844 bleaching agent Substances 0.000 claims description 29
229910052783 alkali metal Inorganic materials 0.000 claims description 27
239000000460 chlorine Substances 0.000 claims description 24
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 23
229910052801 chlorine Inorganic materials 0.000 claims description 23
150000001340 alkali metals Chemical class 0.000 claims description 14
238000005191 phase separation Methods 0.000 claims description 14
150000001875 compounds Chemical class 0.000 claims description 13
239000006260 foam Substances 0.000 claims description 13
235000019832 sodium triphosphate Nutrition 0.000 claims description 13
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 12
229910052751 metal Chemical class 0.000 claims description 11
239000002184 metal Chemical class 0.000 claims description 11
239000008346 aqueous phase Substances 0.000 claims description 8
150000004668 long chain fatty acids Chemical class 0.000 claims description 8
229920000058 polyacrylate Polymers 0.000 claims description 8
229910001415 sodium ion Inorganic materials 0.000 claims description 8
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 7
229920001519 homopolymer Polymers 0.000 claims description 7
229910001414 potassium ion Inorganic materials 0.000 claims description 7
239000011149 active material Substances 0.000 claims description 5
230000000994 depressogenic effect Effects 0.000 claims description 5
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 5
239000005708 Sodium hypochlorite Substances 0.000 claims description 3
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 3
150000008041 alkali metal carbonates Chemical class 0.000 claims description 3
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 3
230000008719 thickening Effects 0.000 claims description 3
239000003849 aromatic solvent Substances 0.000 claims description 2
235000011180 diphosphates Nutrition 0.000 claims description 2
239000000049 pigment Substances 0.000 claims description 2
239000003205 fragrance Substances 0.000 claims 2
239000000975 dye Substances 0.000 claims 1
229910052708 sodium Inorganic materials 0.000 abstract description 16
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 15
235000021355 Stearic acid Nutrition 0.000 abstract description 14
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract description 14
239000008117 stearic acid Substances 0.000 abstract description 14
239000002245 particle Substances 0.000 abstract description 12
239000007791 liquid phase Substances 0.000 abstract description 9
238000010348 incorporation Methods 0.000 abstract description 7
238000004140 cleaning Methods 0.000 abstract description 4
238000009472 formulation Methods 0.000 description 27
239000000047 product Substances 0.000 description 27
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
239000004615 ingredient Substances 0.000 description 17
238000000034 method Methods 0.000 description 16
239000004094 surface-active agent Substances 0.000 description 16
229920000642 polymer Polymers 0.000 description 15
238000002156 mixing Methods 0.000 description 14
239000004480 active ingredient Substances 0.000 description 13
JVTIXNMXDLQEJE-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate 2-octanoyloxypropyl octanoate Chemical compound C(CCCCCCC)(=O)OCC(C)OC(CCCCCCC)=O.C(=O)(CCCCCCCCC)OCC(C)OC(=O)CCCCCCCCC JVTIXNMXDLQEJE-UHFFFAOYSA-N 0.000 description 12
239000000839 emulsion Substances 0.000 description 12
239000006185 dispersion Substances 0.000 description 11
229960003975 potassium Drugs 0.000 description 9
239000002253 acid Substances 0.000 description 8
125000004432 carbon atom Chemical group C* 0.000 description 7
238000004851 dishwashing Methods 0.000 description 7
239000003381 stabilizer Substances 0.000 description 7
NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 6
229910052910 alkali metal silicate Inorganic materials 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 6
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
239000012071 phase Substances 0.000 description 6
235000011121 sodium hydroxide Nutrition 0.000 description 6
AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 6
150000002148 esters Chemical class 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
150000002739 metals Chemical class 0.000 description 5
230000000087 stabilizing effect Effects 0.000 description 5
238000003860 storage Methods 0.000 description 5
238000010521 absorption reaction Methods 0.000 description 4
239000000654 additive Substances 0.000 description 4
239000002518 antifoaming agent Substances 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
239000000499 gel Substances 0.000 description 4
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 4
239000011347 resin Substances 0.000 description 4
229920005989 resin Polymers 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 3
235000021314 Palmitic acid Nutrition 0.000 description 3
239000004698 Polyethylene Substances 0.000 description 3
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
238000010936 aqueous wash Methods 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
238000004132 cross linking Methods 0.000 description 3
239000003431 cross linking reagent Substances 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
239000003112 inhibitor Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
239000000178 monomer Substances 0.000 description 3
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
229920000573 polyethylene Polymers 0.000 description 3
238000000518 rheometry Methods 0.000 description 3
239000000344 soap Substances 0.000 description 3
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
230000035882 stress Effects 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
ATTZFSUZZUNHBP-UHFFFAOYSA-N Piperonyl sulfoxide Chemical compound CCCCCCCCS(=O)C(C)CC1=CC=C2OCOC2=C1 ATTZFSUZZUNHBP-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
239000004115 Sodium Silicate Substances 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
229930006000 Sucrose Natural products 0.000 description 2
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 2
229940063655 aluminum stearate Drugs 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
230000008901 benefit Effects 0.000 description 2
229960003237 betaine Drugs 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
229920006037 cross link polymer Polymers 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
239000012530 fluid Substances 0.000 description 2
238000005187 foaming Methods 0.000 description 2
238000001879 gelation Methods 0.000 description 2
230000036571 hydration Effects 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
230000005764 inhibitory process Effects 0.000 description 2
239000012669 liquid formulation Substances 0.000 description 2
230000007774 longterm Effects 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 2
230000003472 neutralizing effect Effects 0.000 description 2
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
150000003014 phosphoric acid esters Chemical class 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
159000000001 potassium salts Chemical class 0.000 description 2
238000000926 separation method Methods 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
229910052911 sodium silicate Inorganic materials 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000005720 sucrose Substances 0.000 description 2
239000003760 tallow Substances 0.000 description 2
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
229940095095 2-hydroxyethyl acrylate Drugs 0.000 description 1
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical class CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
239000004925 Acrylic resin Substances 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
235000021357 Behenic acid Nutrition 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
235000010469 Glycine max Nutrition 0.000 description 1
244000068988 Glycine max Species 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
241001465754 Metazoa Species 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
239000004111 Potassium silicate Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
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HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
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UBNVDFUEPGQZQS-UHFFFAOYSA-N acetic acid;n,n-dimethyldodecan-1-amine Chemical compound CC([O-])=O.CCCCCCCCCCCC[NH+](C)C UBNVDFUEPGQZQS-UHFFFAOYSA-N 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
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238000005054 agglomeration Methods 0.000 description 1
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229910001413 alkali metal ion Inorganic materials 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
239000008135 aqueous vehicle Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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MWOBKFYERIDQSZ-UHFFFAOYSA-N benzene;sodium Chemical compound [Na].C1=CC=CC=C1 MWOBKFYERIDQSZ-UHFFFAOYSA-N 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
239000007767 bonding agent Substances 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
229960001631 carbomer Drugs 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
238000010382 chemical cross-linking Methods 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
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238000004040 coloring Methods 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
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229910052906 cristobalite Inorganic materials 0.000 description 1
230000000368 destabilizing effect Effects 0.000 description 1
CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
DWVAEDTZGRQKKP-UHFFFAOYSA-N diethyl(tetradecyl)azanium;pentanoate Chemical compound CCCCC([O-])=O.CCCCCCCCCCCCCC[NH+](CC)CC DWVAEDTZGRQKKP-UHFFFAOYSA-N 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
239000012467 final product Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
235000013373 food additive Nutrition 0.000 description 1
239000002778 food additive Substances 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
BXFPJFWOBWLKSR-UHFFFAOYSA-N hexadecyl(dimethyl)azanium;hexanoate Chemical compound CCCCCC([O-])=O.CCCCCCCCCCCCCCCC[NH+](C)C BXFPJFWOBWLKSR-UHFFFAOYSA-N 0.000 description 1
150000004687 hexahydrates Chemical class 0.000 description 1
229940005740 hexametaphosphate Drugs 0.000 description 1
238000011086 high cleaning Methods 0.000 description 1
230000003165 hydrotropic effect Effects 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000000463 material Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000002991 molded plastic Substances 0.000 description 1
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
229940098695 palmitic acid Drugs 0.000 description 1
239000002304 perfume Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
239000001508 potassium citrate Substances 0.000 description 1
229960002635 potassium citrate Drugs 0.000 description 1
QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
235000011082 potassium citrates Nutrition 0.000 description 1
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
229910052913 potassium silicate Inorganic materials 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
230000008569 process Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000010008 shearing Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
235000017550 sodium carbonate Nutrition 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229940080350 sodium stearate Drugs 0.000 description 1
239000013042 solid detergent Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
229960004274 stearic acid Drugs 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
125000005472 straight-chain saturated fatty acid group Chemical group 0.000 description 1
MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
238000012360 testing method Methods 0.000 description 1
230000009974 thixotropic effect Effects 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
JEVFKQIDHQGBFB-UHFFFAOYSA-K tripotassium;2-[bis(carboxylatomethyl)amino]acetate Chemical compound [K+].[K+].[K+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O JEVFKQIDHQGBFB-UHFFFAOYSA-K 0.000 description 1
SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
229960000834 vinyl ether Drugs 0.000 description 1
239000003190 viscoelastic substance Substances 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
239000008096 xylene Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

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Detergent Compositions (AREA)

CA 2069851 1991-11-08 1992-05-28 Linear viscoelastic aqueous liquid automatic dishwasher detergent composition Abandoned CA2069851A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US78956591A	1991-11-08	1991-11-08
US7/789,565		1991-11-08

Publications (1)

Publication Number	Publication Date
CA2069851A1 true CA2069851A1 (en)	1993-05-09

Family

ID=25148005

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2069851 Abandoned CA2069851A1 (en)	1991-11-08	1992-05-28	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition

Country Status (7)

Country	Link
AU (1)	AU662137B2 (fi)
CA (1)	CA2069851A1 (fi)
FI (1)	FI922503A (fi)
IE (1)	IE921746A1 (fi)
NO (1)	NO922062L (fi)
NZ (1)	NZ242832A (fi)
PT (1)	PT100532A (fi)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5064553A (en) *	1989-05-18	1991-11-12	Colgate-Palmolive Co.	Linear-viscoelastic aqueous liquid automatic dishwasher detergent composition
CA1321115C (en) *	1987-12-30	1993-08-10	Robert Corring	Gel detergent compositions
US4836948A (en) *	1987-12-30	1989-06-06	Lever Brothers Company	Viscoelastic gel detergent compositions

1992
- 1992-05-07 AU AU16092/92A patent/AU662137B2/en not_active Ceased
- 1992-05-20 NZ NZ24283292A patent/NZ242832A/en unknown
- 1992-05-25 NO NO92922062A patent/NO922062L/no unknown
- 1992-05-28 CA CA 2069851 patent/CA2069851A1/en not_active Abandoned
- 1992-05-29 FI FI922503A patent/FI922503A/fi not_active Application Discontinuation
- 1992-05-29 PT PT10053292A patent/PT100532A/pt not_active Application Discontinuation
- 1992-07-01 IE IE921746A patent/IE921746A1/en unknown

Also Published As

Publication number	Publication date
NO922062L (no)	1993-05-10
PT100532A (pt)	1993-09-30
NO922062D0 (no)	1992-05-25
NZ242832A (en)	1994-10-26
IE921746A1 (en)	1993-05-19
FI922503A0 (fi)	1992-05-29
AU1609292A (en)	1993-05-13
FI922503A (fi)	1993-05-14
AU662137B2 (en)	1995-08-24

Legal Events

Date	Code	Title	Description
1999-04-29	EEER	Examination request
2001-05-28	FZDE	Dead

Publication	Publication Date	Title
US5252242A (en)	1993-10-12	Linear visoelastic aqueous liquid detergent composition, especially for automatic dishwashers, of improved high temperature stability
US5053158A (en)	1991-10-01	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
US5209863A (en)	1993-05-11	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition having improved anti-filming properties
US5232621A (en)	1993-08-03	Linear viscoelastic gel compositions
CA2069848A1 (en)	1993-05-09	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition having improved chlorine stability
US5298180A (en)	1994-03-29	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
AU656580B2 (en)	1995-02-09	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
US5368766A (en)	1994-11-29	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
EP0560615A1 (en)	1993-09-15	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
US5202046A (en)	1993-04-13	Process for preparing a linear viscoelastic aqueous liquid automatic dishwasher deteregent composition
EP0517314A1 (en)	1992-12-09	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
EP0517311A1 (en)	1992-12-09	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
AU653809B2 (en)	1994-10-13	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
EP0517313A1 (en)	1992-12-09	Linear viscoelastic aqueous liquid detergent composition, especially for automatic dishwashers, of improved high temperature stability
AU662137B2 (en)	1995-08-24	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
AU654008B2 (en)	1994-10-20	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
EP0522604A2 (en)	1993-01-13	Process for preparing a linear viscoelastic aqueous liquid automatic dishwasher detergent composition
EP0517308A1 (en)	1992-12-09	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
CA2069845A1 (en)	1993-05-09	Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
CA2070093A1 (en)	1992-12-08	Linear viscoelastic aqueous liquid detergent composition, especially for automatic dishwashers, of improved high temperature stability
IE921742A1 (en)	1993-01-13	Linear viscoelastic aqueous liquid automatic dishwasher¹detergent composition
IE921748A1 (en)	1993-05-19	Linear viscoelastic aqueous liquid automatic dishwasher¹detergent composition
NZ242833A (en)	1994-10-26	Linear viscoelastic aqueous automatic dishwasher detergent containing alkali metal builder salt, alkali metal silicate, bleach, organic detergent, cross-linked polyacrylic acid thickener, c8-c50 fatty acid and a polymeric chelating agent
IE921747A1 (en)	1992-12-16	Linear viscoelastic aqueous liquid automatic dishwasher¹detergent composition