CA2056159A1 - Non-chromated cobalt conversion coating - Google Patents

Non-chromated cobalt conversion coating

Info

Publication number
CA2056159A1
CA2056159A1 CA002056159A CA2056159A CA2056159A1 CA 2056159 A1 CA2056159 A1 CA 2056159A1 CA 002056159 A CA002056159 A CA 002056159A CA 2056159 A CA2056159 A CA 2056159A CA 2056159 A1 CA2056159 A1 CA 2056159A1
Authority
CA
Canada
Prior art keywords
cobalt
solution
conversion coating
hexacoordinated complex
iii hexacoordinated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002056159A
Other languages
French (fr)
Other versions
CA2056159C (en
Inventor
Matthias P. Schriever
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boeing Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2056159A1 publication Critical patent/CA2056159A1/en
Application granted granted Critical
Publication of CA2056159C publication Critical patent/CA2056159C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82—After-treatment
    • C23C22/83—Chemical after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Chemically Coating (AREA)

Abstract

(A.) A process for forming a cobalt conversion coating on a metal substrate, thereby imparting corrosion resistance and paint adhesion properties. The invention was developed as a replacement for the prior art chromic acid process. The process includes the steps of: (a) providing a cobalt conversion solution comprising an aqueous solution having a pH
of about 7.0 to 7.2 and containing a soluble cobalt-III
hexacoordinated complex, the concentration of the cobalt-III
hexacoordinated complex being from about 0.1 mole per gallon of solution to the saturation limit of the cobalt-III
hexacoordinated complex; and (b) contacting the substrate with the solution for a sufficient amount of time, whereby the cobalt conversion coating is formed. The substrate may be aluminum or aluminum alloy, as well as magnesium and its alloys, Cd plated substrates, and Zn plated substrates. The cobalt-III hexacoordinated complex may be present in the form of Me3[Co(NO2)6] wherein Me is one or more of Na, K, and Li.
(B.) A chemical conversion coating solution for producing the cobalt conversion coating on a metal substrate, the solution being an aqueous solution having a pH of about 7:0 to 7.2 and containing a soluble cobalt-III hexacoordinated complex, the concentration of the cobalt-III hexacoordinated complex being from about 0.1 mole per gallon of solution to the saturation limit of the cobalt-III hexacoordinated complex. The cobalt conversion solution may be prepared by a bath makeup sequence including the steps of: (a) dissolving a metal nitrite salt;
(b) dissolving an accelerator such as NaI; (c) dissolving a cobalt-II salt; and (d) then adding an oxidizer such as H2O2.
(C.) A coated article exhibiting corrosion resistance and paint adhesion properties, the article including: (a) a metal substrate; and (b) a cobalt conversion coating formed on the substrate, the cobalt conversion coating including aluminum oxide Al2O3 as the largest volume percent, and cobalt oxides CoO, Co3O4, and Co2O3.
CA002056159A 1990-11-30 1991-11-25 Non-chromated cobalt conversion coating Expired - Lifetime CA2056159C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US62113290A 1990-11-30 1990-11-30
US621,132 1990-11-30

Publications (2)

Publication Number Publication Date
CA2056159A1 true CA2056159A1 (en) 1992-05-31
CA2056159C CA2056159C (en) 2001-07-03

Family

ID=24488866

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002056159A Expired - Lifetime CA2056159C (en) 1990-11-30 1991-11-25 Non-chromated cobalt conversion coating

Country Status (13)

Country Link
EP (1) EP0488430B1 (en)
JP (1) JP3194607B2 (en)
AT (1) ATE154401T1 (en)
AU (1) AU650494B2 (en)
BR (1) BR9105184A (en)
CA (1) CA2056159C (en)
DE (1) DE69126507T2 (en)
DK (1) DK0488430T3 (en)
ES (1) ES2104655T3 (en)
GR (1) GR3024046T3 (en)
HK (1) HK1006861A1 (en)
MX (1) MX9102254A (en)
NZ (1) NZ240779A (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5472524A (en) * 1990-05-17 1995-12-05 The Boeing Company Non-chromated cobalt conversion coating method and coated articles
US5298092A (en) * 1990-05-17 1994-03-29 The Boeing Company Non-chromated oxide coating for aluminum substrates
US5468307A (en) * 1990-05-17 1995-11-21 Schriever; Matthias P. Non-chromated oxide coating for aluminum substrates
CA2087473C (en) * 1990-05-17 2001-10-16 Matthias P. Schriever Non-chromated oxide coating for aluminum substrates
US5551994A (en) * 1990-05-17 1996-09-03 The Boeing Company Non-chromated oxide coating for aluminum substrates
US5411606A (en) * 1990-05-17 1995-05-02 The Boeing Company Non-chromated oxide coating for aluminum substrates
ES2125231T3 (en) * 1991-07-19 1999-03-01 Boeing Co NON-CHROME OXIDE COATINGS FOR ALUMINUM SUBSTRATES.
CN1138873C (en) * 1992-06-25 2004-02-18 波音公司 Non-chromated oxide coating for aluminum substrates
WO1995008008A1 (en) 1993-09-13 1995-03-23 Commonwealth Scientific And Industrial Research Organisation Metal treatment with acidic, rare earth ion containing cleaning solution
AUPM621194A0 (en) * 1994-06-10 1994-07-07 Commonwealth Scientific And Industrial Research Organisation Conversion coating and process for its formation
AU684238B2 (en) 1994-11-11 1997-12-04 Commonwealth Scientific And Industrial Research Organisation Process and solution for providing a conversion coating on a metal surface
GB9617416D0 (en) * 1996-08-20 1996-10-02 Minnesota Mining & Mfg Thermal bleaching of infrared dyes
FR2752851B1 (en) * 1996-09-02 1998-11-13 Cfpi Ind BATH AND METHOD FOR PHOSPHATION OF METAL SUBSTRATES, CONCENTRATE FOR THE PREPARATION OF THIS BATH AND METAL SUBSTRATES TREATED WITH THE BATH AND METHOD
US5873953A (en) * 1996-12-26 1999-02-23 The Boeing Company Non-chromated oxide coating for aluminum substrates
ZA983867B (en) * 1997-05-16 1998-11-13 Henkel Corp Lithium and vanadium containing sealing composition and process therewith
US6315823B1 (en) 1998-05-15 2001-11-13 Henkel Corporation Lithium and vanadium containing sealing composition and process therewith
US6432225B1 (en) * 1999-11-02 2002-08-13 The Boeing Company Non-chromated oxide coating for aluminum substrates
AUPQ633300A0 (en) 2000-03-20 2000-04-15 Commonwealth Scientific And Industrial Research Organisation Process and solution for providing a conversion coating on a metallic surface ii
AUPQ633200A0 (en) 2000-03-20 2000-04-15 Commonwealth Scientific And Industrial Research Organisation Process and solution for providing a conversion coating on a metallic surface I
WO2003060019A1 (en) 2002-01-04 2003-07-24 University Of Dayton Non-toxic corrosion protection pigments based on cobalt
US7235142B2 (en) 2002-01-04 2007-06-26 University Of Dayton Non-toxic corrosion-protection rinses and seals based on cobalt
US7294211B2 (en) 2002-01-04 2007-11-13 University Of Dayton Non-toxic corrosion-protection conversion coats based on cobalt
US6818313B2 (en) 2002-07-24 2004-11-16 University Of Dayton Corrosion-inhibiting coating
US20040011252A1 (en) 2003-01-13 2004-01-22 Sturgill Jeffrey A. Non-toxic corrosion-protection pigments based on manganese
JP4934984B2 (en) * 2005-03-31 2012-05-23 大日本印刷株式会社 Method for producing metal oxide film

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3905838A (en) * 1974-04-10 1975-09-16 Hikaru Ito Bath for treating aluminum and aluminum alloys to form oxide film nonelectrolytically thereon and method for the treatment
US4381203A (en) * 1981-11-27 1983-04-26 Amchem Products, Inc. Coating solutions for zinc surfaces
JPH0331484A (en) * 1989-06-27 1991-02-12 Nippon Parkerizing Co Ltd Blackening treatment of zinc or zinc-based plating material
JPH03226584A (en) * 1990-01-30 1991-10-07 Nippon Parkerizing Co Ltd Solution for surface-treating galvanized steel sheet and method therefor
US5298092A (en) * 1990-05-17 1994-03-29 The Boeing Company Non-chromated oxide coating for aluminum substrates

Also Published As

Publication number Publication date
ES2104655T3 (en) 1997-10-16
MX9102254A (en) 1992-06-01
NZ240779A (en) 1994-11-25
EP0488430A2 (en) 1992-06-03
HK1006861A1 (en) 1999-03-19
GR3024046T3 (en) 1997-10-31
BR9105184A (en) 1992-07-21
DK0488430T3 (en) 1998-01-05
AU650494B2 (en) 1994-06-23
JP3194607B2 (en) 2001-07-30
CA2056159C (en) 2001-07-03
EP0488430A3 (en) 1992-12-16
DE69126507T2 (en) 1997-09-25
EP0488430B1 (en) 1997-06-11
DE69126507D1 (en) 1997-07-17
AU8822591A (en) 1992-06-04
ATE154401T1 (en) 1997-06-15
JPH059745A (en) 1993-01-19

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Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed
MKEC Expiry (correction)

Effective date: 20121211