CA2035692A1 - Coated glass microbeads and pigment for synthetic material - Google Patents

Coated glass microbeads and pigment for synthetic material

Info

Publication number: CA2035692A1
Authority: CA; Canada
Prior art keywords: microbeads; coated glass; particles; glass microbeads; coated
Prior art date: 1990-02-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002035692A

Other languages

English (en)

French (fr)

Inventor

Pierre Laroche

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

AGC Glass Europe SA

Original Assignee

Glaverbel Belgium SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-02-21

Filing date

1991-02-05

Publication date

1991-08-22

1991-02-05 Application filed by Glaverbel Belgium SA filed Critical Glaverbel Belgium SA

1991-08-22 Publication of CA2035692A1 publication Critical patent/CA2035692A1/en

Status Abandoned legal-status Critical Current

Links

239000011325 microbead Substances 0.000 title claims abstract description 113
239000011521 glass Substances 0.000 title claims abstract description 51
239000000049 pigment Substances 0.000 title claims abstract description 37
229920002994 synthetic fiber Polymers 0.000 title 1
239000002245 particle Substances 0.000 claims abstract description 66
239000000463 material Substances 0.000 claims abstract description 54
239000003973 paint Substances 0.000 claims abstract description 44
229920000642 polymer Polymers 0.000 claims abstract description 42
150000002736 metal compounds Chemical class 0.000 claims abstract description 35
238000000576 coating method Methods 0.000 claims abstract description 28
239000011248 coating agent Substances 0.000 claims abstract description 25
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
239000007822 coupling agent Substances 0.000 claims description 9
239000004094 surface-active agent Substances 0.000 claims description 6
239000003822 epoxy resin Substances 0.000 claims description 4
230000002209 hydrophobic effect Effects 0.000 claims description 4
229920000647 polyepoxide Polymers 0.000 claims description 4
239000007787 solid Substances 0.000 claims description 4
239000004408 titanium dioxide Substances 0.000 claims description 4
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
229920001296 polysiloxane Polymers 0.000 claims description 3
239000004814 polyurethane Substances 0.000 claims description 3
229920002635 polyurethane Polymers 0.000 claims description 3
239000013008 thixotropic agent Substances 0.000 claims description 3
150000001875 compounds Chemical class 0.000 claims description 2
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 2
229920000058 polyacrylate Polymers 0.000 claims description 2
229920000728 polyester Polymers 0.000 claims description 2
239000011324 bead Substances 0.000 description 27
238000009826 distribution Methods 0.000 description 13
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
238000012505 colouration Methods 0.000 description 9
239000007788 liquid Substances 0.000 description 8
239000000203 mixture Substances 0.000 description 6
239000006185 dispersion Substances 0.000 description 5
238000010348 incorporation Methods 0.000 description 5
239000011817 metal compound particle Substances 0.000 description 4
235000011837 pasties Nutrition 0.000 description 4
239000011347 resin Substances 0.000 description 4
229920005989 resin Polymers 0.000 description 4
238000013019 agitation Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000011344 liquid material Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
239000004743 Polypropylene Substances 0.000 description 2
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
239000000945 filler Substances 0.000 description 2
238000000265 homogenisation Methods 0.000 description 2
MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
-1 polypropylene Polymers 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
IEKHISJGRIEHRE-UHFFFAOYSA-N 16-methylheptadecanoic acid;propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O IEKHISJGRIEHRE-UHFFFAOYSA-N 0.000 description 1
KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
WWBITQUCWSFVNB-UHFFFAOYSA-N 3-silylpropan-1-amine Chemical class NCCC[SiH3] WWBITQUCWSFVNB-UHFFFAOYSA-N 0.000 description 1
URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 description 1
239000004925 Acrylic resin Substances 0.000 description 1
229920000178 Acrylic resin Polymers 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
238000006873 Coates reaction Methods 0.000 description 1
239000001856 Ethyl cellulose Substances 0.000 description 1
ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
241000022563 Rema Species 0.000 description 1
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
229920004482 WACKER® Polymers 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
230000008901 benefit Effects 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
229910052980 cadmium sulfide Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
238000004040 coloring Methods 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
235000019325 ethyl cellulose Nutrition 0.000 description 1
229920001249 ethyl cellulose Polymers 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
239000001023 inorganic pigment Substances 0.000 description 1
230000004807 localization Effects 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
238000000465 moulding Methods 0.000 description 1
ICRFXIKCXYDMJD-UHFFFAOYSA-N n'-benzyl-n'-ethenyl-n-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN(C=C)CC1=CC=CC=C1 ICRFXIKCXYDMJD-UHFFFAOYSA-N 0.000 description 1
239000011368 organic material Substances 0.000 description 1
239000012860 organic pigment Substances 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
229920001225 polyester resin Polymers 0.000 description 1
239000004848 polyfunctional curative Substances 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
WIJVUKXVPNVPAQ-UHFFFAOYSA-N silyl 2-methylprop-2-enoate Chemical class CC(=C)C(=O)O[SiH3] WIJVUKXVPNVPAQ-UHFFFAOYSA-N 0.000 description 1
239000011343 solid material Substances 0.000 description 1
238000000935 solvent evaporation Methods 0.000 description 1
229940071182 stannate Drugs 0.000 description 1
230000009974 thixotropic effect Effects 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/48—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
- C03C2217/485—Pigments

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Life Sciences & Earth Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Geochemistry & Mineralogy (AREA)
General Chemical & Material Sciences (AREA)
Composite Materials (AREA)
Medicinal Chemistry (AREA)
Inorganic Chemistry (AREA)
Polymers & Plastics (AREA)
Health & Medical Sciences (AREA)
Dispersion Chemistry (AREA)
Wood Science & Technology (AREA)
Paints Or Removers (AREA)
Pigments, Carbon Blacks, Or Wood Stains (AREA)
Road Signs Or Road Markings (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA002035692A 1990-02-21 1991-02-05 Coated glass microbeads and pigment for synthetic material Abandoned CA2035692A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
LU87682A LU87682A1 (fr)	1990-02-21	1990-02-21	Microbilles constituees de perles de verre portant un revetement et pigment pour matiere polymere synthetique
LU87682		1990-02-21

Publications (1)

Publication Number	Publication Date
CA2035692A1 true CA2035692A1 (en)	1991-08-22

Family

ID=19731217

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002035692A Abandoned CA2035692A1 (en)	1990-02-21	1991-02-05	Coated glass microbeads and pigment for synthetic material

Country Status (14)

Country	Link
JP (1)	JPH04216835A (it)
BE (1)	BE1005673A5 (it)
CA (1)	CA2035692A1 (it)
DE (1)	DE4105319A1 (it)
DK (1)	DK30291A (it)
ES (1)	ES2024377A6 (it)
FR (1)	FR2658502B1 (it)
GB (1)	GB2241179A (it)
IT (1)	IT1244630B (it)
LU (1)	LU87682A1 (it)
NL (1)	NL9100306A (it)
PT (1)	PT96806B (it)
SE (1)	SE9100504L (it)
ZA (1)	ZA911240B (it)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5286682A (en) *	1992-02-19	1994-02-15	Minnesota Mining And Manufacturing Company	Yellow retroreflective pavement markings
DE4334211C2 (de) *	1993-10-07	2000-08-03	Heraeus Kulzer Gmbh & Co Kg	Verfahren zur Herstellung eines feinteiligen anorganischen Füllstoffs in Form eines Verbundfüllstoffs aus Makrofüllstoff-Teilchen und Mikrofüllstoff-Teilchen und seine Verwendung
CN1037898C (zh) *	1994-07-05	1998-04-01	北京医科大学口腔医学研究所	具有固位力外形的复合式无机填料颗粒及其制造方法和应用
FR2740458B1 (fr) *	1995-10-30	1998-01-02	Chaize Bernard	Procede de pigmentation dans la masse de matieres plastiques et produits obtenus selon le procede
ATE342314T1 (de)	1999-01-14	2006-11-15	Reflec Plc	Retroreflektierende tinten
GB2347428A (en) *	1999-03-05	2000-09-06	Reflective Technology Ind Ltd	Retroreflective inks
DE19939267A1 (de) *	1999-08-19	2001-03-01	Michael Albuschat	Fugenmasse zum Verfugen von Gebäudeflächen
FR2869040B1 (fr) *	2004-04-14	2006-05-26	Sunis Sa Sa	Composition retro-reflechissante
FR2869041B1 (fr) *	2004-04-14	2006-12-22	Sunis Sa Sa	Compositions retro reflechissantes pour equipements de securite
US20070077406A1 (en) *	2005-09-30	2007-04-05	Jacobs Jeffry L	Photocatalytic coating
JP6294123B2 (ja) *	2014-03-28	2018-03-14	出光ライオンコンポジット株式会社	樹脂組成物及びそれを用いた洗浄方法
ES2724674T3 (es)	2014-07-16	2019-09-13	Schott Ag	Procedimiento para la producción de un sustrato revestido, de un sustrato en forma de plancha, que comprende al menos dos capas aplicadas por medio de calentamiento, y empleo del sustrato revestido
DE102014220457B4 (de)	2014-10-09	2020-07-30	Schott Ag	Verfahren zur Herstellung eines beschichteten Substrats
EP3056475B2 (en) †	2015-02-11	2022-12-07	Geveko Markings Denmark A/S	Composition, marking and kit of parts for forming a marking, such as a road marking
EP3085306B1 (en)	2015-04-22	2017-11-01	Roche Diabetes Care GmbH	Medical product and method for authenticating the same
CN105419528A (zh) *	2015-12-24	2016-03-23	刘家容	一种热反射涂料及其制备方法和应用
CN109880491A (zh) *	2019-03-26	2019-06-14	重庆交通大学	一种新型超疏水功能涂层及其制备方法
US11867499B2 (en) *	2020-02-19	2024-01-09	Faro Technologies, Inc.	System and method for verifying a position of a component on an object
KR20240009423A (ko) *	2021-05-18	2024-01-22	포터스 인더스트리즈, 엘엘씨	분말 물질용 담체
WO2023210394A1 (ja) *	2022-04-25	2023-11-02	富士フイルム株式会社	組成物、膜、光センサおよび光センサの製造方法
CN114989679A (zh) *	2022-05-05	2022-09-02	安徽盛城新型材料有限公司	外墙多彩仿石涂料的制备方法
CN115806698B (zh) *	2022-12-14	2024-01-16	郑州圣莱特空心微珠新材料有限公司	一种涂料用玻璃微珠及其制备方法和应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3288618A (en) *	1962-08-16	1966-11-29	Prismo Safety Corp	Colored reflective coating composition
US3374105A (en) *	1964-07-02	1968-03-19	Mearl Corp	Particulate reflective elements and method for forming the same
DD65757A1 (de) *	1968-02-12	1969-02-20	Hannalin	Verfahren zur Herstellung von farbigem lichtreflektierendem Material
JPS564884B2 (it) *	1971-09-18	1981-02-02
GB1364675A (en) *	1972-06-07	1974-08-29	Ici Ltd	Composite polymeric materials
JPS52139147A (en) *	1976-05-17	1977-11-19	Kikusui Line Co Ltd	Method of working for such as regged line of demarcation with waterrrepellent paints
JPS5447738A (en) *	1977-09-22	1979-04-14	Hitachi Chem Co Ltd	Method of applying traffic paint
JPH01132770A (ja) *	1987-08-20	1989-05-25	Central Glass Co Ltd	チタン含有酸化物膜用組成物およびその膜の形成方法
AU605606B2 (en) *	1987-08-25	1991-01-17	Minnesota Mining And Manufacturing Company	Retroreflective coating and composition for forming same
US4916014A (en) *	1987-10-30	1990-04-10	Paul Weber	I.R. reflecting paint

1990
- 1990-02-21 LU LU87682A patent/LU87682A1/fr unknown
1991
- 1991-02-05 CA CA002035692A patent/CA2035692A1/en not_active Abandoned
- 1991-02-05 IT ITTO910068A patent/IT1244630B/it active IP Right Grant
- 1991-02-14 BE BE9100142A patent/BE1005673A5/fr not_active IP Right Cessation
- 1991-02-15 FR FR9101922A patent/FR2658502B1/fr not_active Expired - Fee Related
- 1991-02-18 JP JP3045950A patent/JPH04216835A/ja not_active Withdrawn
- 1991-02-19 PT PT96806A patent/PT96806B/pt not_active IP Right Cessation
- 1991-02-20 ES ES9100438A patent/ES2024377A6/es not_active Expired - Lifetime
- 1991-02-20 DE DE4105319A patent/DE4105319A1/de not_active Withdrawn
- 1991-02-20 GB GB9103587A patent/GB2241179A/en not_active Withdrawn
- 1991-02-20 SE SE9100504A patent/SE9100504L/xx not_active Application Discontinuation
- 1991-02-20 ZA ZA911240A patent/ZA911240B/xx unknown
- 1991-02-21 NL NL9100306A patent/NL9100306A/nl not_active Application Discontinuation
- 1991-02-21 DK DK030291A patent/DK30291A/da not_active Application Discontinuation

Also Published As

Publication number	Publication date
SE9100504L (sv)	1991-08-22
ZA911240B (en)	1991-11-27
ITTO910068A1 (it)	1992-08-05
DK30291A (da)	1991-08-22
JPH04216835A (ja)	1992-08-06
DE4105319A1 (de)	1991-08-22
PT96806B (pt)	1998-07-31
IT1244630B (it)	1994-08-08
GB9103587D0 (en)	1991-04-10
GB2241179A (en)	1991-08-28
PT96806A (pt)	1991-10-31
ES2024377A6 (es)	1992-02-16
SE9100504D0 (sv)	1991-02-20
FR2658502A1 (fr)	1991-08-23
DK30291D0 (da)	1991-02-21
ITTO910068A0 (it)	1991-02-05
LU87682A1 (fr)	1991-10-08
BE1005673A5 (fr)	1993-12-14
FR2658502B1 (fr)	1994-05-06
NL9100306A (nl)	1991-09-16

Legal Events

Date	Code	Title	Description
1994-08-06	FZDE	Discontinued

Publication	Publication Date	Title
CA2035692A1 (en)	1991-08-22	Coated glass microbeads and pigment for synthetic material
JP2724733B2 (ja)	1998-03-09	マトリツクス中にガラスビーズを含有する標識
US5618872A (en)	1997-04-08	Inorganic fillers and organic matrix materials with refractive index adaptation
US3175935A (en)	1965-03-30	Method of making reflective particles and resultant article
US5688851A (en)	1997-11-18	Gel coat and method for manufacture thereof
JPS61227942A (ja)	1986-10-11	湿潤性を変性したガラスビーズ
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